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1. 发明申请

US20050214465A1 Method for producing composite materials using a thermoplastic matrix 审中-公开
标题翻译：使用热塑性基质制备复合材料的方法
公开(公告)号：US20050214465A1
公开(公告)日：2005-09-29
申请号：US10499032
申请日：2002-12-17
申请人： Peter Maskus , Christian Kruse , Eduard Schmid , Anreas Mettier , Jonny Lohmiller
发明人： Peter Maskus , Christian Kruse , Eduard Schmid , Anreas Mettier , Jonny Lohmiller
IPC分类号： C08J5/24 , B29B15/12 , B29C70/50 , B05D3/02
CPC分类号： B29C70/50 , B29B15/125
摘要： The invention relates to a method for producing a composite material (33) consisting of reinforcing elements (29) and a thermoplastic polyamide, said method permitting high-speed production with continuous process control, using simple equipment. The method is characterized by the following steps: the supplied reinforcing elements (29) are impregnated with a lactam melt (11) that is activated for anionic polymerization, at a temperature at which the activated lactam melt (11) does not polymerize; the impregnated reinforcing element (30) is heated and polymerized in a heating unit (17) without passing through a heated die and in an essentially contactless manner; the resultant hot polymerized composite material (31) is cooled in a cooling unit (18). The lactam melt (11) that is activated for anionic polymerization is produced by first melting the lactam or more precisely the mixture of lactams to obtain a monomer melt (3) and a liquid initiator (6) is added to the monomer melt (3) immediately prior to the impregnation process of the reinforcing element (29), said liquid initiator (6) containing simultaneously the activator and the catalyst function in solute form.
摘要翻译：本发明涉及一种用于制造由增强元件（29）和热塑性聚酰胺组成的复合材料（33）的方法，所述方法允许使用简单的设备以连续的工艺控制进行高速生产。该方法的特征在于以下步骤：在活化的内酰胺熔体（11）不聚合的温度下，将所供应的增强元件（29）浸渍用于阴离子聚合活化的内酰胺熔体（11）浸渍的增强元件（30）在加热单元（17）中被加热和聚合，而不通过加热的模头并且基本上是非接触的方式; 所得热聚合复合材料（31）在冷却单元（18）中被冷却。用于阴离子聚合活化的内酰胺熔体（11）通过首先熔化内酰胺或更准确地将内酰胺的混合物熔化以获得单体熔体（3），并将液体引发剂（6）加入到单体熔体（3）中，在加强元件（29）的浸渍过程之前，所述液体引发剂（6）同时含有活化剂和催化剂以溶质形式发挥作用。

2. 发明申请

US20090131674A1 POLYMIDE OLIGOMERS AND THEIR USE 有权
标题翻译：聚合物低聚物及其用途
公开(公告)号：US20090131674A1
公开(公告)日：2009-05-21
申请号：US11914916
申请日：2006-04-24
申请人： Eduard Schmid , Botho Hoffmann
发明人： Eduard Schmid , Botho Hoffmann
IPC分类号： C07D211/58 , C07C233/00
CPC分类号： C08G69/14 , C08G69/16 , C08G69/26 , C08G69/28 , C08L77/02 , C08L2666/20
摘要： The present invention relates to polyamide oligomers with linear or branched chain structure with a number average molar mass of 800 to 5000 g/mol, with basic end groups which are at least partially NH2 end groups and carboxyl end groups, produced by condensation of polyamide-forming monomers, the concentration of NH2 end groups being at most 300 mmol/kg and in that these end groups are present in excess in a ratio to the carboxyl end groups.
摘要翻译：本发明涉及具有数均摩尔质量为800至5000g / mol的直链或支链结构的聚酰胺低聚物，碱性端基至少部分为NH 2端基和羧基端基，其通过聚酰胺 - 形成单体时，NH 2端基的浓度为至多300mmol / kg，并且这些端基以与羧基端基的比例过量存在。

3. 发明授权

US07348046B2 Polymer mixture of aliphatic polyamides and partially aromatic polyamides, moulded articles thereof and use thereof 有权
标题翻译：脂族聚酰胺和部分芳族聚酰胺的聚合物混合物，其模塑制品及其用途
公开(公告)号：US07348046B2
公开(公告)日：2008-03-25
申请号：US11154858
申请日：2005-06-16
申请人： Hanns-Jörg Liedloff , Eduard Schmid , Reinhard Hans Hagen
发明人： Hanns-Jörg Liedloff , Eduard Schmid , Reinhard Hans Hagen
IPC分类号： C08L77/00 , B65D1/00
CPC分类号： C08L77/06 , C08L77/00 , C08L77/02 , C08L77/10 , C08L2205/02 , Y10T428/139 , Y10T428/1397 , C08L2666/20
摘要： The invention relates to a polymer mixture of partially crystalline aliphatic polyamides and partially aromatic polyamides, the proportion of aliphatic polyamides being more than 50% by weight and the quantitative ratio of the aliphatic carbon atoms to amide bonds in the aliphatic polyamides being in the range of 8:1 to 12:1 and the partially aromatic polyamides, which are present in deficit, having, in addition to hexamethyleneterephthalamide (6T) units, further partially aromatic and/or aliphatic amide units and being predominantly partially crystalline. The invention relates furthermore to the use of polymer mixtures of this type for various application fields, in particular for express couplings or connectors for fuel lines.
摘要翻译：本发明涉及部分结晶脂族聚酰胺和部分芳族聚酰胺的聚合物混合物，脂族聚酰胺的比例大于50重量％，脂族聚酰胺中脂族碳原子与酰胺键的定量比在 8：1至12：1，部分芳族聚酰胺以赤字存在，除了六亚甲基对苯二甲酰胺（6T）单元之外，还有部分芳族和/或脂族酰胺单元，主要部分结晶。本发明还涉及这种类型的聚合物混合物用于各种应用领域，特别是用于快速联接器或用于燃料管线的连接器的用途。

4. 发明授权

US07312263B2 Thermoplastic polyamide moulding compositions 有权
标题翻译：热塑性聚酰胺模塑组合物
公开(公告)号：US07312263B2
公开(公告)日：2007-12-25
申请号：US11026243
申请日：2004-12-29
申请人： Eduard Schmid , Ornulf Rexin
发明人： Eduard Schmid , Ornulf Rexin
IPC分类号： C08K5/34
CPC分类号： C08K5/3412 , C08K5/21 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2205/02 , C08L2666/20
摘要： The present invention relates to thermoplastic polyamide moulding compositions which contain at least one copolyamide with at least 20% by weight polyamide 12 components and at least one aprotic compound selected from the group of N-alkylated, cyclic carboxylic acid amides with 5 to 7 ring elements and/or of urea derivatives, the alkyl rests of which are linear at the nitrogen or which form a linking of the two N-atoms, and a process for production of the moulding compositions. The thermoplastic polyamide moulding compositions are distinguished by the fact that no solid deposits are formed during thermoplastic conversion.
摘要翻译：本发明涉及含有至少一种具有至少20重量％聚酰胺12组分的共聚酰胺和至少一种非选择性化合物的热塑性聚酰胺模塑组合物，所述非质子化合物选自具有5-7个环元素的N-烷基化的环状羧酸酰胺和/或脲衍生物，其烷基在氮上是直链的或形成两个N-原子的连接，以及制备模塑组合物的方法。热塑性聚酰胺模塑组合物的特征在于在热塑性转化过程中不形成固体沉积物。

5. 发明授权

US07151127B2 Use of thermoplastic polyamide molding compositions with reduced formation of solid deposits and/or coverings 失效
标题翻译：使用减少形成固体沉积物和/或覆盖物的热塑性聚酰胺模塑组合物
公开(公告)号：US07151127B2
公开(公告)日：2006-12-19
申请号：US11026192
申请日：2004-12-29
申请人： Georg Stoeppelmann , Ornulf Rexin , Eduard Schmid , Ralph Kettl , Manfred Hewel
发明人： Georg Stoeppelmann , Ornulf Rexin , Eduard Schmid , Ralph Kettl , Manfred Hewel
IPC分类号： C08L77/00
CPC分类号： C08L77/00 , C08K5/0016 , C08K5/21 , C08K5/3412 , C08K5/42 , C08L77/02 , C08L77/06 , C08L2666/20
摘要： The present invention relates to the use of thermoplastic polyamide moulding compositions with reduced or strongly reduced formation of solid deposits and/or coverings during a thermoplastic conversion into commodity goods in discontinuous processes in particular injection moulding, and continuous processes such as the extrusion of films, fibers, tubes and jacketings containing at least 20% by weight polyamide and/or at least one copolymer with at least 20% by weight polyamide components.
摘要翻译：本发明涉及热塑性聚酰胺模塑组合物在热塑性转化成不连续工艺的商品中，特别是注模成型中的固体沉积物和/或覆盖物的形成减少或强烈减少的用途，以及连续的方法，例如膜的挤出，纤维，管和护套，其含有至少20重量％的聚酰胺和/或至少一种具有至少20重量％聚酰胺组分的共聚物。

6. 发明授权

US07135428B2 Catalyst solution for implementing anionic lactam polymerization, method for production thereof and polyamide moulding compound 失效
标题翻译：用于实施阴离子内酰胺聚合的催化剂溶液，其制备方法和聚酰胺模塑料
公开(公告)号：US07135428B2
公开(公告)日：2006-11-14
申请号：US10937721
申请日：2004-09-09
申请人： Eduard Schmid , Heinz Hoff , Ornulf Rexin
发明人： Eduard Schmid , Heinz Hoff , Ornulf Rexin
IPC分类号： B01J31/00
CPC分类号： C08G69/20 , C08G63/823
摘要： A catalyst solution for the anionic polymerization of lactones and/or lactams comprises a salt of at least one compound of the general formula I In this formula (I), R1 is H or an aliphatic, cycloaliphatic or aromatic radical with 1 to 12 C atoms which can also have heteroatoms or hetero groups, the radical R2, which is the same or different, is H, halogen, C1–C5-alkyl, ethoxy or wherein said solvation agent S comprises N-methylpyrrolidone, N-octylpyrrolidone, N-cyclohexylpyrrolidone, N-octylcaprolactam, tetrabutyl urea or mixtures thereof methoxy, and n=1, 2 or 3, and wherein the salt is dissolved in an aprotic solvation agent S.
摘要翻译：用于内酯和/或内酰胺阴离子聚合的催化剂溶液包含至少一种通式I化合物的盐。在该式（I）中，R 1是H或脂族，脂环族或具有1至12个C原子的芳族基团，其也可以具有杂原子或杂基团，相同或不同的基团R 2是H，卤素，C 1 H 3， -C 5 - 烷基，乙氧基或其中所述溶剂化物S包括N-甲基吡咯烷酮，N-辛基吡咯烷酮，N-环己基吡咯烷酮，N-辛基己内酰胺，四丁基脲或其混合物甲氧基，n = 1,2 或3，并且其中所述盐溶解在非质子溶剂化剂S中。

7. 发明申请

US20050090382A1 Catalyst solution for implementing anionic lactam polymerisation, method for production thereof and polyamide moulding compound 失效
标题翻译：用于实施阴离子内酰胺聚合的催化剂溶液，其制备方法和聚酰胺模塑料
公开(公告)号：US20050090382A1
公开(公告)日：2005-04-28
申请号：US10937721
申请日：2004-09-09
申请人： Eduard Schmid , Heinz Hoff , Ornulf Rexin
发明人： Eduard Schmid , Heinz Hoff , Ornulf Rexin
IPC分类号： C08G69/20 , C08G63/82 , B01J31/00 , C07F1/00
CPC分类号： C08G69/20 , C08G63/823
摘要： The invention relates to a solution of an alkali salt, which is strongly basic, clear, stable in storage and liquid at room temperature, of aniline, amidated with a monocarboxylic acid, or its derivatives in an aprotic solvation agent, a method for production thereof and the polyamides produced using this solution.
摘要翻译：本发明涉及在非质子传递溶剂化剂中，在碱存在下和液体中稳定的碱金属盐，苯胺与单羧酸或其衍生物酰胺化的方法，其生产方法和使用该溶液制备的聚酰胺。

8. 发明授权

US5958283A Thermoplastically processible molding material 失效
标题翻译：热塑性加工成型材料
公开(公告)号：US5958283A
公开(公告)日：1999-09-28
申请号：US991987
申请日：1997-12-17
申请人： Eduard Schmid , Ivano Laudonia , David Jarvis , Etienne Aepli , Gion Antoni Tuor
发明人： Eduard Schmid , Ivano Laudonia , David Jarvis , Etienne Aepli , Gion Antoni Tuor
IPC分类号： C08J3/12 , C08K3/10 , C08K5/17 , C08L77/00 , H01F1/057 , H01F1/08 , C08K5/092
CPC分类号： H01F1/0578 , H01F1/083
摘要： The invention relates to a thermoplastically processible molding material with a two-phase matrix of a partially aromatic copolyamide and an aliphatic polyamide or copolyamide containing permanently magnetic or magnetizable fillers, as well as to a method for producing this molding material and using it for producing molded parts.
摘要翻译：本发明涉及一种具有部分芳族共聚酰胺的两相基质和含有永久磁性或可磁化填料的脂肪族聚酰胺或共聚酰胺的热塑性加工成型材料，以及一种用于生产该成型材料并用于制造成型部分。

9. 发明授权

US5547161A Base for machines and the like 失效
标题翻译：机器基座等
公开(公告)号：US5547161A
公开(公告)日：1996-08-20
申请号：US302717
申请日：1994-09-09
申请人： Werner Gleich , Fritz D. Rothacker , Dieter Bruckel , Eduard Schmid
发明人： Werner Gleich , Fritz D. Rothacker , Dieter Bruckel , Eduard Schmid
IPC分类号： F16M5/00 , F16M13/00
CPC分类号： F16M5/00
摘要： The invention relates to the construction and arrangement of wall components which are to be attached to the posts and spars of a basic frame for machines, instruments, equipment and the like. These wall components extend from the middle of one post to the middle of another and are supported on the upper faces of the posts and the spars between them by their folded upper web. The side edges of the web extend to approximately the middle of the face of the post and then run obliquely inwards. A section covering the posts at the top is recessed where the web is supported. Running around the inside edge of the wall component there is a frame-like spacer, the depth of which determines the distance by which the outer wall of the wall component projects beyond the outside of the post.
摘要翻译： PCT No.PCT / EP93 / 00480 Sec。 371日期1994年9月9日 102（e）1994年9月9日PCT PCT 1993年3月3日PCT公布。公开号WO93 / 18336 日期1993年9月16日本发明涉及要附接到机器，仪器，设备等的基本框架的柱和翼梁上的壁部件的构造和布置。这些壁部分从一个柱的中间延伸到另一个柱的中间，并且通过它们折叠的上腹板支撑在柱的上表面和它们之间的翼梁上。纸幅的侧边缘延伸到大约在柱的面的中间，然后向内倾斜地运行。覆盖顶部的柱的部分被凹入到支撑网的位置。围绕墙壁部件的内侧边缘运行时，有一个框架式间隔件，其深度决定了壁部件外壁伸出柱子外部的距离。

10. 发明授权

US07786222B2 Polyamide oligomers and their use 有权
标题翻译：聚酰胺低聚物及其用途
公开(公告)号：US07786222B2
公开(公告)日：2010-08-31
申请号：US11914916
申请日：2006-04-24
申请人： Eduard Schmid , Botho Hoffmann
发明人： Eduard Schmid , Botho Hoffmann
IPC分类号： C08L77/00 , C08L51/00 , C08G69/14 , C08G69/26 , C08K5/34 , C08J3/20 , C08J3/22 , C07D211/56 , C07D211/98
CPC分类号： C08G69/14 , C08G69/16 , C08G69/26 , C08G69/28 , C08L77/02 , C08L2666/20
摘要： The present invention relates to polyamide oligomers with linear or branched chain structure with a number average molar mass of 800 to 5000 g/mol, with basic end groups which are at least partially NH2 end groups and carboxyl end groups, produced by condensation of polyamide-forming monomers, the concentration of NH2 end groups being at most 300 mmol/kg and in that these end groups are present in excess in a ratio to the carboxyl end groups.
摘要翻译：本发明涉及具有数均摩尔质量为800至5000g / mol的直链或支链结构的聚酰胺低聚物，碱性端基至少部分为NH 2端基和羧基端基，其通过聚酰胺 - 形成单体时，NH 2端基的浓度为至多300mmol / kg，并且这些端基以与羧基端基的比例过量存在。

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