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1. 发明授权

US4087489A Insecticidal N-polychloroallylamido-thiophosphoric esters 失效
标题翻译：杀虫剂N-聚氯代烯丙基 - 硫代磷酸酯
公开(公告)号：US4087489A
公开(公告)日：1978-05-02
申请号：US680694
申请日：1976-04-27
申请人： Paolo Piccardi , Francesco Corda , Franco Gozzo , Angelo Longoni , Giovanni Renis
发明人： Paolo Piccardi , Francesco Corda , Franco Gozzo , Angelo Longoni , Giovanni Renis
IPC分类号： A01N57/30 , C07F9/24 , C07F9/38 , C07F9/40 , A01N9/36
CPC分类号： C07F9/2462 , C07F9/242
摘要： The present invention concerns N-polychloroallylamidothiophosphoric esters. More particularly, this invention relates to new N-polychloroallylamido-thiophosphoric esters, the method for the preparation of same and their application in the fight against noxious insects.
摘要翻译：本发明涉及N-氯氯丙烯酰氨基硫代磷酸酯。更具体地说，本发明涉及新的N-聚氯代烯丙基 - 硫代磷酸酯，其制备方法及其在防治有害昆虫中的应用。

2. 发明授权

US4379163A Pyrethroids 失效
标题翻译：拟除虫菊酯
公开(公告)号：US4379163A
公开(公告)日：1983-04-05
申请号：US273541
申请日：1981-06-15
申请人： Paolo Piccardi , Francesco Corda , Franco Gozzo , Augusto Menconi , Angelo Longoni
发明人： Paolo Piccardi , Francesco Corda , Franco Gozzo , Augusto Menconi , Angelo Longoni
IPC分类号： A01N53/00 , C07C61/40 , C07D307/45 , A01N43/08 , C07D307/54
CPC分类号： C07D307/42 , A01N53/00 , C07C61/40
摘要： Pyrethroid type insecticides are described having the formula: ##STR1## wherein: R.sup.1 =H, CN, C.tbd.CHR.sup.2 =3-phenoxy, 3-benzyl, 4-allyl, 4-propargyl.R.sup.3 =H, alkyl bound to the heterocyclic ring in position 3 or 2;R.sup.4 =(in position 4 or 5 of the heterocyclic ring)=benzyl, benzoyl, phenoxy, allyl, propargyl;Y=O, SR.sup.5 and R.sup.6 =alkyl C.sub.1 -C.sub.3, or R.sup.5 and R.sup.6 together form an orthocondensed aromatic, heteroaromatic or aliphatic, saturated or unsaturated ring;R.sup.7 and R.sup.8 (equal to or different from each other)=H, halogen, CH.sub.3 ;R.sup.9 =phenyl, vinyl, vinyl substituted, phenoxy.Compounds of general formula I are endowed with a high insecticide and acaricide activity.
摘要翻译：描述了拟除虫菊酯型杀虫剂，具有下式：其中（I）（X = H，F，Cl，Br; Y = Cl，Br） + TR 其中：R1 = H，CN，C3BCH2 = 3-苯氧基，3-苄基，4-烯丙基，4-炔丙基。 R3 = H，与3或2位杂环结合的烷基; R4 =（杂环的4或5位）=苄基，苯甲酰基，苯氧基，烯丙基，炔丙基; Y = O，S R5和R6 =烷基C1-C3，或R5和R6一起形成正缩合的芳族，杂芳族或脂族饱和或不饱和环; R7和R8（彼此相同或不同）= H，卤素，CH 3; R9 =苯基，乙烯基，乙烯基取代的苯氧基。通式I的化合物具有高杀虫剂和杀螨剂活性。

3. 发明授权

US4328237A Pyrethroids 失效
标题翻译：拟除虫菊酯
公开(公告)号：US4328237A
公开(公告)日：1982-05-04
申请号：US015105
申请日：1979-02-26
申请人： Paolo Piccardi , Francesco Corda , Franco Gozzo , Augusto Menconi , Angelo Longoni
发明人： Paolo Piccardi , Francesco Corda , Franco Gozzo , Augusto Menconi , Angelo Longoni
IPC分类号： A01N53/00 , C07C61/40 , C07D307/45 , C07C69/743
CPC分类号： C07D307/42 , A01N53/00 , C07C61/40
摘要： Pyrethroid type insecticides are described having the formula: ##STR1## Compounds of general formula I are endowed with a high insecticide and acaricide activity.
摘要翻译：描述拟除虫菊酯型杀虫剂具有下列通式：（I）通式I的化合物具有高杀虫剂和杀螨剂的活性。

4. 发明授权

US4482570A Pyrethroids 失效
标题翻译：拟除虫菊酯
公开(公告)号：US4482570A
公开(公告)日：1984-11-13
申请号：US430474
申请日：1982-09-30
申请人： Paolo Piccardi , Francesco Corda , Franco Gozzo , Augusto Menconi , Angelo Logoni
发明人： Paolo Piccardi , Francesco Corda , Franco Gozzo , Augusto Menconi , Angelo Logoni
IPC分类号： A01N53/00 , C07C61/40 , C07D307/45 , C07C69/743 , C07C121/75
CPC分类号： C07D307/42 , A01N53/00 , C07C61/40
摘要： Pyrethroid type insecticides described having the formula: ##STR1## wherein A=CF.sub.3 -C.dbd.C-, ##STR2## (X=H, F, Cl, Br: Y=Cl, Br) ##STR3## (group ##STR4## is bound to the hererocyclic ring in position 2 or 3) ##STR5## --CH.sub.2 --C.tbd.C--CH.sub.2 --R.sup.9 ; wherein:R.sup.1 =H, CN, C.tbd.CHR.sup.2 =3-phenoxy, 3-benzyl, 4-allyl, 4-propargyl.R.sup.3 =H, alkyl bound to the heterocyclic ring in position 3 or 2;R.sup.4 =(in position 4 or 5 of the heterocyclic ring)=benzyl, benzoyl, phenoxy, allyl, propargyl;Y=O, SR.sup.5 and R.sup.6 =alkyl C.sub.1 -C.sub.3, or R.sup.5 and R.sup.6 together form an orthocondensed aromatic, heteroaromatic or aliphatic, saturated or unsaturated ring;R.sup.7 and R.sup.8 (equal to or different from each other)=H, halogen, CH.sub.3 ; R.sup.9 =phenyl, vinyl, vinyl substituted, phenoxy,Compounds of general formula I are endowed with a high insecticide and acaricide activity.
摘要翻译：所述的拟除虫菊酯型杀虫剂具有下式：其中A = CF 3 -C = C-，X IMAGE（X = H，F，Cl，Br：Y = Cl，Br）与第2位或第3位的本环结合）图像-CH2-C 3BOND C-CH2-R9; 其中：R 1 = H，CN，C 3 CH 2 = 3-苯氧基，3-苄基，4-烯丙基，4-炔丙基。 R3 = H，与3或2位杂环结合的烷基; R4 =（杂环的4或5位）=苄基，苯甲酰基，苯氧基，烯丙基，炔丙基; Y = O，S R5和R6 =烷基C1-C3，或R5和R6一起形成正缩合的芳族，杂芳族或脂族饱和或不饱和环; R7和R8（彼此相同或不同）= H，卤素，CH 3; R9 =苯基，乙烯基，乙烯基取代的苯氧基，通式I的化合物具有高的杀虫剂和杀螨剂活性。

5. 发明授权

US4599358A Pyrethroids 失效
标题翻译：拟除虫菊酯
公开(公告)号：US4599358A
公开(公告)日：1986-07-08
申请号：US209589
申请日：1980-11-24
申请人： Enrico Bosone , Giuseppe Caprara , Francesco Corda , Franco Gozzo , Augusto Menconi , Paolo Piccardi , Vincenzo Caprioli
发明人： Enrico Bosone , Giuseppe Caprara , Francesco Corda , Franco Gozzo , Augusto Menconi , Paolo Piccardi , Vincenzo Caprioli
IPC分类号： C07C69/747 , A01N53/00 , A01N53/08 , A61K31/215 , A61K31/275 , C07C17/278 , C07C45/51 , C07C47/24 , C07C51/00 , C07C61/40 , C07C67/00 , C07C69/743 , C07C253/00 , C07C255/39 , C07C255/53 , C07D307/93 , C07F9/40 , C07F9/54 , C07C69/74 , C07C121/50
CPC分类号： C07C255/00 , A01N53/00 , C07C17/278 , C07C45/513 , C07C47/24 , C07C61/40 , C07D307/93 , C07F9/4015 , C07F9/4075 , C07F9/5435
摘要： There are described 3-phenoxy-benzyl or .alpha.-cyano-3-phenoxy-benzyl esters of 2,2-dimethyl-cyclopropanecarboxylic acids substituted in position 3 by a dienic polyhalogenated chain, as well as their use as insecticides and acaricides. Moreover, there are also described the intermediates for their preparation and processes for their preparation.
摘要翻译：描述了通过二烯多卤代链在位置3取代的2,2-二甲基 - 环丙烷羧酸的3-苯氧基 - 苄基或α-氰基-3-苯氧基 - 苄基酯，以及它们作为杀虫剂和杀螨剂的用途。此外，还描述了其制备中间体及其制备方法。

6. 发明授权

US4258202A Cyclopropanecarboxylic acids and esters 失效
标题翻译：环丙烷羧酸和酯
公开(公告)号：US4258202A
公开(公告)日：1981-03-24
申请号：US15104
申请日：1979-02-26
申请人： Paolo Piccardi , Francesco Corda , Franco Gozzo , Augusto Menconi
发明人： Paolo Piccardi , Francesco Corda , Franco Gozzo , Augusto Menconi
IPC分类号： A01N53/00 , C07C61/40 , C07D307/45 , C07C69/743
CPC分类号： C07D307/42 , A01N53/00 , C07C61/40
摘要： Cyclopropanecarboxylic acids and esters are disclosed, having the formula: ##STR1## wherein A=CF.sub.3 --C.tbd.C--; ##STR2## X=H, F, Cl, Br; Y=Cl, Br; R=H, alkyl C.sub.1 -C.sub.4Compounds of formula I are intermediates for the preparation of insecticide compounds of the pyrethroid type.
摘要翻译：公开了环丙烷羧酸和酯，具有下式：其中A = CF 3 -C 3 CON C; X = H，F，Cl，Br; Y = Cl，Br; R = H，烷基C1-C4式I化合物是制备拟除虫菊酯类杀虫剂化合物的中间体。

7. 发明授权

US4000312A Insecticides containing an unsaturated aliphatic chain and process for preparing the same 失效
标题翻译：含有不饱和脂肪链的杀虫剂及其制备方法
公开(公告)号：US4000312A
公开(公告)日：1976-12-28
申请号：US540167
申请日：1975-01-10
申请人： Paolo Piccardi , Angelo Longoni , Francesco Corda , Ciro Preziuso
发明人： Paolo Piccardi , Angelo Longoni , Francesco Corda , Ciro Preziuso
IPC分类号： C07C69/65 , A01N31/02 , A01N35/02 , A01N37/34 , A01N49/00 , C07C21/19 , C07C41/00 , C07C43/00 , C07C43/17 , C07C43/225 , C07C45/65 , C07C45/67 , C07C45/71 , C07C49/227 , C07C49/84 , C07C67/00 , C07C209/00 , C07C209/08 , C07C211/24 , C07C213/00 , C07C217/84 , C07C229/42 , C07C253/00 , C07C255/10 , C07C313/00 , C07C317/14 , C07C329/00 , C07D317/64 , C07D317/48
CPC分类号： C07D317/64 , C07C323/00 , C07C329/00 , C07C45/65 , C07C45/676 , C07C45/71 , C07C49/227 , C07C49/84
摘要： Compounds consisting of a variously substituted unsaturated aliphatic chain and a terminal vinyl dichloro or trichloro substituted residue are disclosed, as well as a process for preparing them. The compounds are insecticides which exhibit an activity similar to that of the juvenile hormone and inhibit the development and metamorphosis of various insects.
摘要翻译：公开了由不同取代的不饱和脂族链和末端乙烯基二氯或三氯取代的残基组成的化合物，以及它们的制备方法。这些化合物是具有类似于幼体激素的活性并抑制各种昆虫的发育和变态的杀虫剂。

8. 发明授权

US4459308A Pyrethroids 失效
标题翻译：拟除虫菊酯
公开(公告)号：US4459308A
公开(公告)日：1984-07-10
申请号：US287030
申请日：1981-07-27
申请人： Francesco Corda , Franco Gozzo , Vincenzo Caprioli
发明人： Francesco Corda , Franco Gozzo , Vincenzo Caprioli
IPC分类号： C07C69/747 , A01N53/00 , A01N53/04 , A01N53/08 , A01N53/10 , C07C51/00 , C07C61/15 , C07C67/00 , C07C253/00 , C07C255/39 , C07D307/45 , C07C121/75 , C07D307/16
CPC分类号： C07D307/42 , A01N53/00
摘要： There are described 2,2-dimethyl-cyclopropanecarboxylates having in position 3 of the cyclopropane ring, a polyhalogenated chain having from 3 to 6 carbon atoms.Said compounds are insecticide and acaricide compounds with a high activity and long persistence.There is also described the use of the above mentioned compounds, as well as the synthesys processes and the corresponding intermediates.
摘要翻译：描述了具有环丙烷环位置3的2,2-二甲基 - 环丙烷羧酸酯，具有3至6个碳原子的多卤代链。所述化合物是具有高活性和长持久性的杀虫剂和杀螨剂化合物。还描述了上述化合物的用途，以及合成方法和相应的中间体。

9. 发明授权

US5081141A Fungicidal azolyl-derivatives 失效
标题翻译：真菌化合物衍生物
公开(公告)号：US5081141A
公开(公告)日：1992-01-14
申请号：US549648
申请日：1990-07-06
申请人： Roberto Colle , Francesco Corda , Giovanni Camaggi , Franco Gozzo , Luigi Mirenna , Carlo Garavaglia
发明人： Roberto Colle , Francesco Corda , Giovanni Camaggi , Franco Gozzo , Luigi Mirenna , Carlo Garavaglia
IPC分类号： C07D249/12 , A01N43/50 , A01N43/653 , A01P3/00 , C07C67/343 , C07C253/00 , C07D233/56 , C07D233/60 , C07D233/61 , C07D249/08 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07C255/00 , C07D233/56 , C07D249/08
摘要： Disclosed are compounds having the formula: ##STR1## wherein: m=0, 1;n=0, 1;Z=CH, N;R.sub.1 is selected from chlorine, bromine, fluorine, CF.sub.3, phenyl, C.sub.1 -C.sub.2 -alkoxy, C.sub.1 -C.sub.2 -haloalkoxy, alkylthio, and haloalkylthio, wherein the halogen is Cl, Br, F;R.sub.2 is H, fluorine, chlorine, or bromine;R.sub.3 represents H, CH.sub.3, CN, or also F when m=1 or when n=1 and R.sub.4, R.sub.5 are H;R.sub.4, R.sub.5 are independently H or F;R.sub.3 and R.sub.4, furthermore, when m=0, may represent, taken together, a second bond between the two carbon atoms to which they are linked in formula (I); andR.sub.f is selected from the group consisting of polyfluoroalkyls, polyfluoroalkenyls and polyfluoroalkynyls containing up to 4 carbon atoms, containing at least 2 F atoms and, optionally, other halogens selected from Cl and Br.Anti-fungal compositions containing these new compounds.
摘要翻译：公开了具有下式的化合物：其中：m = 0,1; n = 0,1; Z = CH，N; R1选自氯，溴，氟，CF3，苯基，C1-C2-烷氧基，C1-C2-卤代烷氧基，烷硫基和卤代烷硫基，其中卤素为Cl，Br，F; R2是H，氟，氯或溴; 当m = 1或当n = 1且R 4，R 5为H时，R 3表示H，CH 3，CN或F。 R4，R5独立地为H或F; 此外，当m = 0时，R 3和R 4可以一起表示在式（I）中它们连接的两个碳原子之间的第二键; 并且Rf选自包含至少2个F原子的含有至多4个碳原子的多氟烷基，多氟烯基和多氟炔基，以及任选的选自Cl和Br的其它卤素。含有这些新化合物的抗真菌组合物。

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