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    • 1. 发明授权
    • Fungicidal mixture
    • 杀菌剂混合物
    • US6075030A
    • 2000-06-13
    • US849126
    • 1997-06-16
    • Oliver WagnerKarl EickenHerbert BayerHubert SauterEberhard AmmermannGisela Lorenz
    • Oliver WagnerKarl EickenHerbert BayerHubert SauterEberhard AmmermannGisela Lorenz
    • C07D215/22A01N37/10A01N37/18A01N37/36A01N37/50A01N43/36A01N43/42A01N43/54A01N43/653A01P3/00C07D207/34C07D405/06
    • A01N43/42
    • A fungicidal mixture comprises:a) a compound of the formula I ##STR1## an N-oxide or a salt thereof, where the radicals are defined as follows: R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are hydrogen, hydroxyl, nitro, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio;R.sup.5, R.sup.6 and R.sup.7 are hydrogen, hydroxyl, cyano, nitro, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, hydroxyalkyl, acyl, aryl or aryloxy,b) a compound of the formula II, ##STR2## where the radicals are defined as follows: R.sup.8 isphenyl which can have attached to it one to three of the following groups: cyano, halogen, alkyl, haloalkyl and alkoxy, orpyrimidyl which can have attached to it an alkyl group and/or a phenoxy group;A is oxygen or oxymethylene (--OCH.sub.2 --);X is CH or N;Y is oxygen or NR, where R is hydrogen, alkyl or alkoxy, orc) a pyrimidine derivative of the formula III ##STR3## or a salt thereof where the radical R.sup.9 is methyl, propyn-1-yl or cyclopropyl, ord) (2RS,3SR)-1-[3-(2-chlorophenyl)-2-(4-fluorophenyl)oxiran-2-ylmethyl]-1H-1,2,4-triazole (IV) ##STR4## or e) a compound of the formula V ##STR5## in which the radicals are as defined below: R.sup.10 is fluorine or chlorine;R.sup.11 is trifluoromethyl or chlorine, orR.sup.10 and R.sup.11 together are a group --OCF.sub.2 O--,in a synergistically active amount.
    • PCT No.PCT / EP95 / 04785第 371日期:1997年6月16日 102(e)日期1997年6月16日PCT提交1995年12月5日PCT公布。 第WO96 / 18299号公报 日期1996年6月20日一种杀真菌混合物包含:a)式I化合物为N-氧化物或其盐,其中自由基定义如下:R 1,R 2,R 3和R 4为氢,羟基,硝基,卤素 ,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,卤代烷硫基; R5,R6和R7是氢,羟基,氰基,硝基,卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,卤代烷硫基,羟烷基,酰基,芳基或芳氧基,b)式Ⅱ化合物, 如下:R8是可以与其连接的一至三个以下基团的苯基:氰基,卤素,烷基,卤代烷基和烷氧基,或可以与其连接的烷基和/或苯氧基的嘧啶基; A是氧或甲醛(-OCH 2 - ); X是CH或N; 或者其中R为氢,烷基或烷氧基,或c)式III的嘧啶衍生物或其盐,其中基团R 9为甲基,丙炔-1-基或环丙基,或d)(2RS, 3SR)-1- [3-(2-氯苯基)-2-(4-氟苯基)环氧乙烷-2-基甲基] -1H-1,2,4-三唑(Ⅳ)或e)式Ⅴ的化合物 其基团如下所定义:R 10是氟或氯; R11是三氟甲基或氯,或R 10和R 11一起是基团-OCF 2 O-,具有协同活性的量。
    • 4. 发明授权
    • Fungicidal mixture
    • 杀菌剂混合物
    • US06177446B1
    • 2001-01-23
    • US09484529
    • 2000-01-18
    • Oliver WagnerKarl EickenHerbert BayerHubert SauterEberhard AmmermannGisela Lorenz
    • Oliver WagnerKarl EickenHerbert BayerHubert SauterEberhard AmmermannGisela Lorenz
    • A01N4342
    • A01N43/42A01N43/653A01N43/54A01N43/36A01N37/50A01N2300/00
    • A composition comprising effective amounts of a) a compound of the formula I or an N-oxide or salt thereof, wherein R1, R2, R3 and R4 are hydrogen, hydroxyl, nitro, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio or C1-C4-haloalkylthio; R5, R6 and R7 are hydrogen, hydroxyl, cyano, nitro, halogen, C1-C7-alkyl, C1-C7-haloalkyl, C1-C7-alkoxy, C1-C7-haloalkoxy, C1-C7-alkylthio, C1-C7-haloalkylthio, C1-C7-hydroxyalkyl, C2-C4-acyl, aryl or aryloxy, it being possible for the radicals with aryl to carry one to three of the following groups: cyano, nitro, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio and C1-C4-haloalkylthio, and d) (2RS,3SR)-1-[3-(2-chlorophenyl)-2-(4-fluorophenyl)oxiran-2-ylmethyl]-1H-1,2,4-triazole (IV) exhibits a synergistic fungicidal activity.
    • 包含有效量的a)式I的化合物或其N-氧化物或其盐的组合物,其中R 1,R 2,R 3和R 4是氢,羟基,硝基,卤素,C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基,C 1 C 1-4 - 烷氧基,C 1 -C 4 - 卤代烷氧基,C 1 -C 4 - 烷硫基或C 1 -C 4卤代烷硫基; R 5,R 6和R 7是氢,羟基,氰基,硝基, ,C 1 -C 7 - 烷氧基,C 1 -C 7 - 卤代烷氧基,C 1 -C 7 - 烷硫基,C 1 -C 7 - 卤代烷硫基,C 1 -C 7 - 羟基烷基,C 2 -C 4酰基,芳基或芳氧基, 携带一至三个以下基团:氰基,硝基,卤素,C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 卤代烷氧基,C 1 -C 4 - 烷硫基和C 1 -C 4卤代烷硫基 ,和d)(2RS,3SR)-1- [3-(2-氯苯基)-2-(4-氟苯基)环氧乙烷-2-基甲基] -1H-1,2,4-三唑(IV)表现出协同杀真菌剂 活动。
    • 9. 发明授权
    • Fungicidal mixtures
    • 杀菌混合物
    • US06436979B1
    • 2002-08-20
    • US09674542
    • 2000-11-02
    • Klaus SchelbergerMaria SchererReinhold SaurKarl EickenHubert SauterEberhard AmmermannThomas GroteGisela LorenzSiegfried Strathmann
    • Klaus SchelbergerMaria SchererReinhold SaurKarl EickenHubert SauterEberhard AmmermannThomas GroteGisela LorenzSiegfried Strathmann
    • A01N4380
    • A01N47/12A01N47/24A01N37/50A01N2300/00
    • A fungicidal mixture, comprising at least one compound selected from a) [sic] carbamates of the formula I,  in which T is CH or N, n is 0, 1 or 2 and R is halogen, Cl-C4-alkyl or C1-C4-haloalkyl, where the radicals R may be different if n is 2, a2) the oxime ether carboxylate of the formula II  or a3) the oxime ether carboxamide of the formula III,  and b) a compound of the formula IV  where the substituents R1 to R3 have the following meaning: R1 is C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-alkyl-C3-C7-cycloalkyl, where these radicals may carry substituents selected from halogen, cyano and Cl-C4-alkoxy, R2 is C1-C4-alkyl or C1-C4-haloalkyl, R3 is hydrogen, halogen, Cl-C4-alkyl, C1-C4-alkoxy, C1-C4-alkylthio, N—C1-C4-alkylamino, Cl-C4-haloalkyl or C1-C4-haloalkoxy, Y is O, S, CHR4 or NR5, where R4 and R5 may each have the meanings mentioned for R2, n is 0, 1, 2 or 3, in a synergistically effective amount, and methods for controlling harmful fungi using these mixtures are described.
    • 一种杀真菌混合物,其包含至少一种选自以下的化合物:其中T为CH或N,n为0,1或2,R为卤素,C 1 -C 4烷基或C 1 -C 4的式I的(S) - 卤代烷基,其中如果n是2,基团R可以不同,a2)式II的肟醚羧酸酯ora3)式III的肟醚甲酰胺,和b)式IV化合物,其中取代基R 1至R 3 具有以下含义:R 1是C 1 -C 4 - 烷基,C 2 -C 4 - 烯基,C 2 -C 4 - 炔基,C 1 -C 4烷基-C 3 -C 7 - 环烷基,其中这些基团可以带有选自卤素,氰基和Cl C 1-4 - 烷氧基,R 2是C 1 -C 4烷基或C 1 -C 4卤代烷基,R 3是氢,卤素,C 1 -C 4烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,N-C 1 -C 4烷基氨基 ,C 1 -C 4卤代烷基或C 1 -C 4卤代烷氧基,Y是O,S,CHR 4或NR 5,其中R 4和R 5可以各自具有R2,n为0,1,2或3所述的含义, 描述了使用这些混合物来控制有害真菌的量和方法。
    • 10. 发明授权
    • Fungicidal mixtures
    • 杀菌混合物
    • US5591747A
    • 1997-01-07
    • US550540
    • 1995-10-30
    • Karl EickenBernd MullerHubert SauterGisela LorenzEberhard AmmermannKlaus SchelbergerReinhold Saur
    • Karl EickenBernd MullerHubert SauterGisela LorenzEberhard AmmermannKlaus SchelbergerReinhold Saur
    • A01N37/38A01N37/50A01N43/54A01N37/18
    • A01N43/54
    • A fungicidal synergistic mixture containinga) a compound of the formula I ##STR1## where the substituents have the following meanings: R.sup.1 is a phenyl radical which can carry one to three of the following groups: cyano, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.2 -haloalkyl and C.sub.1 -C.sub.4 -alkoxy, or a pyrimidyl radical which can carry a C.sub.1 -C.sub.3 -alkyl group and/or a phenoxy group, the phenoxy group in turn being able to carry one to three of the following radicals: cyano, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.2 -haloalkyl and C.sub.1 -C.sub.4 -alkoxy,A is oxygen or oxymethylene (--OCH.sub.2 --);X is CH or N,Y is oxygen or NR.sup.2, R.sup.2 being hydrogen, C.sub.1 -C.sub.3 -alkyl or C.sub.1 -C.sub.3 -alkoxy,andb) a pyrimidine derivative of the formula II ##STR2## where R is methyl, propyn-1-yl or cyclopropyl, in a synergistically active amount, is described.
    • 一种杀真菌的协同混合物,其含有a)式Ⅰ化合物,其中取代基具有下列含义:R 1是可以携带一至三个下列基团的苯基:氰基,卤素,C 1 -C 4烷基 ,C 1 -C 2卤代烷基和C 1 -C 4 - 烷氧基,或可携带C 1 -C 3 - 烷基和/或苯氧基的嘧啶基,苯氧基依次可携带一至三个下列基团 :氰基,卤素,C 1 -C 4 - 烷基,C 1 -C 2 - 卤代烷基和C 1 -C 4 - 烷氧基,A是氧或甲亚甲基(-OCH 2 - ); X是CH或N,Y是氧或NR 2,R 2是氢,C 1 -C 3 - 烷基或C 1 -C 3 - 烷氧基,和b)式II的嘧啶衍生物,其中R是甲基,丙炔-1 芳基或环丙基,以协同活性的量描述。