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    • 8. 发明授权
    • Amine terminated polymers and the formation of block copolymers
    • 胺封端的聚合物和嵌段共聚物的形成
    • US4157429A
    • 1979-06-05
    • US792283
    • 1977-04-29
    • William L. HergenrotherRichard A. SchwarzRichard J. AmbroseRobert A. Hayes
    • William L. HergenrotherRichard A. SchwarzRichard J. AmbroseRobert A. Hayes
    • C08C19/30C08C19/44C08F8/30C08F8/34C08F293/00C08G8/38C08G12/46C08G18/10C08G18/62C08G18/69C08G81/00C08J9/10C08L77/06
    • C08G81/00C08C19/30C08C19/44C08F293/00C08F8/30C08F8/34C08G12/46C08G18/10C08G18/6204C08G18/69C08G8/38
    • Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic Iactam polymerization catalysts to give a blocked nylon copolymer. Similarly, other block or graft copolymers may be obtained by reacting amine reactive compounds such as various monomers or polymers with the terminated amine polymer and examples of amine reactive polymers include polyepoxy, polyurea-aldehyde, polyphenol-aldehyde, polyamide, polyurea-urethane, polyurethane polyimide, polyurea and similar polymer segments. Of course, identical or similar polymer forming reagents such as monomers as well as identical or similar prepolymers may also be used.
    • 制备阴离子聚合单体如共轭二烯,乙烯基取代芳族化合物,烯烃型化合物和含杂环氮化合物的聚合物,并用多异氰酸酯或多异硫氰酸酯封端。 然后使这样的封端聚合物与含有酰胺如内酰胺的化合物反应,得到酰亚胺型端基。 将酰亚胺型封端的聚合物水解以形成稳定的胺封端的聚合物,其可用作物质组合物或在较短时间内长时间储存​​并与其它各种聚合物和单体或各种组合反应 的单体以形成各种嵌段或接枝聚合物。 也就是说,胺聚合物随后可以与任何胺反应性化合物如聚异氰酸酯或多异硫氰酸酯和内酰胺在已知的阴离子咪唑聚合催化剂存在下反应,得到封闭的尼龙共聚物。 类似地,其它嵌段或接枝共聚物可以通过使胺反应性化合物如各种单体或聚合物与封端的胺聚合物反应而获得,胺反应性聚合物的实例包括聚环氧,聚脲醛,多酚醛,聚酰胺,聚脲 - 聚氨酯,聚氨酯 聚酰亚胺,聚脲和类似的聚合物链段。 当然,也可以使用相同或相似的聚合物形成试剂如单体以及相同或相似的预聚物。
    • 9. 发明授权
    • Amine terminated polymers and the formation of blocked copolymers
    • 胺封端聚合物和封端共聚物的形成
    • US4154773A
    • 1979-05-15
    • US805343
    • 1977-06-10
    • William L. HergenrotherRichard A. SchwarzRichard J. AmbroseRobert A. Hayes
    • William L. HergenrotherRichard A. SchwarzRichard J. AmbroseRobert A. Hayes
    • C08C19/44C08F8/30C08F293/00C08G8/38C08G12/46C08G18/10C08G18/69C08G18/83C08G81/00C08L9/06C08L61/24
    • C08G81/00C08C19/44C08F293/00C08F8/30C08G12/46C08G18/10C08G18/69C08G18/832C08G8/38Y10S525/914
    • Polymers of anionically polymerized monomers such as conjugated dienes, vinyl substituted aromatics, olefinic type compounds, and heterocyclic nitrogen containing compounds, are produced and end capped with a polyisocyanate or polyisothiocyanate. Such end capped polymers are then reacted with compounds containing an amide such as lactam to give an imide type end group. The imide type terminated polymer is hydrolyzed to form a stable amine terminated polymer which may be utilized, as a composition of matter or stored for a short period of time to an extended period of time and reacted with other various polymers and monomers, or various combinations of monomers to form various block or graft polymers. That is the amine polymer may be subsequently reacted with any amine reactive compound such as with a polyisocyanate or polyisothiocyanate and a lactam in the presence of a known anionic Iactam polymerization catalysts to give a blocked nylon copolymer. Similarly, other block or graft copolymers may be obtained by reacting amine reactive compounds such as various monomers or polymers with the terminated amine polymer and examples of amine reactive polymers include polyepoxy, polyurea-aldehyde, polyphenolaldehyde, polyamide, polyurea-urethane, polyurethane, polyimide, polyurea and similar polymer segments. Of course, identical or similar polymer forming reagents such as monomers as well as identical or similar prepolymers may also be used.
    • 制备阴离子聚合单体如共轭二烯,乙烯基取代芳族化合物,烯烃型化合物和含杂环氮化合物的聚合物,并用多异氰酸酯或多异硫氰酸酯封端。 然后使这样的封端聚合物与含有酰胺如内酰胺的化合物反应,得到酰亚胺型端基。 将酰亚胺型封端的聚合物水解以形成稳定的胺封端的聚合物,其可用作物质组合物或在较短时间内长时间储存​​并与其它各种聚合物和单体或各种组合反应 的单体以形成各种嵌段或接枝聚合物。 也就是说,胺聚合物随后可以与任何胺反应性化合物如聚异氰酸酯或多异硫氰酸酯和内酰胺在已知的阴离子咪唑聚合催化剂存在下反应,得到封闭的尼龙共聚物。 类似地,其它嵌段或接枝共聚物可以通过使胺反应性化合物如各种单体或聚合物与封端的胺聚合物反应而获得,胺反应性聚合物的实例包括聚环氧,聚脲醛,多酚醛,聚酰胺,聚脲 - 氨基甲酸酯,聚氨酯,聚酰亚胺 ,聚脲和类似的聚合物链段。 当然,也可以使用相同或相似的聚合物形成试剂如单体以及相同或相似的预聚物。