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1. 发明申请

US20050147892A1 Non-aqueous electrolyte secondary cell 有权
标题翻译：非水电解质二次电池
公开(公告)号：US20050147892A1
公开(公告)日：2005-07-07
申请号：US11010384
申请日：2004-12-14
申请人： Nobumichi Nishida , Shinya Miyazaki
发明人： Nobumichi Nishida , Shinya Miyazaki
IPC分类号： H01M4/525 , H01M6/16 , H01M10/05 , H01M10/0525 , H01M10/0569 , H01M10/058 , H01M10/44 , H01M10/40 , H01M4/52
CPC分类号： H01M4/525 , H01M4/0435 , H01M4/485 , H01M10/0525 , H01M10/0569 , H01M10/0587 , H01M10/44 , H01M2300/004
摘要： The present invention improves the cycle characteristics of a non-aqueous electrolyte secondary cell that uses lithium cobalt oxide as a positive electrode active material. To this end, an element different from cobalt such as zirconium and titanium is added to the lithium cobalt oxide, acting as the positive electrode active material. The non-aqueous electrolyte contains a non-aqueous solvent containing diethyl carbonate at 10 to 30 volume percent on a base of 25 degree Celcius and contains an electrolyte salt.
摘要翻译：本发明改善了使用钴酸锂作为正极活性物质的非水电解质二次电池的循环特性。为此，向作为正极活性物质的钴酸锂中添加不同于钴，如锆和钛的元素。非水电解质含有在25℃的碱下10体积％至30体积％的碳酸二乙酯的非水溶剂，并含有电解质盐。

2. 发明授权

US07939207B2 Non-aqueous electrolyte lithium ion secondary cell with improved cycle characteristics and method for fabricating the same 有权
标题翻译：具有改善循环特性的非水电解质锂离子二次电池及其制造方法
公开(公告)号：US07939207B2
公开(公告)日：2011-05-10
申请号：US11010384
申请日：2004-12-14
申请人： Nobumichi Nishida , Shinya Miyazaki
发明人： Nobumichi Nishida , Shinya Miyazaki
IPC分类号： H01M6/16
CPC分类号： H01M4/525 , H01M4/0435 , H01M4/485 , H01M10/0525 , H01M10/0569 , H01M10/0587 , H01M10/44 , H01M2300/004
摘要： The present invention improves the cycle characteristics of a non-aqueous electrolyte secondary cell that uses lithium cobalt oxide as a positive electrode active material. To this end, an element different from cobalt such as zirconium and titanium is added to the lithium cobalt oxide, acting as the positive electrode active material. The non-aqueous electrolyte contains a non-aqueous solvent containing diethyl carbonate at 10 to 30 volume percent on a base of 25 degree Celsius and contains an electrolyte salt.
摘要翻译：本发明改善了使用钴酸锂作为正极活性物质的非水电解质二次电池的循环特性。为此，向作为正极活性物质的钴酸锂中添加不同于钴，如锆和钛的元素。该非水电解质含有含有10至30体积％的碳酸二乙酯和25℃的非水溶剂，并含有电解质盐。

3. 发明申请

US20060204852A1 Nonaqueous electrolytic secondary battery and method of manufacturing the same 有权
公开(公告)号：US20060204852A1
公开(公告)日：2006-09-14
申请号：US11429259
申请日：2006-05-08
申请人： Nobumichi Nishida , Shinya Miyazaki , Masatoshi Takahashi
发明人： Nobumichi Nishida , Shinya Miyazaki , Masatoshi Takahashi
IPC分类号： H01M4/58 , H01M4/52 , H01M4/50 , C01B11/00
CPC分类号： H01M4/485 , C01G45/1242 , C01G51/42 , C01P2002/32 , C01P2002/52 , C01P2002/54 , C01P2002/60 , C01P2006/12 , C01P2006/40 , C01P2006/80 , H01M4/1315 , H01M4/133 , H01M4/13915 , H01M4/525 , H01M4/582 , H01M4/661 , H01M10/0525 , H01M2004/021 , Y10T29/49108
摘要： In a nonaqueous electrolytic secondary battery according to the invention, hexagonal system lithium containing cobalt composite oxide having a crystallite size in a (110) vector direction of 1000 Å or more and having a halogen compound added thereto by burning at time of synthesis is used as a positive electrode active material. By measuring a pH value of a filtrate obtained by dispersing, in water, the lithium containing cobalt composite oxide having the halogen compound added thereto by the burning at time of the synthesis and a crystallite size in the (110) vector direction of 1000 Å or more, a value of 9.6 to 10.1 is obtained. By using the lithium containing cobalt composite oxide as a positive electrode active material, a high temperature cycle property can be enhanced.

4. 发明授权

US06919144B2 Nonaqueous electrolyte secondary cell and method of manufacturing the same 有权
标题翻译：非水电解质二次电池及其制造方法
公开(公告)号：US06919144B2
公开(公告)日：2005-07-19
申请号：US10305059
申请日：2002-11-27
申请人： Shinya Miyazaki , Nobumichi Nishida
发明人： Shinya Miyazaki , Nobumichi Nishida
IPC分类号： H01M4/36 , H01M4/02 , H01M4/131 , H01M4/38 , H01M4/52 , H01M4/525 , H01M10/052 , H01M10/36 , H01M4/58
CPC分类号： H01M4/525 , H01M4/131 , H01M4/38 , H01M4/388 , H01M10/052 , H01M2004/028 , Y10T29/49108
摘要： The present invention provides a nonaqueous electrolyte secondary cell having a positive electrode comprising mainly of a positive electrode active material, a negative electrode, and a nonaqueous electrolyte. The positive electrode active material is a lithium-containing transition metal composite oxide of a hexagonal crystal system that includes a compound represented by the general formula LiCo1-xMxO2, where M is at least one species selected from the group consisting of V, Cr, Fe, Mn, Ni, Al, and Ti, and x is a decimal number in a range 0
摘要翻译：本发明提供一种具有主要由正极活性物质，负极和非水电解质组成的正极的非水电解质二次电池。正极活性物质是六方晶系的含锂过渡金属复合氧化物，其包含由通式LiCo 1-x M x O O表示的化合物，其中M是选自V，Cr，Fe，Mn，Ni，Al和Ti中的至少一种，x是0

5. 发明申请

US20050069774A1 Non-aqueous electrolyte secondary battery and method of manufacturing the same 有权
标题翻译：非水电解质二次电池及其制造方法
公开(公告)号：US20050069774A1
公开(公告)日：2005-03-31
申请号：US10951732
申请日：2004-09-29
申请人： Shinya Miyazaki , Nobumichi Nishida
发明人： Shinya Miyazaki , Nobumichi Nishida
IPC分类号： C01D1/02 , C01G51/00 , C01G51/04 , H01M4/525 , H01M4/583 , H01M6/16 , H01M10/05 , H01M10/0525 , H01M10/42 , H01M4/52
CPC分类号： H01M4/525 , C01G51/006 , C01G51/42 , C01P2002/52 , C01P2004/61 , C01P2006/40 , H01M4/0471 , H01M4/131 , H01M4/133 , H01M4/485 , H01M10/0525 , H01M10/0587 , H01M2010/4292 , H01M2300/0037
摘要： A positive electrode used in the non-aqueous electrolyte secondary battery of the present invention includes a hexagonal system lithium-containing cobalt composite oxide represented by the general expression ┌LiCo1-XMXO2 (M=Zr, Mg, Al)┘ obtained by synthesizing a lithium compound as a lithium source with a cobalt compound as a cobalt source to which 0.01 mol % or more and 1.0 mol % or less of zirconium is added and magnesium and/or aluminum is added through coprecipitation, as the positive electrode active material, whereby the thermal stability, load performance and charging/discharging cycle performance characteristics of the non-aqueous electrolyte secondary battery are improved without lowering its capacity and charging/discharging efficiency.
摘要翻译：在本发明的非水电解质二次电池中使用的正极包括通过合成锂获得的由通式┌LiCo1-XMXO2（M = Zr，Mg，Al）表示的六方晶系的含锂钴复合氧化物作为锂源的化合物作为正极活性物质，其中钴化合物作为钴源，其中添加了0.01mol％以上且1.0mol％以下的锆，并且通过共沉淀加入了镁和/或铝，由此，非水电解质二次电池的热稳定性，负载性能和充放电循环性能特性得到改善，而不降低其容量和充放电效率。

6. 发明申请

US20060194110A1 Non-aqueous electrolyte secondary battery and charging method thereof 审中-公开
标题翻译：非水电解质二次电池及其充电方法
公开(公告)号：US20060194110A1
公开(公告)日：2006-08-31
申请号：US11355183
申请日：2006-02-16
申请人： Shinya Miyazaki , Nobumichi Nishida
发明人： Shinya Miyazaki , Nobumichi Nishida
IPC分类号： H01M4/52 , H01M10/44
CPC分类号： H01M10/44 , H01M4/131 , H01M4/1391 , H01M4/583 , H01M10/0569 , H01M10/4235 , H01M2004/028
摘要： A non-aqueous electrolyte secondary battery with excellent cycle characteristics and thermal stability in which the potential of the positive electrode active material ranges from 4.4V to 4.6 V based on lithium, and-charging method therefor are provided, wherein the positive electrode active substance of a non-aqueous electrolyte secondary battery comprises a hexagonal system of lithium-containing transition metal composite oxide formed by adding zirconium, magnesium, and aluminum as foreign elements upon synthesis of lithium cobalt oxide, with zirconium content ranging from 0.01 to 1 mol %, magnesium content ranging from 0.01 to 3 mol %, and aluminum content ranging from 0.01 to 3 mol %, and an Li/Co molar ratio ranging from 1.00 to 1.05.
摘要翻译：提供了一种具有优异的循环特性和热稳定性的非水电解质二次电池，其中正极活性物质的电位为基于锂的4.4V至4.6V，其充电方法为：其中正极活性物质为非水电解质二次电池包括通过在合成锂钴氧化物时添加锆，镁和铝作为外来元素而形成的含锂过渡金属复合氧化物的六方晶系，锆含量为0.01〜1摩尔％，镁含量为含量为0.01〜3摩尔％，铝含量为0.01〜3摩尔％，Li / Co摩尔比为1.00〜1.05。

7. 发明授权

US07799458B2 Nonaqueous electrolytic secondary battery and method of manufacturing the same 有权
标题翻译：非水电解二次电池及其制造方法
公开(公告)号：US07799458B2
公开(公告)日：2010-09-21
申请号：US11429259
申请日：2006-05-08
申请人： Nobumichi Nishida , Shinya Miyazaki , Masatoshi Takahashi
发明人： Nobumichi Nishida , Shinya Miyazaki , Masatoshi Takahashi
IPC分类号： H01M4/52
CPC分类号： H01M4/485 , C01G45/1242 , C01G51/42 , C01P2002/32 , C01P2002/52 , C01P2002/54 , C01P2002/60 , C01P2006/12 , C01P2006/40 , C01P2006/80 , H01M4/1315 , H01M4/133 , H01M4/13915 , H01M4/525 , H01M4/582 , H01M4/661 , H01M10/0525 , H01M2004/021 , Y10T29/49108
摘要： In a nonaqueous electrolytic secondary battery according to the invention, hexagonal system lithium containing cobalt composite oxide having a crystallite size in a (110) vector direction of 1000 Å or more and having a halogen compound added thereto by burning at time of synthesis is used as a positive electrode active material. By measuring a pH value of a filtrate obtained by dispersing, in water, the lithium containing cobalt composite oxide having the halogen compound added thereto by the burning at time of the synthesis and a crystallite size in the (110) vector direction of 1000 Å or more, a value of 9.6 to 10.1 is obtained. By using the lithium containing cobalt composite oxide as a positive electrode active material, a high temperature cycle property can be enhanced.
摘要翻译：在根据本发明的非水电解质二次电池中，使用在（110）向量方向上的微晶尺寸为1000以上并且在合成时通过燃烧而添加有卤素化合物的六方晶系含锂复合氧化物，被用作正极活性物质。通过测量通过在合成时通过在合成时的燃烧和在（110）向量方向上的微晶尺寸将在其中分散有添加有卤素化合物的含锂钴复合氧化物而获得的滤液的pH值，更多地，获得9.6至10.1的值。通过使用含锂钴复合氧化物作为正极活性物质，可以提高高温循环特性。

8. 发明授权

US07381395B2 Non-aqueous electrolyte secondary battery and method of manufacturing the same 有权
标题翻译：非水电解质二次电池及其制造方法
公开(公告)号：US07381395B2
公开(公告)日：2008-06-03
申请号：US10951732
申请日：2004-09-29
申请人： Shinya Miyazaki , Nobumichi Nishida
发明人： Shinya Miyazaki , Nobumichi Nishida
IPC分类号： C01G51/04 , H01M4/52
CPC分类号： H01M4/525 , C01G51/006 , C01G51/42 , C01P2002/52 , C01P2004/61 , C01P2006/40 , H01M4/0471 , H01M4/131 , H01M4/133 , H01M4/485 , H01M10/0525 , H01M10/0587 , H01M2010/4292 , H01M2300/0037
摘要： A positive electrode used in the non-aqueous electrolyte secondary battery of the present invention includes a hexagonal system lithium-containing cobalt composite oxide represented by the general expression ┌LiCo1-XMXO2 (M=Zr, Mg, Al)┘ obtained by synthesizing a lithium compound as a lithium source with a cobalt compound as a cobalt source to which 0.01 mol % or more and 1.0 mol % or less of zirconium is added and magnesium and/or aluminum is added through coprecipitation, as the positive electrode active material, whereby the thermal stability, load performance and charging/discharging cycle performance characteristics of the non-aqueous electrolyte secondary battery are improved without lowering its capacity and charging/discharging efficiency.
摘要翻译：在本发明的非水电解质二次电池中使用的正极包括由以下通式表示的六方晶系的含锂钴复合氧化物：＆lt; 1＆lt; 1-X＆lt; 通过将作为锂源的锂化合物与钴化合物作为钴源合成而得到的“O 2”（M = Zr，Mg，Al），0.01mol％以上且1.0mol％或更少的锆，并且通过共沉淀加入镁和/或铝作为正极活性物质，从而提高非水电解质二次电池的热稳定性，负载性能和充放电循环性能，而不降低其容量和充放电效率。

9. 发明授权

US07438991B2 Nonaqueous electrolyte secondary cell and method for charging same 有权
标题翻译：非水电解质二次电池及其充电方法
公开(公告)号：US07438991B2
公开(公告)日：2008-10-21
申请号：US11288355
申请日：2005-11-29
申请人： Nobumichi Nishida , Hidetoshi Inoue
发明人： Nobumichi Nishida , Hidetoshi Inoue
IPC分类号： H01M4/48
CPC分类号： H01M10/0569 , H01M4/366 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M2010/4292
摘要： The invention provides a non-aqueous electrolyte secondary cell that has high capacity and excels in cycle characteristics. The non-aqueous electrolyte secondary cell functions stably at a high potential of from 4.4 to 4.6 V with respect to lithium and inhibits the decomposition of the electrolytic solution at high potential. This is accomplished as follows. The non-aqueous electrolyte secondary cell has a positive electrode having a positive electrode active material; a negative electrode having a negative electrode active material; and a non-aqueous electrolyte having a non-aqueous solvent and electrolytic salt. The positive electrode active material has: lithium cobalt compound oxide having added therein at least zirconium and magnesium; and lithium-nickel-manganese compound oxide having a layered structure. The positive electrode active material has a potential of from 4.4 to 4.6 V with respect to lithium. The non-aqueous solvent contains diethyl carbonate of 10 vol. % or higher at 25° C.
摘要翻译：本发明提供一种具有高容量且循环特性优异的非水电解质二次电池。该非水电解质二次电池在相对于锂的4.4〜4.6V的高电位下稳定地发挥作用，并且抑制电解液在高电位下的分解。这是完成如下。非水电解质二次电池具有正极，具有正极活性物质; 负极，具有负极活性物质; 和具有非水溶剂和电解质盐的非水电解质。正极活性物质具有至少添加有锆和镁的锂钴复合氧化物; 和具有层状结构的锂镍锰复合氧化物。正极活性物质相对于锂具有4.4〜4.6V的电位。非水溶剂含有10体积％的碳酸二乙酯。 25℃以下％以上

10. 发明授权

US08012625B2 Non-aqueous electrolyte secondary cell 有权
标题翻译：非水电解质二次电池
公开(公告)号：US08012625B2
公开(公告)日：2011-09-06
申请号：US11941252
申请日：2007-11-16
申请人： Satoshi Yamamoto , Nobumichi Nishida
发明人： Satoshi Yamamoto , Nobumichi Nishida
IPC分类号： H01M4/48
CPC分类号： H01M4/5825 , H01M4/131 , H01M4/364 , H01M4/525 , H01M4/628 , H01M10/4235 , H01M2004/027
摘要： The present invention aims to provide a non-aqueous electrolyte secondary cell having high capacity and capable of preventing elution of cobalt and decomposition of the electrolyte. This aim can be accomplished by providing a non-aqueous electrolyte secondary cell comprising a positive electrode having a positive electrode active material, an negative electrode having an negative electrode active material, and non-aqueous electrolyte, wherein the positive electrode active material comprises lithium cobalt oxide to which at least one material selected from the group consisting of Mg, Al, Ti, and Zr was added, and the positive electrode comprises lithium phosphate.
摘要翻译：本发明旨在提供一种具有高容量且能够防止钴的析出和电解质分解的非水电解质二次电池。该目的可以通过提供一种非水电解质二次电池，其包括具有正极活性物质的正极，具有负极活性物质的负极和非水电解质，其中，所述正极活性物质包含锂钴氧化物，其中添加了选自Mg，Al，Ti和Zr中的至少一种材料，并且正极包含磷酸锂。

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