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1. 发明申请

US20050189261A1 Process for desulfurization without consumption of hydrogen 审中-公开
标题翻译：无需消耗氢气的脱硫方法
公开(公告)号：US20050189261A1
公开(公告)日：2005-09-01
申请号：US10662817
申请日：2003-09-16
申请人： Patrick Briot , Alain Forestiere , Thierry Chapus , Frederic Morel , Eric Llido
发明人： Patrick Briot , Alain Forestiere , Thierry Chapus , Frederic Morel , Eric Llido
IPC分类号： C10G27/12 , C10G53/14 , C10G27/04 , C10G29/16
CPC分类号： C10G53/14 , C10G27/12
摘要： The desulfurization of a hydrocarbon-containing fraction, e.g. kerosene or gas oil that comprises at least one stage of treatment of said fraction with an oxidizing agent in the presence of a catalyst of said oxidation, in which said catalyst comprises at least one oxide of chemical formula MxOy, whereby M is an element that is selected from the group that consists of the elements of groups IV-B, V-B or VI-B of the periodic table.
摘要翻译：含烃馏分的脱硫，例如煤油或瓦斯油，其包括在所述氧化催化剂存在下用氧化剂处理所述馏分的至少一个阶段，其中所述催化剂包含至少一种化学式M x O y的氧化物，其中M是选自由周期表第IV-B，VB或VI-B族的元素组成的组。

2. 发明授权

US6117306A Catalytic process for conversion of a petroleum residue using a fixed bed hydrodemetallization catalyst 失效
标题翻译：使用固定床加氢脱金属催化剂转化石油残渣的催化方法
公开(公告)号：US6117306A
公开(公告)日：2000-09-12
申请号：US942051
申请日：1997-10-01
申请人： Frederic Morel , Jean-Luc Duplan , Thierry Chapus , Alain Billon , Stephane Kressmann , Gerard Heinrich
发明人： Frederic Morel , Jean-Luc Duplan , Thierry Chapus , Alain Billon , Stephane Kressmann , Gerard Heinrich
IPC分类号： C10G69/04 , C10G45/00
CPC分类号： C10G69/04 , Y10S208/95
摘要： A process for converting a heavy hydrocarbon fraction comprises treating the hydrocarbon feed in a hydrodemetallization section, the section containing at least one fixed bed hydrodemetallization catalyst. At least a portion of the hydrotreated liquid effluent from step a) is sent to an atmospheric distillation zone from which a distillate and an atmospheric residue are recovered; at least a portion of the atmospheric residue is sent to a vacuum distillation zone from which a vacuum distillate and a vacuum residue are recovered; at least a portion of the vacuum residue is sent to a deasphalting section from which a deasphalted hydrocarbon cut and residual asphalt are recovered; at least a portion of the deasphalted hydrocarbon cut is sent to a hydrotreatment section from which a gas fraction, a fuel fraction and a heavier liquid fraction of the hydrotreated feed are recovered, and at least a portion of the heavier liquid fraction of the hydrotreated feed is sent to a catalytic cracking section in which it is treated under conditions such that a gaseous fraction, a gasoline fraction, a gas oil fraction and a slurry fraction are produced.
摘要翻译：用于转化重质烃馏分的方法包括在加氢脱金属部分中处理烃进料，所述部分含有至少一个固定床加氢脱金属催化剂。将来自步骤a）的加氢处理的液体流出物的至少一部分送至常压蒸馏区，回收馏出物和大气残留物; 将至少一部分大气残留物送至减压蒸馏区，从真空蒸馏区回收真空馏分和真空残渣; 将至少一部分真空残渣送至脱沥青部分，从其中回收脱沥青烃馏分和残余沥青; 将脱沥青烃馏分的至少一部分送到加氢处理部分，加氢处理的进料的气体馏分，燃料馏分和较重液体馏分从该加氢处理部分回收，加氢处理的进料的至少一部分较重液体馏分被送到催化裂化部分，其中在气态馏分，汽油馏分，粗柴油馏分和淤浆馏分产生的条件下进行处理。

3. 发明授权

US6017441A Multi-step catalytic process for conversion of a heavy hydrocarbon fraction 失效
$Multi-step catalytic process for conversion of a heavy hydrocarbon fraction$
标题翻译：用于转化重质烃馏分的多步催化方法
公开(公告)号：US6017441A
公开(公告)日：2000-01-25
申请号：US942047
申请日：1997-10-01
申请人： Frederic Morel , Gerard Heinrich , Stephane Kressmann , Alain Billon , Jean-Luc Duplan , Thierry Chapus
发明人： Frederic Morel , Gerard Heinrich , Stephane Kressmann , Alain Billon , Jean-Luc Duplan , Thierry Chapus
IPC分类号： C10G67/04 , C10G69/04 , C10G21/00
CPC分类号： C10G67/0454 , C10G69/04
摘要： A process for converting a heavy hydrocarbon fraction comprises treating the hydrocarbon feed in a hydroconversion section in the presence of hydrogen, the section comprising at least one three-phase reactor containing at least one ebullated bed hydroconversion catalyst, operating in liquid and gas riser mode, said reactor comprising at least one means for removing catalyst from said reactor and at least one means for adding fresh catalyst to said reactor. At least a portion of the hydroconverted liquid effluent is sent to an atmospheric distillation zone from which a distillate and an atmospheric residue are recovered; at least a portion of the atmospheric residue is sent to a vacuum distillation zone from which a vacuum distillate and a vacuum residue are recovered; at least a portion of the vacuum residue is sent to a deasphalting section from which a deasphalted hydrocarbon cut and residual asphalt are recovered; and at least a portion of the deasphalted hydrocarbon cut is sent to a hydrotreatment section from which a gas fraction, an atmospheric distillate and a heavier liquid fraction of the hydrotreated feed are recovered by atmospheric distillation separation, said section comprising at least one three-phase reactor containing at least one ebullated bed hvdroconversion catalyst operating in liquid and gas riser mode, the reactor comprising at least one means for extracting catalyst from the reactor and at least one means for adding fresh catalyst to the reactor.
摘要翻译：用于转化重质烃馏分的方法包括在氢的存在下在加氢转化段中处理烃进料，该部分包含至少一个含有至少一个沸腾床加氢转化催化剂的三相反应器，其以液体和气体提升管模式运行，所述反应器包括至少一种用于从所述反应器除去催化剂的装置和用于将新鲜催化剂加入到所述反应器中的至少一种装置。将至少一部分加氢转化的液体流出物送入常压蒸馏区，回收馏出物和大气残留物; 将至少一部分大气残留物送至减压蒸馏区，从真空蒸馏区回收真空蒸馏物和真空残渣; 将至少一部分真空残渣送至脱沥青部分，从其中回收脱沥青烃馏分和残余沥青; 并且至少一部分脱沥青烃切割被送到加氢处理部分，通过常压蒸馏分离回收加氢处理的进料的气体馏分，常压馏出物和较重的液体馏分，所述部分包含至少一个三相反应器包含至少一种以液体和气体提升管模式运行的沸腾床转化催化剂，该反应器包括至少一种用于从反应器中提取催化剂的装置和至少一种用于向反应器中加入新鲜催化剂的装置。

4. 发明授权

US6007703A Multi-step process for conversion of a petroleum residue 失效
标题翻译：用于转化石油残渣的多步法
公开(公告)号：US6007703A
公开(公告)日：1999-12-28
申请号：US942901
申请日：1997-10-01
申请人： Frederic Morel , Stephane Kressmann , Jean-Luc Duplan , Alain Billon , Thierry Chapus , Gerard Heinrich
发明人： Frederic Morel , Stephane Kressmann , Jean-Luc Duplan , Alain Billon , Thierry Chapus , Gerard Heinrich
IPC分类号： C10G67/04 , C10G69/04 , C10G45/00
CPC分类号： C10G69/04 , C10G67/0454
摘要： A process for converting a heavy hydrocarbon fraction comprises treating the hydrocarbon feed in a hydrodemetallization section, the section comprising at least one fixed bed hydrodemetallization catalyst. At least a portion of the hydrotreated liquid effluent from step a) is sent to an atmospheric distillation zone from which a distillate and an atmospheric residue are recovered; at least a portion of the atmospheric residue is sent to a vacuum distillation zone from which a vacuum distillate and a vacuum residue are recovered; at least a portion of the vacuum residue is sent to a deasphalting section from which a deasphalted hydrocarbon cut and residual asphalt are recovered; and at least a portion of the deasphalted hydrocarbon cut is sent to a hydrotreatment section from which a gas fraction, a fuel fraction and a heavier liquid fraction of the hydrotreated feed are recovered, said section comprising at least one three-phase reactor containing at least one ebullated bed hydrotreatment catalyst operating in liquid and gas riser mode, the reactor comprising at least one means for removing catalyst from the reactor and at least one means for adding fresh catalyst to the reactor.
摘要翻译：用于转化重质烃馏分的方法包括在加氢脱金属部分中处理烃进料，该部分包含至少一个固定床加氢脱金属催化剂。将来自步骤a）的加氢处理的液体流出物的至少一部分送至常压蒸馏区，回收馏出物和大气残留物; 将至少一部分大气残留物送至减压蒸馏区，从真空蒸馏区回收真空馏分和真空残渣; 将至少一部分真空残渣送至脱沥青部分，从其中回收脱沥青烃馏分和残余沥青; 并且至少一部分脱沥青烃切割被送到加氢处理部分，从该馏分回收加氢处理的进料的气体馏分，燃料馏分和较重的液体馏分，所述部分包含至少一个至少包含一个三相反应器一种以液体和气体提升管模式运行的沸腾床加氢处理催化剂，该反应器包括至少一种用于从反应器中除去催化剂的装置和至少一种用于向反应器中加入新鲜催化剂的装置。

5. 发明授权

US5980730A Process for converting a heavy hydrocarbon fraction using an ebullated bed hydrodemetallization catalyst 失效
$Process for converting a heavy hydrocarbon fraction using an ebullated bed hydrodemetallization catalyst$
标题翻译：使用沸腾床加氢脱金属催化剂转化重质烃馏分的方法
公开(公告)号：US5980730A
公开(公告)日：1999-11-09
申请号：US942547
申请日：1997-10-01
申请人： Frederic Morel , Thierry Chapus , Stephane Kressman , Jean-Luc Duplan , Alain Billon , Gerard Heinrich
发明人： Frederic Morel , Thierry Chapus , Stephane Kressman , Jean-Luc Duplan , Alain Billon , Gerard Heinrich
IPC分类号： C10G67/04 , C10G69/04 , C10G21/00
CPC分类号： C10G69/04 , C10G67/0454
摘要： A process for converting a heavy hydrocarbon fraction comprises treating the hydrocarbon feed in a hydroconversion section in the presence of hydrogen, the section comprising at least one three-phase reactor containing at least one ebullated bed hydroconversion catalyst, operating in liquid and gas riser mode, said reactor comprising at least one means for removing catalyst from said reactor and at least one means for adding fresh catalyst to said reactor. At least a portion of the hydroconverted liquid effluent is sent to an atmospheric distillation zone from which a distillate and an atmospheric residue are recovered; at least a portion of the atmospheric residue is sent to a vacuum distillation zone from which a vacuum distillate and a vacuum residue are recovered; at least a portion of the vacuum residue is sent to a deasphalting section from which a deasphalted hydrocarbon cut and residual asphalt are recovered; and at least a portion of the deasphalted hydrocarbon cut is sent to a hydrotreatment section from which a gas fraction, an atmospheric distillate and a heavier liquid fraction of the hydrotreated feed are produced by atmospheric distillation separation.
摘要翻译：用于转化重质烃馏分的方法包括在氢的存在下在加氢转化段中处理烃进料，该部分包含至少一个含有至少一种沸腾床加氢转化催化剂的三相反应器，其以液体和气体提升管模式运行，所述反应器包括至少一种用于从所述反应器除去催化剂的装置和用于将新鲜催化剂加入到所述反应器中的至少一种装置。将至少一部分加氢转化的液体流出物送入常压蒸馏区，回收馏出物和大气残留物; 将至少一部分大气残留物送至减压蒸馏区，从真空蒸馏区回收真空馏分和真空残渣; 将至少一部分真空残渣送至脱沥青部分，从其中回收脱沥青烃馏分和残余沥青; 并将至少一部分脱沥青烃切割物送到加氢处理部分，通过常压蒸馏分离从该馏分产生加氢处理的进料的气体馏分，常压馏出物和较重液体馏分。

6. 发明授权

US6153087A Process for converting heavy crude oil fractions, comprising an ebullating bed conversion step and a hydrocracking step 失效
$Process for converting heavy crude oil fractions, comprising an ebullating bed conversion step and a hydrocracking step$
标题翻译：用于转化重质原油馏分的方法，包括沸腾床转化步骤和加氢裂化步骤
公开(公告)号：US6153087A
公开(公告)日：2000-11-28
申请号：US103526
申请日：1998-06-24
申请人： Pierre-Henri Bigeard , Frederic Morel , Christophe Gueret , Patrick Briot , Pierre Marion
发明人： Pierre-Henri Bigeard , Frederic Morel , Christophe Gueret , Patrick Briot , Pierre Marion
IPC分类号： C10G65/12 , C10G69/02
CPC分类号： C10G65/12
摘要： A process for converting a hydrocarbon fraction comprises a step a) for treating a hydrocarbon feed in the presence of hydrogen in at least one three-phase reactor, containing at least one hydrotreatment catalyst in an ebullating bed, operating in riser mode of liquid and of gas, the reactor comprising at least one means located close to the bottom of the reactor for extracting catalyst from the reactor and at least one means located close to the top of the reactor for adding fresh catalyst to the reactor, a step b) for treating at least a portion of the effluent from step a) in the presence of hydrogen in at least one reactor containing at least one hydrocracking catalyst in a fixed bed under conditions for producing an effluent with a reduced sulphur content, and a step c) in which at least a portion of the product from step b) is sent to a distillation zone from which a gaseous fraction, a gasoline type engine fuel fraction, a diesel type engine fuel fraction and a liquid fraction which is heavier than the diesel type fraction are recovered. The process can also comprise a step d) for catalytic cracking of the heavy fraction obtained from step c).
摘要翻译：用于转化烃馏分的方法包括步骤a），用于在至少一个三相反应器中在氢气存在下处理烃进料，所述三相反应器在沸腾床中含有至少一种加氢处理催化剂，以液体的立管模式运行，气体，反应器包括靠近反应器底部的至少一个装置，用于从反应器中提取催化剂和位于反应器顶部附近的至少一个装置，用于向反应器中加入新鲜的催化剂; b）用于处理在步骤a）的至少一部分流出物在至少一个包含至少一个加氢裂化催化剂的反应器中的反应器中，在固定床中，用于生产具有降低的硫含量的流出物的条件下，步骤c），其中将来自步骤b）的产物的至少一部分送至蒸馏区，从该蒸馏区中将气态馏分，汽油型发动机燃料馏分，柴油型发动机燃料馏分和液体馏分w 比重柴油型馏分回收重。该方法还可以包括步骤d）用于从步骤c）获得的重馏分的催化裂化。

7. 发明授权

US5925234A Process for the production of an internal combustion engine fuel base by hydrotreatment and extraction, and the product therefrom 失效
标题翻译：通过加氢处理和提取生产内燃机燃料基料的方法及其产品
公开(公告)号：US5925234A
公开(公告)日：1999-07-20
申请号：US747739
申请日：1996-11-12
申请人： Frederic Morel , Massimo Zuliani , Paul Mikitenko , Marc Boulet , Roben Loutaty , Jean Claude Company
发明人： Frederic Morel , Massimo Zuliani , Paul Mikitenko , Marc Boulet , Roben Loutaty , Jean Claude Company
IPC分类号： C10G67/00 , C10G67/04
CPC分类号： C10G67/0418 , C10G67/00 , C10G67/04 , C10G2400/04
摘要： The invention concerns a petroleum product and a process for the production of a petroleum product which can form part of a blend for an internal combustion engine fuel, the process comprisinga) hydrotreating a hydrocarbon feedstock at a partial pressure of hydrogen at the reactor outlet of about 0.5 MPa to about 6 MPa,b) separating a product (P) from step a) into a product (P1) with a final boiling point of about 300.degree. C. and a product (P2) with an initial boiling point greater than the final boiling point of product (P1),c) performing a liquid-liquid extraction with a solvent (S1), to produce an extract (E1) and a raffinate (R1) from product (P2),d) recovering solvent (S1) from raffinate (R1) to produce a product (Q1), depleted in solvent (S1), which has improved qualities and contains less than 500 ppm by weight of sulphur.
摘要翻译：本发明涉及石油产品和石油产品的生产方法，该石油产品可以形成内燃机燃料的共混物的一部分，该方法包括：a）在氢的分压下在烃的反应器出口的氢气的加压处理约0.5MPa至约6MPa，b）将步骤a）中的产物（P）分离成终沸点约300℃的产物（P1）和初始沸点大于产物（P1）的最终沸点，c）用溶剂（S1）进行液 - 液萃取，从产物（P2）产生萃取物（E1）和萃余液（R1），d）回收溶剂（S1 ）从残液（R1）生产产生（Q1）的产物（Q1），其消耗溶剂（S1），其具有改善的质量并且含有少于500重量ppm的硫。

8. 发明授权

US6043187A Catalyst for hydrotreating hydrocarbon feeds in a fixed bed reactor 失效
标题翻译：用于在固定床反应器中加氢处理烃进料的催化剂
公开(公告)号：US6043187A
公开(公告)日：2000-03-28
申请号：US94509
申请日：1998-06-10
申请人： Virginie Harle , Slavik Kazstelan , Frederic Morel , Stephane Kressmann , Philippe Courty
发明人： Virginie Harle , Slavik Kazstelan , Frederic Morel , Stephane Kressmann , Philippe Courty
IPC分类号： B01J23/24 , B01J21/04 , B01J23/28 , B01J23/652 , B01J23/755 , B01J23/85 , B01J23/88 , B01J35/10 , B01J37/00 , C10G45/04 , C10G45/08 , C10G45/10 , C10G49/02 , C10G49/04 , B01J23/00 , B01J20/00 , B01J23/56 , B01J23/70 , C01F7/02
CPC分类号： B01J37/0018 , B01J21/04 , B01J23/85 , B01J35/0026 , B01J35/023 , B01J35/1019 , B01J35/1061 , B01J35/108 , C10G45/04 , C10G45/08 , C10G49/02 , C10G49/04
摘要： The present invention relates to a catalyst comprising an extruded essentially alumina-based support, constituted by a plurality of juxtaposed agglomerates and partially in the form of packs of flakes and partially in the form of needles, and optionally comprising at least one catalytic metal or a compound of a catalytic metal from group VIB, and/or optionally at least one catalytic metal or compound of a catalytic metal from group VIII. The invention also relates to its use in a fixed bed reactor, for hydrorefining and hydroconverting hydrocarbon feeds.
摘要翻译：本发明涉及一种催化剂，其包含挤出的基本上为氧化铝的载体，其由多个并置的附聚物构成，并且部分为片状包装形式，部分为针状，并任选地包含至少一种催化金属或来自VIB族的催化金属的化合物和/或任选的至少一种催化金属或来自VIII族的催化金属的化合物。本发明还涉及其在固定床反应器中的用途，用于加氢精制和加氢转化烃进料。

9. 发明授权

US6042716A Process for transforming a gas oil cut to produce a dearomatised and desulphurised fuel with a high cetane number 失效
标题翻译：用于转换瓦斯油切割以产生具有高十六烷值的脱芳香和脱硫燃料的方法
公开(公告)号：US6042716A
公开(公告)日：2000-03-28
申请号：US992486
申请日：1997-12-18
申请人： Frederic Morel , Henri Delhomme , Nathalie George-Marchal
发明人： Frederic Morel , Henri Delhomme , Nathalie George-Marchal
IPC分类号： B01J23/42 , B01J27/19 , C10G45/08 , C10G45/52 , C10G65/08 , C10G69/02
CPC分类号： C10G65/08 , C10G2400/04
摘要： A process for transforming a gas oil cut into a dearomatized fuel with a high cetane number comprises at least one first, deep desulphurization and deep denitrogenation step in which the gas oil cut and hydrogen are passed over a catalyst comprising a mineral support, at least one group VIB metal or metal compound, at least one group VIII metal or metal compound, and phosphorous or at least one phosphorous compound, and at least one subsequent second step, dearomatization, in which the desulphurized and denitrogenated product from the first step is passed with hydrogen over a catalyst comprising a mineral support and at least one group VIII noble metal or noble metal compound.
摘要翻译：将切割成含有高十六烷值的脱气燃料的瓦斯油转化为至少一个第一，深度脱硫和深度脱氮步骤，其中将所述瓦斯油馏分和氢气通过含有矿物载体的催化剂，至少一种 VIB族金属或金属化合物，至少一种VIII族金属或金属化合物，以及磷或至少一种磷化合物，以及至少一个随后的第二步，脱芳化，其中来自第一步骤的脱硫和脱氮产物通过，氢气在包含矿物载体和至少一种VIII族贵金属或贵金属化合物的催化剂上。

10. 发明授权

US5776988A Process for converting synthesis gas into hydrocarbons 失效
标题翻译：将合成气转化为烃的方法
公开(公告)号：US5776988A
公开(公告)日：1998-07-07
申请号：US745288
申请日：1996-11-08
申请人： Patrick Chaumette , Pierre Boucot , Frederic Morel
发明人： Patrick Chaumette , Pierre Boucot , Frederic Morel
IPC分类号： C07C1/06 , C10G2/00 , C07C27/06
CPC分类号： C10G2/342 , C07C1/06 , C07C2523/745 , C07C2523/75
摘要： The invention relates to a process for synthesizing mainly linear and saturated hydrocarbons containing at least 80% by weight of C.sub.5 + hydrocarbons in relation to all of the hydrocarbons formed, from a synthesis gas CO--(CO.sub.2)--H.sub.2, the synthesis gas being converted into hydrocarbons under a total pressure ranging between 0.1 and 15 MPa, the temperature ranging between 150.degree. and 350.degree. C., the hourly space velocity ranging between 100 and 30,000 volumes of synthesis gas per volume of catalyst and per hour, and the H.sub.2 /CO molar ratio in the synthesis gas ranging between 1:2 and 5:1, said process being characterized in that it is carried out in a reaction zone with an ebullating catalytic bed in the presence of a catalyst comprising at least one metal from group VIII, and in the presence of a liquid phase.
摘要翻译：本发明涉及一种主要合成含有至少80重量％的C5 +烃相对于所形成的烃的线性和饱和烃的方法，由合成气CO-（CO 2）-H 2合成，合成气被转化为总压力介于0.1和15MPa之间的碳氢化合物，温度在150-350℃之间，小时空间速度在每体积催化剂和每小时100至30,000体积的合成气和H 2 / CO 合成气中的摩尔比在1:2至5:1之间，所述方法的特征在于，在催化剂存在下，在沸腾催化剂床的反应区中进行反应，所述催化剂包含至少一种来自第VIII族的金属，并在液相存在下进行。

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