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    • 1. 发明授权
    • Shaped articles made from expanded minerals
    • 由膨胀的矿物制成的成型制品
    • US4391644A
    • 1983-07-05
    • US341233
    • 1982-01-21
    • Peter EckardtFranz J. Voetz
    • Peter EckardtFranz J. Voetz
    • C04B20/10C04B28/34C04B31/44
    • C04B28/34C04B20/1022C04B2103/65
    • Shaped articles made from expanded minerals obtained by treating a mixture of a hydrophobized expanded mineral and a calcium aluminate with an aqueous solution of aluminum phosphate, and subsequently consolidating it under the action of pressure and heat; the expanded mineral having been hydrophobized with a hydrophobizing agent consisting substantially of(a) a fatty amine of the formula ##STR1## in which R.sub.1 is C.sub.8 -C.sub.22 -alkyl, preferably C.sub.14 -C.sub.22 -alkyl, C.sub.14 -C.sub.22 -alkenyl or C.sub.8 -C.sub.22 -alkylphenyl, R.sub.2 and R.sub.3 each are hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.2 -C.sub.4 -alkenyl, phenyl or benzyl, and n is a number of from 0 to 4;(b) a fatty acid of the formulaR.sub.5 CO(OCH.sub.2 CH.sub.2).sub.m OH or a fatty alcohol of the formulaR.sub.6 (OCH.sub.2 CH.sub.2).sub.m OH in which R.sub.5 is C.sub.8 -C.sub.22 -alkyl, preferably C.sub.14 -C.sub.22 -alkyl or -alkenyl, R.sub.6 is C.sub.9 -C.sub.23 -alkyl, preferably C.sub.15 -C.sub.23 -alkyl or -alkenyl, and m is a number of from 0 to 2; and(c) a low molecular weight acid.
    • 通过用磷酸铝水溶液处理疏水化膨胀矿物和铝酸钙的混合物而获得的膨胀矿物制成的成型制品,随后在压力和热力的作用下将其固结; 膨胀矿物已用疏水化剂疏水化,疏水化剂基本上由(a)式(a)的脂肪胺组成,其中R 1是C 8 -C 22 - 烷基,优选C 14 -C 22 - 烷基,C 14 -C 22 - 烯基或C 8 -C 22 - C 22 - 烷基苯基,R 2和R 3各自为氢,C 1 -C 4 - 烷基或C 2 -C 4 - 烯基,苯基或苄基,n为0至4的数; (b)式R 5 CO(OCH 2 CH 2)mOH的脂肪酸或式R 6(OCH 2 CH 2)mOH的脂肪醇,其中R 5为C 8 -C 22 - 烷基,优选C 14 -C 22 - 烷基或 - 烯基,R 6为C 9 - C 23 - 烷基,优选C 15 -C 23 - 烷基或 - 烯基,m为0至2的数; 和(c)低分子量酸。
    • 4. 发明授权
    • Shaped articles made from expanded minerals
    • 由膨胀的矿物制成的成型制品
    • US4344797A
    • 1982-08-17
    • US237708
    • 1981-02-24
    • Franz J. Voetz
    • Franz J. Voetz
    • C04B20/10C04B28/26C04B19/04
    • C04B28/26C04B20/1022C04B2103/65C04B2111/00758C04B2111/52
    • Shaped articles made from expanded minerals, obtained by solidification of a mixture of water glass, catalyst and an expanded mineral pretreated with a hydrophobizing agent which comprises substantially(a) a fatty amine of the formula ##STR1## in which R.sub.1 is C.sub.8 -C.sub.22, preferably C.sub.14 -C.sub.22 -alkyl or -alkenyl, or C.sub.8 -C.sub.22 -alkylphenyl, R.sub.2 and R.sub.3 each are hydrogen, C.sub.1 -C.sub.4 -alkyl or -alkenyl, phenyl or benzyl, and n is a number of from 0 to 4:(b) a fatty acid of the formulaR.sub.5 CO (OCH.sub.2 CH.sub.2).sub.m OH or a fatty alcohol of the formulaR.sub.6 (OCH.sub.2 CH.sub.2).sub.m OH in which formulae R.sub.5 is C.sub.8 -C.sub.22, preferably C.sub.14 -C.sub.22 -alkyl or -alkenyl, R.sub.6 is C.sub.9 -C.sub.23, preferably C.sub.15 -C.sub.23 -alkyl or -alkenyl, and m is a number of from 0 to 2; and(c) a low molecular weight acid.
    • 由膨胀的矿物制成的成形制品,通过水玻璃,催化剂和用疏水化剂预处理的膨胀矿物的混合物固化获得,所述疏水化剂基本上包含(a)式(IMAGE)的脂肪胺,其中R1是C8-C22, 优选C 14 -C 22 - 烷基或 - 烯基或C 8 -C 22 - 烷基苯基,R 2和R 3各自为氢,C 1 -C 4 - 烷基或 - 烯基,苯基或苄基,n为0至4的数:(b )式R5CO(OCH2CH2)mOH的脂肪酸或式R6(OCH2CH2)mOH的脂肪醇,其中式R5为C8-C22,优选C14-C22 - 烷基或 - 烯基,R6为C9-C23,优选为 C 15 -C 23 - 烷基或 - 烯基,m为0〜2的数; 和(c)低分子量酸。