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1. 发明授权

US6166140A Elastomer blend and use in tires 有权
标题翻译：弹性体混合和用于轮胎
公开(公告)号：US6166140A
公开(公告)日：2000-12-26
申请号：US264774
申请日：1999-03-09
申请人： Paul Harry Sandstrom , Edward John Blok , David John Zanzig , Howard Allen Colvin , Michael Leslie Senyek
发明人： Paul Harry Sandstrom , Edward John Blok , David John Zanzig , Howard Allen Colvin , Michael Leslie Senyek
IPC分类号： B29C33/02 , B29C35/02 , B29D30/06 , B29K21/00 , B29K105/24 , B29L30/00 , B60C1/00 , C08F2/22 , C08F236/10 , C08L9/00 , C08L9/06 , C08L9/08 , B29D29/00 , B60C5/00
CPC分类号： C08L9/06 , B29L2030/002 , B60C1/0016 , C08F236/10 , Y10T152/10495 , C08F2/22
摘要： High viscosity elastomers are often difficult to utilize in rubber compositions without first creating a pre-blend of the high viscosity elastomer and a rubber processing oil to reduce their overall viscosity. This invention relates to utilization of a specialized pre-blend of high viscosity and low viscosity elastomers for use in rubber compositions and to the resulting rubber composition. The use of such resulting rubber composition may be for component(s) of tires, particularly including tire treads. The specialized pre-blend of high and low viscosity elastomers is required to be created by blending individual latices or, alternatively, by blending individual polymerizates of elastomers with diverse viscosities.
摘要翻译：高粘度弹性体通常难以在橡胶组合物中使用，而无需先制备高粘度弹性体和橡胶加工油的预混合物以降低其总粘度。本发明涉及使用用于橡胶组合物和所得橡胶组合物的高粘度和低粘度弹性体的专用预混物。使用这种所得橡胶组合物可以用于轮胎的组分，特别是包括轮胎胎面。需要通过混合单个胶乳或者通过混合弹性体的各种聚合物与不同粘度来产生高粘度和低粘度弹性体的专门预混合物。

2. 发明授权

US06232404B1 Elastomer blend and use in tires 有权
标题翻译：弹性体混合和用于轮胎
公开(公告)号：US06232404B1
公开(公告)日：2001-05-15
申请号：US09677620
申请日：2000-10-03
申请人： Paul Harry Sandstrom , Edward John Blok , David John Zanzig , Howard Allen Colvin , Michael Leslie Senyek
发明人： Paul Harry Sandstrom , Edward John Blok , David John Zanzig , Howard Allen Colvin , Michael Leslie Senyek
IPC分类号： B29D2900
CPC分类号： C08L9/06 , B29L2030/002 , B60C1/0016 , C08F236/10 , Y10T152/10495 , C08F2/22
摘要： High viscosity elastomers are often difficult to utilize in rubber compositions without first creating a pre-blend of the high viscosity elastomer and a rubber processing oil to reduce their overall viscosity. This invention relates to utilization of a specialized pre-blend of high viscosity and low viscosity elastomers for use in rubber compositions and to the resulting rubber composition. The use of such resulting rubber composition may be for component(s) of tires, particularly including tire treads. The specialized pre-blend of high and low viscosity elastomers is required to be created by blending individual latices or, alternatively, by blending individual polymerizates of elastomers with diverse viscosities.
摘要翻译：高粘度弹性体通常难以在橡胶组合物中使用，而无需先制备高粘度弹性体和橡胶加工油的预混合物以降低其总粘度。本发明涉及使用用于橡胶组合物和所得橡胶组合物的高粘度和低粘度弹性体的专用预混物。使用这种所得橡胶组合物可以用于轮胎的组分，特别是包括轮胎胎面。需要通过混合单个胶乳或者通过混合弹性体的各种聚合物与不同粘度来产生高粘度和低粘度弹性体的专门预混合物。

3. 发明授权

US06469104B1 Emulsion styrene-butadiene rubber 失效
标题翻译：乳液丁苯橡胶
公开(公告)号：US06469104B1
公开(公告)日：2002-10-22
申请号：US09264937
申请日：1999-03-09
申请人： Howard Allen Colvin , Michael Leslie Senyek
发明人： Howard Allen Colvin , Michael Leslie Senyek
IPC分类号： C08L2502
CPC分类号： C08L9/06 , B29L2030/002 , B60C1/0016 , C08F236/10 , Y02T10/862 , Y10T152/10495 , C08F2/22 , C08L2666/08 , C08F2/38
摘要： This invention discloses an emulsion styrene-butadiene rubber (SBR) that can be employed in manufacturing tire tread formulations that have rolling resistance and treadwear characteristics that are similar to those made with solution SBR but with improved traction characteristics. Thus, the emulsion SBR of this invention is superior in many respects for use in tire tread compounds to conventional solution SBR and conventional emulsion SBR. This invention more specifically discloses a styrene-butadiene rubber composition which is comprised of repeat units which are derived from styrene and 1,3-butadiene, wherein the styrene-butadiene rubber composition has a number average molecular weight as determined by thermal field flow fractionation which is within the range of about 50,000 to 150,000, and wherein the styrene-butadiene rubber has a light scattering to refractive index ratio which is within the range of 1.8 to 3.9. The subject invention further reveals a styrene-butadiene rubber composition which is comprised of repeat units which are derived from styrene and 1,3-butadiene, wherein a plot of log frequency versus storage modulus of the styrene-butadiene rubber composition crosses over a plot of log frequency versus loss modulus of the styrene-butadiene rubber composition at a log frequency within the range of 0.001 radians per second to 100 radians per second when conducted at 120° C. using parallel plate geometry in the dynamic oscillation frequency sweep of the styrene-butadiene rubber.
摘要翻译：本发明公开了一种乳液丁苯橡胶（SBR），其可用于制造具有滚动阻力和胎面特性的轮胎胎面配方，其类似于用溶液SBR制成但具有改进的牵引特性的轮胎胎面制剂。因此，本发明的乳液SBR在许多方面在用于轮胎胎面胶料与常规溶液SBR和常规乳液SBR方面是优异的。本发明更具体地公开了一种苯乙烯 - 丁二烯橡胶组合物，其由衍生自苯乙烯和1,3-丁二烯的重复单元组成，其中所述苯乙烯 - 丁二烯橡胶组合物具有通过热场流分馏确定的数均分子量，在约50,000至150,000的范围内，并且其中所述苯乙烯 - 丁二烯橡胶的光散射与折射率之比在1.8至3.9的范围内。本发明进一步揭示了苯乙烯 - 丁二烯橡胶组合物，其由衍生自苯乙烯和1,3-丁二烯的重复单元组成，其中苯乙烯 - 丁二烯橡胶组合物的对数频率对储能模量的曲线与苯乙烯 - 丁二烯橡胶组合物的对数频率与损耗模量的对数频率在0.001弧度/秒至100弧度/秒的范围内，当在120℃下进行时，使用平行板几何形状在苯乙烯 - 丁二烯橡胶。

4. 发明授权

US06458884B1 Emulsion styrene-butadiene rubber 失效
公开(公告)号：US06458884B1
公开(公告)日：2002-10-01
申请号：US09690555
申请日：2000-10-17
申请人： Howard Allen Colvin , Michael Leslie Senyek
发明人： Howard Allen Colvin , Michael Leslie Senyek
IPC分类号： C08L5300
CPC分类号： C08L9/06 , B29L2030/002 , B60C1/0016 , C08F236/10 , Y02T10/862 , Y10T152/10495 , C08F2/22 , C08L2666/08 , C08F2/38
摘要： This invention discloses an emulsion styrene-butadiene rubber (SBR) that can be employed in manufacturing tire tread formulations that have rolling resistance and treadwear characteristics that are similar to those made with solution SBR but with improved traction characteristics. Thus, the emulsion SBR of this invention is superior in many respects for use in tire tread compounds to conventional solution SBR and conventional emulsion SBR. This invention more specifically discloses a styrene-butadiene rubber composition which is comprised of repeat units which are derived from styrene and 1,3-butadiene, wherein the styrene-butadiene rubber composition has a number average molecular weight as determined by thermal field flow fractionation which is within the range of about 50,000 to 150,000, and wherein the styrene-butadiene rubber has a light scattering to refractive index ratio which is within the range of 1.8 to 3.9. The subject invention further reveals a styrene-butadiene rubber composition which is comprised of repeat units which are derived from styrene and 1,3-butadiene, wherein a plot of log frequency versus storage modulus of the styrene-butadiene rubber composition crosses over a plot of log frequency versus loss modulus of the styrene-butadiene rubber composition at a log frequency within the range of 0.001 radians per second to 100 radians per second when conducted at 120° C. using parallel plate geometry in the dynamic oscillation frequency sweep of the styrene-butadiene rubber.

5. 发明授权

US07342065B2 Preparation of nanocomposite of elastomer and exfoliated clay platelets, rubber compositions comprised of said nanocomposite and articles of manufacture, including tires 失效
标题翻译：制备弹性体和剥离粘土片晶的纳米复合材料，由所述纳米复合材料和制品制成的橡胶组合物，包括轮胎
公开(公告)号：US07342065B2
公开(公告)日：2008-03-11
申请号：US10932534
申请日：2004-09-02
申请人： Xiaoping Yang , Martin Paul Cohen , Michael Leslie Senyek , Dane Kenton Parker , Steven Wayne Cronin , Lewis Timothy Lukich , William Paul Francik , Cigdem Gurer
发明人： Xiaoping Yang , Martin Paul Cohen , Michael Leslie Senyek , Dane Kenton Parker , Steven Wayne Cronin , Lewis Timothy Lukich , William Paul Francik , Cigdem Gurer
IPC分类号： C08K3/34
CPC分类号： C08J3/215 , B60C1/00 , B60C1/0008 , B60C1/0016 , B60C1/0025 , B60C17/0009 , B60C2200/02 , C08J2321/00 , C08K3/346 , C08K9/04 , C08L21/00 , C08L2666/08
摘要： This invention relates to preparation of nanocomposites comprised of elastomer and a dispersion of an at least partially exfoliated water swellable clay and to rubber compositions containing such nanocomposite and articles of manufacture which contain at least one component thereof. The nanocomposite is prepared by addition of a water suspension of water swellable clay particles to an anionic aqueous emulsion of elastomer particles to form a mixture to which an amine having at least two amine centers is added to intercalate and at least partially exfoliate the water swelled clay particles by an ion exchange within the galleries of the multilayered clay with cation exchangeable ion(s) and to aid in coagulating the elastomer and resultant clay particles to form said nanocomposite.
摘要翻译：本发明涉及由弹性体和至少部分剥离的水可溶胀粘土的分散体组成的纳米复合材料，以及含有至少一种组分的纳米复合材料和制品。纳米复合材料通过将水溶胀性粘土颗粒的水悬浮液添加到弹性体颗粒的阴离子水性乳液中而形成混合物，其中加入具有至少两个胺中心的胺以插入并至少部分地去除水溶胀粘土颗粒通过离子交换在具有阳离子可交换离子的多层粘土的画廊内，并且有助于使弹性体和所得粘土颗粒凝结形成所述纳米复合材料。

6. 发明授权

US06369158B1 Dibenzyltrithiocarbonate molecular weight regulator for emulsion polymerization 失效
标题翻译：用于乳液聚合的二苄基二硫代碳酸酯分子量调节剂
公开(公告)号：US06369158B1
公开(公告)日：2002-04-09
申请号：US09470413
申请日：1999-12-22
申请人： Michael Leslie Senyek , Joseph John Kulig , Dane Kenton Parker
发明人： Michael Leslie Senyek , Joseph John Kulig , Dane Kenton Parker
IPC分类号： C08F240
CPC分类号： C08F212/08 , C08F236/10 , C08F2438/03 , C08F2/38
摘要： Mercaptans are normally used as chain transfer agents in emulsion polymerizations. The mercaptans used in commercial applications are typically complex mixtures of hundreds of similar compounds having boiling points within a narrow range. The chain transfer activity of different mercaptans with such mixtures can vary substantially. To further complicate the situation, the distribution of various mercaptans can also vary substantially between lots of material obtained from commercial sources. Thus, consistent molecular weight control is typically difficult to attain in free radical emulsion polymerizations. This invention is based upon the unexpected discovery that dibenzyltrithiocarbonate will act as a pure compound to effectively and consistently control molecular weight in free radical emulsion polymerizations. The polydispersity of polymers made using dibenzyltrithiocarbonate as a molecular weight regulator is similar to that obtained using conventional mercaptan systems. This invention more specifically discloses a process for controlling the molecular weight of a polymer synthesized by free radical emulsion polymerization that comprises polymerizing at least one monomer by free radical polymerization in an aqueous emulsion in the presence of dibenzyltrithiocarbonate. For instance, dibenzyltrithiocarbonate can be used as a molecular weight regulator in the synthesis of styrene-butadiene rubber by emulsion polymerization. Accordingly, this invention further discloses a process for synthesizing styrene-butadiene rubber (SBR) that comprises copolymerizing styrene monomer and 1,3-butadiene monomer by free radical polymerization in an aqueous emulsion in the presence of dibenzyltrithiocarbonate. The use of dibenzyltrithiocarbonate is inherently less odorous than the use of mercaptans.
摘要翻译：硫醇通常用作乳液聚合中的链转移剂。在商业应用中使用的硫醇通常是沸点在几个范围内的数百种类似化合物的复杂混合物。具有这种混合物的不同硫醇的链转移活性可以显着变化。为了进一步使情况复杂化，各种硫醇的分布也可以在从商业来源获得的许多材料之间显着变化。因此，在自由基乳液聚合中通常难以获得一致的分子量控制。本发明基于意想不到的发现，即二苄基三硫代碳酸酯将用作纯化合物以有效且一致地控制自由基乳液聚合中的分子量。使用二苄基三硫代碳酸酯作为分子量调节剂制备的聚合物的多分散性与使用常规硫醇体系获得的聚合物相似。本发明更具体地公开了一种控制通过自由基乳液聚合合成的聚合物的分子量的方法，该方法包括在二苄基三硫代碳酸酯的存在下，在水乳液中通过自由基聚合使至少一种单体聚合。例如，二苄基三硫代碳酸酯可以用作通过乳液聚合合成苯乙烯 - 丁二烯橡胶中的分子量调节剂。因此，本发明还公开了一种合成苯乙烯 - 丁二烯橡胶（SBR）的方法，其包括在二苄基三硫代碳酸酯存在下，在水性乳液中通过自由基聚合共聚苯乙烯单体和1,3-丁二烯单体。使用二苄基三硫代碳酸酯本身不如使用硫醇少。

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