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1. 发明申请

US20160207871A1 Method for Post-Treating Polyol Esters 有权
标题翻译：后处理多元醇酯的方法
公开(公告)号：US20160207871A1
公开(公告)日：2016-07-21
申请号：US14915448
申请日：2014-08-29
申请人： OXEA GMBH
发明人： Jens KUBITSCHKE , Thorsten KREICKMANN , Jörg ARNOLD , Matthias KRAMER , Heinz STRUTZ
IPC分类号： C07C67/60
CPC分类号： C07C67/60 , C07C67/08 , C07C67/56 , C07C69/28
摘要： A batchwise process for aftertreatment of polyol esters prepared by reacting polyols of the general formula (II) H—(—O—[—CR1R2—]m—)o—OH (II) in which R1 and R2 are each independently hydrogen, an alkyl radical having 1 to 5 carbon atoms, preferably methyl, ethyl or propyl, or a hydroxyalkyl radical having 1 to 5 carbon atoms, preferably the hydroxymethyl radical, m is an integer from 1 to 10, preferably 1 to 8 and especially 1, 2, 3 or 4, o is an integer from 2 to 15, preferably 2 to 8 and especially 2, 3, 4 or 5, with excess linear or branched aliphatic monocarboxylic acids having 3 to 20 carbon atoms and having a lower boiling point than the polyols used. The process is carried out in the presence of a Lewis acid and in the presence of an adsorbent, while removing the water formed, characterized in that the excess monocarboxylic acid is removed by distillation and water is added to the crude ester obtained at a temperature below the boiling point of water at the particular pressure and the crude ester with added water is aftertreated with avoidance of basic compounds, and the sparingly soluble conversion products and the adsorbent present in the esterification reaction are filtered off.
摘要翻译：用于后处理多元醇酯的分批方法，其通过使通式（II）的多元醇H - （ - O - [ - CR 1 R 2 - ] m - ）o-OH（II）反应制备，其中R 1和R 2各自独立地为氢，具有1至5个碳原子的烷基，优选甲基，乙基或丙基，或具有1至5个碳原子的羟烷基，优选羟甲基，m为1至10，优选1至8，特别是1,2 ，3或4，o是2至15，优选2至8，特别是2，4或5的整数，其中具有3至20个碳原子并具有比其低的沸点的过量的直链或支链脂肪族单羧酸使用多元醇该方法在路易斯酸存在下并且在吸附剂存在下进行，同时除去形成的水，其特征在于通过蒸馏除去过量的单羧酸，并将水加入到在低于在特定压力下的水的沸点和加入水的粗酯进行后处理，避免碱性化合物，并且滤出酯化反应中存在的微溶的转化产物和吸附剂。

2. 发明申请

US20160229789A1 Method for Obtaining Polyol Esters-Enriched Product Streams from the Side-Streams in Polyol Ester Production 有权
标题翻译：在多元醇酯生产中从侧流获得多元醇酯富集产物流的方法
公开(公告)号：US20160229789A1
公开(公告)日：2016-08-11
申请号：US14915915
申请日：2014-10-09
申请人： OXEA GMBH
发明人： Jens KUBITSCHKE , Thorsten KREICKMANN , Jörg ARNOLD , Heinz STRUTZ
IPC分类号： C07C67/54 , C07C67/08
CPC分类号： C07C67/54 , C07C67/08 , C07C67/58 , C07C67/60 , C07C69/28
摘要： A process for obtaining product streams enriched with polyol esters from the secondary streams from polyol ester preparation, comprising a) the reaction of polyols of the general formula (II) H—(—O—[—CR1R2—]m—)o—OH (II) in which R1 and R2 are each independently hydrogen, an alkyl radical having 1 to 5 carbon atoms or a hydroxyalkyl radical having 1 to 5 carbon atoms, m is an integer from 1 to 10, o is an integer from 2 to 15, with linear or branched aliphatic monocarboxylic acids having 3 to 20 carbon atom, with removal of the water formed; b) the removal of unconverted starting compounds from the crude ester formed; c) the treatment of the crude ester obtained in step b) with steam to form a volatile secondary stream; and d) the removal of the volatile secondary stream obtained in step c), characterized in that the volatile secondary stream obtained in step d) is separated into an aqueous phase and an organic phase and the organic phase removed is subjected to a further treatment with steam and a product stream enriched with polyol esters is obtained as residue.
摘要翻译：一种从多元醇酯制备的二次流中获得富含多元醇酯的产物流的方法，其包括a）通式（II）的多元醇H - （ - O - [ - CR 1 R 2 - ] m - ）o-OH （II）其中R 1和R 2各自独立地为氢，具有1至5个碳原子的烷基或具有1至5个碳原子的羟烷基，m为1至10的整数，o为2至15的整数与碳原子数3〜20的直链状或支链状的脂肪族一元羧酸一起除去形成的水分; b）从形成的粗酯中除去未转化的起始化合物; c）用蒸汽处理在步骤b）中获得的粗酯以形成挥发性二级流; 和d）去除步骤c）中获得的挥发性二次物流，其特征在于将步骤d）中获得的挥发性二次水分离成水相和有机相，并将所除去的有机相进一步用获得蒸汽和富含多元醇酯的产物流作为残余物。

3. 发明申请

US20160137582A1 Method for Producing Polyol Esters 有权
公开(公告)号：US20160137582A1
公开(公告)日：2016-05-19
申请号：US15008498
申请日：2016-01-28
申请人： Oxea GmbH
发明人： Guido D. FREY , Tonia WEBER , Jörg ARNOLD , Thorsten KREICKMANN , Heinz STRUTZ
IPC分类号： C07C67/08
CPC分类号： C07C67/08 , C07C69/28
摘要： A process for preparing polyol esters by reacting polyols with linear or branched aliphatic monocarboxylic acids having 3 to 20 carbon atoms, is characterized in that a mixture of the starting compounds is allowed to react in the presence of a Lewis acid containing at least one element of groups 4 to 14 of the periodic table of the elements as a catalyst and in the presence of an adsorbent with removal of the water formed, and then the crude ester obtained is aftertreated by adding a further adsorbent which is an acidic activated carbon having a pH of 1 to 6.5.

4. 发明申请

US20150344400A1 Method for Producing Polyol Esters 有权
标题翻译：多元醇酯的制备方法
公开(公告)号：US20150344400A1
公开(公告)日：2015-12-03
申请号：US14427742
申请日：2013-08-10
申请人： OXEA GmbH
发明人： Guido D. FREY , Tonia WEBER , Jörg ARNOLD , Thorsten KREICKMANN , Heinz STRUTZ
IPC分类号： C07C67/08
CPC分类号： C07C67/08 , C07C69/28
摘要： A process for preparing polyol esters by reacting polyols with linear or branched aliphatic monocarboxylic acids having 3 to 20 carbon atoms, is characterized in that a mixture of the starting compounds is allowed to react in the presence of a Lewis acid containing at least one element of groups 4 to 14 of the periodic table of the elements as a catalyst and in the presence of an adsorbent with removal of the water formed, and then the crude ester obtained is aftertreated by adding a further adsorbent which is an acidic activated carbon having a pH of 1 to 6.5.
摘要翻译：多元醇与碳原子数为3〜20的直链或支链脂族一元羧酸反应制备多元醇酯的方法，其特征在于使起始化合物的混合物在含有至少一种元素的路易斯酸作为催化剂的元素周期表的4至14族，并且在除去所形成的水的吸附剂存在下，然后通过加入另外的吸附剂进行后处理，所述吸附剂是具有pH的酸性活性炭为1〜6.5。

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