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1. 发明授权

US06579937B1 Thermoplastic moulding materials 有权
标题翻译：热塑性成型材料
公开(公告)号：US06579937B1
公开(公告)日：2003-06-17
申请号：US09868516
申请日：2001-06-18
申请人： Norbert Güntherberg , Josef Wünsch , Peter Ittemann , Konrad Knoll , Norbert Niessner
发明人： Norbert Güntherberg , Josef Wünsch , Peter Ittemann , Konrad Knoll , Norbert Niessner
IPC分类号： C08L2508
CPC分类号： C08L51/04 , C08F265/04 , C08F265/06 , C08L53/02 , C08L2666/14 , C08L2666/02 , C08L2666/24
摘要： Thermoplastic molding compositions comprising (A) 5 to 98%-wt., based on components (A) through (E), of at least one elastomeric graft copolymer, (B) 1 to 90%-wt., based on components (A) through (E), of a further copolymer, (C) 1 to 70%-wt., based on components (A) though (D), of an elastomeric block copolymer composed of at least one block CA (hard phase) having copolymerized units of a vinylaromatic monomer, and at least one elastomeric block C(B/A) (soft phase) having copolymerized units of a vinylaromatic monomer, and of a diene, (D) 0 to 300%-wt., based on components (A) through (C), of a polycarbonate, and (E) 0 to 30%-wt., based on components (A) through (E), of conventional additives and processing aids, are useful for producing films, moldings or fibers.
摘要翻译：包含（A）基于组分（A）至（E）的至少一种弹性体接枝共聚物为5至98重量％的热塑性模制组合物，（B）基于组分（A）的1-90重量％）（E）中的另一种共聚物，（C）基于组分（A）至（D）的1-70重量％的由至少一个共聚的嵌段CA（硬相）组成的弹性体嵌段共聚物乙烯基芳族单体的单元和具有乙烯基芳族单体和二烯的共聚单元的至少一种弹性嵌段C（B / A）（软相），（D）基于组分（A）为0至300重量％）通过（C），聚碳酸酯，和（E）0〜30重量％，基于常规添加剂和加工助剂的组分（A）至（E），可用于制备膜，模制品或纤维。

2. 发明授权

US5972519A Transparent antiblocking film 失效
标题翻译：透明防粘膜
公开(公告)号：US5972519A
公开(公告)日：1999-10-26
申请号：US983362
申请日：1998-01-13
申请人： Norbert Niessner , Konrad Knoll
发明人： Norbert Niessner , Konrad Knoll
IPC分类号： B32B27/00 , C08J5/18 , C08L53/02 , B32B25/08
CPC分类号： C08J5/18 , C08L53/02 , C08J2353/02 , Y10T428/31725 , Y10T428/31797 , Y10T428/31855 , Y10T428/31913 , Y10T428/31917
摘要： A film in roll form, in particular for food packaging as substitute for a film made from polyvinyl chloride, comprises from 15 to 99.6% by weight of an elastomeric styrene-butadiene block copolymer, from 15 to 99.6% of a thermoplastic polymer, from 0.1 to 10% of an antifogging agent, from 0.1 to 5% of a primary antioxidant, from 0.1 to 5% of a secondary antioxidant and from 0.1 to 50% of other auxiliaries, and shrinks perpendicularly to the direction of take-off by not more than 3% during a storage period of three months.
摘要翻译： PCT No.PCT / EP97 / 02682 Sec。 371日期1998年1月13日 102（e）日期1998年1月13日PCT提交1997年5月26日PCT公布。公开号WO97 / 46608 日期1997年12月11日卷纸形式的薄膜，特别是用于代替由聚氯乙烯制成的薄膜的食品包装，包含15至99.6重量％的弹性体苯乙烯 - 丁二烯嵌段共聚物，15至99.6重量％热塑性聚合物，0.1〜10％的防雾剂，0.1〜5％的初级抗氧化剂，0.1〜5％的二级抗氧化剂和0.1〜50％的其他助剂，并垂直收缩在三个月的储存期间，不超过3％。

3. 发明授权

US5877242A .alpha.tocopherol-stabilized styrene/butadiene block copolymers 失效
标题翻译： α-生育酚稳定的苯乙烯/丁二烯嵌段共聚物
公开(公告)号：US5877242A
公开(公告)日：1999-03-02
申请号：US750670
申请日：1997-08-14
申请人： Norbert Niessner , Wolfgang Loth , Konrad Knoll , Norbert Guntherberg , Paul Naegele , Hubert Trauth , Jurgen Pohrt
发明人： Norbert Niessner , Wolfgang Loth , Konrad Knoll , Norbert Guntherberg , Paul Naegele , Hubert Trauth , Jurgen Pohrt
IPC分类号： C08K5/49 , C08K5/1545 , C08K5/50 , C08K5/524 , C08L53/02 , C08K5/34
CPC分类号： C08L53/02 , C08K5/1545 , C08K5/524
摘要： A molding material comprises styrene/butadiene block copolymers obtainable by anionic polymerization and from 0.01 to 1% by weight, based on the polymer, of .alpha.-tocopherol.
摘要翻译： PCT No.PCT / EP95 / 02212 Sec。 371日期1997年8月14日 102（e）日期1997年8月14日PCT归档1995年6月8日PCT公布。 WO95 / 34600 PCT出版物日期1995年12月21日一种成型材料包括通过阴离子聚合可获得的苯乙烯/丁二烯嵌段共聚物和基于聚合物的0.01至1重量％的α-生育酚。

4. 发明申请

US20100291383A1 FIBER ADHESIVE 审中-公开
标题翻译：纤维胶粘剂
公开(公告)号：US20100291383A1
公开(公告)日：2010-11-18
申请号：US12278400
申请日：2007-01-30
申请人： Dieter Urban , Norbert Niessner , Bernd-Steffen Von Bernstorff , Konrad Knoll
发明人： Dieter Urban , Norbert Niessner , Bernd-Steffen Von Bernstorff , Konrad Knoll
IPC分类号： D02G3/36 , D01D5/34
CPC分类号： D01F8/06 , B01D39/1623 , D01F8/10 , Y10T428/2929
摘要： Tacky polymeric fibers having a nontacky core and a tacky outer shell.
摘要翻译：粘性聚合物纤维具有非粘性芯和粘性外壳。

5. 发明授权

US06369160B1 Polymer mixtures comprised of styrene polymers 有权
标题翻译：由苯乙烯聚合物组成的聚合物混合物
公开(公告)号：US06369160B1
公开(公告)日：2002-04-09
申请号：US09623179
申请日：2000-08-29
申请人： Konrad Knoll , Norbert Niessner , Josef Wünsch , Hermann Gausepohl
发明人： Konrad Knoll , Norbert Niessner , Josef Wünsch , Hermann Gausepohl
IPC分类号： C08L5302
CPC分类号： C08J5/18 , C08J2325/06 , C08J2353/02 , C08L25/06 , C08L53/02 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2666/24 , C08L2666/04
摘要： Polymer mixtures comprise P1) from 1 to 85% by weight of an elastomeric block copolymer which has been built up from hard blocks S made from vinylaromatic monomers and from random soft blocks B/S made up from dienes and from vinylaromatic monomers, and which contains at least the block structure S-B/S-S, where the diene content is less than 50 percent by weight and the proportion of the soft phase formed from the blocks B/S is at least 60 percent by weight, based in each case on the entire block copolymer, P2) from 5 to 89% by weight of a block copolymer differing from P1) and made from vinylaromatic monomers and from dienes, P3) from 10 to 94% by weight of glass-clear or impact-modified polystyrene or mixtures thereof, and P4) from 0 to 84% by weight of other additives, where the total of components P1) to P4) is 100%.
摘要翻译：聚合物混合物包含1至85重量％的弹性体嵌段共聚物，其由由乙烯基芳族单体制成的硬块S和由二烯和乙烯基芳族单体组成的无规软嵌段B / S构成，并且其包含至少块结构SB / SS，其中二烯含量小于50重量％，并且由块B / S形成的软相的比例为至少60重量％，基于每种情况下在整个嵌段共聚物，P2）5至89重量％的不同于P1的嵌段共聚物，并由乙烯基芳族单体和二烯制成P3）10至94重量％的玻璃透明或冲击改性的聚苯乙烯或其混合物，和P 4 ）0〜84重量％的其他添加剂，其中组分P1）至P4的总量）为100％。

6. 发明授权

US06388149B2 Process for reacting an organic compound in the presence of a supported ruthenium catalyst 有权
标题翻译：在负载型钌催化剂存在下使有机化合物反应的方法
公开(公告)号：US06388149B2
公开(公告)日：2002-05-14
申请号：US09726250
申请日：2000-11-30
申请人： Thomas Rühl , Boris Breitscheidel , Jochem Henkelmann , Andreas Henne , Rolf Lebkücher , Konrad Knoll , Paul Naegele , Hermann Gausepohl , Sabine Weiguny , Norbert Niessner
发明人： Thomas Rühl , Boris Breitscheidel , Jochem Henkelmann , Andreas Henne , Rolf Lebkücher , Konrad Knoll , Paul Naegele , Hermann Gausepohl , Sabine Weiguny , Norbert Niessner
IPC分类号： C07C503
CPC分类号： B01J23/462 , B01J23/44 , B01J35/0053 , B01J35/10 , B01J35/1019 , B01J35/108 , C08F8/04
摘要： A process for the reaction of an organic compound in the presence of a catalyst comprising, as active metal, ruthenium alone or together with at least one Group Ib, VIIb, or VIIIb metal in an amount of from 0.01 to 30 wt %, based on the total weight of the catalyst, applied to a support, wherein from 10 to 50% of the pore volume of the support comprises macropores having a pore diameter in the range of from 50 nm to 10,000 nm and from 50 to 90% of the pore volume of the support comprises mesopores having a pore diameter in the range of from 2 to 50 nm, the sum of said pore volumes being 100%, and said catalyst as such.
摘要翻译：一种有机化合物在催化剂存在下反应的方法，所述催化剂包含作为活性金属的钌单独或与至少一种量为0.01至30重量％的Ib族，VIIb或Ⅷb族金属，基于施加到载体上的催化剂的总重量，其中载体的孔体积的10至50％包含孔径在50nm至10,000nm的孔径和50至90％的孔隙中的大孔载体的体积包含孔径在2至50nm范围内的孔隙，所述孔体积的总和为100％，所述催化剂本身。

7. 发明授权

US06248924B1 Process for reacting an organic compound in the presence of a supported ruthenium catalyst 失效
标题翻译：在负载型钌催化剂存在下使有机化合物反应的方法
公开(公告)号：US06248924B1
公开(公告)日：2001-06-19
申请号：US08877820
申请日：1997-06-16
申请人： Thomas Rühl , Boris Breitscheidel , Jochem Henkelmann , Andreas Henne , Rolf Lebkücher , Konrad Knoll , Paul Naegele , Hermann Gausepohl , Sabine Weiguny , Norbert Niessner
发明人： Thomas Rühl , Boris Breitscheidel , Jochem Henkelmann , Andreas Henne , Rolf Lebkücher , Konrad Knoll , Paul Naegele , Hermann Gausepohl , Sabine Weiguny , Norbert Niessner
IPC分类号： C07C2920
CPC分类号： B01J23/462 , B01J23/44 , B01J35/0053 , B01J35/10 , B01J35/1019 , B01J35/108 , C08F8/04
摘要： A process for the reaction of an organic compound in the presence of a catalyst comprising, as active metal, ruthenium alone or together with at least one Group Ib, VIIb, or VIIIb metal in an amount of from 0.01 to 30 wt %, based on the total weight of the catalyst, applied to a support, wherein from 10 to 50% of the pore volume of the support comprises macropores having a pore diameter in the range of from 50 nm to 10,000 nm and from 50 to 90% of the pore volume of the support comprises mesopores having a pore diameter in the range of from 2 to 50 nm, the sum of said pore volumes being 100%, and said catalyst as such.
摘要翻译：一种有机化合物在催化剂存在下反应的方法，所述催化剂包含作为活性金属的钌单独或与至少一种量为0.01至30重量％的Ib族，VIIb或Ⅷb族金属，基于施加到载体上的催化剂的总重量，其中载体的孔体积的10至50％包含孔径在50nm至10,000nm的孔径和50至90％的孔隙中的大孔载体的体积包含孔径在2至50nm范围内的孔隙，所述孔体积的总和为100％，所述催化剂本身。

8. 发明授权

US6031053A Thermoplastic elastomer 失效
标题翻译：热塑性弹性体
公开(公告)号：US6031053A
公开(公告)日：2000-02-29
申请号：US750705
申请日：1996-12-17
申请人： Konrad Knoll , Hermann Gausepohl , Norbert Niessner , Dietmar Bender , Paul Naegele
发明人： Konrad Knoll , Hermann Gausepohl , Norbert Niessner , Dietmar Bender , Paul Naegele
IPC分类号： C08F297/04 , C08J5/18
CPC分类号： C08J5/18 , C08F297/04 , C08J2353/02
摘要： An elastomeric block copolymer comprising at least one block A having polymerized units of a vinylaromatic monomer and forming a rigid phase and at least one elastomeric block B/A having polymerized units of both vinylaromatic monomers and of a diene and forming a flexible phase, and glass transition temperature Tg of the block A being above 25.degree. C. and that of the block B/A being below 25.degree. C. and the phase volume ratio of block A to block B/A being chosen so that the amount of the rigid phase in the total block copolymer is 1 to 40% by volume and the amount of the diene is less than 50% by weight.
摘要翻译： PCT No.PCT / EP95 / 02207 Sec。 371日期1996年12月17日第 102（e）日期1996年12月17日PCT提交1995年6月8日PCT公布。第WO95 / 35335号公报日期1995年12月28日一种弹性体嵌段共聚物，其包含至少一个具有乙烯基芳族单体的聚合单元并形成刚性相的嵌段A和至少一个具有乙烯基芳族单体和二烯的聚合单元的弹性嵌段B / A，块A的柔性相和玻璃化转变温度Tg高于25℃，块B / A的玻璃化转变温度Tg低于25℃，并且选择块A与嵌段B / A的相体积比，使得总嵌段共聚物中的刚性相的量为1〜40体积％，二烯的量小于50重量％。

9. 发明授权

US06197889B1 Thermoplastic elastomeric block copolymers 失效
标题翻译：热塑性弹性体嵌段共聚物
公开(公告)号：US06197889B1
公开(公告)日：2001-03-06
申请号：US08981051
申请日：1997-12-11
申请人： Konrad Knoll , Hermann Gausepohl , Norbert Niessner , Paul Naegele , Wolfgang Fischer
发明人： Konrad Knoll , Hermann Gausepohl , Norbert Niessner , Paul Naegele , Wolfgang Fischer
IPC分类号： C08F29300
CPC分类号： C08F297/04
摘要： Elastomeric block copolymers comprising at least one hard block A composed of styrene monomers and at least one elastomeric block (B/A) composed of styrene monomers and dienes, the glass transition temperature Tg of the block A being more than 25° C. and that of block (B/A) being less than 25° C. and the phase volume ratio of block A to block (B/A) being chosen so that the proportion of the hard phase in the total block copolymer is from 1 to 40% by volume and the amount by weight of the diene is less than 50% by weight, and the relative proportion of 1,2 linkages of the polydiene, based on the sum of 1,2- and 1,4-cis/trans linkages, being below 15%, are prepared by anionic polymerization by means of a lithium alkyl in a nonpolar solvent in the presence of a soluble potassium salt and are used for the production of shaped articles.
摘要翻译：弹性体嵌段共聚物包含至少一个由苯乙烯单体组成的硬嵌段A和至少一个由苯乙烯单体和二烯构成的弹性嵌段（B / A），嵌段A的玻璃化转变温度Tg高于25℃，（B / A）小于25℃，并且选择块A与嵌段（B / A）的相体积比，使得总嵌段共聚物中硬相的比例为1〜40％并且二烯的重量百分比小于50重量％，并且基于1,2-和1,4-顺/反键的总和的聚二烯的1,2-键的相对比例，低于15％，通过在非极性溶剂中在可溶性钾盐的存在下通过烷基锂进行阴离子聚合制备，并用于生产成型制品。

10. 发明申请

US20120220678A1 THERMOPLASTIC COMPOSITIONS HAVING IMPROVED FLOWABILITY 审中-公开
标题翻译：具有改善流动性的热塑性组合物
公开(公告)号：US20120220678A1
公开(公告)日：2012-08-30
申请号：US13505966
申请日：2010-11-02
申请人： Christof Mehler , Rolf Minkwitz , Christian Schade , Piyada Charoensirisomboon , Norbert Niessner , Kyung Ho Shon
发明人： Christof Mehler , Rolf Minkwitz , Christian Schade , Piyada Charoensirisomboon , Norbert Niessner , Kyung Ho Shon
IPC分类号： C08K5/12 , C08J9/22 , C08L55/02
CPC分类号： C08L55/02 , C08K5/12 , C08K5/1539 , C08K2201/014 , C08L25/12 , D01F6/56 , C08L2666/04
摘要： The present invention relates to compositions comprising (i) as component (I), at least one molding composition comprising components A and B, where A) is a graft copolymer as component A, and B) is a thermoplastic copolymer as component B; and (ii) at least one cyclohexanepolycarboxylic acid derivative of the formula (I); as component (II) in which R1 is C1-C10-alkyl or C3-C8-cycloalkyl, m is 0, 1, 2, or 3, n is 2, 3, or 4, and R is hydrogen or C1-C30-alkyl; or the group —(COOR)n forms an anhydride of the formula where it is essential to the invention that component (I) comprises from 11 to 19.9% by weight of component A and from 80.1 to 89% by weight of component B, where each of the % by weight values is based on the entirety of components A and B, and the total of those values is 100% by weight, and also to a process for producing the composition of the invention, to the use of the composition of the invention for producing moldings, foils, foams, or fibers, and to moldings, foils, foams, or fibers comprising the composition of the invention.
摘要翻译：本发明涉及包含（i）组分（I）的组合物，至少一种包含组分A和B的模塑组合物，其中A）是作为组分A的接枝共聚物，B）是作为组分B的热塑性共聚物; 和（ii）至少一种式（I）的环己烷多羧酸衍生物; 作为其中R 1为C 1 -C 10 - 烷基或C 3 -C 8 - 环烷基的组分（II），m为0,1,2或3，n为2,3或4，并且R为氢或C 1 -C 30 - 烷基; 或（COOR）基团形成下式的酸酐，其中组分（I）占组分A的11至19.9重量％和组分B的80.1至89重量％是本发明必需的，其中每个重量百分比值基于组分A和B的全部，并且这些值的总和为100重量％，并且还涉及制备本发明组合物的方法，使用组合物用于生产模制品，箔，泡沫或纤维的本发明以及包含本发明组合物的模制品，箔，泡沫或纤维。

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