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1. 再颁专利

USRE40697E1 Method for making an aromatic polycarbonate 有权
标题翻译：制备芳族聚碳酸酯的方法
公开(公告)号：USRE40697E1
公开(公告)日：2009-04-07
申请号：US11345691
申请日：2006-01-31
申请人： Norberto Silvi , Mark Howard Giammattei , Patrick Joseph McCloskey , Alberto Nisoli , James Day , Narayan Ramesh , Paul Michael Smigelski, Jr. , Paul Russell Wilson
发明人： Norberto Silvi , Mark Howard Giammattei , Patrick Joseph McCloskey , Alberto Nisoli , James Day , Narayan Ramesh , Paul Michael Smigelski, Jr. , Paul Russell Wilson
IPC分类号： C08G64/00
CPC分类号： B29C47/0004 , B29C47/0009 , B29C47/60 , B29C47/76 , B29C47/767 , B29C67/246 , B29K2069/00 , C08G64/081 , C08G64/14 , C08G64/205 , C08G64/307
摘要： This invention relates to an extrusion method preparing polycarbonates from a solution of an oligomeric polycarbonate. A mixture of bis(methyl salicyl)carbonate (BMSC), BPA and a transesterification catalyst are first equilibrated at moderate temperatures to provide a solution of polycarbonate oligomer in methyl salicylate. The solution is then fed to a devolatilizing extruder, where the polymerization reaction is completed and the methyl salicylate solvent is removed. The solution comprising the oligomeric polycarbonate can also be pre-heated under pressure to a temperature above the boiling point of methyl salicylate and subsequently fed to a devolatilizing extruder equipped for rapid flashing off the solvent. The method provides polycarbonate with greater efficiency than the corresponding process in which unreacted monomers are fed to the extruder. Additionally, the method of the invention does not require the isolation of a precursor polycarbonate comprising ester-substituted phenoxy terminal groups.
摘要翻译：本发明涉及从低聚聚碳酸酯溶液制备聚碳酸酯的挤压方法。首先在中等温度下平衡双（甲基水杨酸）碳酸酯（BMSC），BPA和酯交换催化剂的混合物，以提供聚碳酸酯低聚物在水杨酸甲酯中的溶液。然后将溶液进料到脱挥发分挤出机中，其中聚合反应完成并除去水杨酸甲酯溶剂。包含低聚物聚碳酸酯的溶液也可以在压力下预加热到高于水杨酸甲酯沸点的温度，随后进料到脱挥发分的挤出机中，以便迅速地从溶剂中闪蒸。该方法提供聚碳酸酯比未反应的单体进料到挤出机的相应方法具有更高的效率。另外，本发明的方法不需要分离包含酯取代的苯氧基末端基团的前体聚碳酸酯。

2. 发明授权

US06790929B2 Method for making an aromatic polycarbonate 有权
标题翻译：制备芳族聚碳酸酯的方法
公开(公告)号：US06790929B2
公开(公告)日：2004-09-14
申请号：US10389009
申请日：2003-03-17
申请人： Norberto Silvi , Mark Howard Giammattei , Patrick Joseph McCloskey , Alberto Nisoli , James Day , Narayan Ramesh , Paul Michael Smigelski, Jr. , Paul Russell Wilson
发明人： Norberto Silvi , Mark Howard Giammattei , Patrick Joseph McCloskey , Alberto Nisoli , James Day , Narayan Ramesh , Paul Michael Smigelski, Jr. , Paul Russell Wilson
IPC分类号： C08G6400
CPC分类号： B29C47/0004 , B29C47/0009 , B29C47/60 , B29C47/76 , B29C47/767 , B29C67/246 , B29K2069/00 , C08G64/081 , C08G64/14 , C08G64/205 , C08G64/307
摘要： This invention relates to an extrusion method preparing polycarbonates from a solution of an oligomeric polycarbonate. A mixture of bis(methyl salicyl)carbonate (BMSC), BPA and a transesterification catalyst are first equilibrated at moderate temperatures to provide a solution of polycarbonate oligomer in methyl salicylate. The solution is then fed to a devolatilizing extruder, where the polymerization reaction is completed and the methyl salicylate solvent is removed. The solution comprising the oligomeric polycarbonate can also be pre-heated under pressure to a temperature above the boiling point of methyl salicylate and subsequently fed to a devolatilizing extruder equipped for rapid flashing off the solvent. The method provides polycarbonate with greater efficiency than the corresponding process in which unreacted monomers are fed to the extruder. Additionally, the method of the invention does not require the isolation of a precursor polycarbonate comprising ester-substituted phenoxy terminal groups.
摘要翻译：本发明涉及从低聚聚碳酸酯溶液制备聚碳酸酯的挤压方法。首先在中等温度下平衡双（甲基水杨酸）碳酸酯（BMSC），BPA和酯交换催化剂的混合物，以提供聚碳酸酯低聚物在水杨酸甲酯中的溶液。然后将溶液进料到脱挥发分挤出机中，其中聚合反应完成并除去水杨酸甲酯溶剂。包含低聚物聚碳酸酯的溶液也可以在压力下预加热到高于水杨酸甲酯沸点的温度，随后进料到脱挥发分的挤出机中，以便迅速地从溶剂中闪蒸。该方法提供聚碳酸酯比未反应的单体进料到挤出机的相应方法具有更高的效率。另外，本发明的方法不需要分离包含酯取代的苯氧基末端基团的前体聚碳酸酯。

3. 发明授权

US06506871B1 Extrusion method for making polycarbonate 有权
标题翻译：制造聚碳酸酯的挤出方法
公开(公告)号：US06506871B1
公开(公告)日：2003-01-14
申请号：US10167903
申请日：2002-06-12
申请人： Norberto Silvi , Patrick Joseph McCloskey , James Day , Mark Howard Giammattei
发明人： Norberto Silvi , Patrick Joseph McCloskey , James Day , Mark Howard Giammattei
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： Extrusion of a mixture of an ester-substituted diaryl carbonate, such as bis(methyl salicyl) carbonate, a dihydroxy aromatic compound such as bisphenol A and a transesterification catalyst such as tetrabutylphosphonium acetate (TBPA) affords polycarbonate having a weight average molecular weight of greater than 20,000 daltons. The extruder is equipped with one or more vacuum vents to remove by-product ester-substituted phenol. Similarly, a precursor polycarbonate having ester-substituted phenoxy endgroups, for example methyl salicyl endgroups, when subjected to extrusion affords a polycarbonate having a significantly increased molecular weight relative to the precursor polycarbonate. The reaction to form a higher molecular weight polycarbonate may be catalyzed by residual transesterification catalyst present in the precursor polycarbonate, or by a combination of any residual catalyst and an additional catalyst such as TBPA introduced in the extrusion step. Fries rearrangement products are not observed in the product polycarbonates.
摘要翻译：碳酸二（甲基水杨基）酯，二羟基芳族化合物如双酚A和酯交换催化剂如四丁基鏻乙酸酯（TBPA）的酯取代的二芳基碳酸酯的混合物的挤出得到重均分子量更大的聚碳酸酯超过20,000道尔顿。挤出机配备有一个或多个真空通风口以除去副产物酯取代的苯酚。类似地，具有酯取代的苯氧基端基的前体聚碳酸酯，例如甲基水杨基端基，当进行挤出时，得到相对于前体聚碳酸酯具有显着增加的分子量的聚碳酸酯。形成较高分子量聚碳酸酯的反应可以通过存在于前体聚碳酸酯中的残留酯交换催化剂，或者通过任何残余催化剂和另外的催化剂如在挤出步骤中引入的TBPA的组合来催化。在产品聚碳酸酯中没有观察到薯条重排产物。

4. 发明授权

US08218291B2 Monomers for preparing polycarbonate resins, methods of preparing the monomers, polycarbonate resins prepared with the monomers, and capacitors comprising the polycarbonate resins 失效
标题翻译：用于制备聚碳酸酯树脂的单体，制备单体的方法，用单体制备的聚碳酸酯树脂，以及包含聚碳酸酯树脂的电容器
公开(公告)号：US08218291B2
公开(公告)日：2012-07-10
申请号：US12751649
申请日：2010-03-31
申请人： Norberto Silvi , Gary Charles Davis , Patrick Joseph McCloskey , Sheldon Jay Shafer , Julia Lam Lee , Yang Cao , Patricia Chapman Irwin
发明人： Norberto Silvi , Gary Charles Davis , Patrick Joseph McCloskey , Sheldon Jay Shafer , Julia Lam Lee , Yang Cao , Patricia Chapman Irwin
IPC分类号： H01G9/00
CPC分类号： C08G64/12 , C07C255/53 , H01G4/18 , Y10T29/41 , Y10T29/417
摘要： A monomer and polycarbonate resin are provided, as are methods of making the monomer. The resin may be used to provide a thin film that has a higher dielectric constant and higher glass transition temperature, and similar breakdown strength and similar dissipation factor to films prepared from polycarbonate resins not so modified. The thin films, in turn, may advantageously be used to form, wholly or in part, articles such as capacitors, sensors, batteries, flexible printed circuit boards, keyboard membranes, motor/transformer insulations, cable wrappings, industrial tapes, interior coverage materials, and the like. In particular, a capacitor comprising the polycarbonate resin is also provided.
摘要翻译：提供单体和聚碳酸酯树脂，以及制备单体的方法。该树脂可用于提供具有较高介电常数和较高玻璃化转变温度的薄膜，以及与未进行改性的聚碳酸酯树脂制备的薄膜相似的击穿强度和相似的耗散因数。薄膜又可有利地用于整体或部分地形成诸如电容器，传感器，电池，柔性印刷电路板，键盘膜，电动机/变压器绝缘体，电缆包装，工业胶带，内部覆盖材料，等等。特别地，还提供了包含聚碳酸酯树脂的电容器。

5. 发明授权

US07132498B2 Process to make polycarbonate from bismethylsalicylcarbonate (BMSC) 有权
公开(公告)号：US07132498B2
公开(公告)日：2006-11-07
申请号：US10951574
申请日：2004-09-27
申请人： Patrick Joseph McCloskey , Norberto Silvi , Alberto Nisoli , Mark Giammattei
发明人： Patrick Joseph McCloskey , Norberto Silvi , Alberto Nisoli , Mark Giammattei
IPC分类号： C08G63/00
CPC分类号： B29C47/76 , B29C47/0009 , C08G64/307
摘要： The present invention relates to a method of preparing polycarbonate comprising the steps of: (i) introducing to an extruder through a feed port a plurality of reaction components comprising a polycarbonate oligomer, an activated carbonate residue, and a transesterification catalyst, wherein the extruder comprises the feed port, a first back vent port, and a polycarbonate exit port, wherein the feed port is located between the first back vent port and the polycarbonate exit port, and wherein the resistance to flow of the reaction components from the feed port to the first back vent port is less than or equal to the resistance to flow of the reaction components from the feed port to the polycarbonate exit port; and (ii) extruding the reaction components at one or more temperatures in a range between 100° C. and 400° C., wherein during the extrusion of the reaction components, activated carbonate residue is removed through the first back vent port, thereby preparing a polycarbonate.

6. 发明申请

US20110242729A1 Monomers for preparing polycarbonate resins, methods of preparing the monomers, polycarbonate resins prepared with the monomers, and capacitors comprising the polycarbonate resins 失效
标题翻译：用于制备聚碳酸酯树脂的单体，制备单体的方法，用单体制备的聚碳酸酯树脂，以及包含聚碳酸酯树脂的电容器
公开(公告)号：US20110242729A1
公开(公告)日：2011-10-06
申请号：US12751649
申请日：2010-03-31
申请人： Norberto Silvi , Gary Charles Davis , Patrick Joseph McCloskey , Sheldon Jay Shafer , Julia Lam Lee , Yang Cao , Patricia Chapman Irwin
发明人： Norberto Silvi , Gary Charles Davis , Patrick Joseph McCloskey , Sheldon Jay Shafer , Julia Lam Lee , Yang Cao , Patricia Chapman Irwin
IPC分类号： H01G4/08 , C08G64/04 , C07C255/50
CPC分类号： C08G64/12 , C07C255/53 , H01G4/18 , Y10T29/41 , Y10T29/417
摘要： A monomer and polycarbonate resin are provided, as are methods of making the monomer. The resin may be used to provide a thin film that has a higher dielectric constant and higher glass transition temperature, and similar breakdown strength and similar dissipation factor to films prepared from polycarbonate resins not so modified. The thin films, in turn, may advantageously be used to form, wholly or in part, articles such as capacitors, sensors, batteries, flexible printed circuit boards, keyboard membranes, motor/transformer insulations, cable wrappings, industrial tapes, interior coverage materials, and the like. In particular, a capacitor comprising the polycarbonate resin is also provided.
摘要翻译：提供单体和聚碳酸酯树脂，以及制备单体的方法。该树脂可用于提供具有较高介电常数和较高玻璃化转变温度的薄膜，以及与未进行改性的聚碳酸酯树脂制备的薄膜相似的击穿强度和相似的耗散因数。薄膜又可有利地用于整体或部分地形成诸如电容器，传感器，电池，柔性印刷电路板，键盘膜，电动机/变压器绝缘体，电缆包装，工业胶带，内部覆盖材料，等等。特别地，还提供了包含聚碳酸酯树脂的电容器。

7. 发明授权

US06333394B1 Copolycarbonate preparation by solid state polymerization 有权
标题翻译：通过固态聚合制备共聚碳酸酯
公开(公告)号：US06333394B1
公开(公告)日：2001-12-25
申请号：US09379234
申请日：1999-08-23
申请人： Christian Maria Emile Bailly , Bhaskar Bhairavnath Idage , Swaminathan Sivaram , Nayaku Nivarati Chavan , Rein Mollerus Faber , Shamal Karunakaran Menon , Gautam Chatterjee , Godavarthi Satyana Varadarajan , James Day , Patrick Joseph McCloskey , Joseph Anthony King, Jr. , Arun Savalaram Jadhav
发明人： Christian Maria Emile Bailly , Bhaskar Bhairavnath Idage , Swaminathan Sivaram , Nayaku Nivarati Chavan , Rein Mollerus Faber , Shamal Karunakaran Menon , Gautam Chatterjee , Godavarthi Satyana Varadarajan , James Day , Patrick Joseph McCloskey , Joseph Anthony King, Jr. , Arun Savalaram Jadhav
IPC分类号： C08G6400
CPC分类号： C08G64/20 , C08G64/06 , C08G64/14 , C08G64/183 , C08G64/307
摘要： Copolycarbonates containing such structural units as birefringence-reducing or “soft block” units are prepared by conducting a reaction, such as melt polymerization or equilibration, between a precursor polycarbonate and a monomer, polycarbonate oligomer or high molecular weight polycarbonate which is a source of other structural units. The crystallinity of the resulting precursor copolycarbonate or one of the reagents employed in its preparation is enhanced and the precursor copolycarbonate is subjected to solid state polymerization.
摘要翻译：通过在前体聚碳酸酯和单体，聚碳酸酯低聚物或高分子量聚碳酸酯之间进行诸如熔融聚合或平衡的反应来制备含有诸如双折射降低或“软嵌段”单元的结构单元的共聚碳酸酯结构单位。得到的前体共聚碳酸酯或其制备中使用的试剂之一的结晶度提高，前体共聚碳酸酯进行固态聚合。

8. 发明授权

US06420512B1 Extrusion method for making polycarbonate 有权
标题翻译：制造聚碳酸酯的挤出方法
公开(公告)号：US06420512B1
公开(公告)日：2002-07-16
申请号：US09911439
申请日：2001-07-24
申请人： Patrick Joseph McCloskey , James Day , Paul Michael Smigelski , John Lester Maxam , John Aibangbee Osaheni
发明人： Patrick Joseph McCloskey , James Day , Paul Michael Smigelski , John Lester Maxam , John Aibangbee Osaheni
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： Extrusion of a mixture of an ester-substituted diaryl carbonate, such as bis-methyl salicyl carbonate, a dihydroxy aromatic compound such as bisphenol A and a transesterification catalyst such as tetrabutyl phosphonium acetate (TBPA) affords polycarbonate having a weight average molecular weight of greater than 20,000 Daltons. The extruder is equipped with one or more vacuum vents to remove by-product ester-substituted phenol. Similarly, a precursor polycarbonate having ester-substituted phenoxy endgroups, for example methyl salicyl endgroups, when subjected to extrusion affords a polycarbonate having a significantly increased molecular weight relative to the precursor polycarbonate. The reaction to form a higher molecular weight polycarbonate may be catalyzed by residual transesterification catalyst present in the precursor polycarbonate, or by a combination of any residual catalyst and an additional catalyst such as TBPA introduced in the extrusion step. Fries rearrangement products are not observed in the product polycarbonates.
摘要翻译：酯取代的碳酸二芳基酯如碳酸双甲酯，双酚A等二羟基芳族化合物和乙酸四丁基鏻（TBPA）等酯交换催化剂的混合物的挤出，得到重均分子量大的聚碳酸酯超过20,000道尔顿。挤出机配备有一个或多个真空通风口以除去副产物酯取代的苯酚。类似地，具有酯取代的苯氧基端基的前体聚碳酸酯，例如甲基水杨基端基，当进行挤出时，得到相对于前体聚碳酸酯具有显着增加的分子量的聚碳酸酯。形成较高分子量聚碳酸酯的反应可以通过存在于前体聚碳酸酯中的残留酯交换催化剂，或者通过任何残余催化剂和另外的催化剂如在挤出步骤中引入的TBPA的组合来催化。在产品聚碳酸酯中没有观察到薯条重排产物。

9. 发明授权

US06809817B2 Method and apparatus for in situ determination of molten polycarbonate composition using electronic absorption spectroscopy 失效
标题翻译：使用电子吸收光谱法原位测定熔融聚碳酸酯组合物的方法和装置
公开(公告)号：US06809817B2
公开(公告)日：2004-10-26
申请号：US09682365
申请日：2001-08-24
申请人： Radislav Alexandrovich Potyrailo , Patrick Joseph McCloskey , James Day
发明人： Radislav Alexandrovich Potyrailo , Patrick Joseph McCloskey , James Day
IPC分类号： G01J328
CPC分类号： G01J3/42 , G01J3/28
摘要： The present invention relates to methods and devices for in-situ measurement of reaction components of interest during manufacturing of polycarbonate by melt polymerization. The present invention describes irradiating a molten polymer sample with UV/visible light, and generating an absorbance profile correlated to Fries products as well as uncapped phenolic groups in the sample. The methods and apparatus of the invention are suitable for monitoring of Fries products in reactions ranging in size from small scale combinatorial formats to production scale reactors. Also included in methods of the invention are univariate and multivariate analysis for prediction of linear Fries, branched Fries and uncapped phenolic end-groups in unknowns.
摘要翻译：本发明涉及通过熔融聚合在聚碳酸酯制造过程中原位测量感兴趣的反应组分的方法和装置。本发明描述了用UV /可见光照射熔融聚合物样品，并产生与Fries产品相关的吸光度分布以及样品中未封端的酚基。本发明的方法和装置适用于在尺寸从小规模组合形式到生产规模反应器的反应中监测薯条产品。本发明方法中还包括单变量和多变量分析，用于预测未知物中的线性薯条，分枝油炸饼和未封端的酚类末端基团。

10. 发明授权

US6143859A Copolycarbonate preparation by solid state polymerization 有权
标题翻译：通过固态聚合制备共聚碳酸酯
公开(公告)号：US6143859A
公开(公告)日：2000-11-07
申请号：US370433
申请日：1999-08-09
申请人： Gautam Chatterjee , Godavarthi Satyanarayana Varadarajan , James Day , Patrick Joseph McCloskey , Bhaskar Bhairavnath Idage , Joseph Anthony King, Jr. , Arun Savalaram Jadhav
发明人： Gautam Chatterjee , Godavarthi Satyanarayana Varadarajan , James Day , Patrick Joseph McCloskey , Bhaskar Bhairavnath Idage , Joseph Anthony King, Jr. , Arun Savalaram Jadhav
IPC分类号： C08G64/06 , C08G64/18 , C08G64/20 , C08G64/00
CPC分类号： C08G64/20 , C08G64/06 , C08G64/183
摘要： Copolycarbonates containing such structural units as birefringence-reducing or "soft block" units are prepared by conducting a reaction, such as melt polymerization or equilibration, between a precursor polycarbonate and a monomer, polycarbonate oligomer or high molecular weight polycarbonate which is a source of other structural units. The crystallinity of the resulting precursor copolycarbonate or one of the reagents employed in its preparation is enhanced and the precursor copolycarbonate is subjected to solid state polymerization.
摘要翻译：通过在前体聚碳酸酯和单体，聚碳酸酯低聚物或高分子量聚碳酸酯之间进行诸如熔融聚合或平衡的反应来制备含有诸如双折射降低或“软嵌段”单元的结构单元的共聚碳酸酯结构单位。得到的前体共聚碳酸酯或其制备中使用的试剂之一的结晶度提高，前体共聚碳酸酯进行固态聚合。

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