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1. 发明授权

US4735741A Preparation of solutions of molecular oxygen in liquid hydrocarbons 失效
标题翻译：液态烃中分子氧溶液的制备
公开(公告)号：US4735741A
公开(公告)日：1988-04-05
申请号：US854917
申请日：1986-04-23
申请人： Otto-Alfred Grosskinsky , Guenter Herrmann , Ulrich Loeffler , Rolf Schnabel , Dieter Stuetzer
发明人： Otto-Alfred Grosskinsky , Guenter Herrmann , Ulrich Loeffler , Rolf Schnabel , Dieter Stuetzer
IPC分类号： C07C27/12 , B01F1/00 , B01F3/04 , C01B13/00 , C07C27/00 , C07C35/08 , C07C45/00 , C07C49/403 , C07C67/00 , C07C45/27 , C07C45/33
CPC分类号： B01F3/04439 , B01F2003/04879 , B01F2201/01
摘要： Solutions of molecular oxygen in liquid hydrocarbons are prepared by bringing a liquid hydrocarbon into contact with molecular oxygen under superatmospheric pressure in a vertical absorption zone, by a process in which(a) a layer of water is maintained at the lower end of the absorption zone,(b) molecular oxygen is passed into the layer of water,(c) a liquid hydrocarbon is fed in above the layer of water,(d) the finely divided molecular oxygen rising from the layer of water is passed upward together with the liquid hydrocarbon at from 0.degree. to 50.degree. C., with thorough mixing in the absorption zone, with the proviso that no cohesive gas phase is formed, and(e) the solution of molecular oxygen in the liquid hydrocarbon is discharged in the upper part of the absorption zone.
摘要翻译：在液体烃中的分子氧的溶液是通过在垂直吸收区中在超大气压下使液体烃与分子氧接触的方法制备的，其中（a）一层水保持在吸收区的下端，（b）分子氧进入水层，（c）液体烃进料到水层之上，（d）从水层上升的细分子氧与液体一起向上流动烃在0至50℃下，在吸收区充分混合，条件是不形成凝聚气相，（e）液态烃中的分子氧溶液在上部排出吸收区。

2. 发明授权

US4587363A Continuous preparation of oxygen-containing compounds 失效
标题翻译：含氧化合物的连续制备
公开(公告)号：US4587363A
公开(公告)日：1986-05-06
申请号：US639325
申请日：1984-08-10
申请人： Jurgen Hartig , Gunter Schuch , Armin Stoessel , Guenter Herrmann , Arthur Brunner , Peter Zehner , Otto-Alfred Grosskinsky
发明人： Jurgen Hartig , Gunter Schuch , Armin Stoessel , Guenter Herrmann , Arthur Brunner , Peter Zehner , Otto-Alfred Grosskinsky
IPC分类号： C07C27/12 , C07C27/00 , C07C29/50 , C07C35/08 , C07C45/33 , C07C49/403 , C07C51/16 , C07C51/215 , C07C51/265 , C07C67/00
CPC分类号： C07C51/215 , C07C29/50 , C07C45/33 , C07C51/16 , C07C51/265 , C07C2101/14
摘要： Oxygen-containing compounds are prepared by oxidizing a hydrocarbon in the liquid phase with a gas containing molecular oxygen, at elevated temperatures and under superatmospheric pressure, by a continuous process in which the said gas is fed into the liquid reaction mixture, in a downward direction, at several points along the reaction zone via nozzle apertures, so that it emerges at each nozzle aperture with a velocity of from 0.01 to 1 m/sec in an amount of from 0.001 to 10 liters per second per nozzle aperture, and the said reaction mixture is brought into substantially uniform contact with the gas containing molecular oxygen, over the volume of the reaction zone.
摘要翻译：含氧化合物通过在升高的温度和超大气压下用含有分子氧的气体在液相中氧化烃，通过连续的方法将所述气体沿向下的方向进料到液体反应混合物中在沿反应区的几个点处经由喷嘴孔，使得其以每秒喷嘴孔径为0.001至10升/秒的量以0.01至1米/秒的速度在每个喷嘴孔处出现，并且所述反应使混合物与含有分子氧的气体基本上均匀地接触反应区的体积。

3. 发明授权

US4404176A Preparation of hydroxylammonium salts 失效
标题翻译：羟基铵盐的制备
公开(公告)号：US4404176A
公开(公告)日：1983-09-13
申请号：US344615
申请日：1982-02-01
申请人： Otto-Alfred Grosskinsky , Elmar Frommer , Gunther Rapp, deceased , Erwin Thomas
发明人： Otto-Alfred Grosskinsky , Elmar Frommer , Gunther Rapp, deceased , Erwin Thomas
IPC分类号： C01B21/14
CPC分类号： C01B21/1418
摘要： A process for the preparation of hydroxylammonium salts by catalytic reduction of nitric oxide with hydrogen in a dilute aqueous solution of a mineral acid, in the presence of a suspended supported platinum catalyst, at elevated temperatures, wherein the reaction is carried out in a conventional manner, in one or more reaction zones, under superatmospheric pressure, and the exit gases produced are let down to a lower pressure, and are reacted, in a downstream reaction zone, with the reaction mixture, containing hydroxylammonium salt, the ammonium salt, the supported platinum catalyst and residual mineral acid, from the upstream reaction zone or zones, or with a fresh aqueous solution of the mineral acid, which contains the supported platinum catalyst in suspension.
摘要翻译：在悬浮的负载型铂催化剂的存在下，在升高的温度下，通过在无机酸的稀的水溶液中用氢气将一氧化氮催化还原，制备羟基铵盐的方法，其中反应以常规方式进行在一个或多个反应区域中，在超大气压下，将所产生的出口气体降低至较低压力，并在下游反应区域与反应混合物反应，该反应混合物含有羟基铵盐，铵盐，负载的铂催化剂和残余无机酸，来自上游反应区或区域，或与无机酸的新鲜水溶液混合，其中含有负载的铂催化剂悬浮液。

4. 发明授权

US4457906A Preparation of hydroxylammonium salts 失效
标题翻译：羟基铵盐的制备
公开(公告)号：US4457906A
公开(公告)日：1984-07-03
申请号：US399209
申请日：1982-07-19
申请人： Otto-Alfred Grosskinsky , Elmar Frommer , Guenther Rapp , Erwin Thomas
发明人： Otto-Alfred Grosskinsky , Elmar Frommer , Guenther Rapp , Erwin Thomas
IPC分类号： C07C239/08 , B01J23/42 , C01B21/14 , C07C67/00 , C07C239/00
CPC分类号： C01B21/1418
摘要： Hydroxylammonium salts are prepared by an improved process, wherein nitric oxide is reduced catalytically with hydrogen in a dilute aqueous solution of a mineral acid in the presence of a suspended supported platinum catalyst and at elevated temperatures, and wherein the improvement comprises avoiding the formation of foam at the surface of the reaction mixture.
摘要翻译：羟基铵盐通过改进的方法制备，其中一氧化氮在悬浮的负载型铂催化剂存在下和在升高的温度下在无机酸的稀水溶液中用氢催化还原，其中改进包括避免形成泡沫在反应混合物的表面。

5. 发明授权

US4178317A Manufacture of olefinically unsaturated aliphatic or cycloaliphatic hydrocarbons 失效
标题翻译：制备烯属不饱和脂肪族或脂环族烃
公开(公告)号：US4178317A
公开(公告)日：1979-12-11
申请号：US907678
申请日：1978-05-19
申请人： Peter Horn , Otto-Alfred Grosskinsky , Hugo Fuchs
发明人： Peter Horn , Otto-Alfred Grosskinsky , Hugo Fuchs
IPC分类号： C07C1/20 , B01J23/00 , B01J27/00 , C07B61/00 , C07C1/00 , C07C1/207 , C07C1/213 , C07C11/02 , C07C67/00 , C07C3/00
CPC分类号： C07C1/213 , C07C1/2078 , C07C2101/10 , C07C2101/16 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/14 , C07C2527/24 , Y02P20/582
摘要： Olefinically unsaturated aliphatic or cycloaliphatic hydrocarbons are manufactured by bringing alkanecarboxylic acids of 3 to 20 carbon atoms, alkanedicarboxylic acids of 4 to 20 carbon atoms or 5-membered or 6-membered cycloalkanecarboxylic acids or their alkyl, cycloalkyl, aralkyl or phenyl esters, in the gas phase, at from 250.degree. to 800.degree. C., into contact with catalysts in which the active composition consists of boron trioxide, boric acid and/or boron nitride, together with one or more of the oxides of aluminum, silicon, tin, lead, titanium and zirconium.
摘要翻译：通过使3-20个碳原子的链烷羧酸，4-20个碳原子的链烷二羧酸或五元或6-元环烷烃羧酸或它们的烷基，环烷基，芳烷基或苯基酯引入到烯属不饱和脂族或脂环族烃中气相在250℃至800℃下与催化剂接触，其中活性组合物由三氧化硼，硼酸和/或氮化硼组成，以及一种或多种铝，硅，锡，铅，钛和锆。

6. 发明授权

US4257950A Continuous preparation of .epsilon.-caprolactam by Beckmann rearrangement 失效
标题翻译：通过贝克曼重排连续制备ε-己内酰胺
公开(公告)号：US4257950A
公开(公告)日：1981-03-24
申请号：US79329
申请日：1979-09-27
申请人： Peter Horn , Otto-Alfred Grosskinsky , Richard Thoma , Hugo Fuchs
发明人： Peter Horn , Otto-Alfred Grosskinsky , Richard Thoma , Hugo Fuchs
IPC分类号： C07D201/04
CPC分类号： C07D201/04
摘要： A process for the continuous preparation of .epsilon.-caprolactam by Beckmann rearrangement of cyclohexanone-oxime, dissolved in a solvent which is inert toward oleum and is immiscible with oleum and water, at an elevated temperature, with removal of the heat of rearrangement by evaporation of the solvent, wherein oleum containing caprolactam is circulated successively through a conveying zone, a mixing zone, a boiling zone and a separating zone, upstream of the conveying zone oleum is added at the rate at which it is consumed, in the mixing zone cyclohexanone-oxime dissolved in solvent is added under turbulent conditions, in the boiling zone the heat of rearrangement is removed in a conventional manner by evaporating the solvent and recycling the condensate, and in the separating zone the reaction mixture is separated into a solvent phase, from which solvent is withdrawn at the rate at which the phase is formed, and a caprolactam-containing oleum phase, which is removed at the rate at which it is formed.
摘要翻译：通过贝克曼重排环己酮 - 肟连续制备ε-己内酰胺的方法，该方法在升高的温度下溶解在对发烟硫酸是惰性的且与发烟硫酸和水不混溶的溶剂中，通过蒸发除去重排热将其中含有发烟硫酸的己内酰胺在输送区上游的输送区，混合区，沸点区和分离区连续循环的溶剂以其消耗的速率在混合区中加入环己酮 - 在湍流条件下加入溶解在溶剂中的肟，在沸腾区中，以常规方式通过蒸发溶剂并再循环冷凝物来除去重排热，并且在分离区中将反应混合物分离成溶剂相，从其中溶剂以形成相的速率被抽出，含己内酰胺的发烟硫酸相以它是形成的。

7. 发明授权

US4634584A Stabilized solutions of hydroxylamine or its salts in water or alcohols, and their preparation 失效
标题翻译：羟胺或其盐在水或醇中的稳定溶液及其制备
公开(公告)号：US4634584A
公开(公告)日：1987-01-06
申请号：US682068
申请日：1984-12-17
申请人： Otto-Alfred Grosskinsky , Elmar Frommer , Josef Ritz , Erwin Thomas , Franz-Josef Weiss
发明人： Otto-Alfred Grosskinsky , Elmar Frommer , Josef Ritz , Erwin Thomas , Franz-Josef Weiss
IPC分类号： C07D307/62 , C01B21/14 , C07C53/10 , C07C53/122
CPC分类号： C07C53/10 , C01B21/149 , C07C53/122
摘要： Stabilized solutions of hydroxylamine or its salts in water or alcohols, containing the lactone of the formula ##STR1## and their preparation.
摘要翻译：稳定的羟胺或其盐在水或醇中的溶液，其含有式（I）的内酯及其制备。

8. 发明授权

US4576804A Stabilized solutions of hydroxylamine or its salts 失效
标题翻译：稳定的羟胺或其盐的溶液
公开(公告)号：US4576804A
公开(公告)日：1986-03-18
申请号：US677306
申请日：1984-12-03
申请人： Otto-Alfred Grosskinsky , Elmar Frommer , Josef Ritz , Erwin Thomas , Franz-Josef Weiss
发明人： Otto-Alfred Grosskinsky , Elmar Frommer , Josef Ritz , Erwin Thomas , Franz-Josef Weiss
IPC分类号： C01B21/14 , C07C53/10 , C07C53/122
CPC分类号： C07C53/122 , C01B21/149 , C07C53/10
摘要： Stabilized solutions of hydroxylamine or its salts in water or alcohols, containing hydroxyanthraquinones, and their preparation.
摘要翻译：羟胺或其盐在含有羟基蒽醌的水或醇中的稳定溶液及其制备。

9. 发明授权

US4360461A Process for obtaining caprolactam by cleaving caprolactam oligomers 失效
标题翻译：通过裂解己内酰胺低聚物获得己内酰胺的方法
公开(公告)号：US4360461A
公开(公告)日：1982-11-23
申请号：US287696
申请日：1981-07-28
申请人： Hugo Fuchs , Elmar Frommer , Otto-Alfred Grosskinsky
发明人： Hugo Fuchs , Elmar Frommer , Otto-Alfred Grosskinsky
IPC分类号： C07D201/12 , C08J11/02
CPC分类号： C08J11/02 , C07D201/12 , C08J2377/02
摘要： In a process for obtaining caprolactam by cleaving caprolactam oligomers by passing them through an alumina catalyst bed at an elevated temperature, the improvement that the oligomers are introduced, as liquid or solid, into a fluidized bed of alumina and are cleaved at from 290.degree. to 400.degree. C. in the presence of steam.
摘要翻译：在通过使己内酰胺低聚物通过在高温下通过氧化铝催化剂床而获得己内酰胺的方法中，将低聚物作为液体或固体引入到氧化铝的流化床中并且在290°至 400℃，在蒸汽存在下。

10. 发明授权

US4227021A Production of adipic acid from acidic wash waters 失效
标题翻译：从酸性洗涤水中生产己二酸
公开(公告)号：US4227021A
公开(公告)日：1980-10-07
申请号：US901235
申请日：1978-04-28
申请人： Otto-Alfred Grosskinsky , Norbert Petri , Johannes Hein , Hans Leitner
发明人： Otto-Alfred Grosskinsky , Norbert Petri , Johannes Hein , Hans Leitner
IPC分类号： C07C55/14 , C07C51/00 , C07C51/42 , C07C51/487 , C07C67/00 , C07C51/24
CPC分类号： C07C51/487
摘要： An improved process for producing adipic acid from the acidic wash waters which arise in the process for oxidizing cyclohexane with air, by treatment with nitric acid at from 10.degree. to 50.degree. C., with removal of the heat of reaction by external cooling, wherein the reaction mixture is led, at a flow velocity of at least 2.0 m/sec, as a thin layer spirally in counter-current to the coolant, under conditions which do not perturb the flow of the reaction mixture.
摘要翻译：通过在10℃至50℃下用硝酸处理，通过外部冷却除去反应热而在由空气氧化环己烷的过程中产生的酸性洗涤水中生产己二酸的改进方法，其中在不干扰反应混合物的流动的条件下，反应混合物以至少2.0m / sec的流速被引导为与冷却剂逆流螺旋形的薄层。

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