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1. 发明授权

US4933477A Preparation of phenyl-substituted epoxides 失效
标题翻译：苯基取代的环氧化物的制备
公开(公告)号：US4933477A
公开(公告)日：1990-06-12
申请号：US236216
申请日：1988-08-25
申请人： Norbert Goetz , Hans-Gert Recker , Hubert Smuda
发明人： Norbert Goetz , Hans-Gert Recker , Hubert Smuda
IPC分类号： C07C33/46 , C07C27/00 , C07C29/136 , C07C29/143 , C07C67/00 , C07D301/26 , C07D303/04 , C07D303/08 , C07D303/22 , C07D303/34
CPC分类号： C07D303/22 , C07D303/08
摘要： Phenyl-substituted epoxides of the formula ##STR1## where R.sup.1 and R.sup.2 are each hydrogen, alkyl, alkenyl, phenyl, halogen, nitro, alkoxy, haloalkyl, phenoxy or phenylsulfonyl, are prepared by reducing a haloacetophenone to a halohydrin and reacting the halohydrin with an alkali metal hydroxide by a process in which the reduction with the alkali metal borohydride and the reaction are carried out in aqueous organic solution, or the cyclization of a halohydrin with an alkali metal hydroxide is carried out in an organic liquid.
摘要翻译：其中R 1和R 2各自为氢，烷基，烯基，苯基，卤素，硝基，烷氧基，卤代烷基，苯氧基或苯基磺酰基的苯基取代的环氧化物通过将卤代苯乙酮还原成卤代醇并使卤代醇与碱金属氢氧化物通过碱金属硼氢化合物的还原和反应在含水有机溶液中进行，或卤代醇与碱金属氢氧化物的环化在有机液体中进行。

2. 发明授权

US4929765A Preparation of phenylacetaldehydes 失效
标题翻译：苯乙醛的制备
公开(公告)号：US4929765A
公开(公告)日：1990-05-29
申请号：US274930
申请日：1988-11-22
申请人： Hubert Smuda , Wolfgang Hoelderich , Norbert Goetz , Hans-Gert Recker
发明人： Hubert Smuda , Wolfgang Hoelderich , Norbert Goetz , Hans-Gert Recker
IPC分类号： C07C45/51 , C07C45/52 , C07C45/54 , C07C45/58
CPC分类号： C07C45/52 , C07C45/512 , C07C45/513 , C07C45/54 , C07C45/58 , Y02P20/582
摘要： Phenylacetaldehydes of the general formula I ##STR1## where R.sup.1 to R.sup.5 are each independently of the others hydrogen, alkyl, alkoxy, halogen, haloalkyl, haloalkoxy or haloalkylthio, by catalytic rearrangement in the presence of a zeolite, are prepared by reacting an epoxy of the formula II or a phenylglycol of the formula III ##STR2## where Y and Z can be identical to or different from each other and are each hydroxyl, alkoxy, aryloxy or acyloxy, in the gas phase over a borosilicate zeolite catalyst at from 70.degree. to 200.degree. C. under reduced pressure.
摘要翻译：通过在沸石存在下通过催化重排，其中R 1至R 5各自独立地为氢，烷基，烷氧基，卤素，卤代烷基，卤代烷氧基或卤代烷硫基的通式I（I）的苯基乙醛通过使式II的环氧基或式III的苯基二醇其中Y和Z可以彼此相同或不同，并且各自为羟基，烷氧基，芳氧基或酰氧基，其中气相在硼硅酸盐沸石催化剂上在70〜200℃下减压。

3. 发明授权

US4997989A Tert-butylalkynols 失效
标题翻译：叔丁基炔醇
公开(公告)号：US4997989A
公开(公告)日：1991-03-05
申请号：US293447
申请日：1989-01-04
申请人： Hubert Smuda , Wolfgang Rohr
发明人： Hubert Smuda , Wolfgang Rohr
IPC分类号： C07C41/00 , C07C43/23 , C07C43/295 , C07C67/00
CPC分类号： C07C43/23
摘要： Novel tert-butylalkynols of the formula (I) ##STR1## where Y is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl, aryl, aryloxy or benzyl and m is an integer from 1 to 3, and the individual groups Y may be identical or different when m>1, and a process for their preparation are described.
摘要翻译：式（I）的新型叔丁基炔醇其中Y是氢，卤素，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷基，芳基，芳氧基或苄基，m是 1〜3的整数，当m> 1时，各个基团Y可以相同或不同，对其制备方法进行说明。

4. 发明授权

US5159117A Preparation of .alpha.,.alpha.-dialkoxy ketones 失效
标题翻译：（ALPHA），（ALPHA） - 二羟基酮的制备
公开(公告)号：US5159117A
公开(公告)日：1992-10-27
申请号：US747575
申请日：1991-08-20
申请人： Guenter Wegner , Stefan Karbach , Hubert Smuda , Eckhard Hickmann , Reiner Kober , Rainer Seele , Thomas Zierke
发明人： Guenter Wegner , Stefan Karbach , Hubert Smuda , Eckhard Hickmann , Reiner Kober , Rainer Seele , Thomas Zierke
IPC分类号： C07C45/68 , C07C45/71 , C07C49/175 , C07C49/255 , C07C49/517 , C07C49/84 , C07D307/46 , C07D333/22
CPC分类号： C07D333/22 , C07C45/68 , C07C45/71 , C07C49/175 , C07C49/255 , C07C49/517 , C07C49/84 , C07D307/46
摘要： A process for preparing .alpha.,.alpha.-dialkoxy ketones of the formula I ##STR1## where R.sup.1 and R.sup.2 are each, independently of one another, hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.30 -cycloalkylakyl, C.sub.9 -C.sub.30 -alkylcycloalkyl, unsubstituted or C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy-, halogen-, C.sub.1 -C.sub.4 -haloalkyl-, C.sub.1 -C.sub.4 -haloalkoxy-, phenyl-, phenoxy-, halophenyl-, halophenoxy- and/or cyano-substituted aryl, C.sub.7 -C.sub.20 -aralkyl or heterocyclyl,R.sup.2 is also ##STR2## R.sup.3 and R.sup.4 are each, independently of one another, C.sub.1 -C.sub.20 -alkyl, C.sub.3 -C.sub.20 -cycloalkyl, aryl, C.sub.7 -C.sub.20 -arylalkyl, or together are an unsubstituted or C.sub.1-C.sub.4 -alkyl- substituted C.sub.2 -C.sub.7 -alkylene chain andR.sup.5 is R.sup.1 or together with R.sup.1 is an unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted C.sub.2 -C.sub.7 -alkylene chain,which entails reacting ketones or aldehydes of the formula II ##STR3## with nitrites of the formula IIIR.sup.3/4 --(NO.sub.2).sub.n (III)where n is 1 or 2, and n is 2 when R.sup.3 and R.sup.4 together are an unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted C.sub.2 -C.sub.7 -alkylene chain, with the proviso that the nitrite radicals are located at the termini, or with a mixture of alcohol of the formula IVR.sup.3/4 --(OH).sub.n IVwhere n is 1 or 2, and n is 2 when R.sup.3 and R.sup.4 together are an unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted C.sub.2 -C.sub.7 -alkylene chain, with the proviso that the hydroxyl group is located at the terminus, and dinitrogen trioxide in a molar ratio of 2:1 in the presence of an acid catalyst at from 0.degree. to 170.degree. C.
摘要翻译：制备式I的α，α-二烷氧基酮的方法，其中R 1和R 2各自独立地为氢，C 1 -C 20 - 烷基，C 3 -C 20 - 环烷基，C 4 -C 30 - 环烷基，C 9 -C 30 - 烷基环烷基，未取代的或C 1 -C 8 - 烷基，C 1 -C 8 - 烷氧基 - ，卤素 - ，C 1 -C 4卤代烷基 - ，C 1 -C 4 - 卤代烷氧基 - ，苯基 - ，苯氧基 - ，卤代苯基 - ，卤代苯氧基 - 和/或氰基取代的芳基，C 7 -C 20 - 芳烷基或杂环基，R 2也是R 3和R 4彼此独立地为C 1 -C 20 - 烷基，C 3 -C 20 - 环烷基，芳基，或者一起是未取代的或C 1 -C 4烷基取代的C 2 -C 7亚烷基链，R 5是R 1或与R 1一起是未取代的或C 1 -C 4烷基取代的C 2 -C 7亚烷基链，其中需要使式II（II）的酮或醛与式III R3 / 4-（NO2）n（III）的亚硝酸盐反应，其中n为1或2，n为2，当R3和R4一起为未取代的或C 1 -C 4烷基取代的C 2 -C 7 - 亚烷基链条件是亚硝酸根自由基位于末端，或与式IV R3 / 4-（OH）n IV的醇的混合物，其中n为1或2，n为2，当R 3和R 4一起为未取代的或 C1-C4烷基取代的C2-C7-亚烷基链，条件是羟基位于末端，二氧化二氮在摩尔比为2:1的酸催化剂存在下，0℃至 170℃

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