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1. 发明授权

US5576397A Acid-modified polyesters and their use in stoving enamels 失效
标题翻译：酸改性聚酯及其在烘烤搪瓷中的应用
公开(公告)号：US5576397A
公开(公告)日：1996-11-19
申请号：US389324
申请日：1995-02-16
申请人： Paul Oberressl , Joachim Zoeller
发明人： Paul Oberressl , Joachim Zoeller
IPC分类号： C08G63/20 , B65D25/34 , C08G63/12 , C08G63/16 , C08G63/60 , C09D167/00 , C09D167/02
CPC分类号： C09D167/00 , C08G63/60
摘要： Acid-modified polyesters obtained by reacting(a) from 20 to 60, preferably 30-50, mol % of at least one dicarboxylic acid,(b) from 3 to 30, preferably 5-20, mol % of a dihydroxyalkanecarboxylic acid,(c) from 10 to 60, preferably 20-50, mol % of a diol,(d) from 0 to 30 mol % of a polyalcohol having more than two OH groups or of a polycarboxylic acid, and(e) from 0 to 20, preferably up to 10, mol % of a monocarboxylic acid,the ratio of the sum of the hydroxyl equivalents to the sum of the carboxyl equivalents in the reactants being between 0.5 and 2.0, the quantities of free hydroxyl groups in the end product being between 30 and 350 mmol of hydroxyl groups per 100 g of solid resin, preferably between 100 and 250 mmol of hydroxyl groups per 100 g of solid resin, and the content of free, neutralized and/or neutralizable acid groups being between 5 and 350 mmol of acid groups per 100 g of solid resin, preferably between 9 and 120 mmol of acid groups per 100 g of solid resin.
摘要翻译：通过（a）20重量％至60重量％，优选30-50摩尔％的至少一种二羧酸，（b）3-30重量％，优选5-20摩尔％的二羟基烷烃羧酸反应获得的酸改性聚酯， c）10至60，优选20-50摩尔％的二醇，（d）0至30摩尔％的具有多于2个OH基团的多元醇或多元羧酸，和（e）0至20 ，优选至多10摩尔％的单羧酸，羟基当量的总和与反应物中的羧基当量之和的比率在0.5和2.0之间，最终产物中游离羟基的量介于每100克固体树脂含有30至350毫摩尔羟基，每100克固体树脂优选为100至250毫摩尔羟基，游离，中和和/或可中和酸基团的含量为5- 350毫摩尔酸固体树脂，每100g固体树脂优选为9至120mmol酸基。

2. 发明授权

US5466772A Unsaturated polyurethanes and their use as dispersants for alkyd resins 失效
标题翻译：不饱和聚氨酯及其作为醇酸树脂分散剂的用途
公开(公告)号：US5466772A
公开(公告)日：1995-11-14
申请号：US205600
申请日：1994-03-03
申请人： Karl-Hans Angelmayer , Gerd Walz , Joachim Zoeller
发明人： Karl-Hans Angelmayer , Gerd Walz , Joachim Zoeller
IPC分类号： C08G18/67 , B01F17/52 , C08G18/08 , C08G18/28 , C08G18/32 , C08G18/34 , C08G18/48 , C08G18/66 , C08J3/03 , C08L67/00 , C08L67/02 , C08L75/16 , C09D175/14
CPC分类号： C08J3/03 , C08G18/0819 , C08G18/2825 , C08G18/283 , C08G18/284 , C08G18/2865 , C08G18/4833 , C08J2367/08 , Y10T428/31645 , Y10T428/31649
摘要： Unsaturated polyurethanes containing from 20 to 80% by weight of polyethylene glycol units, which can be prepared by reactinga) at least one organic polyisocyanate,b) an unsaturated fatty alcohol or its polyalkylene glycol ether, an unsaturated fatty amine or a reaction product of an unsaturated fatty acid and a monoepoxide,c) a compound which contains not only two groups which react with isocyanate groups but also at least one group which is ionic.d) a polyalkylene glycol having a molecular mass of from 750 to 10,000, and if desirede) a compound containing from three to six hydroxyl or amino groups,the ratio of the isocyanate groups in a) to the hydroxyl and amino groups in the remaining components being from 0.7:1 to 1.2:1. These unsaturated polyurethanes are used as dispersants for alkyd resins.
摘要翻译：含有20至80重量％的聚乙二醇单元的不饱和聚氨酯可通过使a）至少一种有机多异氰酸酯，b）不饱和脂肪醇或其聚亚烷基二醇醚，不饱和脂肪胺或不饱和脂肪胺或不饱和脂肪酸和单环氧化物，c）不仅含有与异氰酸酯基反应的两个基团，而且还含有至少一个离子性基团的化合物。 d）分子量为750至10,000的聚亚烷基二醇，如果需要，e）含有3-6个羟基或氨基的化合物，a）中的异氰酸酯基与剩余的羟基和氨基的比例组分为0.7:1至1.2:1。这些不饱和聚氨酯用作醇酸树脂的分散剂。

3. 发明授权

US5391613A Unsaturated polyurethanes, and the use thereof as reactive emulsifiers 失效
标题翻译：不饱和聚氨酯，以及作为反应性乳化剂的用途
公开(公告)号：US5391613A
公开(公告)日：1995-02-21
申请号：US205606
申请日：1994-03-03
申请人： Gerhard Brindoepke , Joachim Zoeller
发明人： Gerhard Brindoepke , Joachim Zoeller
IPC分类号： C08F2/24 , B01F17/52 , C08F290/00 , C08F299/06 , C08G18/28 , C08G18/36 , C08G18/48 , C08G18/66 , C08G18/67 , C08J3/03 , C08L75/16 , C09D175/14 , C08G18/04
CPC分类号： C08J3/03 , C08G18/2825 , C08G18/283 , C08G18/284 , C08G18/4833 , C08G18/672
摘要： Unsaturated polyurethanes, and the use thereof as reactive emulsifiersUnsaturated polyurethanes which contain from 20 to 80% by weight of polyethylene glycol units and can be prepared by reactinga) at least one organic polyisocyanate,b) an unsaturated fatty alcohol, a polyalkylene glycol ether thereof or an unsaturated acid ester containing one hydroxyl group,c) one or more diols which additionally contain at least one further hydroxyl group or carboxyl group andd) a polyethylene glycol having a molecular weight in the region of 750 to 10,000, with maintenance of an NCO/OH equivalent ratio, based on all the starting components a) to d), of from 0.7:1 to 1.2:1.These unsaturated polyurethanes are used as reactive emulsifiers for the preparation of dispersions of hydrophobic synthetic resins which can be cured by means of free radicals and/or oxidatively.
摘要翻译：不饱和聚氨酯及其作为反应性乳化剂的用途不饱和聚氨酯，其含有20至80重量％的聚乙二醇单元，可通过使a）至少一种有机多异氰酸酯，b）不饱和脂肪醇，聚亚烷基二醇醚或者含有一个羟基的不饱和酸酯，c）另外含有至少一个其它羟基或羧基的一种或多种二醇，和d）分子量在750〜10,000的范围内的聚乙二醇，维持基于所有起始组分a）至d）的NCO / OH当量比为0.7:1至1.2:1。这些不饱和聚氨酯用作反应性乳化剂，用于制备可通过自由基和/或氧化固化的疏水性合成树脂的分散体。

4. 发明授权

US5693736A Reactive emulsifiers based on unsaturated polyurethanes 失效
标题翻译：基于不饱和聚氨酯的反应性乳化剂
公开(公告)号：US5693736A
公开(公告)日：1997-12-02
申请号：US548723
申请日：1995-10-26
申请人： Joachim Zoeller , Katja Thiergaertner
发明人： Joachim Zoeller , Katja Thiergaertner
IPC分类号： C08F299/06 , B01F17/52 , C08F290/00 , C08G18/00 , C08G18/08 , C08G18/48 , C08G18/65 , C08G18/67 , C08G18/69 , C09D5/02 , C09D167/08 , C09D175/14 , C09D175/16 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C09D5/027 , C08G18/6576 , C08G18/698 , C09D167/08
摘要： Polyurethanes which have olefinic double bonds and a content by mass of ethylene oxide units, incorporated via polyethylene glycol, of from 20 to 80% and which are obtainable by reacting (a) at least one organic polyisocyanate with (b) at least one polybutadiene derivative which is reactive toward isocyanates, and (c) if desired, one or more diols which contain, in addition, at least one further hydroxyl group or carboxyl group, and (d) a polyoxyalkylene glycol component having a molar mass of from 500 to 10,000 g/mol, wherein the ratio of NCO to OH equivalents, based on all the starting components (a) to (d), is from 0.5:1 to 1.2:1. The polyurethanes are useful, for example, as reactive emulsifiers.
摘要翻译：具有20〜80％的具有烯属双键和通过聚乙二醇掺入的环氧乙烷单元含量的聚氨酯，其通过使（a）至少一种有机多异氰酸酯与（b）至少一种聚丁二烯衍生物其对异氰酸酯具有反应性，和（c）如果需要，还含有至少一个其它羟基或羧基的一种或多种二醇，和（d）摩尔质量为500至10,000的聚氧亚烷基二醇组分 g / mol，其中基于所有起始组分（a）至（d），NCO与OH当量的比例为0.5:1至1.2:1。聚氨酯可用作例如反应性乳化剂。

5. 发明授权

US5817712A Self-crosslinking aqueous dispersions of polyesters and vinyl polymers 失效
标题翻译：聚酯和乙烯基聚合物的自交联水分散体
公开(公告)号：US5817712A
公开(公告)日：1998-10-06
申请号：US882081
申请日：1997-06-25
申请人： Manfred Weinberger , Joachim Zoeller
发明人： Manfred Weinberger , Joachim Zoeller
IPC分类号： C08L51/08 , C08F283/02 , C08L57/00 , C08L67/00 , C09D125/14
CPC分类号： C08L67/00 , C08F283/02 , C09D125/14
摘要： Self-crosslinking aqueous polymer dispersions comprising water-thinnable polyesters, vinyl polymers that have either carbonyl or hydrazine functional groups, and a crosslinker having at least two hydrazine or other groups which react with carbonyl groups or crosslinkers having at least two carbonyl groups; and where the vinyl polymer is prepared by free-radical-initiated emulsion polymerization in the presence of an aqueous solution or dispersion of the polyester.
摘要翻译：包含水可稀释聚酯，具有羰基或肼官能团的乙烯基聚合物和具有至少两个与羰基反应的肼或其它基团或具有至少两个羰基的交联剂的交联剂的自交联水性聚合物分散体; 并且其中乙烯基聚合物通过在聚酯的水溶液或分散体的存在下通过自由基引发的乳液聚合制备。

6. 发明授权

US5646236A Polyesters and their use as additives in coating compositions 失效
标题翻译：聚酯及其作为涂料组合物中添加剂的用途
公开(公告)号：US5646236A
公开(公告)日：1997-07-08
申请号：US380662
申请日：1995-01-30
申请人： Markus A. Schafheutle , Achim Voelker , Susanne Wehner , Gerd Walz , Joachim Zoeller
发明人： Markus A. Schafheutle , Achim Voelker , Susanne Wehner , Gerd Walz , Joachim Zoeller
IPC分类号： C08G59/40 , C08G63/16 , C08G63/20 , C08G63/52 , C08G63/60 , C08G63/685 , C08G63/688 , C08G69/44 , C09D5/44 , C09D7/12 , C08G63/44
CPC分类号： C08G63/52 , C08G63/16 , C08G63/20 , C08G63/60 , C08G69/44 , C09D5/4492
摘要： Polyesters obtained by reacting from 5 to 50 parts of at least one linear or branched, aliphatic or cycloaliphatic, at least dihydric alcohol, from 2 to 40 parts of at least one at least dibasic, aromatic carboxylic acid, from 0 to 40 parts of at least one 2-alkenyldicarboxylic anhydride, from 10 to 30 parts of at least one at least dibasic, linear or branched, aliphatic carboxylic acid, from 0 to 15 parts of an aliphatic, linear or branched hydroxy acid, from 0 to 15 parts of an aliphatic, linear or branched polyamine having at least one primary and at least one secondary or tertiary amino group, from 0 to 15 parts of a glycidyl ester of a branched, aliphatic monocarboxylic acid or of a glycidyl ether of a branched, aliphatic alcohol, and from 0 to 15 parts of polyhydroxyamine are useful, for example, as additives in coating compositions.
摘要翻译：通过使5至50份至少一种直链或支链脂肪族或脂环族基团，至少二元醇，2-40份至少一种至少二元芳香族羧酸，0至40份，至少一种2-链烯基二羧酸酐，10-30份至少一种至少二元，直链或支链脂族羧酸，0-15份脂族，直链或支链羟基酸，0至15份具有至少一个伯和至少一个仲或叔氨基的脂族，直链或支链多胺，0至15份支链脂肪族单羧酸缩水甘油酯或支链脂族醇的缩水甘油醚，和 0至15份的多羟基胺可用作例如涂料组合物中的添加剂。

7. 发明授权

US5436312A Aqueous filler composition 失效
标题翻译：水性填料组合物
公开(公告)号：US5436312A
公开(公告)日：1995-07-25
申请号：US306813
申请日：1994-09-15
申请人： Reiner Exner , Michael Schwab , Ute Kuhn , Joachim Zoeller
发明人： Reiner Exner , Michael Schwab , Ute Kuhn , Joachim Zoeller
IPC分类号： C08L67/00 , C08G63/68 , C08G63/688 , C08G63/692 , C09D167/00 , C08G63/00 , C08G63/02
CPC分类号： C08G63/6884 , C08G63/6924 , C09D167/00
摘要： Aqueous filler composition comprising a polyester resin, which is built up of the educts (a), (b), (c), (d) and (e) or their ester-forming derivatives, the sum of the reactants corresponding to 100 mol-% and the ratio of the sum of the hydroxyl equivalents (eg OH) to the sum of the carboxyl equivalents in the reactants being between 0.5 and 2.0, where(a) is at least one dicarboxylic acid which is not a sulfo or phosphorus monomer,(b) is 0 to 15 mol-% of at least one difunctional sulfo or phosphono monomer, the functional groups of which are carboxyl and/or hydroxyl groups, having at least one sulfonate or phosphonate group,(c) is at least one difunctional compound which is derived from a glycol containing two --C(R).sub.2 --OH groups,(d) is up to 40 mol-% of a higher functional compound (functionality >2), the functional groups of which comprise hydroxyl and/or carboxyl groups, and(e) is 0 to 20 mol-% of a monofunctional carboxylic acid,it being possible for the radicals R in (c) independently of one another to be hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.6 -C.sub.10 -aryl, the amounts of free hydroxyl groups being between 30 and 350 milliequivalents OH/100 g, preferably between 100 and 250 meq (OH)/100 g, and the content of free neutralized and/or neutralizable acid groups, in particular sulfonic acid groups, phosphonic acid groups and carboxylic acid groups, being between 5 and 350 meq acid groups/100 g, preferably between 9 and 120 meq acid groups/100 g.
摘要翻译：包含由（a），（b），（c），（d）和（e）衍生物或其酯形成衍生物构成的聚酯树脂的水性填料组合物，相当于100mol - ％，羟基当量（例如OH）之和与反应物中的羧基当量之和的比例在0.5和2.0之间，其中（a）是至少一种不是磺基或磷单体的二羧酸，（b）为0至15摩尔％的至少一种二官能磺基或膦酰基单体，其官能团为羧基和/或羟基，具有至少一个磺酸酯或膦酸酯基团，（c）为至少一种衍生自含有两个-C（R）2 -OH基团的二元醇的二官能化合物，（d）为高达40mol％的高官能化合物（官能度> 2），其官能团包含羟基和/ 或羧基，（e）为0〜20摩尔％的单官能羧酸，（c）中的基团R 彼此之间是氢，C 1 -C 4 - 烷基或C 6 -C 10 - 芳基，游离羟基的量为30-350毫当量OH / 100g，优选为100-250meq（OH）/ 100g，和游离中和和/或可中和的酸基团，特别是磺酸基团，膦酸基团和羧酸基团的含量为5- 350meq酸基团/ 100g，优选9至120meq酸基团/ 100g 。

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