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1. 发明授权

US07816457B2 Method for producing crosslinked poly(meth)acrylate compound 有权
标题翻译：交联聚（甲基）丙烯酸酯化合物的制备方法
公开(公告)号：US07816457B2
公开(公告)日：2010-10-19
申请号：US11569819
申请日：2005-05-30
申请人： Nobutaka Fujimoto , Koji Ueda , Masato Fujikake
发明人： Nobutaka Fujimoto , Koji Ueda , Masato Fujikake
IPC分类号： C08F20/02 , C08F16/00 , C08F26/06 , C08F2/00
CPC分类号： H01M10/052 , C08F8/00 , C08F220/36 , C08F222/1006 , H01M4/137 , H01M4/1399 , H01M4/60 , H01M4/602 , C08F20/00
摘要： It is an object of the invention to provide a method of producing a crosslinked poly(meth)acrylic acid compound, in particular a method of producing a crosslinked poly(meth)acrylic acid nitroxide compound, which is a radical compound excellent in solvent stability.The invention is a method of producing a crosslinked poly(meth)acrylic acid compound resulting from crosslinking of a poly(meth)acrylic acid compound represented by the general formula (1): (in the formula, n Z1s represent a hydrogen atom(s) and/or an oxygen atom(s) having one unpaired electron, R represents a hydrogen atom or a methyl group and n represents an integer of 5 to 1000000), which method is characterized by comprising a polymerization step of polymerizing a (meth)acrylic acid compound represented by the general formula (2): (in the formula, Z2 represents a hydrogen atom when Z1 is a hydrogen atom, or a hydrogen atom or an oxygen atom having one unpaired electron when Z1 is an oxygen atom having one unpaired electron; and R represents the same group as R in the above general formula (1)) in the presence of a crosslinking agent.
摘要翻译：本发明的目的是提供一种生产交联聚（甲基）丙烯酸化合物的方法，特别是制备交联聚（甲基）丙烯酸氮氧化合物的方法，其是溶剂稳定性优异的自由基化合物。本发明是由通式（1）表示的聚（甲基）丙烯酸化合物交联而得到的交联聚（甲基）丙烯酸化合物的制造方法：（式中，n Z1表示氢原子）和/或具有一个不成对电子的氧原子，R表示氢原子或甲基，n表示5〜1000000的整数），该方法的特征在于包括聚合（甲基）由通式（2）表示的丙烯酸化合物：（式中Z 1表示氢原子，Z 1表示氢原子时的氢原子，Z 1表示不成对的氧原子时的氢原子或具有1个不成对电子的氧原子）电子; R表示与上述通式（1）中的R相同的基团）。

2. 发明申请

US20080319149A1 Method for Producing Crosslinked Poly (Meth) Acrylate Compound 有权
标题翻译：生产交联聚（甲基）丙烯酸酯化合物的方法
公开(公告)号：US20080319149A1
公开(公告)日：2008-12-25
申请号：US11569819
申请日：2005-05-30
申请人： Nobutaka Fujimoto , Koji Ueda , Masato Fujikake
发明人： Nobutaka Fujimoto , Koji Ueda , Masato Fujikake
IPC分类号： C08F226/06 , C08F2/00
CPC分类号： H01M10/052 , C08F8/00 , C08F220/36 , C08F222/1006 , H01M4/137 , H01M4/1399 , H01M4/60 , H01M4/602 , C08F20/00
摘要： It is an object of the invention to provide a method of producing a crosslinked poly(meth)acrylic acid compound, in particular a method of producing a crosslinked poly(meth)acrylic acid nitroxide compound, which is a radical compound excellent in solvent stability.The invention is a method of producing a crosslinked poly(meth)acrylic acid compound resulting from crosslinking of a poly(meth)acrylic acid compound represented by the general formula (1): (in the formula, n Z1s represent a hydrogen atom(s) and/or an oxygen atom(s) having one unpaired electron, R represents a hydrogen atom or a methyl group and n represents an integer of 5 to 1000000), which method is characterized by comprising a polymerization step of polymerizing a (meth)acrylic acid compound represented by the general formula (2): (in the formula, Z2 represents a hydrogen atom when Z1 is a hydrogen atom, or a hydrogen atom or an oxygen atom having one unpaired electron when Z1 is an oxygen atom having one unpaired electron; and R represents the same group as R in the above general formula (1)) in the presence of a crosslinking agent.
摘要翻译：本发明的目的是提供一种生产交联聚（甲基）丙烯酸化合物的方法，特别是制备交联聚（甲基）丙烯酸氮氧化合物的方法，其是溶剂稳定性优异的自由基化合物。本发明是由通式（1）表示的聚（甲基）丙烯酸化合物交联而得到的交联聚（甲基）丙烯酸化合物的制造方法：（式中，n Z1表示氢原子）和/或具有一个不成对电子的氧原子，R表示氢原子或甲基，n表示5〜1000000的整数），该方法的特征在于包括聚合（甲基）由通式（2）表示的丙烯酸化合物：（式中Z 1表示氢原子，Z 1表示氢原子时的氢原子，Z 1表示不成对的氧原子时的氢原子或具有1个不成对电子的氧原子）电子; R表示与上述通式（1）中的R相同的基团）。

3. 发明授权

US08252869B2 Process for production of crosslinked poly(meth) acrylic acid nitroxide compounds 有权
标题翻译：交联聚（甲基）丙烯酸硝基氧化合物的制备方法
公开(公告)号：US08252869B2
公开(公告)日：2012-08-28
申请号：US11989722
申请日：2006-06-29
申请人： Nobutaka Fujimoto , Koji Ueda , Masato Fujikake
发明人： Nobutaka Fujimoto , Koji Ueda , Masato Fujikake
IPC分类号： C08F8/06 , C08F26/06
CPC分类号： H01M4/60 , C08F8/06 , C08F220/34 , C08F220/36 , C08F2800/10 , H01M4/608 , C08F2222/1013
摘要： The present invention relates to a crosslinked poly(meth)acrylic acid nitroxide compound resulting from crosslinking of a poly(meth)acrylic acid nitroxide compound, and an object of the present invention is to provide a method of inexpensively and easily producing a crosslinked poly(meth)acrylic acid nitroxide compound having a high radical concentration.The present invention is a method of producing a crosslinked poly(meth)acrylic acid nitroxide compound including a repeating unit represented by the general formula (2): (in the formula, R represents a hydrogen atom or a methyl group), comprising a nitroxidation step carried out in a state that a crosslinked poly(meth)acrylic acid imino compound resulting from crosslinking of a poly(meth)acrylic acid imino compound including a repeating unit represented by the general formula (1): (in the formula, R represents the same group as that represented by R in said general formula (2)) is dispersed in water.
摘要翻译：本发明涉及由聚（甲基）丙烯酸氮氧化合物交联而得到的交联的聚（甲基）丙烯酸氮氧化合物，本发明的目的是提供一种廉价且容易地制备交联聚（甲基）丙烯酸硝基氧化合物。本发明是一种包含由通式（2）表示的重复单元的交联聚（甲基）丙烯酸氮氧化合物的方法：（式中，R表示氢原子或甲基），其包含硝基氧化在由通式（1）表示的重复单元的聚（甲基）丙烯酸亚氨基化合物交联而得到的交联聚（甲基）丙烯酸亚氨基化合物：（式中，R表示与通式（2）中的R表示的基团相同）分散在水中。

4. 发明授权

US08088874B2 Crosslinked (meth)acrylic acid copolymer and secondary-cell electrode employing the same 有权
标题翻译：交联的（甲基）丙烯酸共聚物和使用其的二次电池电极
公开(公告)号：US08088874B2
公开(公告)日：2012-01-03
申请号：US12309437
申请日：2007-06-04
申请人： Nobutaka Fujimoto , Koji Ueda
发明人： Nobutaka Fujimoto , Koji Ueda
IPC分类号： C08F26/06
CPC分类号： C08F220/34 , C08F8/06 , C08F220/18 , C08F222/1006 , C08F2220/1891 , C08F2810/20 , C08L2312/00 , H01M4/60 , H01M4/621 , H01M10/0525 , C08F2222/1013 , C09D133/14 , C08L27/16 , C08K3/04
摘要： It is an object of the present invention to provide a crosslinked (meth)acrylic acid-type copolymer excellent in stability to a solvent, which causes substantially no crack due to drying when applied onto the surface of a current collector, and a secondary-cell electrode using the copolymer.The present invention relates to a crosslinked (meth)acrylic acid-type copolymer obtained by the steps of: polymerization of a (meth)acrylic acid imino compound represented by the general formula (1): (in the formula (1), R represents a hydrogen atom or a methyl group) and a (meth)acrylic acid ester in the presence of a crosslinking agent, and nitroxidation.
摘要翻译：本发明的目的是提供一种对溶剂的稳定性优异的交联（甲基）丙烯酸型共聚物，其在施加到集电体表面上时基本上不会由于干燥而产生裂纹，二次电池使用共聚物的电极。本发明涉及通过以下步骤获得的交联的（甲基）丙烯酸类共聚物：聚合由通式（1）表示的（甲基）丙烯酸亚氨基化合物：（式（1）中R表示氢原子或甲基）和（甲基）丙烯酸酯在交联剂的存在下进行硝基氧化。

5. 发明申请

US20090306304A1 CROSSLINKED (METH)ACRYLIC ACID COPOLYMER AND SECONDARY-CELL ELECTRODE EMPLOYING THE SAME 有权
标题翻译：交联（甲基）丙烯酸共聚物和使用其的二次电池电极
公开(公告)号：US20090306304A1
公开(公告)日：2009-12-10
申请号：US12309437
申请日：2007-06-04
申请人： Nobutaka Fujimoto , Koji Ueda
发明人： Nobutaka Fujimoto , Koji Ueda
IPC分类号： C08F26/06
CPC分类号： C08F220/34 , C08F8/06 , C08F220/18 , C08F222/1006 , C08F2220/1891 , C08F2810/20 , C08L2312/00 , H01M4/60 , H01M4/621 , H01M10/0525 , C08F2222/1013 , C09D133/14 , C08L27/16 , C08K3/04
摘要： It is an object of the present invention to provide a crosslinked (meth)acrylic acid-type copolymer excellent in stability to a solvent, which causes substantially no crack due to drying when applied onto the surface of a current collector, and a secondary-cell electrode using the copolymer.The present invention relates to a crosslinked (meth)acrylic acid-type copolymer obtained by the steps of: polymerization of a (meth)acrylic acid imino compound represented by the general formula (1): (in the formula (1), R represents a hydrogen atom or a methyl group) and a (meth)acrylic acid ester in the presence of a crosslinking agent, and nitroxidation.
摘要翻译：本发明的目的是提供一种对溶剂的稳定性优异的交联（甲基）丙烯酸型共聚物，其在施加到集电体表面上时基本上不会由于干燥而产生裂纹，二次电池使用共聚物的电极。本发明涉及通过以下步骤获得的交联的（甲基）丙烯酸类共聚物：聚合由通式（1）表示的（甲基）丙烯酸亚氨基化合物：（式（1）中R表示氢原子或甲基）和（甲基）丙烯酸酯在交联剂的存在下进行硝基氧化。

6. 发明申请

US20140008588A1 METAL PASTE COMPOSITION 有权
标题翻译：金属组合物
公开(公告)号：US20140008588A1
公开(公告)日：2014-01-09
申请号：US14005618
申请日：2012-03-06
申请人： Nobutaka Fujimoto , Tomoki Kawakita , Ryou Miyabara , Masami Nakamoto , Toshinobu Ohno , Mari Yamamoto , Yukiyasu Kashiwagi
发明人： Nobutaka Fujimoto , Tomoki Kawakita , Ryou Miyabara , Masami Nakamoto , Toshinobu Ohno , Mari Yamamoto , Yukiyasu Kashiwagi
IPC分类号： H05K1/09
CPC分类号： H05K1/092 , C08K3/08 , C08K5/109 , C08K5/3415 , H01B1/22 , H05K1/095
摘要： The present invention provides a metal paste composition which can obtain the calcined bodies having low volume resistivity in a wiring substrate after calcining. More specifically, the present invention provides a metal paste composition comprising a metal, an aliphatic polycarbonate, and an organic solvent.
摘要翻译：本发明提供一种金属糊剂组合物，其可以在煅烧后得到在布线基板中具有低体积电阻率的煅烧体。更具体地，本发明提供了包含金属，脂族聚碳酸酯和有机溶剂的金属膏组合物。

7. 发明授权

US06235828B1 Aqueous polymerization of acrylamide in the presence of polyvinylpyrrolidone 失效
标题翻译：丙烯酰胺在聚乙烯吡咯烷酮存在下的水聚合
公开(公告)号：US06235828B1
公开(公告)日：2001-05-22
申请号：US09341475
申请日：1999-08-31
申请人： Masato Fujikake , Shigeki Hamamoto , Nobutaka Fujimoto , Kimihiko Kondo , Morio Nakamura , Takao Okada
发明人： Masato Fujikake , Shigeki Hamamoto , Nobutaka Fujimoto , Kimihiko Kondo , Morio Nakamura , Takao Okada
IPC分类号： C08F12056
CPC分类号： C08F271/02 , C08F220/56 , C08F263/04 , C08F291/00 , C08F2/16
摘要： A method for producing a highly concentrated aqueous acrylic amide-based polymer dispersion which is inexpensive, good in fluidity and easy to handle is provided. The method comprises polymerizing a water-soluble monomer composition containing an acrylic amide monomer in an aqueous solution of an inorganic salt in the presence of a homopolymer of vinylpyrrolidone and/or a copolymer of vinylpyrrolidone and other monomer(s).
摘要翻译：提供廉价的流动性和易于处理的高浓度水性丙烯酸酰胺类聚合物分散体的制造方法。该方法包括在乙烯基吡咯烷酮的均聚物和/或乙烯基吡咯烷酮和其它单体的共聚物存在下，将无机盐的水溶液中含有丙烯酰胺单体的水溶性单体组合物聚合。

8. 发明授权

US09356292B2 Radical composition and battery using same 有权
标题翻译：激进组成和电池使用相同
公开(公告)号：US09356292B2
公开(公告)日：2016-05-31
申请号：US14005988
申请日：2012-03-23
申请人： Hiroyuki Nishide , Kenichi Oyaizu , Sosuke Yamaguchi , Nobutaka Fujimoto , Yuji Kinpara , Shun Hashimoto , Shigeyuki Iwasa , Kentaro Nakahara
发明人： Hiroyuki Nishide , Kenichi Oyaizu , Sosuke Yamaguchi , Nobutaka Fujimoto , Yuji Kinpara , Shun Hashimoto , Shigeyuki Iwasa , Kentaro Nakahara
IPC分类号： H01M4/60 , C08L71/02 , H01M10/052
CPC分类号： H01M4/602 , C08L71/02 , H01M10/052 , C08L39/04
摘要： The present invention provides a radical composition capable of suppressing elution of electrode components in an electrolyte solution when used in an electrode for a secondary battery, and a battery using the radical composition. The present invention relates to a radical composition including a pyrroline nitroxide polymer and polyethylene glycols.
摘要翻译：本发明提供了当用于二次电池的电极时，能够抑制电解质溶液中的电极组分的溶出的自由基组合物和使用该自由基组合物的电池。本发明涉及包含吡咯啉氮氧化物聚合物和聚乙二醇的自由基组合物。

9. 发明授权

US08816040B2 Polymer dye 有权
标题翻译：聚合物染料
公开(公告)号：US08816040B2
公开(公告)日：2014-08-26
申请号：US13461933
申请日：2012-05-02
申请人： Takaki Kanbara , Junpei Kuwabara , Hikaru Yamada , Nobutaka Fujimoto
发明人： Takaki Kanbara , Junpei Kuwabara , Hikaru Yamada , Nobutaka Fujimoto
IPC分类号： C08G73/06
CPC分类号： C08G73/02 , C09B69/101 , C09B69/104 , C09B69/109
摘要： A polymer dye has repeating units of formula (I): Each of R1, R2, and R3 is independently a monocyclic carbocyclic group, a condensed polycyclic carbocyclic group, a monocyclic heterocyclic group, or a condensed polycyclic heterocyclic group. In any case, each of R1, R2, and R3 independently may have a substituent. R1 is a divalent group, and R2 and R3 are monovalent groups. D is an organic dye group and n is an integer of from 0 to 10. The polymer dye has a number-average molecular weight of from 500 to 500,000. The dye can be a component in a film. The dye can also be included in various industrial materials in automobiles; communication instruments, such as mobile phones, PDA, remote controllers, mobile information terminals, electronic dictionaries, and electronic organizers; home electric appliances; construction parts; and the like.
摘要翻译：聚合物染料具有式（I）的重复单元：R 1，R 2和R 3各自独立地为单环碳环基，稠合多环碳环基，单环杂环基或缩合多环杂环基。在任何情况下，R 1，R 2和R 3各自独立地可以具有取代基。 R1是二价基团，R2和R3是一价基团。 D为有机染料基团，n为0〜10的整数。聚合物染料的数均分子量为500〜500,000。染料可以是膜中的一种成分。染料也可以包含在汽车的各种工业材料中; 通讯仪器，如手机，PDA，遥控器，移动信息终端，电子词典和电子组织者; 家用电器; 施工部件; 等等。

10. 发明申请

US20120329978A1 POLYMER DYE 有权
公开(公告)号：US20120329978A1
公开(公告)日：2012-12-27
申请号：US13461933
申请日：2012-05-02
申请人： Takaki Kanbara , Junpei Kuwabara , Hikaru Yamada , Nobutaka Fujimoto
发明人： Takaki Kanbara , Junpei Kuwabara , Hikaru Yamada , Nobutaka Fujimoto
IPC分类号： C08G73/06
CPC分类号： C08G73/02 , C09B69/101 , C09B69/104 , C09B69/109
摘要： A polymer dye has repeating units of formula (I): Each of R1, R2, and R3 is independently a monocyclic carbocyclic group, a condensed polycyclic carbocyclic group, a monocyclic heterocyclic group, or a condensed polycyclic heterocyclic group. In any case, each of R1, R2, and R3 independently may have a substituent. R1 is a divalent group, and R2 and R3 are monovalent groups. D is an organic dye group and n is an integer of from 0 to 10. The polymer dye has a number-average molecular weight of from 500 to 500,000. The dye can be a component in a film. The dye can also be included in various industrial materials in automobiles; communication instruments, such as mobile phones, PDA, remote controllers, mobile information terminals, electronic dictionaries, and electronic organizers; home electric appliances; construction parts; and the like.
摘要翻译：聚合物染料具有式（I）的重复单元：R 1，R 2和R 3各自独立地为单环碳环基，稠合多环碳环基，单环杂环基或稠合多环杂环基。在任何情况下，R 1，R 2和R 3各自独立地可以具有取代基。 R1是二价基团，R2和R3是一价基团。 D为有机染料基团，n为0〜10的整数。聚合物染料的数均分子量为500〜500,000。染料可以是膜中的一种成分。染料也可以包含在汽车的各种工业材料中; 通讯仪器，如手机，PDA，遥控器，移动信息终端，电子词典和电子组织者; 家用电器; 施工部件; 等等。

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