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    • 3. 发明授权
    • Composition and process for chromating galvanized steel and like
materials
    • 用于镀铬钢和类似材料的组合物和方法
    • US5091023A
    • 1992-02-25
    • US589146
    • 1990-09-27
    • Kenshi SaekiNoriaki Yoshitake
    • Kenshi SaekiNoriaki Yoshitake
    • C23C22/30C23C22/34C23C22/38
    • C23C22/38
    • The resistance of chromated zinc surfaced steel objects, particularly plates and sheets, to extraction of hexavalent chromium by alkaline degreasing solutions used on the chromated objects, can be substantially increased by utilizing an aqueous acidic liquid chromating composition containing (A) about 9.6 to about 96 g/L, expressed as its stoichiometric equivalent as chromic acid, of total chromium; (B) about 2 to about 35 g/L of trivalent chromium ions; (C) about 1 to about 128 g/L of phosphate ions; and (D) about 0.3 to about 4 g/L of fluorozirconate ions, with the chromium ratio in the aqueous acidic liquid composition being about 0.41 to about 0.70, the chromic acid/fluorozirconate weight ratio being about 10 to about 40, and the PO.sub.4 /Cr.sup.+3 ratio being greater than about 0.03, greater than or equal to about {(9.2) (the chromium ratio)-4.0}, and less than or equal to about {(9.2) (the chromium ratio)-1.2}. . . The corrosion resistance of the coatings formed can be further improved if the chromating composition also contains about 0.1 to about 200 g/L of dispersed silica.
    • 通过使用含有(A)约9.6至约96的酸性液体铬酸盐组合物的酸性液体铬酸盐组合物,可以显着增加铬酸锌表面的钢物体,特别是板和片材对用于铬酸盐物体的碱性脱脂溶液萃取六价铬的电阻 以铬的化学计量当量表示的总铬的g / L; (B)约2〜约35g / L的三价铬离子; (C)约1至约128g / L磷酸根离子; 和(D)约0.3至约4g / L的氟锆酸根离子,酸性液体组合物中的铬比为约0.41至约0.70,铬酸/氟锆酸酯的重量比为约10至约40,PO4 / Cr + 3比大于约0.03,大于或等于约{(9.2)(铬比)-4.0},小于或等于约{(9.2)(铬比)-1.2}。 。 。 如果铬酸盐组合物还含有约0.1至约200g / L的分散二氧化硅,则可以进一步改善所形成的涂层的耐腐蚀性。