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1. 发明授权

US5973194A Process for preparing dialkylphosphinate salts 有权
标题翻译：制备二烷基次膦酸盐的方法
公开(公告)号：US5973194A
公开(公告)日：1999-10-26
申请号：US198542
申请日：1998-11-24
申请人： Norbert Weferling , Hans-Peter Schmitz , Gunter Kolbe
发明人： Norbert Weferling , Hans-Peter Schmitz , Gunter Kolbe
IPC分类号： C01B25/163 , C07B61/00 , C07F9/30
CPC分类号： C07F9/30
摘要： The invention relates to a process for preparing dialkylphosphinate salts, which comprisesa) reacting elemental yellow phosphorus with alkyl halides in the presence of alkali metal hydroxide or alkaline earth metal hydroxide to form a mixture which comprises as main constituents the salts of alkylphosphonous, phosphorous and hypophosphorous acids,b) adjusting the mixture to a pH below 7 and then reacting the mixture with olefins in the presence of a free-radical initiator andc) reacting the dialkylphosphinic acids obtained according to b) and/or alkali metal salts thereof with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K to give the metal dialkylphosphinate salts.The invention likewise relates to the use of the metal dialkylphosphinate salts prepared by the process according to the invention to prepare flame retardants.
摘要翻译：本发明涉及一种制备二烷基次膦酸盐的方法，该方法包括：a）在碱金属氢氧化物或碱土金属氢氧化物存在下使元素黄磷与烷基卤化物反应形成一种混合物，该混合物包含烷基亚磷酸，磷和次磷酸，b）将混合物调节至低于7的pH，然后在自由基引发剂存在下使该混合物与烯烃反应，和c）将根据b）获得的二烷基次膦酸与/或其碱金属盐与金属反应 Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na和/或K的化合物，得到二烷基次膦酸金属盐。本发明同样涉及通过本发明方法制备的二烷基次膦酸金属盐制备阻燃剂的用途。

2. 发明授权

US06534673B1 Process for preparing salts of dialkylphosphinic acids 有权
标题翻译：制备二烷基次膦酸的盐的方法
公开(公告)号：US06534673B1
公开(公告)日：2003-03-18
申请号：US09198540
申请日：1998-11-24
申请人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
发明人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
IPC分类号： C07F930
CPC分类号： C07F9/30
摘要： The invention relates to a process for preparing salts of dialkylphosphinic acids, which comprises a) reacting alkylphosphonous and/or hypo- phosphorous acid and/or alkali metal salts thereof with olefins in the presence of a free-radical initiator to give dialkylphosphinic acids and/or alkali metal salts thereof and b) reacting the dialkylphosphinic acids and/or alkali metal salts thereof obtained according to a) with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K to give the metal dialkyl20 phosphinate salts.
摘要翻译：本发明涉及一种制备二烷基次膦酸的盐的方法，该方法包括：a）在自由基引发剂存在下，使烷基亚磷酸和/或其次亚磷酸和/或其碱金属盐与烯烃反应，得到二烷基次膦酸和/或 b）使根据a）得到的二烷基次膦酸和/或其碱金属盐与Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi的金属化合物反应， Sr，Mn，Li，Na和/或K，得到二烷基二烷基二膦酸金属盐。

3. 发明授权

US06300516B1 Process for preparing dialkylphosphinic acids 有权
标题翻译：制备二烷基次膦酸的方法
公开(公告)号：US06300516B1
公开(公告)日：2001-10-09
申请号：US09198541
申请日：1998-11-24
申请人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
发明人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
IPC分类号： C07F930
CPC分类号： C07F9/30
摘要： The invention relates to a process for preparing dialkylphosphinic acids and/or alkali metal salts thereof by reacting olefins with alkylphosphonous and/or hypophosphorous acid and/or alkali metal salts thereof, which comprises carrying out the reaction in the presence of a free-radical initiator. The invention also relates to the use of the products prepared by the abovementioned process for preparing flame retardants.
摘要翻译：本发明涉及通过烯烃与烷基亚磷酸和/或次磷酸和/或其碱金属盐反应制备二烷基次膦酸和/或其碱金属盐的方法，其包括在自由基引发剂存在下进行反应。本发明还涉及通过上述方法制备的产品用于制备阻燃剂的用途。

4. 发明申请

US20070027297A1 Modified polyethylenephosphinic acids and their salts 失效
标题翻译：改性聚亚乙基次膦酸及其盐
公开(公告)号：US20070027297A1
公开(公告)日：2007-02-01
申请号：US11540476
申请日：2006-09-29
申请人： Martin Sicken , Werner Krause , Norbert Weferling , Hans-Peter Schmitz
发明人： Martin Sicken , Werner Krause , Norbert Weferling , Hans-Peter Schmitz
IPC分类号： C08G79/02
CPC分类号： C08K5/5313 , C07F9/305 , C08G79/04 , C09K21/14
摘要： The invention relates to polymeric phosphinic acids and their salts of the formula (I) where X is hydrogen or 1/m of a metal of valency m, or is a protonated nitrogen base, R1 and R2 are identical or different and are hydrogen, a carboxy group, a carboxylic acid derivative, an unsubstituted or substituted alkyl group having from 1 to 10 carbon atoms, phenyl, benzyl, or alkyl-substituted aromatic systems, R3 and R4 may be identical or different and are an unsubstituted or substituted alkyl group having from 2 to 20 carbon atoms, or are OX, with the above meaning for X, and u is the average number of monomer units. The invention further relates to a process for preparing the abovementioned compounds, and to their use.
摘要翻译：本发明涉及式（I）的聚合物次膦酸及其盐，其中X是氢或1 / m的价态m的金属，或是质子化的氮碱，R 1和R 2， R 2是相同或不同的并且是氢，羧基，羧酸衍生物，未取代或取代的具有1-10个碳原子的烷基，苯基，苄基或烷基取代的芳族体系，R R 3和R 4可以相同或不同，为未取代或取代的碳原子数为2〜20的烷基，或为O X，X为上述含义，和（超出（u是单体单元的平均数）。本发明还涉及制备上述化合物的方法及其用途。

5. 发明授权

US07348396B2 Modified polyethylenephosphinic acids and their salts 失效
标题翻译：改性聚亚乙基次膦酸及其盐
公开(公告)号：US07348396B2
公开(公告)日：2008-03-25
申请号：US11540476
申请日：2006-09-29
申请人： Martin Sicken , Werner Krause , Norbert Weferling , Hans-Peter Schmitz
发明人： Martin Sicken , Werner Krause , Norbert Weferling , Hans-Peter Schmitz
IPC分类号： C08G79/02 , C08F30/02
CPC分类号： C08K5/5313 , C07F9/305 , C08G79/04 , C09K21/14
摘要： The invention relates to polymeric phosphinic acids and their salts of the formula (I) where X is hydrogen or 1/m of a metal of valency m, or is a protonated nitrogen base, R1 and R2 are identical or different and are hydrogen, a carboxy group, a carboxylic acid derivative, an unsubstituted or substituted alkyl group having from 1 to 10 carbon atoms, phenyl, benzyl, or alkyl-substituted aromatic systems, R3 and R4 may be identical or different and are an unsubstituted or substituted alkyl group having from 2 to 20 carbon atoms, or are OX, with the above meaning for X, and ū is the average number of monomer units. The invention further relates to a process for preparing the abovementioned compounds, and to their use.
摘要翻译：本发明涉及式（I）的聚合物次膦酸及其盐，其中X是氢或1 / m的价态m的金属，或是质子化的氮碱，R 1和R 2， R 2是相同或不同的并且是氢，羧基，羧酸衍生物，未取代或取代的具有1-10个碳原子的烷基，苯基，苄基或烷基取代的芳族体系，R R 3和R 4可以相同或不同，为未取代或取代的碳原子数为2〜20的烷基，或为O X，X为上述含义， u是单体单元的平均数。本发明还涉及制备上述化合物的方法及其应用。

6. 发明授权

US06727335B2 Polymeric phosphinic acids and salts thereof 失效
标题翻译：聚合次膦酸及其盐
公开(公告)号：US06727335B2
公开(公告)日：2004-04-27
申请号：US10417692
申请日：2003-04-17
申请人： Martin Sicken , Norbert Weferling , Hans-Peter Schmitz
发明人： Martin Sicken , Norbert Weferling , Hans-Peter Schmitz
IPC分类号： C08F13002
CPC分类号： C07F9/305 , C07F9/485
摘要： The invention relates to polymeric phosphinic acids and their salts of the formula (I) in which X is hydrogen or a 1/m metal of valency m, R1 and R2 are identical or different and are hydrogen, a carboxyl group, a carboxylic acid derivative, an unsubstituted or substituted alkyl group having 1 to 10 carbon atoms, phenyl, benzyl or alkyl-substituted aromatics, R3 and R4 are identical or different and are hydrogen or a vinyl group of the formula (VI) —CR1═CHR2 (VI) in which R1 and R2 have the abovementioned meaning, and {overscore (u)} is the average number of monomer units. The invention also relates to a process for the preparation of the abovementioned compounds and their use.
摘要翻译：本发明涉及式（I）的聚合物次膦酸及其盐，其中X是氢或1价金属的价态m，R 1和R 2相同或不同，为氢，羧基，羧酸衍生物，具有1-10个碳原子的未取代或取代的烷基，苯基，苄基或烷基取代的芳族化合物，R 3和R 4相同或不同，为氢或式（Ⅵ）的乙烯基，其中R 1和R 2具有上述意思和{超核（u是单体单元的平均数）。本发明还涉及制备上述化合物的方法及其用途。

7. 发明授权

US06420598B1 Process for preparing alkylphosphonic acids 有权
标题翻译：制备烷基膦酸的方法
公开(公告)号：US06420598B1
公开(公告)日：2002-07-16
申请号：US09591712
申请日：2000-06-12
申请人： Norbert Weferling , Martin Sicken , Hans-Peter Schmitz
发明人： Norbert Weferling , Martin Sicken , Hans-Peter Schmitz
IPC分类号： C07F930
CPC分类号： C07F9/3808
摘要： The present invention relates to a process for the preparation of alkylphosphonic acids, which comprises reacting phosphorous acid (H3PO3) with short-chain olefins, and to the use of the products prepared by this process.
摘要翻译：本发明涉及一种制备烷基膦酸的方法，其包括使亚磷酸（H 3 PO 3）与短链烯烃反应，以及使用通过该方法制备的产物。

8. 发明授权

US06355832B1 Processing for preparing salts of dialkylphosphinic acids 有权
标题翻译：加工制备二烷基次膦酸的盐
公开(公告)号：US06355832B1
公开(公告)日：2002-03-12
申请号：US09610953
申请日：2000-03-10
申请人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
发明人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
IPC分类号： C07F930
CPC分类号： C07F9/30
摘要： The invention relates to a process for preparing salts of dialkylphosphinic acids, which comprises a) reacting alkylphosphonous and/or hypophosphorous acid and/or alkali metal salts thereof with olefins in the presence of a free-radical initiator to give dialkylphosphinic acids and/or alkali metal salts thereof and b) reacting the dialkylphosphinic acids and/or alkali metal salts thereof obtained according to a) with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K to give the metal dialkylphosphinate salts. The invention likewise relates to the use of the metal dialkylphosphinate salts prepared by the process according to the invention for preparing flame retardants.
摘要翻译：本发明涉及一种制备二烷基次膦酸的盐的方法，该方法包括：a）在自由基引发剂存在下，使烷基亚磷酸和/或次磷酸和/或其碱金属盐与烯烃反应，得到二烷基次膦酸和/或碱金属其盐和b）使根据a）获得的二烷基次膦酸和/或其碱金属盐与Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr， Mn，Li，Na和/或K，得到二烷基次膦酸金属盐。本发明同样涉及通过本发明方法制备的二烷基次膦酸金属盐用于制备阻燃剂的用途。

9. 发明授权

US06329544B1 Process for preparing dialkylphosphinic acids 有权
标题翻译：制备二烷基次膦酸的方法
公开(公告)号：US06329544B1
公开(公告)日：2001-12-11
申请号：US09527950
申请日：2000-03-10
申请人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
发明人： Norbert Weferling , Hans-Peter Schmitz , Günter Kolbe
IPC分类号： C07F930
CPC分类号： C07F9/30
摘要： The invention relates to a process for preparing dialkylphosphinic acids and/or alkali metal salts thereof by reacting olefins with alkylphosphonous and/or hypophosphorous acid and/or alkali metal salts thereof, which comprises carrying out the reaction in the presence of a azo free-radical initiator. The invention also relates to the use of the products prepared by the abovementioned process for preparing flame retardants.
摘要翻译：本发明涉及通过烯烃与烷基亚磷酸和/或次磷酸和/或其碱金属盐反应制备二烷基次膦酸和/或其碱金属盐的方法，其包括在偶氮自由基存在下进行反应发起人本发明还涉及通过上述方法制备的产品用于制备阻燃剂的用途。

10. 发明授权

US06242642B1 Process for preparing arylalphosphinic acids 失效
标题翻译：制备芳基次膦酸的方法
公开(公告)号：US06242642B1
公开(公告)日：2001-06-05
申请号：US09198538
申请日：1998-11-24
申请人： Norbert Weferling , Hans-Peter Schmitz
发明人： Norbert Weferling , Hans-Peter Schmitz
IPC分类号： C07F930
CPC分类号： C07F9/304
摘要： The invention relates to a process for preparing arylalkyiphosphinic acids and/or alkali metal salts thereof by reacting olefins with arylphosphonous acids and/or alkali metal salts thereof, which comprises carrying out the reaction in the presence of a free-radical initiator. The invention also relates to the use of the products prepared by the abovementioned process for preparing flame retardants.
摘要翻译：本发明涉及通过烯烃与芳基亚磷酸和/或其碱金属盐反应制备芳基亚磷酸和/或其碱金属盐的方法，其包括在自由基引发剂存在下进行反应。本发明还涉及涉及通过上述方法制备的产品用于制备阻燃剂的用途。

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