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    • 5. 发明授权
    • Production of a synthesis gas blend and use in a fischer-tropsch process
    • 合成气共混物的生产和在费托过程中使用
    • US08759406B2
    • 2014-06-24
    • US13265362
    • 2010-04-20
    • Maarten BrachtMartin John Fernie
    • Maarten BrachtMartin John Fernie
    • C07C27/00
    • C01B3/384C01B3/36C01B3/382C01B2203/0233C01B2203/0244C01B2203/025C01B2203/062C01B2203/0844C01B2203/1017C01B2203/1058C01B2203/1082C01B2203/1241C01B2203/143C01B2203/148C10G2/32C10G2/341Y02P20/52
    • The invention is directed to a process for the production of hydrocarbon products from a methane comprising feedstock comprising of the steps of: preparing a feed syngas comprising hydrogen and carbon monoxide having a hydrogen/carbon monoxide molar feed ratio in a syngas manufacturing process and using the feed syngas in a Fischer-Tropsch process using one or more fixed bed catalyst beds as present in one or more syngas conversion reactors thereby obtaining the hydrocarbon product and an residual tail gas. The manufacturing process comprises of two parallel operated syngas manufacturing processes starting from the same gaseous methane comprising feedstock. One syngas manufacturing process is a partial oxidation (POX) process which prepares a syngas having a hydrogen/carbon monoxide [H2/CO] molar ratio below the molar feed ratio and The second syngas manufacturing process is a heat exchange reforming (HER) process, which prepares a syngas having a hydrogen/carbon monoxide [H2/CO] molar ratio above the molar feed ratio.
    • 本发明涉及从包含原料的甲烷生产烃产物的方法,包括以下步骤:在合成气制备过程中制备包含氢气和一氧化碳摩尔进料比的氢气和一氧化碳的进料合成气,并使用 在一种或多种合成气转化反应器中使用一种或多种固定床催化剂床在费 - 托工艺中进料合成气,从而获得烃产物和残余尾气。 该制造方法包括从包含原料的相同气态甲烷开始的两个平行操作的合成气制造方法。 一种合成气制造方法是部分氧化(POX)方法,其制备具有低于摩尔进料比的氢/一氧化碳[H 2 / CO]摩尔比的合成气,并且第二合成气制备方法是热交换重整(HER)方法, 其制备具有高于摩尔进料比的氢/一氧化碳[H 2 / CO]摩尔比的合成气。
    • 6. 发明申请
    • PRODUCTION OF A SYNTHESIS GAS BLEND AND USE IN A FISCHER-TROPSCH PROCESS
    • 合成气体混合物的生产和使用FISCHER-TROPSCH工艺
    • US20120095118A1
    • 2012-04-19
    • US13265362
    • 2010-04-20
    • Maarten BrachtMartin Jonh Fernie
    • Maarten BrachtMartin Jonh Fernie
    • C07C1/04
    • C01B3/384C01B3/36C01B3/382C01B2203/0233C01B2203/0244C01B2203/025C01B2203/062C01B2203/0844C01B2203/1017C01B2203/1058C01B2203/1082C01B2203/1241C01B2203/143C01B2203/148C10G2/32C10G2/341Y02P20/52
    • The invention is directed to a process for the production of hydrocarbon products from a methane comprising feed-stock comprising of the steps of: preparing a feed syngas comprising hydrogen and carbon monoxide having a hydrogen/carbon monoxide molar feed ratio in a syngas manufacturing process and using the feed syngas in a Fischer-Tropsch process using one or more fixed bed catalyst beds as present in one or more syngas conversion reactors thereby obtaining the hydrocarbon product and an residual tail gas. The manufacturing process comprises of two parallel operated syngas manufacturing processes starting from the same gaseous methane comprising feedstock. One syngas manufacturing process is a partial oxidation (POX) process which prepares a syngas having a hydrogen/carbon monoxide [H2/CO] molar ratio below the molar feed ratio and The second syngas manufacturing process is a heat exchange reforming (HER) process, which prepares a syngas having a hydrogen/carbon monoxide [H2/CO] molar ratio above the molar feed ratio.
    • 本发明涉及从包含原料的甲烷生产烃产物的方法,包括以下步骤:在合成气制备过程中制备包含氢气和一氧化碳摩尔进料比的氢气和一氧化碳的进料合成气,以及 使用一种或多种合成气转化反应器中存在的一种或多种固定床催化剂床,在费 - 托法中使用进料合成气,从而获得烃产物和残余尾气。 该制造方法包括从包含原料的相同气态甲烷开始的两个平行操作的合成气制造方法。 一种合成气制造方法是部分氧化(POX)方法,其制备具有低于摩尔进料比的氢/一氧化碳[H 2 / CO]摩尔比的合成气,并且第二合成气制备方法是热交换重整(HER)方法, 其制备具有高于摩尔进料比的氢/一氧化碳[H 2 / CO]摩尔比的合成气。
    • 7. 发明申请
    • MULTI STAGE PROCESS FOR PRODUCING HYDROCARBONS FROM SYNGAS
    • 从SYNGAS生产石油烃的多阶段工艺
    • US20100184873A1
    • 2010-07-22
    • US12640298
    • 2009-12-17
    • Maarten BrachtMaarten HesselinkChristiaan NijstThomas Joris Remans
    • Maarten BrachtMaarten HesselinkChristiaan NijstThomas Joris Remans
    • C07C27/06
    • C10G2/30C10K3/06
    • The invention pertains to a multi-stage process for the production of hydrocarbons from syngas comprising hydrogen and carbon monoxide, which comprises the steps of: a) providing a fresh syngas feed to a first stage Fischer-Tropsch reactor and allowing CO and hydrogen to convert into hydrocarbon products at a temperature in the range from 125 to 400° C. and a pressure in the range from 5 to 150 bar absolute, and a gaseous hourly space velocity in the range from 500 to 10000 Nl/l/h; b) feeding the effluent from the first stage reactor to a separation unit; c) removing a gasous effluent stream comprising hydrogen and CO from the separation unit; d) removing one or more other streams comprising hydrocarbon and/or water from the separation unit; e) conveying a first portion of the gaseous effluent stream to a second stage Fischer-Tropsch reactor and allowing CO and hydrogen to convert into hydrocarbon products in the second stage Fischer-Tropsch reactor at a temperature in the range from 125 to 400° C. and a pressure in the range from 5 to 150 bar absolute, and a gaseous hourly space velocity in the range from 500 to 10000 Nl/l/h, whereby the first stage Fischer-Tropsch reactor and the second stage Fischer-Tropsch reactor are separate reactors; f) feeding the effluent from the second stage Fischer-Tropsch reactor to the separation unit; g) removing a second portion of the gaseous effluent stream as off-gas.
    • 本发明涉及用于从包含氢气和一氧化碳的合成气生产碳氢化合物的多级方法,其包括以下步骤:a)向新的第一阶段费 - 托反应器提供新的合成气进料并允许CO和氢转化 在125至400℃的温度和5至150巴绝对压力的范围内的气体产物,并且气时空速在500至10000Nl / l / h的范围内; b)将来自第一级反应器的流出物供给到分离单元; c)从分离单元中除去包含氢和CO的气体流出物流; d)从分离单元去除包含烃和/或水的一种或多种其它流; e)将第一部分气态流出物流输送到第二级费 - 托反应器,并允许CO和氢在第二级费 - 托反应器中在125-400℃的温度下转化成烃产物。 压力范围为5至150巴绝对压力,气时空速为500至10000Nl / l / h,其中第一级费 - 托反应器和第二级费 - 托反应器是分开的 反应堆 f)将来自第二级费 - 托反应器的流出物供给到分离单元; g)除去作为废气的气态流出物流的第二部分。