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1. 发明申请

US20190218166A1 Continuous Production Method for 2-Methylene Alkanals 审中-公开
公开(公告)号：US20190218166A1
公开(公告)日：2019-07-18
申请号：US16325950
申请日：2017-09-05
申请人： OXEA GmbH
发明人： Kurt SCHALAPSKI , Jan-Henry RAHE , Christoph BALZAREK , Gregor MEIER , Heinz STRUTZ
IPC分类号： C07C45/75 , C07C47/21 , B01J19/24 , B01J19/00
CPC分类号： C07C45/75 , B01J19/0013 , B01J19/2415 , B01J2219/00051 , B01J2219/00164 , B01J2219/3322 , C07C47/21
摘要： The present invention relates to the continuous production of 2-methylene alkanals in a tube reactor, wherein in the 2-position non-branched alkanals are reacted with formaldehyde under acid-base catalysis in the presence of secondary amines and carboxylic acids under laminar flow conditions.

2. 发明授权

US09434672B2 Method for producing isononanoic acids from 2-ethyl hexanol 有权
标题翻译：由2-乙基己醇生产异壬酸的方法
公开(公告)号：US09434672B2
公开(公告)日：2016-09-06
申请号：US14413503
申请日：2013-06-18
申请人： Oxea GmbH
发明人： Guido D. Frey , Matthias Eisenacher , Kristina Kockrick , Heinz Strutz
IPC分类号： C07C51/235 , C07C1/24 , C07C45/50 , C07C51/56 , C07C51/60 , C07C53/126 , C07C67/04 , C07C67/08 , C07C67/10 , C07C231/02 , C07D301/30
CPC分类号： C07C51/235 , C07C1/24 , C07C45/50 , C07C51/56 , C07C51/60 , C07C53/126 , C07C67/04 , C07C67/08 , C07C67/10 , C07C231/02 , C07C2521/04 , C07D301/30 , C07C11/02 , C07C47/02
摘要： Process for preparing isononanoic acid proceeding from 2-ethylhexanol, characterized in that (a) 2-ethylhexanol is dehydrated to octene in the presence of a catalyst; (b) the octene obtained in step a) is reacted in the presence of a transition metal compound of group VIII of the periodic table of the elements with carbon monoxide and hydrogen to give isononanal; and (c) the isononanal obtained in step b) is oxidized to isononanoic acid.
摘要翻译：由2-乙基己醇制备异壬酸的方法，其特征在于（a）2-乙基己醇在催化剂存在下脱水至辛烯; （b）步骤a）中获得的辛烯在元素周期表第Ⅷ族过渡金属化合物与一氧化碳和氢气存在下反应，得到异壬醛; 和（c）步骤b）中获得的异壬醛被氧化成异壬酸。

3. 发明授权

US09334225B2 Vinyl esters of isononanoic acid starting from 2-ethyl hexanol, methods for the production thereof and use thereof 有权
标题翻译：从2-乙基己醇开始的异壬酸的乙烯基酯，其制备方法和用途
公开(公告)号：US09334225B2
公开(公告)日：2016-05-10
申请号：US14413429
申请日：2013-06-19
申请人： Oxea GmbH
发明人： Leif Johnen , Guido D. Frey , Matthias Eisenacher , Kristina Kockrick , Heinz Strutz
IPC分类号： C07B33/00 , C07C67/04 , C07C67/10 , C07C1/24 , C07C45/50 , C07C51/14 , C07C51/235 , C07C51/21 , C08F220/68
CPC分类号： C07C67/04 , C07C1/24 , C07C45/50 , C07C51/14 , C07C51/21 , C07C51/235 , C07C67/10 , C07C2521/04 , C07C2521/08 , C07C2523/755 , C07C2527/173 , C08F220/68 , C07C11/02 , C07C47/02 , C07C53/126 , C07C69/24
摘要： Process for preparing the vinyl ester of isononanoic acid starting out from 2-ethylhexanol, characterized in that (a) 2-ethylhexanol is dehydrated in the presence of a catalyst to form octene; (b) the octene obtained in step a) is converted into an isononanoic acid having one more carbon atom; and (c) the isononanoic acid obtained in step b) is converted into the corresponding vinyl ester.
摘要翻译：从2-乙基己醇开始制备异壬酸乙烯基酯的方法，其特征在于（a）2-乙基己醇在催化剂存在下脱水形成辛烯; （b）将步骤a）中获得的辛烯转化为具有一个以上碳原子的异壬酸; 和（c）将步骤b）中获得的异壬酸转化成相应的乙烯基酯。

4. 发明授权

US09174922B2 Method for producing vinyl esters 有权
标题翻译：乙烯基酯的制备方法
公开(公告)号：US09174922B2
公开(公告)日：2015-11-03
申请号：US14372290
申请日：2013-01-18
申请人： Oxea GmbH
发明人： Leif Johnen , Heinz Strutz , Kurt Schalapski , Norman Nowotny , Wolfgang Höfs , Sebastian Geisel
IPC分类号： C07C67/10 , C07C67/333 , C07C69/01 , C07C67/54
CPC分类号： C07C67/333 , C07C67/10 , C07C67/54 , C07C69/01 , C07C69/24 , C07C69/78
摘要： The present invention relates to a continuous, catalytic process for preparing a vinyl ester of the formula R—C(O)O—CH═CH2 by reaction of a carboxylic acid of the formula R—C(O)OH with a transvinylating reagent of the formula R1—C(O)O—CH═CH2, wherein the reaction is effected at a temperature of 90 to 160° C. and at a pressure of 0.5 to 15 MPa without withdrawal of a reactant in the presence of a transition metal catalyst containing at least one transition metal from the group of ruthenium, osmium, rhodium, iridium, palladium and platinum, and then the resulting reaction mixture is separated into its constituents.
摘要翻译：本发明涉及通过式R-C（O）OH的羧酸与式R-C（O）OH的羧酸反应制备式R-C（O）O-CH = CH 2的乙烯基酯的连续催化方法，式R 1 -C（O）O-CH = CH 2，其中反应在90至160℃的温度和0.5至15MPa的压力下进行，而在过渡金属的存在下不引发反应物含有来自钌，锇，铑，铱，钯和铂的至少一种过渡金属的催化剂，然后将所得反应混合物分离成其组分。

5. 发明授权

US09174921B2 Transvinylation as a first stage of coupling production of vinyl esters and acetic acid or propionic acid reaction products 有权
标题翻译：作为乙烯基酯和乙酸或丙酸反应产物的偶联生产的第一阶段的转乙烯化
公开(公告)号：US09174921B2
公开(公告)日：2015-11-03
申请号：US14372235
申请日：2013-01-18
申请人： Oxea GmbH
发明人： Leif Johnen , Heinz Strutz
IPC分类号： C07C67/10 , C07C69/01 , C07C29/149 , C07C67/055 , C07C67/08 , C07C67/54 , C07C51/02 , C07C51/09 , C07C51/363 , C07C67/333
CPC分类号： C07C67/333 , C07C29/149 , C07C51/02 , C07C51/09 , C07C51/363 , C07C67/055 , C07C67/08 , C07C67/10 , C07C67/54 , C07C69/01 , C07C69/24 , C07C69/78 , C07C53/16 , C07C53/19 , C07C69/15 , C07C31/08 , C07C31/10 , C07C53/40 , C07C53/42 , C07C53/12 , C07C53/122 , C07C53/08 , C07C69/14
摘要： Process for coproduction of a vinyl ester of the formula R—C(O)O—CH═CH2 by transvinylation reaction of a carboxylic acid of the formula R—C(O)OH with a transvinylating reagent of the formula R1—C(O)O—CH═CH2, characterized in that (a) the transvinylation reaction is conducted continuously at a temperature of 90 to 160° C. and at a pressure of 0.5 to 15 MPa without withdrawal of a reactant in the presence of a transition metal catalyst containing at least one transition metal selected from the group of ruthenium, osmium, rhodium, iridium, palladium and platinum; (b) the resulting reaction mixture is separated into its constituents and the vinyl ester of the formula R—C(O)O—CH═CH2 and the carboxylic acid of the formula R1—C(O)—OH are removed; and (c) the carboxylic acid obtained after step (b) is converted to a derivative of the formula R1—C(O)—X, R1—CH2—OH or R6—C(O)—OH in which X is vinyloxy, O—CH═CH2, halogen, alkoxy of the formula OR2 in which R2 is a substituted or unsubstituted hydrocarbyl radical having 1 to 10 carbon atoms, amino of the formula NR3R4 in which R3 and R4 are each independently hydrogen or a substituted or unsubstituted hydrocarbyl radical having 1 to 10 carbon atoms, or carboxyl of the formula O—C(O)—R5 in which R5 is hydrogen or a substituted or unsubstituted hydrocarbyl radical having 1 to 10 carbon atoms, and R6 is the partly or fully halogen-substituted R1 radical.
摘要翻译：通过式R-C（O）OH的羧酸与式R1-C（O）的转乙烯化试剂进行反式化反应，共同制备式R-C（O）O-CH = CH 2的乙烯基酯的方法）O-CH = CH 2，其特征在于：（a）在90至160℃的温度和0.5至15MPa的压力下连续进行转化反应，而在过渡金属存在下不引发反应物含有选自钌，锇，铑，铱，钯和铂中的至少一种过渡金属的催化剂; （b）将所得反应混合物分离成其组分，并且除去式R-C（O）O-CH = CH 2的乙烯基酯和式R 1 -C（O）-OH的羧酸; 和（c）将步骤（b）后获得的羧酸转化为其中X为乙烯氧基的式R 1 -C（O）-X，R 1 -CH 2 -OH或R 6 -C（O）-OH的衍生物， O-CH = CH 2，卤素，式OR 2的烷氧基，其中R 2是具有1至10个碳原子的取代或未取代的烃基，式NR 3 R 4的氨基，其中R 3和R 4各自独立地为氢或取代或未取代的烃基具有1-10个碳原子的基团，或其中R 5是氢的式O-C（O）-R 5的羧基或具有1至10个碳原子的取代或未取代的烃基，R 6是部分或完全卤素取代的 R1激进。

6. 发明申请

US20150166457A1 Method for the Production of Terephthalic Acid and the Derivatives Thereof 审中-公开
标题翻译：对苯二甲酸及其衍生物的制备方法
公开(公告)号：US20150166457A1
公开(公告)日：2015-06-18
申请号：US14406890
申请日：2013-06-20
申请人： Oxea GmbH
发明人： Jens Klabunde , Heinz Strutz , Guido D. Frey
IPC分类号： C07C67/08 , C12P7/62 , C07C5/41 , C07C2/46 , C07C51/265 , C07C2/08
CPC分类号： C07C67/08 , C07C2/08 , C07C2/46 , C07C2/76 , C07C5/41 , C07C51/265 , C07C2521/12 , C07C2523/14 , C07C2523/18 , C07C2523/26 , C07C2523/36 , C12P5/026 , C12P7/44 , C12P7/62 , C07C15/08 , C07C63/26 , C07C69/82 , C07C11/02
摘要： The present invention relates to a method of producing terephthalic acid derivatives from isobutene via p-xylene. The isobutene is fermentatively produced isobutene, the higher purity of which improves the method and the properties of the produced p-xylene and the terephthalic acid derivatives derived therefrom.
摘要翻译：本发明涉及通过对二甲苯从异丁烯生产对苯二甲酸衍生物的方法。异丁烯是发酵生产的异丁烯，其较高的纯度改善了生产的对二甲苯和由其衍生的对苯二甲酸衍生物的方法和性质。

7. 发明授权

US09045451B2 Method for recovering di-trimethylolpropane and trimethylolpropane-enriched product streams from the side streams of trimethylolpropane production 有权
标题翻译：从三羟甲基丙烷生产的侧流回收二羟甲基丙烷和三羟甲基丙烷富集产物流的方法
公开(公告)号：US09045451B2
公开(公告)日：2015-06-02
申请号：US14351205
申请日：2012-10-24
申请人： Oxea GmbH
发明人： Guido D. Frey , Thorsten Kreickmann , Heinz Strutz
IPC分类号： C07C41/42 , C07C29/10 , C07D319/06 , C07C29/80 , C07C29/90 , C07C41/44
CPC分类号： C07D319/06 , C07C29/10 , C07C29/80 , C07C29/90 , C07C41/42 , C07C41/44 , C07C31/22 , C07C43/132
摘要： Process for obtaining ditrimethylolpropane and trimethylolpropane-enriched product streams from the high-boiling fractions and residues which are obtained in the distillative purification of trimethylolpropane, characterized in that these high-boiling fractions and residues are combined and a polar solvent is added to produce a solution and the solution is treated at a temperature of 120 to 280° C. and at a pressure of 2 to 25 MPa with hydrogen in the presence of a solid nickel catalyst and an acidic compound. After catalytic treatment, the solution is subjected to multi-stage distillation including with a thin film evaporator with a column attachment in order to recover ditrimethylolpropane and trimethylolpropane-enriched product streams.
摘要翻译：从三沸石馏分和三羟甲基丙烷的蒸馏提纯中获得的高沸点馏分和残余物获得三羟甲基丙烷和三羟甲基丙烷富集产物流的方法，其特征在于将这些高沸点馏分和残余物合并，加入极性溶剂以产生溶液在固体镍催化剂和酸性化合物的存在下，用氢气在120〜280℃的温度和2〜25MPa的压力下处理溶液。在催化处理后，将溶液进行多级蒸馏，包括用柱式附件的薄膜蒸发器，以回收二羟甲基丙烷和富含三羟甲基丙烷的产物流。

8. 发明申请

US20150105507A1 Mixtures Containing Trimellitic Acid Ester and Polyether Polyol Ester as Plasticizers, Use of the Mixtures for Producing Polymer Compounds and PVC materials Containing Said Mixtures 有权
标题翻译：含有偏苯三酸酯和聚醚多元醇作为增塑剂的混合物，用于生产含有所述混合物的聚合物和PVC材料的混合物
公开(公告)号：US20150105507A1
公开(公告)日：2015-04-16
申请号：US14391431
申请日：2013-06-05
申请人： Oxea GmbH
发明人： Guido D. Frey , Horst Lange , Heinz Strutz , Jacco de Haas
IPC分类号： C08K5/12 , C08K5/103
CPC分类号： C08K5/12 , C08K5/0016 , C08K5/103 , C08L71/02 , C08L27/06
摘要： A mixture useful as plasticizer comprises trimellitic esters and polyether polyol esters, characterized in that the mixture comprises from 1 to 99% by weight of trimellitic esters and 99 to 1% by weight of polyether polyol esters, wherein the polyether polyol esters can be derived from linear or branched, aliphatic monocarboxylic acids having 3 to 20 carbon atoms in the molecule.
摘要翻译：可用作增塑剂的混合物包括偏苯三酸酯和聚醚多元醇酯，其特征在于该混合物包含1至99重量％的偏苯三酸酯和99至1重量％的聚醚多元醇酯，其中聚醚多元醇酯可衍生自在分子中具有3至20个碳原子的直链或支链的脂族单羧酸。

9. 发明授权

US10450254B2 Method for the combined production of polyols in the presence of an inorganic base 有权
公开(公告)号：US10450254B2
公开(公告)日：2019-10-22
申请号：US16327041
申请日：2017-09-05
申请人： OXEA GmbH
发明人： Guido D. Frey , Melanie Bothe , Heinz Strutz , William E. Slinkard
IPC分类号： C07C29/38 , C07C31/22 , C07C31/20
摘要： The present invention relates to a process for simultaneously consecutive preparation of polyols by base-catalyzed reaction of at least two different mid-chain aldehydes with formaldehyde. The simultaneous consecutive mode of operation makes it possible to achieve high conversions and high selectivities for both aldehydes, with additional achievement of a distinct reduction in the amount of unreacted formaldehyde remaining. This leads to improved process economics, since the energy costs for workup of the formaldehyde stream are distinctly reduced.

10. 发明授权

US09840454B2 Method for obtaining polyol esters-enriched product streams from the side-streams in polyol ester production 有权
公开(公告)号：US09840454B2
公开(公告)日：2017-12-12
申请号：US14915915
申请日：2014-10-09
申请人： Oxea GmbH
发明人： Jens Kubitschke , Thorsten Kreickmann , Jörg Arnold , Heinz Strutz
IPC分类号： C07C67/54 , C07C67/08 , C07C67/58 , C07C67/60
CPC分类号： C07C67/54 , C07C67/08 , C07C67/58 , C07C67/60 , C07C69/28
摘要： A process for obtaining product streams enriched with polyol esters from the secondary streams from polyol ester preparation, comprising a) the reaction of polyols of the general formula (II) H—(—O—[—CR1R2—]m—)o—OH (II) in which R1 and R2 are each independently hydrogen, an alkyl radical having 1 to 5 carbon atoms or a hydroxyalkyl radical having 1 to 5 carbon atoms, m is an integer from 1 to 10, o is an integer from 2 to 15, with linear or branched aliphatic monocarboxylic acids having 3 to 20 carbon atom, with removal of the water formed; b) the removal of unconverted starting compounds from the crude ester formed; c) the treatment of the crude ester obtained in step b) with steam to form a volatile secondary stream; and d) the removal of the volatile secondary stream obtained in step c), characterized in that the volatile secondary stream obtained in step d) is separated into an aqueous phase and an organic phase and the organic phase removed is subjected to a further treatment with steam and a product stream enriched with polyol esters is obtained as residue.

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