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    • 1. 发明授权
    • Ink compositions containing disazo dyes
    • 含有双偶氮染料的油墨组合物
    • US5820661A
    • 1998-10-13
    • US831938
    • 1997-04-02
    • Peter GregoryMark KenworthyAndrew Hunter Morris Renfrew
    • Peter GregoryMark KenworthyAndrew Hunter Morris Renfrew
    • C09B43/40C09B62/09C09B62/44C09D11/00D06P5/30G03G9/09C09D11/02
    • C09D11/328C09B43/40C09B62/09C09B62/4415D06P5/30G03G9/091G03G9/0914Y10T428/24802
    • An ink composition comprising: (i) a dye of Formula (1) or a salt thereof: ##STR1## wherein: A is optionally substituted phenylene; B and E each independently is optionally substituted phenylene or optionally substituted naphthylene; D is a coupling component; each R.sup.1 independently is H or optionally substituted alkyl; X is a labile or non-labile atom or group; each Z independently is --OR.sup.3, --SR.sup.3, --NR.sup.4 R.sup.5 or --Y--SO.sub.3 H in which Y is O or S; and R.sup.3, R.sup.4 and R.sup.5 each independently is H, optionally substituted alkyl, optionally substituted alkenyl, cycloalkyl, optionally substituted aralkyl, optionally substituted aryl or R.sup.4 or R.sup.5 together with the nitrogen atom to which they are attached form a 5 or 6 membered ring; and (ii) a medium comprising a low melting point solid, an organic solvent, or a mixture of water and one or more water-soluble organic solvent(s). Also claimed is a process for ink jet printing using the inks, a process for ink jet printing of textiles using the inks and a toner containing a dye with at least one group of Formula (1).
    • 一种油墨组合物,其包含:(i)式(1)的染料或其盐:式(1)ESO 2 NHCH 2 CH 2 Z其中:A是任选取代的亚苯基; B和E各自独立地为任选取代的亚苯基或任选取代的亚萘基; D是耦合元件; 每个R 1独立地是H或任选取代的烷基; X是不稳定或不稳定的原子或组; 各Z独立地为-OR3,-SR3,-NR4R5或-Y-SO3H,其中Y为O或S; 并且R 3,R 4和R 5各自独立地为H,任选取代的烷基,任选取代的烯基,环烷基,任选取代的芳烷基,任选取代的芳基或R 4或R 5与它们所连接的氮原子一起形成5或6元环; 和(ii)包含低熔点固体,有机溶剂或水与一种或多种水溶性有机溶剂的混合物的介质。 还要求保护的是使用油墨的喷墨印刷方法,使用该油墨的纺织品的喷墨印刷方法和含有至少一种式(1)的染料的调色剂。
    • 2. 发明授权
    • Phthalocyanine compounds used in inks for ink jet printing
    • 用于喷墨印刷油墨的酞菁化合物
    • US06235097B1
    • 2001-05-22
    • US09486832
    • 2000-03-02
    • Mark KenworthyPeter Gregory
    • Mark KenworthyPeter Gregory
    • C09D1102
    • C09D11/328C09B47/20C09B47/24
    • Suitable phthalocyanine compounds of Formula (1) have utility as colorants in inks for ink-jet printing, where Formula (1) represents: which comprises any form of the compound: such as salt; stereoisomer, zwitterion, polymorph, complex, isotopic form, combinations thereof in the same species and mixtures thereof; where: M represents a metal or H; Pc represents a phthalocyanine nucleus of Formula (2): L represents a linking group comprising an optionally substituted C1-30hydrocarbyl; A represents a group comprising at least one of: amino and optionally substituted C1-30hydrocarbyl comprising at least one protonable nitrogen atom; but where A comprises other than an alkyl group substituted by at least one of: hydroxy, carboxy and sulpho; R1 represents a group independently comprising at least one of: an optional substituent and optionally substituted C1-5hydrocarbyl; z represents an integer from 0 to 4; w represents an integer from 1 to 5; and the sum of w+z is from 1 to 5; and x and y each independently represent a non-zero number; and the mean of the sum of x+y is from about 1 to about 6; where the optional substituents comprise at least one of: carboxy, sulpho, hydroxy, amino, mercapto, cyano, nitro and halo.
    • 式(1)的合适的酞菁化合物可用作喷墨印刷用油墨中的着色剂,其中式(1)表示:其包含任何形式的化合物如盐; 立体异构体,两性离子,多晶型物,复合物,同位素形式,它们在同一物种及其混合物中的组合; 其中:M表示金属或H; Pc表示式(2)的酞菁核:L表示包含任选取代的C 1-30烃基的连接基团; A表示包含至少一个氨基和任选取代的C 1-30烃基 包含至少一个可质子化的氮原子; 但是其中A不包括被至少一个羟基,羧基和磺基取代的烷基; R 1表示独立地包含任选的取代基和任选取代的C 1-5烃基中的至少一个的基团; z表示0至 4; w表示1〜5的整数, w + z的和为1〜5; andx和y各自独立地表示非零数; 并且x + y之和的平均值为约1至约6;其中任选的取代基包括以下中的至少一个:羧基,磺基,羟基,氨基,巯基,氰基,硝基和卤素。
    • 7. 发明授权
    • Multiple-level occulting using a mask buffer
    • US5619627A
    • 1997-04-08
    • US237285
    • 1994-05-03
    • Brian T. SoderbergDale D. MillerHenrik LindRichard JarvisMark Kenworthy
    • Brian T. SoderbergDale D. MillerHenrik LindRichard JarvisMark Kenworthy
    • H04N1/387G06T15/40G06T15/10
    • G06T15/40
    • Occulting apparatus for use with an image generator that provides for multiple-level occulting of image data. The occulting apparatus comprises a mask buffer and control logic for processing image data to construct and store an obscurance mask in the mask buffer. Foreground entities contained in the image data are logically ORed into the mask buffer until the entities extend beyond a predefined range from a predetermined image viewpoint. Thereafter, the mask is used by the control logic to reject entities contained in subsequently processed image data that are fully obscured by the foreground entities comprising the obscurance mask. The control logic includes an obscurance manager, a region processor, an object processor, a polygon processor, and insertion logic. The obscurance manager is a controller for building and applying the obscurance mask to the image data. The region, object, and polygon processors respectively process regions, objects, and polygons in the image to determine if they are obscured, reject obscured entities, and transmits unobscured entities to subsequent processors. The insertion logic processes unobscured polygons and applies them to the obscurance manager for storage and use by the respective region, object, and polygon processors. The present invention performs real-time occulting of all objects in an image scene, whether they are fixed or moving. Hidden area modules (large groups of objects in a geographic region), single objects, polygons, and pixels are sequentially filtered-out in real-time. The mask buffer and control logic provide three levels of occulting. A hybrid Z-buffer 51 provides pixel-level occulting. The present invention rejects regions, objects, and polygons, early in the graphics processing pipeline to reduce the number of required pixel processing computational elements in the image generator. By rendering objects generally from front to back, entities that are completely hidden by nearer objects can be detected and discarded before tiling and pixel processing.
    • 10. 发明授权
    • Mono-azo dyes and inks for ink-jet printing
    • 用于喷墨打印的单偶氮染料和油墨
    • US06514329B1
    • 2003-02-04
    • US09555895
    • 2000-06-05
    • Kathryn CarrMark Kenworthy
    • Kathryn CarrMark Kenworthy
    • C09D1100
    • C09D11/328C09B43/16
    • A mono-azo compound of Formula (1) or a salt thereof: wherein: A is N, C—Cl, C—CN or C—NO2; R1 is H or optionally substituted alkyl; G is H, sulpho, carboxy, optionally substituted alkyl, optionally substituted alkoxy, —CF3, halo or —PO3H2; L1 and L2 each independently is —SR2, —OR3 or —NR4R5; R2, R3, R4 and R5 each independently is H, optionally substituted alkyl or optionally substituted aryl; or R4 and R5 together with the nitrogen to which they are attached form an optionally substituted five or six membered ring; provided that L1 and L2 are free from carboxy, sulpho and —PO3H2 groups; and the use of a mono-azo compound of Formula (1) or a salt thereof in inks, an ink jet printing process using the inks, a substrate printed with the inks and an ink jet printer cartridge containing the inks.
    • 式(1)的单偶氮化合物或其盐:其中:A为N,C-Cl,C-CN或C-NO 2; R 1为H或任选取代的烷基; G为H,磺基,羧基, 取代的烷基,任选取代的烷氧基,-CF 3,卤素或-PO 3 H 2; L 1和L 2各自独立地为-SR 2,-OR 3或-NR 4 R 5; R 2,R 3,R 4和R 5各自独立地为H,任选取代的烷基或任选取代的芳基; 或R 4和R 5与它们所连接的氮一起形成任选取代的五元或六元环;条件是L 1和L 2不含羧基,磺基和-PO 3 H 2基; 以及在油墨中使用式(1)的单偶氮化合物或其盐,使用该油墨的喷墨印刷方法,印刷有油墨的基材和含有该油墨的喷墨打印机墨盒。