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1. 发明授权

US06428901B1 Films formed from blends of polyethylene and polypropylene 失效
标题翻译：由聚乙烯和聚丙烯的共混物形成的膜
公开(公告)号：US06428901B1
公开(公告)日：2002-08-06
申请号：US09467651
申请日：1999-12-20
申请人： Pawan K. Agarwal , Armenag H. Dekmezian
发明人： Pawan K. Agarwal , Armenag H. Dekmezian
IPC分类号： B32B2708
CPC分类号： C08J5/18 , B32B27/32 , C08J2323/04 , Y10T428/31855 , Y10T428/31913 , Y10T428/31946
摘要： Disclosed are compositions comprising: a) an ethylene polymer component having a melting temperature greater than or equal to about 75° C., an ethylene crystallinity level of 5 weight percent or more, and a narrow compositional distribution; and b) a propylene polymer component having a melt flow rate of 500 dg/min. or more at 230° C. and a melting temperature greater than or equal to about 125° C. Further disclosed are films and articles made thereof.
摘要翻译：公开的组合物包括：a）具有大于或等于约75℃的熔融温度，5重量％以上的乙烯结晶度水平和窄的组成分布的乙烯聚合物组分; 和b）熔体流动速率为500dg / min的丙烯聚合物组分。或更高，并且熔融温度大于或等于约125℃。还公开了其制成的薄膜和制品。

2. 发明授权

US06407171B1 Blends of polyethylene and polypropylene 失效
标题翻译：聚乙烯和聚丙烯的共混物
公开(公告)号：US06407171B1
公开(公告)日：2002-06-18
申请号：US09468290
申请日：1999-12-20
申请人： Pawan K. Agarwal , Armenag H. Dekmezian
发明人： Pawan K. Agarwal , Armenag H. Dekmezian
IPC分类号： C08L2300
CPC分类号： C08L23/06 , C08L23/10 , C08L2666/06
摘要： Disclosed are compositions comprising: a) an ethylene polymer component having a melting temperature greater than or equal to about 75° C., an ethylene crystallinity level of 5 weight percent or more, and a narrow compositional distribution; and b) a propylene polymer component having a melt flow rate of 500 dg/min. or more at 230° C. and a melting temperature greater than or equal to about 125° C.
摘要翻译：公开的组合物包括：a）具有大于或等于约75℃的熔融温度，5重量％以上的乙烯结晶度水平和窄的组成分布的乙烯聚合物组分; 和b）熔体流动速率为500dg / min的丙烯聚合物组分。或更高，并且熔化温度大于或等于约125℃。

3. 发明授权

US08481647B2 Thermoplastic elastomer polyolefin in-reactor blends and molded articles therefrom 失效
标题翻译：热塑性弹性体聚烯烃反应器内共混物及其模塑制品
公开(公告)号：US08481647B2
公开(公告)日：2013-07-09
申请号：US13329461
申请日：2011-12-19
申请人： Peijun Jiang , Armenag H. Dekmezian , Kevin R. Squire , Cesar A. Garcia-Franco
发明人： Peijun Jiang , Armenag H. Dekmezian , Kevin R. Squire , Cesar A. Garcia-Franco
IPC分类号： C08F8/00 , C08L33/00 , C08L33/04
CPC分类号： C08L23/06 , C08L23/08 , C08L2205/02 , C08L2314/06 , C08L2666/06
摘要： This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene-containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm3 wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%.
摘要翻译：本发明涉及一种反应器内聚合物共混物，其包含：（a）密度大于0.90g / cm 3，Mw大于20,000g / mol的第一含乙烯聚合物和（b）第二含乙烯的聚合物聚合物的密度小于0.90g / cm 3，其中聚合物共混物具有至少90℃的Tm（DSC第二熔体），小于0.92g / cm 3的密度和第一和第二聚合物的密度至少1％不等。

4. 发明授权

US08436100B2 Homogeneous polymer blend and process of making the same 失效
标题翻译：均相聚合物混合物和制造方法相同
公开(公告)号：US08436100B2
公开(公告)日：2013-05-07
申请号：US13035573
申请日：2011-02-25
申请人： Peijun Jiang , Sunny Jacob , Aspy K. Mehta , Pradeep P. Shirodkar , Armenag H. Dekmezian , Palanisamy Arjunan
发明人： Peijun Jiang , Sunny Jacob , Aspy K. Mehta , Pradeep P. Shirodkar , Armenag H. Dekmezian , Palanisamy Arjunan
IPC分类号： C08L23/00 , C08L23/10 , C08L23/16
CPC分类号： C08F210/06 , C08F110/06 , C08L23/04 , C08L23/083 , C08L23/10 , C08L23/12 , C08L23/145 , C08L23/16 , C08L91/00 , C08L2205/03 , C08L2205/22 , C08L2308/00 , C08L2312/00 , C08L2666/02 , C08L2666/06 , C08L2666/04 , C08F2/001 , C08F210/18 , C08F236/20 , C08F2500/20
摘要： A homogeneous polymer blend comprises a thermoplastic first polymer having a crystallinity of at least 30%; and a second polymer having a crystallinity of more than 5% and being at least partially cross-linked.
摘要翻译：均匀的聚合物共混物包含具有至少30％的结晶度的热塑性第一聚合物; 和具有大于5％的结晶度并且至少部分交联的第二聚合物。

5. 发明申请

US20120149846A1 Thermoplastic Elastomer Polyolefin In-Reactor Blends and Molded Articles Therefrom 失效
标题翻译：热塑性弹性体聚烯烃反应器共混物和成型制品
公开(公告)号：US20120149846A1
公开(公告)日：2012-06-14
申请号：US13329461
申请日：2011-12-19
申请人： Peijun JIANG , Armenag H. Dekmezian , Kevin R. Squire , Cesar A. Garcia-Franco
发明人： Peijun JIANG , Armenag H. Dekmezian , Kevin R. Squire , Cesar A. Garcia-Franco
IPC分类号： C08L23/04 , C08L23/16 , C08L23/20 , C08L23/06
CPC分类号： C08L23/06 , C08L23/08 , C08L2205/02 , C08L2314/06 , C08L2666/06
摘要： This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene-containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm3 wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%.
摘要翻译：本发明涉及一种反应器内聚合物共混物，其包含：（a）密度大于0.90g / cm 3，Mw大于20,000g / mol的第一含乙烯聚合物和（b）第二含乙烯的聚合物聚合物的密度小于0.90g / cm 3，其中聚合物共混物具有至少90℃的Tm（DSC第二熔体），小于0.92g / cm 3的密度和第一和第二聚合物的密度至少1％不等。

6. 发明申请

US20120045600A1 Solution Blending Process for Preparing Thermoplastic Vulcanizates 有权
标题翻译：用于制备热塑性硫化橡胶的溶液混合方法
公开(公告)号：US20120045600A1
公开(公告)日：2012-02-23
申请号：US13033171
申请日：2011-02-23
申请人： Weiqing Weng , Sunny Jacob , Peijun Jiang , Armenag H. Dekmezian , Aspy K. Mehta , James R. Ayers , David J. Lohse , Peter W. Manders , Palanisamy Arjunan
发明人： Weiqing Weng , Sunny Jacob , Peijun Jiang , Armenag H. Dekmezian , Aspy K. Mehta , James R. Ayers , David J. Lohse , Peter W. Manders , Palanisamy Arjunan
IPC分类号： B32B25/02 , B32B1/02 , B32B1/08 , C08L9/00
CPC分类号： C08J3/005 , C08K3/011 , C08K5/0025 , C08L23/10 , C08L23/16 , C08L63/00 , C08L101/00 , C08L2312/04 , Y10T428/1372 , C08L2666/06
摘要： This invention relates to the preparation of thermoplastic vulcanizates (TPVs) with unique morphological features, more specifically, this invention relates to a method for preparing TPV compositions wherein the mixing of plastomers and elastomers are carried out in solvent with curatives to induce cross-linking.
摘要翻译：本发明涉及具有独特形态特征的热塑性硫化橡胶（TPV）的制备，更具体地说，本发明涉及制备TPV组合物的方法，其中塑性体和弹性体的混合物在溶剂中用固化剂进行以引发交联。

7. 发明授权

US06573350B1 Branched semi-crystalline high-C3 ethylene-propylene compositions 有权
标题翻译：支化半结晶高C3乙烯 - 丙烯组合物
公开(公告)号：US06573350B1
公开(公告)日：2003-06-03
申请号：US09461797
申请日：1999-12-15
申请人： Eric J. Markel , Weiqing Weng , Armenag H. Dekmezian
发明人： Eric J. Markel , Weiqing Weng , Armenag H. Dekmezian
IPC分类号： C08F464
CPC分类号： C08F210/16 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F10/06 , C08F210/06 , Y10S526/943 , C08F4/65927 , C08F2500/03 , C08F2500/09
摘要： Branched ethylene-propylene compositions which have improved melt strength and shear thinning are provided. The weight average branching index g′ for the higher molecular weight region of the ethylene-propylene composition is less than 0.95. Additionally, a novel process is provided for efficiently producing a branched ethylene-propylene composition comprising: a) contacting propylene monomers and ethylene monomers in a reactor with an inert hydrocarbon solvent or diluent and a catalyst composition comprising one or more single site catalyst compounds capable of producing an ethylene-propylene polymer at a temperature from about 50° C. to about 180° C., wherein the ratio in the reactor of the propylene and ethylene monomers to the inert hydrocarbon solvent or diluent is less than 2.0, and further, wherein the propylene and ethylene monomers and the inert hydrocarbon solvent or diluent comprise no more than 90 percent of the total contents of the reactor; and b) recovering a branched ethylene-propylene composition, wherein the weight average branching index g′ for the higher molecular weight region of the ethylene-propylene composition is less than 0.95.
摘要翻译：提供了具有改善的熔体强度和剪切稀化的分支乙烯 - 丙烯组合物。乙烯 - 丙烯组合物的较高分子量区域的重均分支指数g'小于0.95。另外，提供了一种有效生产支化乙烯 - 丙烯组合物的新方法，其包括：a）使反应器中的丙烯单体和乙烯单体与惰性烃溶剂或稀释剂和包含一种或多种单中心催化剂化合物的催化剂组合物接触，在约50℃至约180℃的温度下生产乙烯 - 丙烯聚合物，其中丙烯和乙烯单体的反应器与惰性烃溶剂或稀释剂的比例小于2.0，此外，其中丙烯和乙烯单体和惰性烃溶剂或稀释剂不超过反应器总含量的90％; 和b）回收支链乙烯 - 丙烯组合物，其中乙烯 - 丙烯组合物的较高分子量区域的重均分支指数g'小于0.95。

8. 发明授权

US08038917B2 Process for preparing articles 有权
公开(公告)号：US08038917B2
公开(公告)日：2011-10-18
申请号：US13069721
申请日：2011-03-23
申请人： Weiqing Weng , Sunny Jacob , Peijun Jiang , Armenag H. Dekmezian , Aspy K. Mehta , Peter W. Manders , Pradeep Shirodkar , Palanisamy Arjunan
发明人： Weiqing Weng , Sunny Jacob , Peijun Jiang , Armenag H. Dekmezian , Aspy K. Mehta , Peter W. Manders , Pradeep Shirodkar , Palanisamy Arjunan
IPC分类号： B32B25/12 , B32B27/28 , B32B27/34
CPC分类号： B29C43/003 , C08L21/00 , C08L23/04 , C08L23/10 , C08L23/16 , C08L61/06 , C08L67/00 , C08L69/00 , C08L2312/04 , C08L2666/06 , C08L2666/08 , C08L2666/02
摘要： The present invention relates to a process for preparing a thermoplastic vulcanizate (TPV) comprising: contacting a thermoplastic polymer, a cross-linkable elastomer, at least one curative, and at least one cure activator in a solvent to form Composition A. The solvent is then removed, and thereafter the cross-linkable elastomer is at least partially cured. The average particle size of the cross-linkable elastomer is 10 microns or less after the solvent is removed.

9. 发明申请

US20110196102A1 Heterogeneous Polymer Blend With Continuous Elastomeric Phase And Process Of Making The Same 失效
标题翻译：具有连续弹性相的异质聚合物共混物及其制备方法
公开(公告)号：US20110196102A1
公开(公告)日：2011-08-11
申请号：US13090750
申请日：2011-04-20
申请人： Sunny JACOB , Peijun Jiang , Aspy K. Mehta , Pradeep P. Shirodkar , Armenag H. Dekmezian , Weiqing Weng
发明人： Sunny JACOB , Peijun Jiang , Aspy K. Mehta , Pradeep P. Shirodkar , Armenag H. Dekmezian , Weiqing Weng
IPC分类号： C08L23/16
CPC分类号： C08L23/16 , C08L23/10 , C08L2312/00 , C08L2666/06
摘要： A heterogeneous polymer blend comprises a dispersed phase comprising a thermoplastic first polymer having a crystallinity of at least 30% and a continuous phase comprising a second polymer different from the first polymer. The second polymer has a crystallinity of less than 20% and is at least partially cross-linked.
摘要翻译：非均相聚合物共混物包含分散相，其包含结晶度至少为30％的热塑性第一聚合物和包含不同于第一聚合物的第二聚合物的连续相。第二聚合物具有小于20％的结晶度并且至少部分交联。

10. 发明申请

US20100152360A1 Thermoplastic Polyolefin In-Reactor Blends And Molded Articles Therefrom 有权
标题翻译：热塑性聚烯烃反应器共混物和成型制品
公开(公告)号：US20100152360A1
公开(公告)日：2010-06-17
申请号：US12638843
申请日：2009-12-15
申请人： Peijun Jiang , Armenag H. Dekmezian , Joseph Gustaaf M. Flendrig
发明人： Peijun Jiang , Armenag H. Dekmezian , Joseph Gustaaf M. Flendrig
IPC分类号： C08L23/14 , C08K5/00
CPC分类号： C08L23/12 , C08L23/14 , C08L2205/02 , C08L2314/06 , C08L2666/06
摘要： This invention relates to a molded article comprising an in-reactor polymer blend comprising: (a) a first propylene polymer comprising 90 to 100 wt % propylene and from 0 to less than 10 wt % comonomer, said first propylene component having a Tm of 135° C. or more; and (b) a second propylene polymer comprising from 30 to 90 wt % propylene and 70 to 10 wt % comonomer, said second propylene polymer having an Mw of 30,000 g/mol or more, and said second propylene-containing polymer having a crystallinity different by at least 5% from the first polymer, wherein the polymer blend has: (a) a Tm of at least 135° C., (b) a melt flow rate of at least 70 dg/min, (c) a tensile strength of at least 8 MPa, (d) an elongation at break of at least 200%, (e) a tensile strength at break of 10 MPa or more, and (f) a GME 60280 scratch resistance of less than 1.2 DL at a scratching load of 5 Newtons.
摘要翻译：本发明涉及包含反应器内聚合物共混物的模制品，其包含：（a）包含90至100重量％丙烯和0至小于10重量％共聚单体的第一丙烯聚合物，所述第一丙烯组分的Tm为135 ℃以上; 和（b）第二丙烯聚合物，其包含30至90重量％的丙烯和70至10重量％的共聚单体，所述第二丙烯聚合物的Mw为30,000g / mol或更高，并且所述第二丙烯聚合物具有不同的结晶度与第一聚合物相比至少5％，其中聚合物共混物具有：（a）Tm至少为135℃，（b）熔体流动速率至少为70dg / min，（c）拉伸强度至少8MPa，（d）断裂伸长率至少为200％，（e）断裂时的拉伸强度为10MPa以上，（f）在刮擦时GME 60280耐擦伤性小于1.2DL 负荷5牛顿。

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