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    • 2. 发明申请
    • High strength seamless steel pipe excellent in hydrogen-induced cracking resistance and its production method
    • 高强度无缝钢管耐氢破坏性优良及其制备方法
    • US20080283161A1
    • 2008-11-20
    • US12219390
    • 2008-07-22
    • Nobutoshi MuraoNobuyuki HisamuneHajime OsakoKunio Kondo
    • Nobutoshi MuraoNobuyuki HisamuneHajime OsakoKunio Kondo
    • C21D9/08
    • C21D9/08C21D8/10C21D2211/002C21D2211/005C21D2211/008C22C38/002C22C38/02C22C38/04C22C38/22C22C38/24
    • The present invention relates to a high strength seamless steel pipe excellent in hydrogen-induced cracking resistance, characterized by consisting of, by mass %, C: 0.03-0.11%, Si: 0.05-0.5%, Mn: 0.8-1.6%, P: 0.025% or less, S: 0.003% or less, Ti: 0.002-0.017%, Al: 0.001-0.10%, Cr: 0.05-0.5%, Mo: 0.02-0.3%, V: 0.02-0.20%, Ca: 0.0005-0.005%, N: 0.008% or less and O (Oxygen): 0.004% or less, and the balance Fe and impurities, and also characterized in that the microstructure of the steel is bainite and/or martensite, ferrite is precipitated at grain boundaries and yield stress is 483 MPa or more. Further, to ensure high strength of the steel, the seamless steel pipe preferably contains, by mass %, at least one of Cu: 0.05-0.5% and Ni: 0.05-0.5%. To produce the above-mentioned steel pipe, it is desirable to limit a starting temperature of quenching after rolling, a cooling rate and a tempering temperature. By this configuration a seamless steel pipe having an yield stress of 483 MPa or more and excellent HIC resistance, which is suitable for a pipeline, can be provided.
    • 本发明涉及氢诱发抗裂性优异的高强度无缝钢管,其特征在于以质量%计含有C:0.03-0.11%,Si:0.05-0.5%,Mn:0.8-1.6%,P :0.025%以下,S:0.003%以下,Ti:0.002〜0.017%,Al:0.001-0.10%,Cr:0.05〜0.5%,Mo:0.02〜0.3%,V:0.02〜0.20%,Ca: 0.0005-0.005%,N:0.008%以下,O(氧):0.004%以下,余量为Fe和杂质,其特征在于,钢的组织为贝氏体和/或马氏体,铁素体析出 晶界和屈服应力为483MPa以上。 此外,为了确保钢的高强度,无缝钢管优选以质量%计含有Cu:0.05〜0.5%和Ni:0.05〜0.5%中的至少一种。 为了制造上述钢管,优选限制轧制后的淬火起始温度,冷却速度和回火温度。 通过这种结构,可以提供一种适用于管道的屈服应力为483MPa以上,耐HIC电阻优异的无缝钢管。
    • 4. 发明授权
    • Seamless steel pipe and manufacturing method thereof
    • 无缝钢管及其制造方法
    • US07815755B2
    • 2010-10-19
    • US12010459
    • 2008-01-25
    • Yuji AraiKunio KondoNobuyuki Hisamune
    • Yuji AraiKunio KondoNobuyuki Hisamune
    • C22C38/44C22C38/50
    • C21D8/10C21D9/08C22C38/001C22C38/002C22C38/44C22C38/50C22C38/52
    • The present invention relates to the following seamless steel pipes excellent in strength, toughness and weldability, particularly suitable for submarine flow lines, and a manufacturing method thereof. An as-quenched seamless steel pipe having a chemical composition consisting of, by mass%, C: 0.03 to 0.08%, Mn: 0.3 to 2.5%, Al: 0.001 to 0.10%, Cr: 0.02 to 1.0%, Ni: 0.02 to 1.0%, Mo: 0.02 to 0.8%, Ti: 0.004 to 0.010%, N: 0.002 to 0.008%, Ca: 0.0005 to 0.005%, and the balance Fe and impurities, with not more than 0.25% of Si, not more than 0.05% of P, not more than 0.005% of S, less than 0.005% Nb, and less than 0.0003% of B as the impurities, and having a microstructure consisting of not more than 20 volume% of polygonal ferrite, not more than 10 volume% of a mixed microstructure of martensite and retained austenite, and balance bainite. B can be 0.0003 to 0.001%. Mg and/or REM can be contained. The manufacturing method is characterized by the cooling rate during quenching.
    • 本发明涉及以下具有优异的强度,韧性和焊接性的无缝钢管,特别适用于海底流水线及其制造方法。 一种淬火后的无缝钢管,其组成为以质量%计含有C:0.03〜0.08%,Mn:0.3〜2.5%,Al:0.001〜0.10%,Cr:0.02〜1.0%,Ni:0.02〜 1.0%,Mo:0.02〜0.8%,Ti:0.004〜0.010%,N:0.002〜0.008%,Ca:0.0005〜0.005%,余量为Fe和杂质,不大于0.25% 0.05%的P,不大于0.005%的S,小于0.005%的Nb和小于0.0003%的作为杂质的B,并且具有由不大于20体积%的多边形铁素体组成的微结构,不大于10 马氏体和残留奥氏体的混合显微组织的体积%,以及平衡贝氏体。 B可以为0.0003〜0.001%。 可以含有Mg和/或REM。 制造方法的特征在于淬火时的冷却速度。
    • 5. 发明授权
    • Seamless steel pipe for line pipe and a process for its manufacture
    • 管道无缝钢管及其制造工艺
    • US07896985B2
    • 2011-03-01
    • US12071493
    • 2008-02-21
    • Yuji AraiKunio KondoNobuyuki Hisamune
    • Yuji AraiKunio KondoNobuyuki Hisamune
    • C21D9/08C22C38/44
    • C22C38/005C21D8/105C21D9/08C22C38/001C22C38/04C22C38/06C22C38/12Y10S148/909
    • A seamless steel pipe for line pipe having a high strength and good toughness and corrosion resistance even though having a thick wall has a chemical composition comprising, in mass percent, C: 0.02-0.08%, Si: at most 0.5%, Mn: 1.5-3.0%, Al: 0.001-0.10%, Mo: greater than 0.4% to 1.2%, N: 0.002-0.015%, Ca: 0.0002-0.007%, and a remainder of Fe and impurities, wherein the contents of the impurities are at most 0.03% for P, at most 0.005% for S, at most 0.005% for O and less than 0.0005% for B and wherein the value of Pcm calculated by the following Equation (1) is at least 0.185 and at most 0.250. The steel pipe has a microstructure which primarily comprises bainite and which has a length of cementite of at most 20 micrometers: Pcm=[C]+[Si]/30+([Mn]+[Cr]+[Cu])/20+[Mo]/15+[V]/10+5[B]  (1) wherein [C], [Si], [Mn], [Cr], [Cu], [Mo], [V] and [B] are numbers respectively indicating the content in mass percent of C, Si, Mn, Cr, Cu, Mo, V and B.
    • 即使具有厚壁,也具有高强度,良好的韧性和耐腐蚀性的线管用无缝钢管,其化学成分的质量百分比含有C:0.02〜0.08%,Si:0.5%以下,Mn:1.5 -3.0%,Al:0.001-0.10%,Mo:大于0.4%-1.2%,N:0.002-0.015%,Ca:0.0002-0.007%,余量为Fe和杂质,杂质含量为 P最多为0.03%,S为0.005%以下,O为0.005%以下,B为0.0005%以下,其中,通过下述式(1)计算出的Pcm值为0.185以上且0.250以下。 钢管具有主要包括贝氏体并且具有至多20微米的渗碳体长度的微结构:Pcm = [C] + [Si] / 30 +([Mn] + [Cr] + [Cu])/ 20 + [Mo] / 15 + [V] / 10 + 5 [B](1)其中〔C〕,〔Si〕,〔Mn〕,〔Cr〕,〔Cu〕,〔Mo〕,〔V〕, B]是分别表示C,Si,Mn,Cr,Cu,Mo,V和B的质量含量的数字。
    • 6. 发明申请
    • Seamless steel pipe for line pipe and a process for its manufacture
    • 管道无缝钢管及其制造工艺
    • US20090114318A1
    • 2009-05-07
    • US12071493
    • 2008-02-21
    • Yuji AraiKunio KondoNobuyuki Hisamune
    • Yuji AraiKunio KondoNobuyuki Hisamune
    • C21D9/08C22C38/00C22C38/04
    • C22C38/005C21D8/105C21D9/08C22C38/001C22C38/04C22C38/06C22C38/12Y10S148/909
    • A seamless steel pipe for line pipe having a high strength and good toughness and corrosion resistance even though having a thick wall has a chemical composition comprising, in mass percent, C: 0.02-0.08%, Si: at most 0.5%, Mn: 1.5-3.0%, Al: 0.001-0.10%, Mo: greater than 0.4% to 1.2%, N: 0.002-0.015%, Ca: 0.0002-0.007%, and a remainder of Fe and impurities, wherein the contents of the impurities are at most 0.03% for P, at most 0.005% for S, at most 0.005% for O and less than 0.0005% for B and wherein the value of Pcm calculated by the following Equation (1) is at least 0.185 and at most 0.250. The steel pipe has a microstructure which primarily comprises bainite and which has a length of cementite of at most 20 micrometers: Pcm=[C]+[Si]/30+([Mn]+[Cr]+[Cu])/20+[Mo]/15+[V]/10+5[B]  (1) wherein [C], [Si], [Mn], [Cr], [Cu], [Mo], [V] and [B] are numbers respectively indicating the content in mass percent of C, Si, Mn, Cr, Cu, Mo, V and B.
    • 即使具有厚壁,也具有高强度,良好的韧性和耐腐蚀性的线管用无缝钢管,其化学成分的质量百分比含有C:0.02〜0.08%,Si:0.5%以下,Mn:1.5 -3.0%,Al:0.001-0.10%,Mo:大于0.4%-1.2%,N:0.002-0.015%,Ca:0.0002-0.007%,余量为Fe和杂质,杂质含量为 P最多为0.03%,S为0.005%以下,O为0.005%以下,B为0.0005%以下,其中,通过下述式(1)计算出的Pcm值为0.185以上且0.250以下。 钢管具有主要包括贝氏体并且具有至多20微米的渗碳体长度的微结构:<?在线公式描述=“在线公式”end =“lead”?> Pcm = [C] + [Si] / 30 +([Mn] + [Cr] + [Cu])/ 20+ [Mo] / 15 + [V] / 10 + 5 [B](1) 其中[C],[Si],[Mn],[Cr],[Cu],[Mo],[V]和[B]分别表示 C,Si,Mn,Cr,Cu,Mo,V和B的质量含量。