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1. 发明授权

US07049270B2 Potassium glyphosate formulations 有权
标题翻译：草甘膦制剂
公开(公告)号：US07049270B2
公开(公告)日：2006-05-23
申请号：US09926521
申请日：2001-05-21
申请人： Patrick J. Lennon , Xiangyang Chen , Graciela B. Arhancet , Jeanette A. Glaenzer , Jane L. Gillespie , Jeffrey A. Graham , David Z. Becher , Daniel R. Wright , Henry E. Agbaje , Xiaodong C. Xu , William Abraham , Ronald J. Brinker , Norman R. Pallas , Al S. Wideman , Martin D. Mahoney , Susan L. Henke
发明人： Patrick J. Lennon , Xiangyang Chen , Graciela B. Arhancet , Jeanette A. Glaenzer , Jane L. Gillespie , Jeffrey A. Graham , David Z. Becher , Daniel R. Wright , Henry E. Agbaje , Xiaodong C. Xu , William Abraham , Ronald J. Brinker , Norman R. Pallas , Al S. Wideman , Martin D. Mahoney , Susan L. Henke
IPC分类号： A01N25/00 , A01N57/02
CPC分类号： A01N61/00 , A01N25/30 , A01N37/04 , A01N57/20 , A01N2300/00
摘要： A herbicidal composition is provided comprising an aqueous solution of N-phosphonomethylglycine, predominantly in the form of the potassium salt thereof, at a concentration of at least 300 g a.e./l of the composition; and a surfactant component in solution or stable suspension, emulsion, or dispersion in the water, comprising one or more surfactants in a total amount of about 20 to about 300 g/l of the composition, wherein the composition has a viscosity of less than about 250 centipoise at 0° C. or a Gardner color value less than 10.
摘要翻译：提供除草组合物，其包含主要以其钾盐形式的N-膦酰基甲基甘氨酸的水溶液，其浓度为组合物的至少300g a.e./l; 和在水中的溶液或稳定悬浮液，乳液或分散体中的表面活性剂组分，其包含总量为组合物总量约20至约300g / l的一种或多种表面活性剂，其中所述组合物的粘度小于约在0°C时250厘泊或加德纳颜色值小于10。

2. 发明授权

US10736325B2 Surfactants and formulations 有权
公开(公告)号：US10736325B2
公开(公告)日：2020-08-11
申请号：US12698636
申请日：2010-02-02
申请人： Patrick J. Lennon , Xiangyang Chen , Graciela B. Arhancet , Jeanette A. Glaenzer , Jane L. Gillespie , Jeffrey A. Graham , David Z. Becher , Daniel R. Wright , Henry E. Agbaje , Xiaodong C. Xu , William Abraham , Ronald J. Brinker , Norman R. Pallas , Al S. Wideman , Martin D. Mahoney , Susan L. Henke
发明人： Patrick J. Lennon , Xiangyang Chen , Graciela B. Arhancet , Jeanette A. Glaenzer , Jane L. Gillespie , Jeffrey A. Graham , David Z. Becher , Daniel R. Wright , Henry E. Agbaje , Xiaodong C. Xu , William Abraham , Ronald J. Brinker , Norman R. Pallas , Al S. Wideman , Martin D. Mahoney , Susan L. Henke
IPC分类号： A01N61/00 , A01N25/30 , A01N37/04 , A01N57/20
摘要： A herbicidal composition is provided comprising an aqueous solution of N-phosphonomethylglycine, predominantly in the form of the potassium salt thereof, at a concentration of at least 300 g a.e./l of the composition; and a surfactant component in solution or stable suspension, emulsion, or dispersion in the water, comprising one or more surfactants in a total amount of about 20 to about 300 g/l of the composition, wherein the composition has a viscosity of less than about 250 centipoise at 0° C. or a Gardner color value less than 10.

3. 发明申请

US20100234228A1 NOVEL SURFACTANTS AND FORMULATIONS 审中-公开
标题翻译：新型表面活性剂和配方
公开(公告)号：US20100234228A1
公开(公告)日：2010-09-16
申请号：US12698636
申请日：2010-02-02
申请人： Patrick J. Lennon , Xiangyang Chen , Graciela Arhancet , Jeanette A. Glaenzer , Jane L. Gillespie , Jeffrey A. Graham , David Z. Becher , Daniel R. Wright , Henry E. Agbaje , Xiaodong C. Xu , William Abraham , Ronald J. Brinker , Norman R. Pallas , Al S. Wideman , Martin D. Mahoney , Susan L. Henke
发明人： Patrick J. Lennon , Xiangyang Chen , Graciela Arhancet , Jeanette A. Glaenzer , Jane L. Gillespie , Jeffrey A. Graham , David Z. Becher , Daniel R. Wright , Henry E. Agbaje , Xiaodong C. Xu , William Abraham , Ronald J. Brinker , Norman R. Pallas , Al S. Wideman , Martin D. Mahoney , Susan L. Henke
IPC分类号： A01N57/20 , A01P13/00
CPC分类号： A01N61/00 , A01N25/30 , A01N37/04 , A01N57/20 , A01N2300/00
摘要： A herbicidal composition is provided comprising an aqueous solution of N-phosphonomethylglycine, predominantly in the form of the potassium salt thereof, at a concentration of at least 300 g a.e./l of the composition; and a surfactant component in solution or stable suspension, emulsion, or dispersion in the water, comprising one or more surfactants in a total amount of about 20 to about 300 g/l of the composition, wherein the composition has a viscosity of less than about 250 centipoise at 0° C. or a Gardner color value less than 10.
摘要翻译：提供除草组合物，其包含主要以其钾盐形式的N-膦酰基甲基甘氨酸的水溶液，其浓度为组合物的至少300g a.e./l; 和在水中的溶液或稳定悬浮液，乳液或分散体中的表面活性剂组分，其包含总量为组合物总量约20至约300g / l的一种或多种表面活性剂，其中所述组合物的粘度小于约在0°C时250厘泊或加德纳颜色值小于10。

4. 发明授权

US06172004B2 Composition and method for treating plants with exogenous chemicals 失效
标题翻译：用外源化学品处理植物的组成和方法
公开(公告)号：US06172004B2
公开(公告)日：2001-01-09
申请号：US09016101
申请日：1998-01-30
申请人： Ronald J. Brinker , Jane L. Gillespie , Peter J. Raymond , Joseph J. Sandbrink , James M. Warner , Al S. Wideman , Daniel R. Wright
发明人： Ronald J. Brinker , Jane L. Gillespie , Peter J. Raymond , Joseph J. Sandbrink , James M. Warner , Al S. Wideman , Daniel R. Wright
IPC分类号： A01N3506
CPC分类号： A01N47/24 , A01N25/28 , A01N25/30 , A01N33/22 , A01N35/06 , A01N37/22 , A01N37/40 , A01N39/04 , A01N41/04 , A01N43/40 , A01N43/50 , A01N47/36 , A01N57/20 , A01N2300/00 , A01N61/00 , A01N37/48 , A01N37/38 , A01N37/34 , A01N37/28 , A01N37/20 , A01N37/10 , A01N37/02 , A01N35/02 , A01N31/04
摘要： Compositions of exogenous chemicals, particularly phloem-mobile exogenous chemicals, are provided for treatment of plants, wherein the composition comprises the exogenous chemical and an enhancing agent consisting of an anthraquinone or substituted anthraquinone. Specific compositions contain herbicides, particularly N-phosphonomethylglycine and herbicidal derivatives thereof, i.e., glyphosate. The compositions exhibit enhanced effectiveness compared to compositions in which the enhancing agent is not present. Also provided are processes for applying an exogenous chemical with an anthraquinone or substituted anthraquinone enhancing agent to achieve enhanced biological effectiveness.
摘要翻译：提供外源化学品的组合物，特别是韧皮部移动的外源性化学品，用于处理植物，其中组合物包含外源化学品和由蒽醌或取代的蒽醌组成的增强剂。特定组合物含有除草剂，特别是N-膦酰甲基甘氨酸及其除草衍生物，即草甘膦。与不存在增强剂的组合物相比，组合物表现出增强的效果。还提供了用蒽醌或取代的蒽醌增强剂施用外源化学品以实现增强的生物学效力的方法。

5. 再颁专利

USRE37866E1 Glyphosate formulations containing etheramine surfactants 有权
标题翻译：含有醚胺表面活性剂的草甘膦制剂
公开(公告)号：USRE37866E1
公开(公告)日：2002-10-01
申请号：US09569800
申请日：2000-05-12
申请人： Daniel R. Wright , Ronald J. Brinker , Joseph J. Sandbrink , Al S. Wideman
发明人： Daniel R. Wright , Ronald J. Brinker , Joseph J. Sandbrink , Al S. Wideman
IPC分类号： A01N5702
CPC分类号： A01N57/20 , A01N25/30 , A01N2300/00
摘要： Herbicidal compositions are provided comprising glyphosate or a salt thereof and an etheramine surfactant having the representative chemical structure (a) wherein R1 is a straight or branched chain C6 to about C22 alkyl, aryl or alkylaryl group, m is an average number from 1 to about 10, R2 in each of the m (O—R2) groups is independently C1-C4 alkylene, R3 groups are independently C1-C4 alkylene, and x and y are average numbers such that x+y is in the range from 2 to about 60; or (b) wherein R1 is a straight or branched chain C6 to about C22 alkyl, aryl or alkylaryl group, m is an average number from 1 to about 10, R2 in each of the m (O—R2) groups is independently C1-C4 alkylene, R3 groups are independently C1-C4 alkylene, R4 is C1-C4 alkyl, x and y are average numbers such that x+y is in the range from 0 to about 60, and A− is an agriculturally acceptable anion; or (c) wherein R1 is a straight or branched chain C6 to about C22 alkyl, aryl or alkylaryl group, m is an average number from 1 to about 10, R2 is each of the m (O—R2) groups is independently C1-C4 alkylene, R3 groups are independently C1-C4 alkylene, and x and y are average numbers such that x+y is in the range from 2 to about 60.
摘要翻译：提供除草组合物，其包含草甘膦或其盐和具有代表性化学结构（a）的醚胺表面活性剂，其中R 1是直链或支链C 6至C 22烷基，芳基或烷芳基，m是1至约 10，各个m（O-R 2）基团中的R 2独立地为C 1 -C 4亚烷基，R 3基团独立地为C 1 -C 4亚烷基，x和y为平均数，使得x + y在2至约 60; 或（b）其中R1是直链或支链C6至约C22烷基，芳基或烷基芳基，m是1至约10的平均数，m（O-R2）基团中的每个独立地为C1- C4亚烷基，R3基团独立地为C1-C4亚烷基，R4为C1-C4烷基，x和y为x + y为0至约60的平均数，A-为农业上可接受的阴离子; 或（c）其中R 1是直链或支链C 6至C 22烷基，芳基或烷基芳基，m是1至约10的平均数，R 2各自为m（O-R 2）基团， C4亚烷基，R3基团独立地为C1-C4亚烷基，x和y为平均数，使得x + y在2至约60的范围内。

6. 发明授权

US5750468A Glyphosate formulations containing etheramine surfactants 失效
标题翻译：含有醚胺表面活性剂的草甘膦制剂
公开(公告)号：US5750468A
公开(公告)日：1998-05-12
申请号：US599363
申请日：1996-03-15
申请人： Daniel R. Wright , Ronald J. Brinker , Joseph J. Sandbrink , Al S. Wideman
发明人： Daniel R. Wright , Ronald J. Brinker , Joseph J. Sandbrink , Al S. Wideman
IPC分类号： A01N57/20 , A01N25/30 , A01N57/02
CPC分类号： A01N57/20
摘要： Herbicidal compositions are provided comprising glyphosate or a salt thereof and an etheramine surfactant having the representative chemical structure (a) ##STR1## wherein R.sub.1 is a straight or branched chain C.sub.6 to about C.sub.22 alkyl, aryl or alkylaryl group, m is an average number from 1 to about 10, R.sub.2 in each of the m (O--R.sub.2) groups is independently C.sub.1 -C.sub.4 alkylene, R.sub.3 groups are independently C.sub.1 -C.sub.4 alkylene, and x and y are average numbers such that x+y is in the range from 2 to about 60; or (b) ##STR2## wherein R.sub.1 is a straight or branched chain C.sub.6 to about C.sub.22 alkyl, aryl or alkylaryl group, m is an average number from 1 to about 10, R.sub.2 in each of the m (O--R.sub.2) groups is independently C.sub.1 -C.sub.4 alkylene, R.sub.3 groups are independently C.sub.1 -C.sub.4 alkylene, R.sub.4 is C.sub.1 -C.sub.4 alkyl, x and y are average numbers such that x+y is in the range from 0 to about 60, and A.sup.- is an agriculturally acceptable anion; or (c) ##STR3## wherein R.sub.1 is a straight or branched chain C.sub.6 to about C.sub.22 alkyl, aryl or alkylaryl group, m is an average number from 1 to about 10, R.sub.2 in each of the m (O--R.sub.2) groups is independently C.sub.1 -C.sub.4 alkylene, R.sub.3 groups are independently C.sub.1 -C.sub.4 alkylene, and x and y are average numbers such that x+y is in the range from 2 to about 60.
摘要翻译：提供了除草组合物，其包含草甘膦或其盐和具有代表性化学结构的（a）的醚胺表面活性剂，其中R 1是直链或支链C 6至C 22烷基，芳基或烷芳基，m是 1至约10个，m（O-R 2）基团中的R 2独立地为C 1 -C 4亚烷基，R 3基团独立地为C 1 -C 4亚烷基，x和y为平均数，使得x + y在 2到约60; 或（b）链C6至约C22烷基，芳基或烷基芳基，m为1至约10的平均数，m（O-R 2）基团中的每个独立地为C 1 -C 4亚烷基，R 3基团独立地为 C1-C4亚烷基，R4是C1-C4烷基，x和y是平均数，使得x + y在0至约60的范围内，A-是农业上可接受的阴离子; 或（c）其中R 1是直链或支链C 6至C 22烷基，芳基或烷基芳基，m是1至约10的平均数，m（O-R 2）基团中的每个为独立地，C 1 -C 4亚烷基，R 3基团独立地是C 1 -C 4亚烷基，x和y是平均数，使得x + y在2至约60的范围内。

7. 发明授权

US06908882B1 Enhanced method of killing weeds with glyphosate herbicide 有权
标题翻译：用草甘膦除草剂杀死杂草的增强方法
公开(公告)号：US06908882B1
公开(公告)日：2005-06-21
申请号：US09652771
申请日：2000-08-31
申请人： David Z. Becher , Al S. Wideman , James C. Forbes
发明人： David Z. Becher , Al S. Wideman , James C. Forbes
IPC分类号： A01N25/00 , A01N25/30 , A01N37/20 , A01N57/20 , A01N3/02 , A01N57/00
CPC分类号： A01N57/20 , A01N25/30 , A01N2300/00
摘要： A method is provided of enhancing the herbicidal activity of a glyphosate herbicide, comprising adding to the glyphosate herbicide a mixture of a first surfactant and a second surfactant at a weight ratio of total surfactant to glyphosate of about 1:30 to about 2:1, wherein the first surfactant has a chemical structure comprising a cationic or protonatable amino group and a C8-24 linear or branched, saturated or unsaturated hydrocarbyl group, and the second surfactant has the formula R—CO—NR′—(CR′2)n—COOM where R is a C7-23 linear or branched, saturated or unsaturated hydrocarbyl group, n is 1 to 4, M is hydrogen or a cationic counterion, and R′ groups are each independently hydrogen, C1-4 alkyl or a group —(CH2)m—COOM where m is 1 to 4 and M is as defined immediately above, with the proviso that no more than one R′ group is such a group —(CH2)m—COOM; the weight ratio of the first to the second surfactant being about 1:10 to about 10:1. Also provided is a herbicidal composition prepared according to the above method. The first and second surfactants exhibit a synergistic interaction in enhancing herbicidal activity of the glyphosate herbicide.
摘要翻译：提供了提高草甘膦除草剂除草活性的方法，其包括以总表面活性剂与草甘膦的重量比为1:30至约2:1，向草甘膦除草剂中加入第一表面活性剂和第二表面活性剂的混合物，其中所述第一表面活性剂具有包含阳离子或可质子化氨基和C 8-24直链或支链饱和或不饱和烃基的化学结构，并且所述第二表面活性剂具有式 -formulae description =“In-line Formulas”end =“lead”？> R-CO-NR' - （CR'2 n）-COOM < line-formula description =“In-line Formulas”end =“tail”？>其中R是直链或支链饱和或不饱和烃基，n为1至4，M 是氢或阳离子抗衡离子，R'基团各自独立地为氢，C 1-4烷基或基团 - （CH 2 CH 2）m > -COOM，其中m为1至4，M如上所定义 iso，不超过一个R'基团是这样的基团 - （CH 2 CH 2）m -COOM; 第一和第二表面活性剂的重量比为约1:10至约10:1。还提供了根据上述方法制备的除草组合物。第一和第二表面活性剂在增强草甘膦除草剂的除草活性方面表现出协同相互作用。

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