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1. 发明授权

US08372930B2 High vinyl terminated propylene based oligomers 有权
标题翻译：高乙烯基封端的丙烯基低聚物
公开(公告)号：US08372930B2
公开(公告)日：2013-02-12
申请号：US12143663
申请日：2008-06-20
申请人： Patrick Brant , Donna J. Crowther , Andrew G. Narvaez, Jr.
发明人： Patrick Brant , Donna J. Crowther , Andrew G. Narvaez, Jr.
IPC分类号： C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18
CPC分类号： C08F210/06 , C08F210/16 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94 (mole % ethylene incorporated)+100), when 10 to 60 mole % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mole % ethylene is present in the co-oligomer, and 3) X=(1.83*(mole % ethylene incorporated)−83), when 70 to 90 mole % ethylene is present in the co-oligomer. This invention also relates to a homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making homo-oligomer, comprising propylene, wherein the productivity is greater than 4500 g/mmol Hf (or Zr)/hour.
摘要翻译：本发明涉及Mn为300〜30,000g / mol，包含10-90mol％丙烯和10-90mol％乙烯的共低聚物，其中低聚物具有至少X％的烯丙基链末端，其中：1）当共聚低聚物中存在10至60摩尔％的乙烯时，X =（ - 0.94（摩尔％乙烯掺入）+100），和2）X = 45，当大于60且小于70摩尔％时存在乙烯在共低聚物中，3）X =（1.83 *（摩尔％乙烯掺入）-83），当共聚低聚物中存在70至90摩尔％的乙烯时。本发明还涉及包含丙烯的均聚物，其中低聚物具有：至少93％的烯丙基链端，约500至约20,000g / mol的Mn，异丁基链端至烯丙基乙烯基的比例为0.8： 1至1.2：1.0和小于100ppm的铝。本发明还涉及制备包含丙烯的均聚物的方法，其中生产率大于4500g / mmol Hf（或Zr）/小时。

2. 发明授权

US08318998B2 Enhanced catalyst performance for production of vinyl terminated propylene and ethylene/propylene macromers 有权
标题翻译：用于生产乙烯基封端的丙烯和乙烯/丙烯大分子单体的增强的催化剂性能
公开(公告)号：US08318998B2
公开(公告)日：2012-11-27
申请号：US13072279
申请日：2011-03-25
申请人： Donna J. Crowther , Renuka N. Ganesh , Andrew G. Narvaez, Jr. , Patrick Brant
发明人： Donna J. Crowther , Renuka N. Ganesh , Andrew G. Narvaez, Jr. , Patrick Brant
IPC分类号： C08F4/6592 , C08F4/643 , B01J31/22
CPC分类号： C08F10/06 , B01J31/2295 , B01J2231/12 , B01J2531/48 , B01J2531/49 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , Y10S526/943 , C08F4/65922 , C08F2500/03 , C08F210/16
摘要： This invention relates to a transition metal catalyst compound represented by the structure: wherein M is hafnium or zirconium; each X is, independently, selected from the group consisting of hydrocarbyl radicals having from 1 to 20 carbon atoms, hydrides, amides, alkoxides, sulfides, phosphides, halogens, dienes, amines, phosphines, ethers, or a combination thereof; each R1 and R3 are, independently, a C1 to C8 alkyl group; and each R2, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, and R14 are, independently, hydrogen, or a substituted or unsubstituted hydrocarbyl group having from 1 to 8 carbon atoms, provided however that at least three of the R10-R14 groups are not hydrogen, compositions thereof and methods of use thereof to prepare polymers.
摘要翻译：本发明涉及由以下结构表示的过渡金属催化剂化合物：其中M是铪或锆; 每个X独立地选自具有1至20个碳原子的烃基，氢化物，酰胺，醇盐，硫化物，磷化物，卤素，二烯，胺，膦，或其组合; 每个R 1和R 3独立地为C 1至C 8烷基; 并且每个R 2，R 4，R 5，R 6，R 7，R 8，R 9，R 10，R 11，R 12，R 13和R 14独立地为氢，或具有1至8个碳原子的取代或未取代的烃基，至少三个R10-R14基团不是氢，其组合物及其制备聚合物的方法。

3. 发明授权

US08283419B2 Olefin functionalization by metathesis reaction 有权
标题翻译：烯烃通过复分解反应进行功能化
公开(公告)号：US08283419B2
公开(公告)日：2012-10-09
申请号：US12488093
申请日：2009-06-19
申请人： John R. Hagadorn , Matthew W. Holtcamp , Andrew G. Narvaez, Jr. , Donna J. Crowther , Patrick Brant
发明人： John R. Hagadorn , Matthew W. Holtcamp , Andrew G. Narvaez, Jr. , Donna J. Crowther , Patrick Brant
IPC分类号： C08F255/00 , C08F255/02 , C08F210/06 , C08F110/06
CPC分类号： C08F210/06 , C08F210/16 , C08F220/06 , C08F220/14 , C08F255/02 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)−83), when 70 to 90 mol % ethylene is present in the co-oligomer. This invention also relates to a process to functionalize propylene homo-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum.
摘要翻译：本发明涉及官能化丙烯共聚低聚物的方法，包括使烯烃复分解催化剂与含杂原子的烯烃接触，以及丙烯，共聚低聚物，其Mn为300至30,000g / mol，包含10至90mol％的丙烯和10 至90mol％的乙烯，其中低聚物具有至少X％的烯丙基链端，其中：1）X =（ - 0.94（加入的乙烯的摩尔％）+100），当共聚物中存在10至60mol％的乙烯时 - 低聚物，和2）X = 45，当共聚低聚物中存在大于60且小于70摩尔％的乙烯时，和3）X =（1.83×（摩尔乙烯加入）-83），当70〜共聚低聚物中存在90mol％的乙烯。本发明还涉及使丙烯均聚物低聚物官能化的方法，包括使烯烃复分解催化剂与含杂原子的烯烃和包含丙烯的丙烯均聚物接触，其中低聚物具有：至少93％的烯丙基链端，Mn 约500至约20,000g / mol，异丁基链端至烯丙基乙烯基的比例为0.8:1至1.2:1.0，低于100ppm的铝。

4. 发明申请

US20090318647A1 Olefin Functionalization By Metathesis Reaction 有权
标题翻译：烯烃功能化通过复分解反应
公开(公告)号：US20090318647A1
公开(公告)日：2009-12-24
申请号：US12488093
申请日：2009-06-19
申请人： John R. Hagadorn , Matthew W. Holtcamp , Andrew G. Narvaez, JR. , Donna J. Crowther , Patrick Brant
发明人： John R. Hagadorn , Matthew W. Holtcamp , Andrew G. Narvaez, JR. , Donna J. Crowther , Patrick Brant
IPC分类号： C08F4/80 , C08F118/02 , C08F210/02 , C08F220/06 , C08F4/72
CPC分类号： C08F210/06 , C08F210/16 , C08F220/06 , C08F220/14 , C08F255/02 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)−83), when 70 to 90 mol % ethylene is present in the co-oligomer. This invention also relates to a process to functionalize propylene homo-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum.
摘要翻译：本发明涉及官能化丙烯共聚低聚物的方法，包括使烯烃复分解催化剂与含杂原子的烯烃接触，以及丙烯，共聚低聚物，其Mn为300至30,000g / mol，包含10至90mol％的丙烯和10 至90mol％的乙烯，其中低聚物具有至少X％的烯丙基链端，其中：1）X =（ - 0.94（加入的乙烯的摩尔％）+100），当共聚物中存在10至60mol％的乙烯时 - 低聚物，和2）X = 45，当共聚低聚物中存在大于60且小于70摩尔％的乙烯时，和3）X =（1.83×（摩尔乙烯加入）-83），当70〜共聚低聚物中存在90mol％的乙烯。本发明还涉及使丙烯均聚物低聚物官能化的方法，包括使烯烃复分解催化剂与含杂原子的烯烃和包含丙烯的丙烯均聚物接触，其中低聚物具有：至少93％的烯丙基链端，Mn 约500至约20,000g / mol，异丁基链端至烯丙基乙烯基的比例为0.8:1至1.2:1.0，低于100ppm的铝。

5. 发明授权

US08431662B2 Polymacromonomer and process for production thereof 失效
标题翻译：聚共聚物及其制备方法
公开(公告)号：US08431662B2
公开(公告)日：2013-04-30
申请号：US13589388
申请日：2012-08-20
申请人： Patrick Brant , Andrew G. Narvaez, Jr. , Donna J. Crowther
发明人： Patrick Brant , Andrew G. Narvaez, Jr. , Donna J. Crowther
IPC分类号： C08F4/76 , C08F4/64 , C08F210/06 , C08F210/00
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F255/02 , C08F4/7042 , C08F4/64193 , C08F210/06 , C08F2500/03 , C08F2500/02
摘要： This invention relates to a polymacromonomer comprising at least one macromonomer and from 0 to 20 wt % of a C2 to C12 comonomer, wherein the macromonomer has vinyl termination of at least 70%, and wherein the polymacromonomer has: a) a g value of less than 0.6, b) an Mw of greater than 30,000 g/mol, c) an Mn of greater than 20,000 g/mol, d) a branching index (g′)vis of less than 0.5, e) less than 25% vinyl terminations, f) at least 70 wt % macromonomer, based upon the weight of the polymacromonomer, g) from 0 to 20 wt % aromatic containing monomer, based upon the weight of the polymacromonomer and h) optionally, a melting point of 50° C. or more. This invention also relates to processes to make such polymacromonomers.
摘要翻译：本发明涉及包含至少一种大分子单体和0-20重量％的C 2 -C 12共聚单体的聚异氰酸酯，其中所述大分子单体具有至少70％的乙烯基封端，并且其中所述聚异淀粉体具有：a）ag值小于 0.6，b）大于30,000g / mol的Mw，c）大于20,000g / mol的Mn，d）支链指数（g'）vis小于0.5，e）小于25％的乙烯基封端， f）至少70重量％的大分子单体，基于聚共聚单体的重量，g）0至20重量％的含芳族单体，基于聚共聚单体的重量，以及h）任选地，熔点为50℃，或更多。本发明还涉及制备这种聚异构体的方法。

6. 发明申请

US20090318640A1 Polymacromonomer And Process For Production Thereof 失效
标题翻译：聚异构体及其制备方法
公开(公告)号：US20090318640A1
公开(公告)日：2009-12-24
申请号：US12488066
申请日：2009-06-19
申请人： Patrick Brant , Andrew G. Narvaez, JR. , Donna J. Crowther
发明人： Patrick Brant , Andrew G. Narvaez, JR. , Donna J. Crowther
IPC分类号： C08F10/14 , C08F4/76 , C08F4/12 , C08F2/00
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F255/02 , C08F4/7042 , C08F4/64193 , C08F210/06 , C08F2500/03 , C08F2500/02
摘要： This invention relates to a polymacromonomer comprising at least one macromonomer and from 0 to 20 wt % of a C2 to C12 comonomer, wherein the macromonomer has vinyl termination of at least 70%, and wherein the polymacromonomer has: a) a g value of less than 0.6, b) an Mw of greater than 30,000 g/mol, c) an Mn of greater than 20,000 g/mol, d) a branching index (g′)vis of less than 0.5, e) less than 25% vinyl terminations, f) at least 70 wt % macromonomer, based upon the weight of the polymacromonomer, g) from 0 to 20 wt % aromatic containing monomer, based upon the weight of the polymacromonomer and h) optionally, a melting point of 50° C. or more. This invention also relates to processes to make such polymacromonomers.
摘要翻译：本发明涉及包含至少一种大分子单体和0-20重量％的C 2 -C 12共聚单体的聚异氰酸酯，其中所述大分子单体具有至少70％的乙烯基封端，并且其中所述聚异淀粉体具有：a）ag值小于 0.6，b）大于30,000g / mol的Mw，c）大于20,000g / mol的Mn，d）支链指数（g'）vis小于0.5，e）小于25％的乙烯基封端， f）至少70重量％的大分子单体，基于聚共聚单体的重量，g）0至20重量％的含芳族单体，基于聚共聚单体的重量，以及h）任选地，熔点为50℃，或更多。本发明还涉及制备这种聚异构体的方法。

7. 发明申请

US20120309903A1 Polymacromonomer and Process For Production Thereof 失效
标题翻译：聚异构体及其制备方法
公开(公告)号：US20120309903A1
公开(公告)日：2012-12-06
申请号：US13589388
申请日：2012-08-20
申请人： Patrick BRANT , Andrew G. Narvaez, JR. , Donna J. Crowther
发明人： Patrick BRANT , Andrew G. Narvaez, JR. , Donna J. Crowther
IPC分类号： C08F210/06 , C08F4/76 , C08F4/80
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F255/02 , C08F4/7042 , C08F4/64193 , C08F210/06 , C08F2500/03 , C08F2500/02
摘要： This invention relates to a polymacromonomer comprising at least one macromonomer and from 0 to 20 wt % of a C2 to C12 comonomer, wherein the macromonomer has vinyl termination of at least 70%, and wherein the polymacromonomer has: a) a g value of less than 0.6, b) an Mw of greater than 30,000 g/mol, c) an Mn of greater than 20,000 g/mol, d) a branching index (g′)vis of less than 0.5, e) less than 25% vinyl terminations, f) at least 70 wt % macromonomer, based upon the weight of the polymacromonomer, g) from 0 to 20 wt % aromatic containing monomer, based upon the weight of the polymacromonomer and h) optionally, a melting point of 50° C. or more. This invention also relates to processes to make such polymacromonomers.
摘要翻译：本发明涉及包含至少一种大分子单体和0-20重量％的C 2 -C 12共聚单体的聚异氰酸酯，其中所述大分子单体具有至少70％的乙烯基封端，并且其中所述聚异淀粉体具有：a）ag值小于 0.6，b）大于30,000g / mol的Mw，c）大于20,000g / mol的Mn，d）支链指数（g'）vis小于0.5，e）小于25％的乙烯基封端， f）至少70重量％的大分子单体，基于聚共聚单体的重量，g）0至20重量％的含芳族单体，基于聚共聚单体的重量，以及h）任选地，熔点为50℃，或更多。本发明还涉及制备这种聚异构体的方法。

8. 发明授权

US08283428B2 Polymacromonomer and process for production thereof 失效
标题翻译：聚共聚物及其制备方法
公开(公告)号：US08283428B2
公开(公告)日：2012-10-09
申请号：US12488066
申请日：2009-06-19
申请人： Patrick Brant , Andrew G. Narvaez, Jr. , Donna J. Crowther
发明人： Patrick Brant , Andrew G. Narvaez, Jr. , Donna J. Crowther
IPC分类号： C08F4/72 , C08F210/06 , C08F210/16 , C08F10/06
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F255/02 , C08F4/7042 , C08F4/64193 , C08F210/06 , C08F2500/03 , C08F2500/02
摘要： This invention relates to a polymacromonomer comprising at least one macromonomer and from 0 to 20 wt % of a C2 to C12 comonomer, wherein the macromonomer has vinyl termination of at least 70%, and wherein the polymacromonomer has: a) a g value of less than 0.6, b) an Mw of greater than 30,000 g/mol, c) an Mn of greater than 20,000 g/mol, d) a branching index (g′)vis of less than 0.5, e) less than 25% vinyl terminations, f) at least 70 wt % macromonomer, based upon the weight of the polymacromonomer, g) from 0 to 20 wt % aromatic containing monomer, based upon the weight of the polymacromonomer and h) optionally, a melting point of 50° C. or more. This invention also relates to processes to make such polymacromonomers.
摘要翻译：本发明涉及包含至少一种大分子单体和0-20重量％的C 2 -C 12共聚单体的聚异氰酸酯，其中所述大分子单体具有至少70％的乙烯基封端，并且其中所述聚异淀粉体具有：a）ag值小于 0.6，b）大于30,000g / mol的Mw，c）大于20,000g / mol的Mn，d）支链指数（g'）vis小于0.5，e）小于25％的乙烯基封端， f）至少70重量％的大分子单体，基于聚共聚单体的重量，g）0至20重量％的含芳族单体，基于聚共聚单体的重量，以及h）任选地，熔点为50℃，或更多。本发明还涉及制备这种聚异构体的方法。

9. 发明申请

US20120245313A1 ENHANCED CATALYST PERFORMANCE FOR PRODUCTION OF VINYL TERMINATED PROPYLENE AND ETHYLENE/PROPYLENE MACROMERS 有权
标题翻译：乙烯终止丙烯和乙烯/丙烯酸硬化剂的增强催化剂性能
公开(公告)号：US20120245313A1
公开(公告)日：2012-09-27
申请号：US13072279
申请日：2011-03-25
申请人： Donna J. Crowther , Renuka N. Ganesh , Andrew G. Narvaez, JR. , Patrick Brant
发明人： Donna J. Crowther , Renuka N. Ganesh , Andrew G. Narvaez, JR. , Patrick Brant
IPC分类号： C08F4/6592 , C08F110/06 , B01J31/12 , C08F4/76
CPC分类号： C08F10/06 , B01J31/2295 , B01J2231/12 , B01J2531/48 , B01J2531/49 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , Y10S526/943 , C08F4/65922 , C08F2500/03 , C08F210/16
摘要： This invention relates to a transition metal catalyst compound represented by the structure: wherein M is hafnium or zirconium; each X is, independently, selected from the group consisting of hydrocarbyl radicals having from 1 to 20 carbon atoms, hydrides, amides, alkoxides, sulfides, phosphides, halogens, dienes, amines, phosphines, ethers, or a combination thereof; each R1 and R3 are, independently, a C1 to C8 alkyl group; and each R2, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, and R14 are, independently, hydrogen, or a substituted or unsubstituted hydrocarbyl group having from 1 to 8 carbon atoms, provided however that at least three of the R10-R14 groups are not hydrogen, compositions thereof and methods of use thereof to prepare polymers.
摘要翻译：本发明涉及由以下结构表示的过渡金属催化剂化合物：其中M是铪或锆; 每个X独立地选自具有1至20个碳原子的烃基，氢化物，酰胺，醇盐，硫化物，磷化物，卤素，二烯，胺，膦，或其组合; 每个R 1和R 3独立地为C 1至C 8烷基; 并且每个R 2，R 4，R 5，R 6，R 7，R 8，R 9，R 10，R 11，R 12，R 13和R 14独立地为氢，或具有1至8个碳原子的取代或未取代的烃基，至少三个R10-R14基团不是氢，其组合物及其制备聚合物的方法。

10. 发明申请

US20090318644A1 High Vinyl Terminated Propylene Based Oligomers 有权
标题翻译：高乙烯基终止丙烯基低聚物
公开(公告)号：US20090318644A1
公开(公告)日：2009-12-24
申请号：US12143663
申请日：2008-06-20
申请人： Patrick Brant , Donna J. Crowther , Andrew G. Narvaez, JR.
发明人： Patrick Brant , Donna J. Crowther , Andrew G. Narvaez, JR.
IPC分类号： C08F210/16 , C08F110/06 , C08F2/00
CPC分类号： C08F210/06 , C08F210/16 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94 (mole % ethylene incorporated)+100), when 10 to 60 mole % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mole % ethylene is present in the co-oligomer, and 3) X=(1.83*(mole % ethylene incorporated)−83), when 70 to 90 mole % ethylene is present in the co-oligomer. This invention also relates to a homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making homo-oligomer, comprising propylene, wherein the productivity is greater than 4500 g/mmol Hf (or Zr)/hour.
摘要翻译：本发明涉及Mn为300〜30,000g / mol，包含10-90mol％丙烯和10-90mol％乙烯的共低聚物，其中低聚物具有至少X％的烯丙基链末端，其中：1）当共聚低聚物中存在10至60摩尔％的乙烯时，X =（ - 0.94（摩尔％乙烯掺入）+100），和2）X = 45，当大于60且小于70摩尔％时存在乙烯在共低聚物中，3）X =（1.83 *（摩尔％乙烯掺入）-83），当共聚低聚物中存在70至90摩尔％的乙烯时。本发明还涉及包含丙烯的均聚物，其中低聚物具有：至少93％的烯丙基链端，约500至约20,000g / mol的Mn，异丁基链端至烯丙基乙烯基的比例为0.8： 1至1.2：1.0和小于100ppm的铝。本发明还涉及制备包含丙烯的均聚物的方法，其中生产率大于4500g / mmol Hf（或Zr）/小时。

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