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    • 1. 发明授权
    • Electrochemical synthesis of ammonia
    • 电化学合成氨
    • US07314544B2
    • 2008-01-01
    • US11212038
    • 2005-08-25
    • Oliver J. MurphyAdrian J. DenvirSorin G. TeodorescuKyle B. Uselton
    • Oliver J. MurphyAdrian J. DenvirSorin G. TeodorescuKyle B. Uselton
    • C25B1/00
    • C25B1/00
    • A method for the anodic electrochemical synthesis of ammonia gas. The method comprises providing an electrolyte between an anode and a cathode, providing nitrogen and hydrogen gases to the cathode, oxidizing negatively charged nitrogen-containing species and negatively charged hydrogen-containing species present in the electrolyte at the anode to form adsorbed nitrogen species and adsorbed hydrogen species, respectively, and reacting the adsorbed nitrogen species with the adsorbed hydrogen species to form ammonia. Nitrogen and hydrogen gases may be provided through a porous cathode substrate. The negatively charged nitrogen-containing species in the electrolyte may be produced by reducing nitrogen gas at the cathode and/or by supplying a nitrogen-containing salt, such as lithium nitride, into the molten salt electrolyte. Similarly, the negatively charged hydrogen-containing species in the electrolyte may be produced by reducing hydrogen gas at the cathode and/or by supplying a hydrogen-containing salt, such as lithium hydride, into the molten salt electrolyte.
    • 一种用于阳极电化学合成氨气的方法。 该方法包括在阳极和阴极之间提供电解质,向阴极提供氮气和氢气,在阳极处氧化带负电荷的含氮物质和存在于电解质中的带负电荷的含氢物质以形成吸附的氮物质并吸附 氢物种,并将吸附的氮物质与吸附的氢物质反应形成氨。 可以通过多孔阴极基底提供氮气和氢气。 电解质中带负电的含氮物质可以通过在阴极处还原氮气和/或通过向熔融盐电解质中提供氮化钠等含氮盐来制备。 类似地,电解质中带负电荷的含氢物质可以通过还原阴极处的氢气和/或通过向熔融盐电解质中提供氢化锂等含氢盐来制备。