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1. 再颁专利

USRE40697E1 Method for making an aromatic polycarbonate 有权
标题翻译：制备芳族聚碳酸酯的方法
公开(公告)号：USRE40697E1
公开(公告)日：2009-04-07
申请号：US11345691
申请日：2006-01-31
申请人： Norberto Silvi , Mark Howard Giammattei , Patrick Joseph McCloskey , Alberto Nisoli , James Day , Narayan Ramesh , Paul Michael Smigelski, Jr. , Paul Russell Wilson
发明人： Norberto Silvi , Mark Howard Giammattei , Patrick Joseph McCloskey , Alberto Nisoli , James Day , Narayan Ramesh , Paul Michael Smigelski, Jr. , Paul Russell Wilson
IPC分类号： C08G64/00
CPC分类号： B29C47/0004 , B29C47/0009 , B29C47/60 , B29C47/76 , B29C47/767 , B29C67/246 , B29K2069/00 , C08G64/081 , C08G64/14 , C08G64/205 , C08G64/307
摘要： This invention relates to an extrusion method preparing polycarbonates from a solution of an oligomeric polycarbonate. A mixture of bis(methyl salicyl)carbonate (BMSC), BPA and a transesterification catalyst are first equilibrated at moderate temperatures to provide a solution of polycarbonate oligomer in methyl salicylate. The solution is then fed to a devolatilizing extruder, where the polymerization reaction is completed and the methyl salicylate solvent is removed. The solution comprising the oligomeric polycarbonate can also be pre-heated under pressure to a temperature above the boiling point of methyl salicylate and subsequently fed to a devolatilizing extruder equipped for rapid flashing off the solvent. The method provides polycarbonate with greater efficiency than the corresponding process in which unreacted monomers are fed to the extruder. Additionally, the method of the invention does not require the isolation of a precursor polycarbonate comprising ester-substituted phenoxy terminal groups.
摘要翻译：本发明涉及从低聚聚碳酸酯溶液制备聚碳酸酯的挤压方法。首先在中等温度下平衡双（甲基水杨酸）碳酸酯（BMSC），BPA和酯交换催化剂的混合物，以提供聚碳酸酯低聚物在水杨酸甲酯中的溶液。然后将溶液进料到脱挥发分挤出机中，其中聚合反应完成并除去水杨酸甲酯溶剂。包含低聚物聚碳酸酯的溶液也可以在压力下预加热到高于水杨酸甲酯沸点的温度，随后进料到脱挥发分的挤出机中，以便迅速地从溶剂中闪蒸。该方法提供聚碳酸酯比未反应的单体进料到挤出机的相应方法具有更高的效率。另外，本发明的方法不需要分离包含酯取代的苯氧基末端基团的前体聚碳酸酯。

2. 发明授权

US06790929B2 Method for making an aromatic polycarbonate 有权
标题翻译：制备芳族聚碳酸酯的方法
公开(公告)号：US06790929B2
公开(公告)日：2004-09-14
申请号：US10389009
申请日：2003-03-17
申请人： Norberto Silvi , Mark Howard Giammattei , Patrick Joseph McCloskey , Alberto Nisoli , James Day , Narayan Ramesh , Paul Michael Smigelski, Jr. , Paul Russell Wilson
发明人： Norberto Silvi , Mark Howard Giammattei , Patrick Joseph McCloskey , Alberto Nisoli , James Day , Narayan Ramesh , Paul Michael Smigelski, Jr. , Paul Russell Wilson
IPC分类号： C08G6400
CPC分类号： B29C47/0004 , B29C47/0009 , B29C47/60 , B29C47/76 , B29C47/767 , B29C67/246 , B29K2069/00 , C08G64/081 , C08G64/14 , C08G64/205 , C08G64/307
摘要： This invention relates to an extrusion method preparing polycarbonates from a solution of an oligomeric polycarbonate. A mixture of bis(methyl salicyl)carbonate (BMSC), BPA and a transesterification catalyst are first equilibrated at moderate temperatures to provide a solution of polycarbonate oligomer in methyl salicylate. The solution is then fed to a devolatilizing extruder, where the polymerization reaction is completed and the methyl salicylate solvent is removed. The solution comprising the oligomeric polycarbonate can also be pre-heated under pressure to a temperature above the boiling point of methyl salicylate and subsequently fed to a devolatilizing extruder equipped for rapid flashing off the solvent. The method provides polycarbonate with greater efficiency than the corresponding process in which unreacted monomers are fed to the extruder. Additionally, the method of the invention does not require the isolation of a precursor polycarbonate comprising ester-substituted phenoxy terminal groups.
摘要翻译：本发明涉及从低聚聚碳酸酯溶液制备聚碳酸酯的挤压方法。首先在中等温度下平衡双（甲基水杨酸）碳酸酯（BMSC），BPA和酯交换催化剂的混合物，以提供聚碳酸酯低聚物在水杨酸甲酯中的溶液。然后将溶液进料到脱挥发分挤出机中，其中聚合反应完成并除去水杨酸甲酯溶剂。包含低聚物聚碳酸酯的溶液也可以在压力下预加热到高于水杨酸甲酯沸点的温度，随后进料到脱挥发分的挤出机中，以便迅速地从溶剂中闪蒸。该方法提供聚碳酸酯比未反应的单体进料到挤出机的相应方法具有更高的效率。另外，本发明的方法不需要分离包含酯取代的苯氧基末端基团的前体聚碳酸酯。

3. 发明授权

US06506871B1 Extrusion method for making polycarbonate 有权
标题翻译：制造聚碳酸酯的挤出方法
公开(公告)号：US06506871B1
公开(公告)日：2003-01-14
申请号：US10167903
申请日：2002-06-12
申请人： Norberto Silvi , Patrick Joseph McCloskey , James Day , Mark Howard Giammattei
发明人： Norberto Silvi , Patrick Joseph McCloskey , James Day , Mark Howard Giammattei
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： Extrusion of a mixture of an ester-substituted diaryl carbonate, such as bis(methyl salicyl) carbonate, a dihydroxy aromatic compound such as bisphenol A and a transesterification catalyst such as tetrabutylphosphonium acetate (TBPA) affords polycarbonate having a weight average molecular weight of greater than 20,000 daltons. The extruder is equipped with one or more vacuum vents to remove by-product ester-substituted phenol. Similarly, a precursor polycarbonate having ester-substituted phenoxy endgroups, for example methyl salicyl endgroups, when subjected to extrusion affords a polycarbonate having a significantly increased molecular weight relative to the precursor polycarbonate. The reaction to form a higher molecular weight polycarbonate may be catalyzed by residual transesterification catalyst present in the precursor polycarbonate, or by a combination of any residual catalyst and an additional catalyst such as TBPA introduced in the extrusion step. Fries rearrangement products are not observed in the product polycarbonates.
摘要翻译：碳酸二（甲基水杨基）酯，二羟基芳族化合物如双酚A和酯交换催化剂如四丁基鏻乙酸酯（TBPA）的酯取代的二芳基碳酸酯的混合物的挤出得到重均分子量更大的聚碳酸酯超过20,000道尔顿。挤出机配备有一个或多个真空通风口以除去副产物酯取代的苯酚。类似地，具有酯取代的苯氧基端基的前体聚碳酸酯，例如甲基水杨基端基，当进行挤出时，得到相对于前体聚碳酸酯具有显着增加的分子量的聚碳酸酯。形成较高分子量聚碳酸酯的反应可以通过存在于前体聚碳酸酯中的残留酯交换催化剂，或者通过任何残余催化剂和另外的催化剂如在挤出步骤中引入的TBPA的组合来催化。在产品聚碳酸酯中没有观察到薯条重排产物。

4. 发明授权

US07132498B2 Process to make polycarbonate from bismethylsalicylcarbonate (BMSC) 有权
公开(公告)号：US07132498B2
公开(公告)日：2006-11-07
申请号：US10951574
申请日：2004-09-27
申请人： Patrick Joseph McCloskey , Norberto Silvi , Alberto Nisoli , Mark Giammattei
发明人： Patrick Joseph McCloskey , Norberto Silvi , Alberto Nisoli , Mark Giammattei
IPC分类号： C08G63/00
CPC分类号： B29C47/76 , B29C47/0009 , C08G64/307
摘要： The present invention relates to a method of preparing polycarbonate comprising the steps of: (i) introducing to an extruder through a feed port a plurality of reaction components comprising a polycarbonate oligomer, an activated carbonate residue, and a transesterification catalyst, wherein the extruder comprises the feed port, a first back vent port, and a polycarbonate exit port, wherein the feed port is located between the first back vent port and the polycarbonate exit port, and wherein the resistance to flow of the reaction components from the feed port to the first back vent port is less than or equal to the resistance to flow of the reaction components from the feed port to the polycarbonate exit port; and (ii) extruding the reaction components at one or more temperatures in a range between 100° C. and 400° C., wherein during the extrusion of the reaction components, activated carbonate residue is removed through the first back vent port, thereby preparing a polycarbonate.

5. 发明申请

US20080262196A1 APPARATUS AND METHOD OF SEPARATING A POLYMER FROM A SOLVENT 审中-公开
标题翻译：从溶剂中分离聚合物的装置和方法
公开(公告)号：US20080262196A1
公开(公告)日：2008-10-23
申请号：US12059217
申请日：2008-03-31
申请人： Mark Howard Giammattei , Bernabe Quevedo Sanchez , Narayan Ramesh , Norberto Silvi
发明人： Mark Howard Giammattei , Bernabe Quevedo Sanchez , Narayan Ramesh , Norberto Silvi
IPC分类号： C08F6/12 , B29C47/08 , B29C47/66
CPC分类号： C08F6/12 , B29C48/03 , B29C48/268 , B29C48/395 , B29C48/402 , B29C48/45 , B29C48/687 , B29C48/767 , C08F6/003 , C08F6/10
摘要： The present invention relates to various embodiments of a system and method for separating polymer from a solvent. In one embodiment a system for separating polymer from a solvent comprises an extrusion apparatus includes a hollow member having a first end portion, a second end portion, and a feed port between the first end portion and the second end portion. The extrusion apparatus includes a back flash vent port disposed upstream of the feed port and a forward flash vent port disposed downstream of the feed port. The extrusion apparatus further includes a vent insert located at the forward flash vent port, a screw disposed inside the hollow member, and an internal superheating section disposed between the feed port and the downstream vent opening of the hollow member such that the length of the internal superheating section is greater than about four times the diameter, 4D, of the hollow member.
摘要翻译：本发明涉及从溶剂中分离聚合物的系统和方法的各种实施方案。在一个实施方案中，用于从溶剂中分离聚合物的系统包括挤出装置，其包括具有第一端部，第二端部和在第一端部和第二端部之间的进料口的中空构件。挤出装置包括设置在进料口上游的后部闪蒸排放口和设置在进料口下游的前部快闪通气口。挤出装置还包括位于前部快闪通气口处的通气插入件，设置在中空构件内部的螺钉和设置在中空构件的进料口和下游排气口之间的内部过热部分，使得内部过热部分大于中空部件直径的四倍。

6. 发明授权

US06388001B1 Compounding filled silicone compositions 有权
公开(公告)号：US06388001B1
公开(公告)日：2002-05-14
申请号：US09468623
申请日：1999-12-21
申请人： Norberto Silvi , Mark Howard Giammattei
发明人： Norberto Silvi , Mark Howard Giammattei
IPC分类号： C08K906
CPC分类号： C08J3/2053 , B29B7/90 , B29C47/0023 , B29C47/003 , B29C47/1045 , B29C47/1063 , B29C47/1081 , B29C47/38 , B29C47/402 , B29C47/50 , B29C47/6056 , B29K2105/0005 , B29K2105/16 , C08J2383/04
摘要： High levels of silica, processing fluid and high molecular weight silicone polymer are compounded into a homogeneous silica filled composition without forming a preconcentrate of fumed silica and polymer. A fumed silica is fed into a unitary continuous compounding apparatus at a first location prior to addition of the silicone polymer. The fumed silica is then compounded with the silicone polymer, which is fed into the compounding apparatus at a location down-stream in the compounding apparatus from the first location. The compounding apparatus can be a co-rotating, intermeshing double screw extruder.

7. 发明授权

US06511217B1 Method and system to compound silicone compositions 失效
标题翻译：组合硅酮组合物的方法和系统
公开(公告)号：US06511217B1
公开(公告)日：2003-01-28
申请号：US09705266
申请日：2000-11-03
申请人： Norberto Silvi , Mark Howard Giammattei
发明人： Norberto Silvi , Mark Howard Giammattei
IPC分类号： B01F702
CPC分类号： B29B7/7466 , B29B7/007 , B29B7/426 , B29B7/90 , B29C47/0009 , B29C47/50 , B29K2083/00
摘要： A method and system are provided that efficiently compound high levels of inorganic filler, processing fluid and silicone polymer at a commercial rate into homogeneous filled and devolatilized silicone compositions. In the method, filled silicone compositions are compounded by compounding a filler, processing fluid and silicone polymer in a first compounding apparatus to produce a first dispersed composition and simultaneously compounding a filler, processing fluid and silicone polymer in a second compounding apparatus that shares a common extruder shaft with the first compounding apparatus to produce a second dispersed composition. The system comprises a first compounding apparatus and a sequential second compounding apparatus that shares a common shaft with the first compounding apparatus. An extruder transition section of the system includes an enclosed discharge chamber defined by a first sectioning wall, a second sectioning wall and a contoured lower wall that transitions toward a discharge port and a shaft extends through the first sectioning wall, traverses the chamber and extends through the second sectioning wall.
摘要翻译：提供了一种方法和系统，其以商业速率有效地将高含量的无机填料，加工流体和硅氧烷聚合物复合到均匀的填充和脱挥发份的硅氧烷组合物中。在该方法中，填充的硅氧烷组合物通过在第一配混装置中混合填料，加工流体和硅氧烷聚合物来混合，以制备第一分散组合物，并且在共享共同的第二配混装置中同时混合填料，加工液和硅氧烷聚合物挤出机轴与第一配混设备产生第二分散组合物。该系统包括与第一混合装置共用公共轴的第一混合装置和顺序第二混合装置。系统的挤出机过渡部分包括由第一分段壁，第二分段壁和轮廓下壁限定的封闭排放室，该下壁朝向排放口转变，并且轴延伸穿过第一分段壁，穿过室并延伸穿过第二分段墙。

8. 发明授权

US6107415A Uncompatibilized polyphenylene ether-polyamide compositions 失效
标题翻译：未相容化的聚苯醚 - 聚酰胺组合物
公开(公告)号：US6107415A
公开(公告)日：2000-08-22
申请号：US149062
申请日：1998-09-08
申请人： Norberto Silvi , Mark Howard Giammattei
发明人： Norberto Silvi , Mark Howard Giammattei
IPC分类号： C08J3/20 , C08L71/12 , C08L77/00
CPC分类号： C08L71/123 , C08L77/00
摘要： Compatible polyphenylene ether-polyamide blends are prepared without the need for compatibilizing compounds such as citric acid or maleic anhydride. The preparation method includes melt blending of the constituents, with other materials such as impact modifiers and fillers optionally being present, at an apparatus temperature maintained no lower than about 295.degree. C. and a pressure maintained below about 200 torr. Blending is preferably by extrusion, with filler and optionally a portion of the polyamide being introduced downstream.
摘要翻译：制备相容的聚苯醚 - 聚酰胺共混物，而不需要相容化合物如柠檬酸或马来酸酐。制备方法包括在保持不低于约295℃的装置温度和保持在约200托以下的压力下，将组分与其它材料如抗冲改性剂和任选存在的填料熔融共混。混合优选通过挤出，填料和任选地一部分聚酰胺被引入下游。

9. 发明授权

US07053168B2 Method for preparing polyimide and polyimide prepared thereby 有权
标题翻译：由此制备聚酰亚胺和聚酰亚胺的方法
公开(公告)号：US07053168B2
公开(公告)日：2006-05-30
申请号：US10683226
申请日：2003-10-10
申请人： Norberto Silvi , Mark Howard Giammattei , Paul Edward Howson , Farid Fouad Khouri
发明人： Norberto Silvi , Mark Howard Giammattei , Paul Edward Howson , Farid Fouad Khouri
IPC分类号： C08G73/00 , C08F6/00 , C08L79/00
CPC分类号： C08G73/1028 , C08G73/1032
摘要： A method for preparing a polyimide includes introducing a mixture of an oligomer and a solvent to an extruder, removing solvent via at least one extruder vent, and melt kneading the oligomer to form a polyimide. The polyimide has a low residual solvent content. The method is faster than solution polymerization of polyimides, and it avoids the stoichiometric inaccuracies associated with reactive extrusion processes that use monomers as starting materials.
摘要翻译：制备聚酰亚胺的方法包括将低聚物和溶剂的混合物引入挤出机中，通过至少一个挤出机出口除去溶剂，并熔融捏合低聚物以形成聚酰亚胺。聚酰亚胺的残留溶剂含量低。该方法比聚酰亚胺的溶液聚合更快，并且避免了使用单体作为起始原料的反应挤出方法的化学计量不准确性。

10. 发明授权

US06391234B1 Compounding filled silicone compositions 有权
标题翻译：填充有机硅组合物
公开(公告)号：US06391234B1
公开(公告)日：2002-05-21
申请号：US09468622
申请日：1999-12-21
申请人： Norberto Silvi , Robert Edward Dean , Mark Howard Giammattei , John William Carbone , Navjot Singh , Gerardo Rocha Galicia , John Peter Banevicius
发明人： Norberto Silvi , Robert Edward Dean , Mark Howard Giammattei , John William Carbone , Navjot Singh , Gerardo Rocha Galicia , John Peter Banevicius
IPC分类号： B29B782
CPC分类号： B01F13/1027 , B29B7/007 , B29B7/42 , B29B7/7466 , B29B7/84 , B29B7/90 , B29C47/0016 , B29C47/50 , B29K2083/00 , B29K2105/16
摘要： High levels of inorganic filler, processing fluid and silicone polymer are compounded and devolatilized into homogeneous filled compositions with requisite reinforcing properties and levels of volatiles. In the method, a filler, processing fluid and silicone polymer are mixed in a first compounding apparatus to produce a dispersed composition containing volatiles. The dispersed composition is then compounded in a long extruder having an L/D ratio of greater than 50 to devolatilize the dispersed composition.
摘要翻译：将高含量的无机填料，加工液和硅氧烷聚合物复合并脱挥发分成具有必需的增强性能和挥发物含量的均匀填充的组合物。在该方法中，将填料，加工液和硅氧烷聚合物混合在第一配混装置中以制备含有挥发物的分散组合物。然后将分散的组合物在L / D比大于50的长挤出机中混合，使分散的组合物脱挥发分。

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