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    • 3. 发明授权
    • Reinforced polyamide moulding materials
    • 增强聚酰胺成型材料
    • US08846800B2
    • 2014-09-30
    • US11594228
    • 2006-11-08
    • Ornulf RexinJean-Jacques LinsterManfred Hewel
    • Ornulf RexinJean-Jacques LinsterManfred Hewel
    • C08G69/26C08G69/02C08G69/32C08L77/10C08L77/00C08L77/06C08L77/02C08K7/14
    • C08L77/06C08K7/14C08L77/00C08L77/02C08L77/10C08L2666/20
    • The present invention relates to reinforced polyamide molding materials which can be prepared from a polyamide blend and, for example, by compounding with cut fibers or continuous filaments on twin-screw extruders and have mechanical properties which are usually not compatible with one another, namely a combination of exceptionally high rigidity and strength and at the same time good toughness. Furthermore, a high heat distortion temperature (HDT) is achieved according to the invention.The thermoplastic polyamide molding materials according to the invention are suitable for the production of moldings or other semifinished products or finished articles, which can be produced, for example, by extrusion, injection molding, direct methods or direct compounding, in which the compounded polyamide molding material is processed directly by injection molding, or other deformation techniques.
    • 本发明涉及增强的聚酰胺成型材料,其可以由聚酰胺共混物制备,例如通过在双螺杆挤出机上与切割的纤维或连续长丝混合并且具有通常彼此不相容的机械性质,即 组合极高的刚度和强度,同时具有良好的韧性。 此外,根据本发明实现了高热变形温度(HDT)。 根据本发明的热塑性聚酰胺成型材料适用于生产可通过例如挤出,注射成型,直接方法或直接混合来制备的模制品或其他半成品或成品,其中复合聚酰胺模制品 材料通过注射成型或其他变形技术直接加工。
    • 4. 发明申请
    • Reinforced polyamide moulding materials
    • 增强聚酰胺成型材料
    • US20070123632A1
    • 2007-05-31
    • US11594249
    • 2006-11-08
    • Ornulf RexinJean-Jacques LinsterManfred Hewel
    • Ornulf RexinJean-Jacques LinsterManfred Hewel
    • C08K3/40C08K3/04
    • C08L77/02C08G69/26C08K7/14C08L77/00C08L77/06C08L77/10C08L2205/02C08L2666/20
    • The present invention relates to reinforced polyamide moulding materials which can be prepared from a polyamide blend and, for example, by compounding with cut fibres or continuous filaments on twin-screw extruders and have mechanical properties which are usually not compatible with one another, namely a combination of exceptionally high rigidity and strength and at the same time good toughness. Furthermore, a high heat distortion temperature (HDT) is achieved according to the invention. The thermoplastic polyamide moulding materials according to the invention are suitable for the production of mouldings or other semifinished products or finished articles, which can be produced, for example, by extrusion, injection moulding, direct methods or direct compounding, in which the compounded polyamide moulding material is processed directly by injection moulding, or other deformation techniques.
    • 本发明涉及增强的聚酰胺成型材料,其可以由聚酰胺共混物制备,例如通过在双螺杆挤出机上与切割的纤维或连续长丝混合并且具有通常彼此不相容的机械性质,即 组合极高的刚度和强度,同时具有良好的韧性。 此外,根据本发明实现了高热变形温度(HDT)。 根据本发明的热塑性聚酰胺成型材料适用于生产可通过例如挤出,注射成型,直接方法或直接混合来制备的模制品或其他半成品或成品,其中复合聚酰胺模制品 材料通过注射成型或其他变形技术直接加工。
    • 5. 发明授权
    • Polyamide molding materials reinforced with glass fibers and injection molded parts thereof
    • 用玻璃纤维增​​强的聚酰胺成型材料及其注模部件
    • US09567462B2
    • 2017-02-14
    • US13025953
    • 2011-02-11
    • Georg StoeppelmannOrnulf RexinVolker Eichhorn
    • Georg StoeppelmannOrnulf RexinVolker Eichhorn
    • B60C1/00C08K7/02C08L7/02C08L77/00C08L77/02C08L77/06C08K3/40C08K7/14
    • C08L77/00C08K3/40C08K7/14C08L77/02C08L77/06C08L2205/02C08L2205/16C08L2666/20
    • The present invention relates to reinforced polyamide molding materials with high notch impact strengths, comprising low viscous polyamides and flat glass fibers as a reinforcing medium, characterized in a polyamide matrix, comprising the following components: (A) 0 to 60 wt.-% of at least one aliphatic, partly crystalline polyamide with a solution viscosity, measured in m-cresol (0.5 wt-%), of ηrel less than 1.9, (B) 0 to 60 wt.-% of at least one amorphous or microcrystalline polyamide based on aliphatic, cycloaliphatic or aromatic diamines, dicarboxylic acids, lactams and/or aminocarboxylic acids, preferably with 6 to 36 carbon atoms, or a mixture of such homopolyamides and/or copolyamides, wherein the components (A) and (B) fulfill the condition: (A)+(B)=20 to 60 wt.-% and that, in the case of a mixture of components (A) and (B), at least 50 weight parts aliphatic blocks (A) are present in the mixture, and a filler component, comprising: (C) 40 to 80 wt.-% flat glass fibers with elongated shape, and the glass fibers have a non-circular cross-sectional area and a size ratio of the main cross-sectional axis to the secondary cross-sectional axis of between 2 to 5, particularly between 3 and 4, and (D) 0 to 40 wt.-% particle like or layer like fillers, with the prerequisite that carbon fibers are excluded, wherein the polyamide molding materials optionally comprise up to 5 wt.-% of further usual additives and auxiliary agents (E), and wherein the weight of the components (A) to (E) sums up to 100%.
    • 本发明涉及具有高缺口冲击强度的增强聚酰胺成型材料,其包含低粘度聚酰胺和平板玻璃纤维作为增强介质,其特征在于聚酰胺基质,其包含以下组分:(A)0至60重量% 至少一种脂族部分结晶的聚酰胺,其溶液粘度在间甲酚(0.5重量%)中测得,ηrel小于1.9,(B)0至60重量%至少一种非晶或微晶聚酰胺基 脂肪族,脂环族或芳族二胺,二羧酸,内酰胺和/或氨基羧酸,优选具有6至36个碳原子,或这些均聚酰胺和/或共聚酰胺的混合物,其中组分(A)和(B)满足条件 :(A)+(B)= 20〜60重量%,在(A)成分和(B)成分的混合物的情况下,混合物中存在至少50重量份脂肪族嵌段(A) 和填充剂组分,其包含:(C)40至80重量%的具有el的平板玻璃纤维 并且玻璃纤维具有非圆形横截面积和主横截面轴线与二次横截面轴线的尺寸比在2至5,特别是3至4之间,(D) 0至40重量%的颗粒状或层状填料,前提是不排除碳纤维,其中聚酰胺模塑材料任选地包含最多5重量%的通常的添加剂和助剂(E),其中 组分(A)至(E)的重量总计达100%。
    • 6. 发明申请
    • POLYAMIDE MOLDING MATERIALS REINFORCED WITH GLASS FIBERS AND INJECTION MOLDED PARTS THEREOF
    • 用玻璃纤维增​​强的聚酰胺模塑材料和注塑成型部件
    • US20110240930A1
    • 2011-10-06
    • US13025953
    • 2011-02-11
    • Georg STOEPPELMANNOrnulf RexinVolker Eichhorn
    • Georg STOEPPELMANNOrnulf RexinVolker Eichhorn
    • H01B1/24C08K3/40C08L77/06H01B1/20B29C45/00B29C49/00B82Y30/00
    • C08L77/00C08K3/40C08K7/14C08L77/02C08L77/06C08L2205/02C08L2205/16C08L2666/20
    • The present invention relates to reinforced polyamide molding materials with high notch impact strengths, comprising low viscous polyamides and flat glass fibers as a reinforcing medium, characterized in a polyamide matrix, comprising the following components: (A) 0 to 60 wt.-% of at least one aliphatic, partly crystalline polyamide with a solution viscosity, measured in m-cresol (0.5 wt-%), of ηrel less than 1.9, (B) 0 to 60 wt.-% of at least one amorphous or microcrystalline polyamide based on aliphatic, cycloaliphatic or aromatic diamines, dicarboxylic acids, lactams and/or aminocarboxylic acids, preferably with 6 to 36 carbon atoms, or a mixture of such homopolyamides and/or copolyamides, wherein the components (A) and (B) fulfill the condition: (A)+(B)=20 to 60 wt.-% and that, in the case of a mixture of components (A) and (B), at least 50 weight parts aliphatic blocks (A) are present in the mixture, and a filler component, comprising: (C) 40 to 80 wt.-% flat glass fibers with elongated shape, and the glass fibers have a non-circular cross-sectional area and a size ratio of the main cross-sectional axis to the secondary cross-sectional axis of between 2 to 5, particularly between 3 and 4, and (D) 0 to 40 wt.-% particle like or layer like fillers, with the prerequisite that carbon fibers are excluded, wherein the polyamide molding materials optionally comprise up to 5 wt.-% of further usual additives and auxiliary agents (E), and wherein the weight of the components (A) to (E) sums up to 100%.
    • 本发明涉及具有高缺口冲击强度的增强聚酰胺成型材料,其包含低粘度聚酰胺和平板玻璃纤维作为增强介质,其特征在于聚酰胺基质,其包含以下组分:(A)0至60重量% 至少一种脂族部分结晶的聚酰胺,其溶液粘度在间甲酚(0.5重量%)中测定为小于1.9,(B)0至60重量%的至少一种无定形或微晶 优选具有6至36个碳原子的脂族,脂环族或芳族二胺,二羧酸,内酰胺和/或氨基羧酸的聚酰胺,或这些均聚酰胺和/或共聚酰胺的混合物,其中组分(A)和(B)满足 条件:(A)+(B)= 20至60重量%,并且在组分(A)和(B)的混合物的情况下,至少50重量份脂肪族嵌段(A)存在于 混合物和填料组分,其包含:(C)40至80重量%的扁平玻璃纤维 h细长形状,并且玻璃纤维具有非圆形横截面积,并且主横截面轴线与次横截面轴线的尺寸比在2至5之间,特别在3和4之间,并且(D )0至40重量%的颗粒状或层状填料,前提是不排除碳纤维,其中聚酰胺模塑材料任选地包含最多5重量%的通常的添加剂和助剂(E),和 其中组分(A)至(E)的重量总计高达100%。
    • 7. 发明授权
    • Reinforced polyamide moulding materials
    • 增强聚酰胺成型材料
    • US09221974B2
    • 2015-12-29
    • US11594249
    • 2006-11-08
    • Ornulf RexinJean-Jacques LinsterManfred Hewel
    • Ornulf RexinJean-Jacques LinsterManfred Hewel
    • C08L77/10C08L77/02C08L77/06C08L77/00C08G69/26C08K7/14
    • C08L77/02C08G69/26C08K7/14C08L77/00C08L77/06C08L77/10C08L2205/02C08L2666/20
    • The present invention relates to reinforced polyamide molding materials which can be prepared from a polyamide blend and, for example, by compounding with cut fibers or continuous filaments on twin-screw extruders and have mechanical properties which are usually not compatible with one another, namely a combination of exceptionally high rigidity and strength and at the same time good toughness. Furthermore, a high heat distortion temperature (HDT) is achieved according to the invention.The thermoplastic polyamide molding materials according to the invention are suitable for the production of moldings or other semifinished products or finished articles, which can be produced, for example, by extrusion, injection molding, direct methods or direct compounding, in which the compounded polyamide molding material is processed directly by injection molding, or other deformation techniques.
    • 本发明涉及增强的聚酰胺成型材料,其可以由聚酰胺共混物制备,例如通过在双螺杆挤出机上与切割的纤维或连续长丝混合并且具有通常彼此不相容的机械性质,即 组合极高的刚度和强度,同时具有良好的韧性。 此外,根据本发明实现了高热变形温度(HDT)。 根据本发明的热塑性聚酰胺成型材料适用于生产可通过例如挤出,注射成型,直接方法或直接混合来制备的模制品或其他半成品或成品,其中复合聚酰胺模制品 材料通过注射成型或其他变形技术直接加工。