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1. 发明授权

US06770779B1 Process for preparing alkylphosphonite esters 失效
标题翻译：烷基亚膦酸酯的制备方法
公开(公告)号：US06770779B1
公开(公告)日：2004-08-03
申请号：US09577464
申请日：2000-05-24
申请人： Norbert Weferling , Martin Sicken , Hans-Peter Schmitz , Günter Kolbe
发明人： Norbert Weferling , Martin Sicken , Hans-Peter Schmitz , Günter Kolbe
IPC分类号： C07F928
CPC分类号： C07F9/48
摘要： The present invention relates to a process for the preparation of alkylphosphonous acid esters which comprises a) reacting elemental yellow phosphorus with alkylating agents in the presence of a base to give a mixture which comprises, as principal constituents, the (metal) salts of alkylphosphonous, phosphorous and hypophosphorous acids, b) esterifying the principal constituents of the mixture from a) to give an ester mixture, c) isolating the ester of the alkylphosphonous acid from the ester mixture. The invention likewise relates to the use of the alkylphosphonous acid esters prepared by this process as precursors for further syntheses, inter alia for the preparation of crop protection agents.
摘要翻译：本发明涉及一种制备烷基亚磷酸酯的方法，该方法包括：a）在碱存在下，使元素黄磷与烷基化剂反应得到一种混合物，其中包含作为主要成分的烷基亚磷酸，磷酸的（金属）盐和次磷酸，b）从a）酯化混合物的主要成分得到酯混合物，c）从酯混合物中分离出烷基亚磷酸的酯。本发明同样涉及由烷基亚磷酸酯由该方法作为进一步合成的前体，尤其用于制备作物保护剂。

2. 发明授权

US06359171B1 Process for preparing dialkylphosphinic acids and their salts 失效
标题翻译：制备二烷基次膦酸及其盐的方法
公开(公告)号：US06359171B1
公开(公告)日：2002-03-19
申请号：US09577463
申请日：2000-05-24
申请人： Norbert Weferling , Martin Sicken , Günter Kolbe , Hans-Peter Schmitz
发明人： Norbert Weferling , Martin Sicken , Günter Kolbe , Hans-Peter Schmitz
IPC分类号： C07F930
CPC分类号： C07F9/48 , C07F9/30
摘要： The invention relates to a process for the preparation of dialkylphosphinic acids and salts thereof, which comprises a) reacting elemental yellow phosphorus with alkylating agents in the presence of a base to give a mixture which comprises, as principal constituents, the (metal) salts of alkylphosphonous, phosphorous and hypophosphorous acids, b) esterifying the principal constituents of the mixture from a) to give an ester mixture, c) isolating the ester of the alkylphosphonous acid from the ester mixture, d) preparing the corresponding ester of the dialkylphosphinic acid from the ester of the alkylphosphonous acid by free-radical-initiated reaction with olefins, e) converting the ester of the dialkylphosphinic acid into the free acid or into the dialkylphosphinic acid salts of metals from groups IA, IIA, IIIA, IVA, VA, IIB, IVB, VIIB or VIIIB of the Periodic Table or of cerium. The invention likewise relates to the use of the dialkylphosphinic acids/salts prepared by this process for the preparation of various products, in particular flame retardants.
摘要翻译：本发明涉及一种制备二烷基次膦酸及其盐的方法，该方法包括：a）在碱存在下使元素黄磷与烷基化剂反应得到一种混合物，该混合物包含作为主要成分的烷基磷酸的（金属）盐，磷和次磷酸，b）从a）酯化混合物的主要成分得到酯混合物，c）从酯混合物中分离出烷基亚磷酸的酯，d）从相应的二烷基次膦酸的酯通过与烯烃的自由基引发的反应，烷基亚磷酸的酯，e）将二烷基次膦酸的酯转化为游离酸或转化成IA，IIA，IIIA，IVA，VA，IIB族的金属的二烷基次膦酸盐，周期表IVB，VIIB或VIIIB或铈。本发明同样涉及通过该方法制备的二烷基次膦酸/盐在p 各种产品的修补，特别是阻燃剂。

3. 发明授权

US06534673B1 Process for preparing salts of dialkylphosphinic acids 有权
标题翻译：制备二烷基次膦酸的盐的方法
公开(公告)号：US06534673B1
公开(公告)日：2003-03-18
申请号：US09198540
申请日：1998-11-24
申请人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
发明人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
IPC分类号： C07F930
CPC分类号： C07F9/30
摘要： The invention relates to a process for preparing salts of dialkylphosphinic acids, which comprises a) reacting alkylphosphonous and/or hypo- phosphorous acid and/or alkali metal salts thereof with olefins in the presence of a free-radical initiator to give dialkylphosphinic acids and/or alkali metal salts thereof and b) reacting the dialkylphosphinic acids and/or alkali metal salts thereof obtained according to a) with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K to give the metal dialkyl20 phosphinate salts.
摘要翻译：本发明涉及一种制备二烷基次膦酸的盐的方法，该方法包括：a）在自由基引发剂存在下，使烷基亚磷酸和/或其次亚磷酸和/或其碱金属盐与烯烃反应，得到二烷基次膦酸和/或 b）使根据a）得到的二烷基次膦酸和/或其碱金属盐与Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi的金属化合物反应， Sr，Mn，Li，Na和/或K，得到二烷基二烷基二膦酸金属盐。

4. 发明授权

US06300516B1 Process for preparing dialkylphosphinic acids 有权
标题翻译：制备二烷基次膦酸的方法
公开(公告)号：US06300516B1
公开(公告)日：2001-10-09
申请号：US09198541
申请日：1998-11-24
申请人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
发明人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
IPC分类号： C07F930
CPC分类号： C07F9/30
摘要： The invention relates to a process for preparing dialkylphosphinic acids and/or alkali metal salts thereof by reacting olefins with alkylphosphonous and/or hypophosphorous acid and/or alkali metal salts thereof, which comprises carrying out the reaction in the presence of a free-radical initiator. The invention also relates to the use of the products prepared by the abovementioned process for preparing flame retardants.
摘要翻译：本发明涉及通过烯烃与烷基亚磷酸和/或次磷酸和/或其碱金属盐反应制备二烷基次膦酸和/或其碱金属盐的方法，其包括在自由基引发剂存在下进行反应。本发明还涉及通过上述方法制备的产品用于制备阻燃剂的用途。

5. 发明授权

US06355832B1 Processing for preparing salts of dialkylphosphinic acids 有权
标题翻译：加工制备二烷基次膦酸的盐
公开(公告)号：US06355832B1
公开(公告)日：2002-03-12
申请号：US09610953
申请日：2000-03-10
申请人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
发明人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
IPC分类号： C07F930
CPC分类号： C07F9/30
摘要： The invention relates to a process for preparing salts of dialkylphosphinic acids, which comprises a) reacting alkylphosphonous and/or hypophosphorous acid and/or alkali metal salts thereof with olefins in the presence of a free-radical initiator to give dialkylphosphinic acids and/or alkali metal salts thereof and b) reacting the dialkylphosphinic acids and/or alkali metal salts thereof obtained according to a) with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K to give the metal dialkylphosphinate salts. The invention likewise relates to the use of the metal dialkylphosphinate salts prepared by the process according to the invention for preparing flame retardants.
摘要翻译：本发明涉及一种制备二烷基次膦酸的盐的方法，该方法包括：a）在自由基引发剂存在下，使烷基亚磷酸和/或次磷酸和/或其碱金属盐与烯烃反应，得到二烷基次膦酸和/或碱金属其盐和b）使根据a）获得的二烷基次膦酸和/或其碱金属盐与Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr， Mn，Li，Na和/或K，得到二烷基次膦酸金属盐。本发明同样涉及通过本发明方法制备的二烷基次膦酸金属盐用于制备阻燃剂的用途。

6. 发明授权

US06329544B1 Process for preparing dialkylphosphinic acids 有权
标题翻译：制备二烷基次膦酸的方法
公开(公告)号：US06329544B1
公开(公告)日：2001-12-11
申请号：US09527950
申请日：2000-03-10
申请人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
发明人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
IPC分类号： C07F930
CPC分类号： C07F9/30
摘要： The invention relates to a process for preparing dialkylphosphinic acids and/or alkali metal salts thereof by reacting olefins with alkylphosphonous and/or hypophosphorous acid and/or alkali metal salts thereof, which comprises carrying out the reaction in the presence of a azo free-radical initiator. The invention also relates to the use of the products prepared by the abovementioned process for preparing flame retardants.
摘要翻译：本发明涉及通过烯烃与烷基亚磷酸和/或次磷酸和/或其碱金属盐反应制备二烷基次膦酸和/或其碱金属盐的方法，其包括在偶氮自由基存在下进行反应发起人本发明还涉及通过上述方法制备的产品用于制备阻燃剂的用途。

7. 发明授权

US06248921B1 Process for preparing salts of dialkylphosphinic acids 有权
公开(公告)号：US06248921B1
公开(公告)日：2001-06-19
申请号：US09198540
申请日：1998-11-24
申请人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
发明人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
IPC分类号： C07F930
摘要： The invention relates to a process for preparing salts of dialkylphosphinic acids, which comprises a) reacting alkylphosphonous and/or hypophosphorous acid and/or alkali metal salts thereof with olefins in the presence of a free-radical initiator to give dialkylphosphinic acids and/or alkali metal salts thereof and b) reacting the dialkylphosphinic acids and/or alkali metal salts thereof obtained according to a) with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K to give the metal dialkylphosphinate salts. The invention likewise relates to the use of the metal dialkylphosphinate salts prepared by the process according to the invention for preparing flame retardants.

8. 发明申请

US20070027297A1 Modified polyethylenephosphinic acids and their salts 失效
标题翻译：改性聚亚乙基次膦酸及其盐
公开(公告)号：US20070027297A1
公开(公告)日：2007-02-01
申请号：US11540476
申请日：2006-09-29
申请人： Martin Sicken , Werner Krause , Norbert Weferling , Hans-Peter Schmitz
发明人： Martin Sicken , Werner Krause , Norbert Weferling , Hans-Peter Schmitz
IPC分类号： C08G79/02
CPC分类号： C08K5/5313 , C07F9/305 , C08G79/04 , C09K21/14
摘要： The invention relates to polymeric phosphinic acids and their salts of the formula (I) where X is hydrogen or 1/m of a metal of valency m, or is a protonated nitrogen base, R1 and R2 are identical or different and are hydrogen, a carboxy group, a carboxylic acid derivative, an unsubstituted or substituted alkyl group having from 1 to 10 carbon atoms, phenyl, benzyl, or alkyl-substituted aromatic systems, R3 and R4 may be identical or different and are an unsubstituted or substituted alkyl group having from 2 to 20 carbon atoms, or are OX, with the above meaning for X, and u is the average number of monomer units. The invention further relates to a process for preparing the abovementioned compounds, and to their use.
摘要翻译：本发明涉及式（I）的聚合物次膦酸及其盐，其中X是氢或1 / m的价态m的金属，或是质子化的氮碱，R 1和R 2， R 2是相同或不同的并且是氢，羧基，羧酸衍生物，未取代或取代的具有1-10个碳原子的烷基，苯基，苄基或烷基取代的芳族体系，R R 3和R 4可以相同或不同，为未取代或取代的碳原子数为2〜20的烷基，或为O X，X为上述含义，和（超出（u是单体单元的平均数）。本发明还涉及制备上述化合物的方法及其用途。

9. 发明授权

US07348396B2 Modified polyethylenephosphinic acids and their salts 失效
标题翻译：改性聚亚乙基次膦酸及其盐
公开(公告)号：US07348396B2
公开(公告)日：2008-03-25
申请号：US11540476
申请日：2006-09-29
申请人： Martin Sicken , Werner Krause , Norbert Weferling , Hans-Peter Schmitz
发明人： Martin Sicken , Werner Krause , Norbert Weferling , Hans-Peter Schmitz
IPC分类号： C08G79/02 , C08F30/02
CPC分类号： C08K5/5313 , C07F9/305 , C08G79/04 , C09K21/14
摘要： The invention relates to polymeric phosphinic acids and their salts of the formula (I) where X is hydrogen or 1/m of a metal of valency m, or is a protonated nitrogen base, R1 and R2 are identical or different and are hydrogen, a carboxy group, a carboxylic acid derivative, an unsubstituted or substituted alkyl group having from 1 to 10 carbon atoms, phenyl, benzyl, or alkyl-substituted aromatic systems, R3 and R4 may be identical or different and are an unsubstituted or substituted alkyl group having from 2 to 20 carbon atoms, or are OX, with the above meaning for X, and ū is the average number of monomer units. The invention further relates to a process for preparing the abovementioned compounds, and to their use.
摘要翻译：本发明涉及式（I）的聚合物次膦酸及其盐，其中X是氢或1 / m的价态m的金属，或是质子化的氮碱，R 1和R 2， R 2是相同或不同的并且是氢，羧基，羧酸衍生物，未取代或取代的具有1-10个碳原子的烷基，苯基，苄基或烷基取代的芳族体系，R R 3和R 4可以相同或不同，为未取代或取代的碳原子数为2〜20的烷基，或为O X，X为上述含义， u是单体单元的平均数。本发明还涉及制备上述化合物的方法及其应用。

10. 发明授权

US06727335B2 Polymeric phosphinic acids and salts thereof 失效
标题翻译：聚合次膦酸及其盐
公开(公告)号：US06727335B2
公开(公告)日：2004-04-27
申请号：US10417692
申请日：2003-04-17
申请人： Martin Sicken , Norbert Weferling , Hans-Peter Schmitz
发明人： Martin Sicken , Norbert Weferling , Hans-Peter Schmitz
IPC分类号： C08F13002
CPC分类号： C07F9/305 , C07F9/485
摘要： The invention relates to polymeric phosphinic acids and their salts of the formula (I) in which X is hydrogen or a 1/m metal of valency m, R1 and R2 are identical or different and are hydrogen, a carboxyl group, a carboxylic acid derivative, an unsubstituted or substituted alkyl group having 1 to 10 carbon atoms, phenyl, benzyl or alkyl-substituted aromatics, R3 and R4 are identical or different and are hydrogen or a vinyl group of the formula (VI) —CR1═CHR2 (VI) in which R1 and R2 have the abovementioned meaning, and {overscore (u)} is the average number of monomer units. The invention also relates to a process for the preparation of the abovementioned compounds and their use.
摘要翻译：本发明涉及式（I）的聚合物次膦酸及其盐，其中X是氢或1价金属的价态m，R 1和R 2相同或不同，为氢，羧基，羧酸衍生物，具有1-10个碳原子的未取代或取代的烷基，苯基，苄基或烷基取代的芳族化合物，R 3和R 4相同或不同，为氢或式（Ⅵ）的乙烯基，其中R 1和R 2具有上述意思和{超核（u是单体单元的平均数）。本发明还涉及制备上述化合物的方法及其用途。

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