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1. 发明申请

US20070066703A1 Radiation-curable resin composition, cured film of the composition, and laminate 审中-公开
标题翻译：可辐射固化树脂组合物，组合物的固化膜和层压体
公开(公告)号：US20070066703A1
公开(公告)日：2007-03-22
申请号：US10564816
申请日：2004-07-23
申请人： Noriyasu Shinohara , Hiroyuki Mano , Takayoshi Tanabe , John Southwell , Christopher Tronche
发明人： Noriyasu Shinohara , Hiroyuki Mano , Takayoshi Tanabe , John Southwell , Christopher Tronche
IPC分类号： C03C25/10
CPC分类号： C09K3/10 , B32B27/08 , C08J5/04 , C08J2323/12 , C08K5/09 , C09C1/00 , C09C1/3063 , C09C1/3072 , C09C3/08 , C09C3/10 , C08L71/02
摘要： The present invention relates to a radiation-curable resin composition which produces a cured film having low surface resistivity and high transparency, a cured film of the composition, and a laminate including a layer of the cured film. The laminate of the present invention is suitably used as a hard coat material for preventing scratches or stains on a plastic optical part, touch panel, film-type liquid crystal element, plastic container, or flooring material, wall material, or artificial marble as an architectural interior finish; adhesive and sealing material for various substrates; vehicle for printing ink; or the like.
摘要翻译：本发明涉及产生具有低表面电阻率和高透明度的固化膜的辐射固化树脂组合物，该组合物的固化膜和包含该固化膜层的层压体。本发明的层压体适合用作防止塑料光学部件，触摸屏，薄膜型液晶元件，塑料容器或地板材料，壁材料或人造大理石上的划痕或污渍的硬涂层材料建筑内饰; 各种基材的粘合剂和密封材料; 印刷油墨车辆; 或类似物。

2. 发明申请

US20110144271A1 RADIOACTIVE RAY-CURABLE LIQUID RESIN COMPOSITION FOR USE IN OPTICAL STEREOLITHOGRAPHY, AND OPTICALLY SHAPED ARTICLE PRODUCED BY CURING THE COMPOSITION 审中-公开
标题翻译：放射性光固化液体树脂组合物，用于光学立体成像，以及通过固化而成的光学形状制品
公开(公告)号：US20110144271A1
公开(公告)日：2011-06-16
申请号：US11917632
申请日：2006-06-16
申请人： Katsuyuki Takase , Takayoshi Tanabe , Noriyasu Shinohara
发明人： Katsuyuki Takase , Takayoshi Tanabe , Noriyasu Shinohara
IPC分类号： C08K5/47 , C08K5/372 , C08K5/13 , C08K5/51
CPC分类号： C08L63/00 , B33Y70/00 , C08G59/687
摘要： The present invention aims to provide a radiation-curing liquid resin composition for optical tridimensional modeling having good storage stability. The suitable radiation-curing liquid resin composition for optical tridimensional modeling of the present invention includes a compound represented by the below general formula (1), a compound having phenolic hydroxyl group, a cationic polymerizable compound, a radical polymerization initiator, a radical polymerizable compound, one or more sulfur compound selected from the group consisting of 2-mercaptobenzothiazole, 2-(4-morpholinodithiobenzothiazole, diisopropylxantogendisulfide and diphenyldisulfide, a polyether polyol compound.
摘要翻译：本发明旨在提供一种具有良好的储存稳定性的用于光学三维建模的辐射固化液体树脂组合物。本发明的适用于光学三维建模的辐射固化液体树脂组合物包括由下列通式（1）表示的化合物，具有酚羟基的化合物，阳离子可聚合化合物，自由基聚合引发剂，可自由基聚合的化合物，一种或多种选自2-巯基苯并噻唑，2-（4-吗啉代二硫代苯并噻唑，二异丙基十三硫代二硫化物和二苯基二硫醚）的硫化合物，聚醚多元醇化合物。

3. 发明申请

US20080096033A1 Curable Composition, Cured Layer, and Laminate 审中-公开
标题翻译：可固化组合物，固化层和层压材料
公开(公告)号：US20080096033A1
公开(公告)日：2008-04-24
申请号：US11576166
申请日：2005-10-14
申请人： Noriyasu Shinohara , Ryousuke Iinuma , Jiro Ueda , Takayoshi Tanabe
发明人： Noriyasu Shinohara , Ryousuke Iinuma , Jiro Ueda , Takayoshi Tanabe
IPC分类号： C08L33/02
CPC分类号： C09D175/16 , C08G18/289 , C08G18/673 , C08K9/04 , Y10T428/31855 , C08L75/16
摘要： To provide a curable a composition exhibiting excellent applicability and capable of forming a coating having high hardness, low curling properties, and excellent flexibility on the surface of a substrate, and a cured film including a cured product of the composition. A curable composition comprising: (A) 30 to 80 wt % of metal oxide particles to which an organic compound containing a polymerizable unsaturated group is bonded, and (B) 5 to 50 wt % of a urethane (meth)acrylate having an aromatic cyclic structure in the molecule and including three or more (meth)acryloyl groups, provided that the total amount of the composition excluding an organic solvent is 100 wt %; and a cured layer formed by curing the composition, and a laminate.
摘要翻译：为了提供一种表现出优异适用性并且能够形成具有高硬度，低卷曲性和在基材表面上的优异柔软性的涂层的固化性组合物，以及包含该组合物的固化产物的固化膜。一种可固化组合物，其包含：（A）30〜80重量％的含有可聚合不饱和基团的有机化合物的金属氧化物粒子，和（B）5〜50重量％的具有芳香族环状的氨基甲酸酯（甲基）丙烯酸酯并且包括三个以上（甲基）丙烯酰基，但不包括有机溶剂的组合物的总量为100重量％以及通过固化该组合物形成的固化层和层压体。

4. 发明申请

US20070219314A1 CURABLE COMPOSITION, CURED PRODUCT, AND LAMINATE 审中-公开
标题翻译：可固化组合物，固化产品和层压材料
公开(公告)号：US20070219314A1
公开(公告)日：2007-09-20
申请号：US11575978
申请日：2005-10-14
申请人： Noriyasu Shinohara , Shinji Usui , Takayoshi Tanabe
发明人： Noriyasu Shinohara , Shinji Usui , Takayoshi Tanabe
IPC分类号： C08G18/28 , C08G18/67 , C08K9/04 , C09D175/16
CPC分类号： C09D175/16 , C08G18/289 , C08G18/673
摘要： To provide a curable composition exhibiting excellent applicability and capable of forming a coating having high hardness, showing a small amount of curling after hot water immersion, and exhibiting excellent scratch resistance on the surface of a substrate, and a cured product of the composition. [Means for the Solution] A curate composition, comprising: (A) 5 to 70 wt % of metal oxide particles having a refractive index of 1.50 or more, to which an organic compound containing a polymerizable unsaturated group is bonded; and (B) 10 to 50 wt % of a compound shown by the following formula (I), the amount of each component being based on the total amount of the composition excluding a solvent, and a cured product produced by curing the curate composition.
摘要翻译：为了提供具有优异适用性且能够形成具有高硬度的涂层，在热水浸渍后显示少量卷曲并且在基材表面上表现出优异的耐刮擦性的组合物和该组合物的固化产物的可固化组合物。 [溶液的方法]一种护理组合物，其包含：（A）5〜70重量％的折射率为1.50以上的金属氧化物粒子，所述有机化合物含有可聚合不饱和基团; 和（B）10〜50重量％的下述式（I）所示的化合物，各成分的量以不包括溶剂的组合物的总量为基准，以及通过固化该组合物而得到的固化物。

5. 发明授权

US08207239B2 Radioactive ray-curable liquid resin composition for use in optical stereolithography, and optically shaped article produced by curing the composition 有权
标题翻译：用于光学立体光刻的放射线可固化液体树脂组合物和通过固化该组合物制备的光学成型制品
公开(公告)号：US08207239B2
公开(公告)日：2012-06-26
申请号：US13317375
申请日：2011-10-17
申请人： Katsuyuki Takase , Takayoshi Tanabe , Noriyasu Shinohara
发明人： Katsuyuki Takase , Takayoshi Tanabe , Noriyasu Shinohara
IPC分类号： C08L63/00 , C08G2/02
CPC分类号： C08L63/00 , B33Y70/00 , C08G59/687
摘要： The present invention aims to provide a radiation-curing liquid resin composition for optical tridimensional modeling having good storage stability. The suitable radiation-curing liquid resin composition for optical tridimensional modeling of the present invention includes a compound represented by the below general formula (1), a compound having phenolic hydroxyl group, a cationic polymerizable compound, a radical polymerization initiator, a radical polymerizable compound, one or more sulfur compound selected from the group consisting of 2-mercaptobenzothiazole, 2-(4-morpholinodithiobenzothiazole, diisopropylxantogendisulfide and diphenyldisulfide, a polyether polyol compound.
摘要翻译：本发明旨在提供一种具有良好的储存稳定性的用于光学三维建模的辐射固化液体树脂组合物。本发明的适用于光学三维建模的辐射固化液体树脂组合物包括由下列通式（1）表示的化合物，具有酚羟基的化合物，阳离子可聚合化合物，自由基聚合引发剂，可自由基聚合的化合物，一种或多种选自2-巯基苯并噻唑，2-（4-吗啉代二硫代苯并噻唑，二异丙基十三硫代二硫化物和二苯基二硫醚）的硫化合物，聚醚多元醇化合物。

6. 发明申请

US20060155016A1 Curable composition, cured product, and laminate 审中-公开
标题翻译：可固化组合物，固化产物和层压材料
公开(公告)号：US20060155016A1
公开(公告)日：2006-07-13
申请号：US10508621
申请日：2003-03-21
申请人： Noriyasu Shinohara , Yasunobu Suzuki , Yoshikazu Yamaguchi , Takayoshi Tanabe
发明人： Noriyasu Shinohara , Yasunobu Suzuki , Yoshikazu Yamaguchi , Takayoshi Tanabe
IPC分类号： C08K5/34
CPC分类号： C08K5/34922 , C08F283/12 , C08F290/068 , C08L51/08 , C08L2666/02
摘要： The invention relates to a curable composition comprising (A) particles prepared by bonding at least one oxide of an element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium, and an organic compound which comprises a polymerizable group, (B) a compound having a melamine group and no polymerizable unsaturated groups and (C) a compound having at least two polymerizable groups in the molecule other than the component (B); and to cured products and laminates with a with low reflectance and superior chemical resistance.
摘要翻译：本发明涉及一种可固化组合物，其包含（A）通过键合选自硅，铝，锆，钛，锌，锗，铟，锡，锑和铈中的至少一种元素的氧化物而制备的颗粒，以及包含可聚合基团的有机化合物，（B）具有三聚氰胺基团并且不具有可聚合不饱和基团的化合物和（C）在分子中除了组分（B）之外具有至少两个可聚合基团的化合物; 并且具有低反射率和优异的耐化学性的固化产品和层压材料。

7. 发明申请

US20120041091A1 Radioactive ray-curable liquid resin composition for use in optical stereolithography, and optically shaped article produced by curing the composition 有权
公开(公告)号：US20120041091A1
公开(公告)日：2012-02-16
申请号：US13317375
申请日：2011-10-17
申请人： Katsuyuki Takase , Takayoshi Tanabe , Noriyasu Shinohara
发明人： Katsuyuki Takase , Takayoshi Tanabe , Noriyasu Shinohara
IPC分类号： C08L63/00 , C08L35/02
CPC分类号： C08L63/00 , B33Y70/00 , C08G59/687
摘要： The present invention aims to provide a radiation-curing liquid resin composition for optical tridimensional modeling having good storage stability. The suitable radiation-curing liquid resin composition for optical tridimensional modeling of the present invention includes a compound represented by the below general formula (1), a compound having phenolic hydroxyl group, a cationic polymerizable compound, a radical polymerization initiator, a radical polymerizable compound, one or more sulfur compound selected from the group consisting of 2-mercaptobenzothiazole, 2-(4-morpholinodithiobenzothiazole, diisopropylxantogendisulfide and diphenyldisulfide, a polyether polyol compound.

8. 发明申请

US20060247353A1 Curable compositions and cured film thereof 审中-公开
标题翻译：可固化组合物及其固化膜
公开(公告)号：US20060247353A1
公开(公告)日：2006-11-02
申请号：US10556819
申请日：2004-05-18
申请人： Jiro Ueda , Noriyasu Shinohara , Isao Nishiwaki , Takayoshi Tanabe
发明人： Jiro Ueda , Noriyasu Shinohara , Isao Nishiwaki , Takayoshi Tanabe
IPC分类号： C08K3/22
CPC分类号： C08F292/00 , C08F283/12 , C08K3/20 , C08K9/06 , C09D7/62
摘要： A curable composition comprising: (A) reactive particles prepared by bonding oxide particles of at least one element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium to an organic compound having a polymerizable unsaturated group and a hydrolyzable silyl group, (B) an organic compound having two or more polymerizable unsaturated groups, and (C) a both terminal reactive polysiloxane compound other than the component (B).
摘要翻译：一种可固化组合物，其包含：（A）通过将选自硅，铝，锆，钛，锌，锗，铟，锡，锑和铈中的至少一种元素的氧化物颗粒结合到有机化合物而制备的反应性颗粒具有可聚合不饱和基团和可水解甲硅烷基，（B）具有两个或多个可聚合不饱和基团的有机化合物，和（C）除了组分（B）之外的两末端反应性聚硅氧烷化合物。

9. 发明申请

US20060115669A1 Curable composition, cured product, and laminate 审中-公开
标题翻译：可固化组合物，固化产物和层压材料
公开(公告)号：US20060115669A1
公开(公告)日：2006-06-01
申请号：US10546206
申请日：2004-02-18
申请人： Noriyasu Shinohara , Yasunobu Suzuki , Takayoshi Tanabe
发明人： Noriyasu Shinohara , Yasunobu Suzuki , Takayoshi Tanabe
IPC分类号： B32B27/42
CPC分类号： B32B27/08 , C08F283/00 , C08F283/12 , C08F290/06 , C08F292/00 , G02B1/105 , G02B1/111 , G02B1/14 , Y10T428/31942
摘要： To provide a curable composition having excellent applicability and capable of forming a coat (film) having high hardness and high refractive index, excelling in scratch resistance and adhesion to a substrate and a low-refractive-index layer, and excelling in scratch resistance even in the case where the cured product is allowed to stand in a high pH environment or the composition is cured under anaerobic conditions on the surface of various types of substrates, a cured product of the curable composition, and a laminate having low reflectance and excelling in chemical resistance. Means for the Solution. A curable composition comprising (A) particles obtained by bonding oxide particles of at least one element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium with an organic compound having a polymerizable unsaturated group, (B) a melamine compound having no polymerizable unsaturated group, and (C) a compound which has a polymerizable unsaturated group and has a hydroxyl value of 110 mgKOH/g or more.
摘要翻译：为了提供具有优异适用性并且能够形成具有高硬度和高折射率的涂层（膜）的可固化组合物，具有优异的耐擦伤性和对基材和低折射率层的粘附性，并且即使在使固化物在高pH环境下静置或在厌氧条件下在各种基材的表面上固化，固化性组合物的固化物，反射率低，化学性优异的层压体的情况抵抗性。解决办法一种可固化组合物，其包含（A）通过将选自硅，铝，锆，钛，锌，锗，铟，锡，锑和铈中的至少一种元素的氧化物颗粒与具有聚合性不饱和基团，（B）不具有聚合性不饱和基团的三聚氰胺化合物，（C）具有聚合性不饱和基团，羟基值为110mgKOH / g以上的化合物。

10. 发明申请

US20070155882A1 Curable liquid composition, cured film, and antistatic laminate 审中-公开
标题翻译：可固化液体组合物，固化膜和抗静电层压板
公开(公告)号：US20070155882A1
公开(公告)日：2007-07-05
申请号：US10552510
申请日：2004-04-05
申请人： Yoshikazu Yamaguchi , Shingo Itai , Jiro Ueda , Takayoshi Tanabe , John Southwell
发明人： Yoshikazu Yamaguchi , Shingo Itai , Jiro Ueda , Takayoshi Tanabe , John Southwell
IPC分类号： C08G73/10 , C08K3/22
CPC分类号： C09D5/006 , C08F290/068 , C08K3/22 , C08K9/06 , C09D5/24 , C09D7/62 , C09D11/101
摘要： To provide a curable liquid composition excelling in storage stability and curability and capable of forming a coat (film) which excels in antistatic properties, hardness, scratch resistance, and transparency on the surface of various substrates, a cured film of the composition, and an antistatic laminate. A curable liquid composition comprising (A) particles including an oxide of at least one element selected from the group consisting of indium, antimony, zinc, and tin as a major component, (B) a compound having at least two polymerizable unsaturated groups in the molecule, (C) a solvent in which solubility of the component (B) is less than 10 wt %, and (D) a solvent in which solubility of the component (B) is 10 wt % or more, the components (A) and (B) being uniformly dispersed or dissolved in the composition.
摘要翻译：为了提供优异的储存稳定性和固化性的可固化液体组合物，并且能够形成在各种基材的表面上的抗静电性，硬度，耐刮擦性和透明性优异的涂层（膜），该组合物的固化膜和抗静电层压板一种可固化液体组合物，其包含（A）包含选自由铟，锑，锌和锡组成的组中的至少一种元素的氧化物的主要成分的颗粒，（B）具有至少两个可聚合不饱和基团的化合物分子，（C）成分（B）的溶解度小于10重量％的溶剂，（D）成分（B）的溶解度为10重量％以上的成分（A）和（B）均匀地分散或溶解在组合物中。

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