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1. 发明授权

US5382721A Process for the preparation of 1,1,1,2-tetrafluoroethane 失效
标题翻译： 1,1,1,2-四氟乙烷的制备方法
公开(公告)号：US5382721A
公开(公告)日：1995-01-17
申请号：US72759
申请日：1993-06-07
申请人： Pascal Pennetreau , Francine Janssens , Max Braun , Johannes Eicher , Werner Rudolph , Eckhard Hausmann
发明人： Pascal Pennetreau , Francine Janssens , Max Braun , Johannes Eicher , Werner Rudolph , Eckhard Hausmann
IPC分类号： B01J21/06 , B01J23/14 , B01J27/08 , C07B61/00 , C07C17/04 , C07C17/087 , C07C19/08 , C07C17/08
CPC分类号： C07C17/087
摘要： Process for the preparation of 1,1,1,2-tetrafluoroethane by reaction of hydrogen fluoride with a trihaloethylene according to which trifluoroethylene is chosen as trihaloethylene and the reaction is carried out in the liquid phase.
摘要翻译：通过氟化氢与三卤乙烯的反应制备1,1,1,2-四氟乙烷的方法，根据该方法，三氟乙烯被选择为三卤代乙烯，反应在液相中进行。

2. 发明授权

US06252105B1 Synthesis of low-fluoride organic compounds 失效
标题翻译：低氟有机化合物的合成
公开(公告)号：US06252105B1
公开(公告)日：2001-06-26
申请号：US09348072
申请日：1999-07-06
申请人： Max Braun , Johannes Eicher , Francine Janssens , Kerstin Eichholz , Stefan Palsherm
发明人： Max Braun , Johannes Eicher , Francine Janssens , Kerstin Eichholz , Stefan Palsherm
IPC分类号： C07C6963
CPC分类号： C07C67/56 , C07C51/47 , C07C51/64 , C07C53/18 , C07C67/14 , C07C67/58 , C07C53/48 , C07C59/195 , C07C69/63 , C07C69/72
摘要： Organic compounds, e.g. fluorinated organic compounds such as fluorinated carboxylic acids or fluorinated carboxylic acid chlorides, may contain small amounts of carboxylic acid fluorides, hydrogen fluoride or hydrolyzable fluoride, which during the preparation of derivatives of the fluorinated organic compounds, for example by esterification, may yield corrosive fluorides or hydrogen fluoride. The invention is a method for the synthesis and/or purification of preferably fluorinated organic compounds such as carboxylic acids, carboxylic acid chlorides and derivatives such as esters thereof, starting from corresponding carboxylic acid chlorides containing acid fluorides or hydrolyzable fluoride, and alcohols under the catalytic action of “onium” salts of carboxylic acids, to obtain products which have a low fluoride content. Alternatively, an inorganic oxide adsorbent is utilized. The method is especially suitable for the synthesis of esters of trifluoroacetic acid, chlorodifluoroacetic acid, trifluoroacetoacetic acid and/or difluoroacetoacetic acid.
摘要翻译：有机化合物，例如含氟有机化合物如氟化羧酸或氟化羧酸氯化物可含有少量羧酸氟化物，氟化氢或水解性氟化物，其在氟化有机化合物衍生物的制备过程中，例如通过酯化反应，可产生腐蚀性氟化物或氟化氢。本发明是一种合成和/或纯化优选氟化有机化合物如羧酸，羧酸氯化物及其衍生物如酯的方法，起始于含有酸性氟化物或可水解氟化物的相应的羧酸氯化物和催化剂下的醇羧酸的“鎓”盐的作用，以获得具有低氟含量的产物。或者，使用无机氧化物吸附剂。该方法特别适用于三氟乙酸，氯二氟乙酸，三氟乙酰乙酸和/或二氟乙酰乙酸的酯的合成。

3. 发明授权

US5481029A Process for preparation of ketones 失效
标题翻译：酮的制备方法
公开(公告)号：US5481029A
公开(公告)日：1996-01-02
申请号：US233622
申请日：1994-04-26
申请人： Max Braun , Johannes Eicher , Werner Rudolph , Kerstin Eichholz
发明人： Max Braun , Johannes Eicher , Werner Rudolph , Kerstin Eichholz
IPC分类号： B01J31/02 , C07B61/00 , C07C45/48 , C07C45/65 , C07C45/67 , C07C49/04 , C07C49/167 , C07C67/10 , C07C67/313 , C07C67/343 , C07C69/63 , C07C69/716
CPC分类号： C07C45/48 , C07C45/676 , C07C49/167 , C07C67/10
摘要： A process for preparing ketones, for example CF.sub.3 C(O)CH.sub.3, CF.sub.3 C(O)CH.sub.2 C(O)CF.sub.3 and CF.sub.3 C(O)CF.sub.2 H, in which .beta.-ketoesters are transesterified and decarboxylated using a carboxylic acid, for example trifluoroacetic acid, in the presence of a catalyst, particularly an "onium" salt of a carboxylic acid or an effective amount of a proton-donating acid, preferably a sulfonic acid such as alkyl- or arylsulfonic acids, or a mineral acid. The process is advantageously carried out in the absence of water, so that no formation of acetals or hydrates occurs, and no dehydrating step is needed. The process is simple to carry out, and if transesterification is carried out with a sufficiently active carboxylic acid, for example with trifluoroacetic acid, the presence of an additional catalyst is unnecessary.
摘要翻译：制备酮的方法，例如CF 3 C（O）CH 3，CF 3 C（O）CH 2 C（O）CF 3和CF 3 C（O）CF 2 H），其中β-酮酯使用羧酸（例如三氟乙酸）进行酯交换和脱羧存在催化剂，特别是羧酸的“鎓”盐或有效量的质子供体酸，优选磺酸如烷基或芳基磺酸或无机酸。该方法有利地在没有水的情况下进行，使得不会发生缩醛或水合物的形成，并且不需要脱水步骤。该方法很容易进行，如果用足够活泼的羧酸（例如三氟乙酸）进行酯交换反应，则不需要另外的催化剂的存在。

4. 发明授权

US06723874B1 Method of producing acid fluorides from acid chlorides 失效
标题翻译：从酰氯生产酸性氟化物的方法
公开(公告)号：US06723874B1
公开(公告)日：2004-04-20
申请号：US09856909
申请日：2001-05-30
申请人： Max Braun , Matthias Rieland , Francine Janssens , Kerstin Eichholz , Stefan Palsherm
发明人： Max Braun , Matthias Rieland , Francine Janssens , Kerstin Eichholz , Stefan Palsherm
IPC分类号： C07C5158
CPC分类号： C01B17/4576 , C01B17/4561 , C07C51/58
摘要： Acid fluorides, for example carboxylic acid fluorides and sulfuryl fluoride are produced by reacting the corresponding acid chlorides with hydrogen fluoride adducts of ammonium fluoride or amine hydrofluorides (which act as a catalyst or as a fluorination agent). Consumed HF adducts may be regenerated with HF.
摘要翻译：酸性氟化物，例如羧酸氟化物和硫酰氟通过使相应的酰氯与氟化铵或胺氢氟酸（其充当催化剂或氟化剂）的氟化氢加合物反应来制备。消耗的HF加合物可以用HF再生。

5. 发明申请

US20050147693A1 Carboxylic acid fluorides as pesticides 审中-公开
公开(公告)号：US20050147693A1
公开(公告)日：2005-07-07
申请号：US11052138
申请日：2005-02-08
申请人： Max Braun , Francine Janssens , Reiner Fischer
发明人： Max Braun , Francine Janssens , Reiner Fischer
IPC分类号： A01N37/02 , A01N43/20 , A01N43/24 , A01N47/40 , A01N47/46 , A01N47/48
CPC分类号： A01N37/02 , A01N2300/00
摘要： Carboxylic acid fluorides having a boiling point of preferably less than 100° C. are suitable for use as pesticides. Acetyl fluoride is highly suitable, and Chlorodifluoroacetyl fluoride and trifluoroacetyl fluoride are also very useful. Mixtures of carboxylic acid fluoride pesticides and other pesticides are also disclosed.

6. 发明授权

US06861451B2 Carboxylic acid fluorides as pesticides 失效
标题翻译：羧酸氟化物作为农药
公开(公告)号：US06861451B2
公开(公告)日：2005-03-01
申请号：US10116125
申请日：2002-04-05
申请人： Max Braun , Francine Janssens , Reiner Fischer
发明人： Max Braun , Francine Janssens , Reiner Fischer
IPC分类号： A01N37/02 , A01N29/00 , A01N29/02
CPC分类号： A01N37/02 , A01N2300/00
摘要： Carboxylic acid fluorides having a boiling point of preferably less than 100° C. are suitable for use as pesticides. Acetyl fluoride is highly suitable, and Chlorodifluoroacetyl fluoride and trifluoroacetyl fluoride are also very useful. Mixtures of carboxylic acid fluoride pesticides and other pesticides are also disclosed.
摘要翻译：沸点优选小于100℃的羧酸氟化物适合用作农药。乙酰氟是非常合适的，氯二氟乙酰氟和三氟乙酰氟也是非常有用的。还公开了羧酸氟化物农药和其他农药的混合物。

7. 发明授权

US07880039B2 Production of carbonyl fluoride 失效
标题翻译：生产碳酰氟
公开(公告)号：US07880039B2
公开(公告)日：2011-02-01
申请号：US10591783
申请日：2005-02-09
申请人： Max Braun , Johannes Eicher
发明人： Max Braun , Johannes Eicher
IPC分类号： C07C19/08 , C07C21/18 , C07C51/58
CPC分类号： C01B32/80
摘要： Carbonyl fluoride, which can also be used as an etching gas, can be prepared by photochemical oxidation of chlorodifluoromethane or trifluoromethane with light, for example with light of a wavelength ≧280 nm in the presence of chlorine.
摘要翻译：也可以用作蚀刻气体的碳酰氟可以通过用氯代二氟甲烷或三氟甲烷用光进行光化学氧化来制备，例如在氯存在下用波长≥280nm的光进行光化学反应。

8. 发明申请

US20070197826A1 Production of carbonyl fluoride 失效
标题翻译：生产碳酰氟
公开(公告)号：US20070197826A1
公开(公告)日：2007-08-23
申请号：US10591783
申请日：2005-02-09
申请人： Max Braun , Johannes Eicher
发明人： Max Braun , Johannes Eicher
IPC分类号： C07C59/245
CPC分类号： C01B32/80
摘要： Carbonyl fluoride, which can also be used as an etching gas, can be prepared by photochemical oxidation of chlorodifluoromethane or trifluoromethane with light, for example with light of a wavelength ≧280 nm in the presence of chlorine.
摘要翻译：也可以用作蚀刻气体的碳酰氟可以通过用氯代二氟甲烷或三氟甲烷用光进行光化学氧化来制备，例如在氯存在下，例如波长> 280nm的光。

9. 发明申请

US20060217533A1 Production of N-acyl compounds 审中-公开
标题翻译： N-酰基化合物的制备
公开(公告)号：US20060217533A1
公开(公告)日：2006-09-28
申请号：US11372167
申请日：2006-03-10
申请人： Max Braun , Johannes Eicher , Saskia Braukmueller
发明人： Max Braun , Johannes Eicher , Saskia Braukmueller
IPC分类号： C07K1/02 , C07C231/02
CPC分类号： C07C231/02 , C07C233/46 , C07C233/47
摘要： A process for producing a compound containing an acylated nitrogen atom in which the adduct compound formed from an N-protonated cation and a chloride, bromide or iodide anion or the free nitrogen base is reacted with an acyl halide, preferably an acyl chloride, in the presence of an acid that drives off the released hydrogen chloride (HCl), hydrogen bromide (HBr) or hydrogen iodide (HI).
摘要翻译：一种制备含有酰化氮原子的化合物的方法，其中将由N-质子化阳离子和氯化物，溴化物或碘化物阴离子形成的加合物化合物或游离氮碱与酰卤，优选酰氯反应，存在释放氯化氢（HCl），溴化氢（HBr）或碘化氢（HI）的酸。

10. 发明授权

US06423866B1 Production of aminohalogencrotonates 失效
标题翻译：生产氨基卤代巴豆酸酯
公开(公告)号：US06423866B1
公开(公告)日：2002-07-23
申请号：US09530909
申请日：2000-05-08
申请人： Max Braun , Francine Jannssens , Werner Rudolph , Kerstin Eichholz
发明人： Max Braun , Francine Jannssens , Werner Rudolph , Kerstin Eichholz
IPC分类号： C07C22900
CPC分类号： C07C227/08 , C07C229/30
摘要： Lower alkyl esters of 3-amino crotonates substituted by halogen in the C-4 position, e.g. ethyl 3-amino-4,4,4-trifluoro-crotonate, in which the amino group optionally may be substituted by one or two C1 to C3 alkyl groups or by one or two aryl groups, e.g. phenyl, are synthesized by thermolysis of ammonium salts of corresponding lower alkyl esters of acetoacetic acid substituted in the C-4 position by halogen, and removal of the resulting water of reaction. The water of reaction may be removed by an entraining agent, which preferably has a specific gravity heavier than that of the aqueous phase which forms in the reaction. This minimizes yield losses due to the ammonium salt becoming dissolved in the aqueous phase and results in especially high yields. Formation of the ammonium salt and thermolysis can be carried out simultaneously. Alternatively, it is possible to start from a molten ammonium salt of the halogencrotonate, e.g. the salt of the lower alkyl ester of 4,4,4-trifluoroacetoacetic acid, or to produce the salt in situ, and to pass an inert gas through the molten salt under thermolytic conditions and in the absence of a solvent. In this way the desired product can be produced in high yield and in high purity. This alternative can be implemented as a continuous process.
摘要翻译： C-4位被卤素取代的3-氨基巴豆酸酯的低级烷基酯，例如 3-氨基-4,4,4-三氟巴豆酸乙酯，其中氨基可任意地被一个或两个C 1至C 3烷基取代，或被一个或两个芳基取代。苯基，通过用卤素热解在C-4位置取代的乙酰乙酸的相应低级烷基酯的铵盐，除去所得的反应水来合成。反应水可以通过夹带剂除去，该夹带剂优选具有比在反应中形成的水相重的比重。这使得由于铵盐溶解在水相中导致的产量损失最小化并导致特别高的产率。铵盐的形成和热解可以同时进行。或者，可以从卤代克酸内酯的熔融铵盐开始，例如， 4,4,4-三氟乙酰乙酸的低级烷基酯的盐，或者在原位产生盐，并在惰性溶解条件下和不溶于溶剂的条件下使惰性气体通过熔融盐。以这种方式，可以以高产率和高纯度生产所需的产物。这种替代方案可以被实现为连续过程。

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