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    • 2. 发明授权
    • Dry type developer for electrophotography
    • 用于电子照相的干式显影剂
    • US4980258A
    • 1990-12-25
    • US436551
    • 1989-11-14
    • Mitsuo AokiNobuhiro NakayamaYasuo AsahinaHiroyuki FushimiKayo MakitaYasuaki Iwamoto
    • Mitsuo AokiNobuhiro NakayamaYasuo AsahinaHiroyuki FushimiKayo MakitaYasuaki Iwamoto
    • G03G9/09G03G9/097
    • G03G9/0975G03G9/0918G03G9/09741
    • The present invention relates to the positively chargeable black toner particles which comprise binder resins, carbonblack as a main colorant, quaternary anmonium salt of the following formula (I) as a charge control agent and .beta.-form Cu-phthalocyanine as a stabilizing agent for chargeability of toner particles without being affected by the change of environmental conditions. ##STR1## Wherein R.sub.1 is C.sub.1 -C.sub.8 alkyl or benzyl, R.sub.2 and R.sub.3 are each C.sub.1 -C.sub.18 alkyl, R is C.sub.1 -C.sub.118 alkyl or benzyl, X is hydroxy or amino, and Y is hydoroxy or hydrogen; (c) .beta.-form Cu-phthalocyanine; and (d) carbonblack.The present invention further relates to the two component dry-type developer composed by the improved above said positively chargeable toner particles and the carrier particles coated with silicone polylmers which have the strong durability without being changed to a supent carrier particles for a use of long time period.
    • 本发明涉及包含粘合剂树脂,炭黑作为主要着色剂的正电荷黑色调色剂颗粒,作为电荷控制剂的下式(I)的季铵盐和作为带电性的稳定剂的β-型Cu-酞菁 的调色剂颗粒,而不受环境条件的变化的影响。 (I)其中R1是C1-C8烷基或苄基,R2和R3各自是C1-C18烷基,R是C1-C118烷基或苄基,X是羟基或氨基,Y是羟基或氢; (c)β-型Cu-酞菁; 和(d)炭黑。 本发明还涉及由改进的上述可充正电的调色剂颗粒和涂覆有硅氧烷聚合物的载体颗粒组成的双组分干式显影剂,其具有强的耐久性而不会改变为长时间使用的载体颗粒 期。
    • 4. 发明授权
    • Dry type toner for electrophotography
    • 用于电子照相的干式调色剂
    • US5061588A
    • 1991-10-29
    • US338599
    • 1989-04-14
    • Hiroyuki FushimiNobuhiro NakayamaYasuo AsahinaMitsuo AokiKayo Makita
    • Hiroyuki FushimiNobuhiro NakayamaYasuo AsahinaMitsuo AokiKayo Makita
    • G03G9/087
    • G03G9/08753Y10S430/105
    • A dry type toner for electrophotography is disclosed which comprises as the main components (a) a coloring agent; and (b) a polyol resin serving as a binder agent in an effective amount, the polyol resin being prepared by subjecting a bisphenol-type epoxy resin containing epoxy groups, which may contain secondary hydroxyl groups, to reaction steps (1), (2) and (3), or steps (2) and (3), in any sequential combination, until substantially no epoxy groups remain in the polyol resin, wherein the reaction step (1) comprises a step of causing the epoxy groups in the bisphenol-type epoxy resin to react with a primary amine; the reaction step (2) comprising a step of causing the epoxy groups to react with a compound containing one active hydrogen capable of reacting with the epoxy groups; and the reaction step (3) comprising a step of esterifying at least part of the secondary hydroxyl groups or hydroxyl groups produced in the bisphenol-type epoxy resin by reaction step (1) and/or reaction step (2) by use of an esterifying agent.
    • 公开了用于电子照相的干式调色剂,其包含作为主要组分(a)着色剂; 和(b)作为有效量的粘合剂的多元醇树脂,所述多元醇树脂通过将含有可以含有仲羟基的环氧基的双酚型环氧树脂进行反应步骤(1),(2) )和(3)或步骤(2)和(3),以任何顺序的组合,直到基本上没有环氧基保留在多元醇树脂中,其中反应步骤(1)包括使双酚 型环氧树脂与伯胺反应; 反应步骤(2)包括使环氧基与含有能够与环氧基反应的一个活性氢的化合物反应的步骤; 反应步骤(3)包括通过反应步骤(1)和/或反应步骤(2)通过使用酯化反应步骤(1)和/或反应步骤(2)酯化在双酚型环氧树脂中产生的至少一部分仲羟基或羟基的步骤 代理商
    • 6. 发明申请
    • IMAGE FORMATION METHOD
    • 图像形成方法
    • US20080227000A1
    • 2008-09-18
    • US12047807
    • 2008-03-13
    • Takahiro HONDAHiroyuki FushimiFumihiro SasakiHisashi NakajimaHiroshi YamadaYasuo Asahina
    • Takahiro HONDAHiroyuki FushimiFumihiro SasakiHisashi NakajimaHiroshi YamadaYasuo Asahina
    • G03G13/04
    • G03G9/08753G03G9/0823G03G9/0827G03G9/08759G03G9/08795G03G9/08797
    • An image formation method including charging an image bearing member; irradiating the surface of the image bearing member to form a latent electrostatic image thereon; developing the latent electrostatic image with a two component developing agent including a carrier and a toner including a mother toner particle and an external additive by a development device including a stirring and transfer device for transferring and stirring the developing agent; transferring the developed image to a transfer medium; and fixing the developed image on the transfer medium, wherein the toner includes a polyol-based resin as a binder resin, the polyol based resin having multiple hydroxyl groups in a molecular chain thereof in which the ratio (EX/OH) of epoxy group (EX) to hydroxyl group (OH) is from 0.990 to 1.010, the stirring and transfer device satisfies the following relationship (I): 1.0×106≦α×β×γ≦16.0×106, wherein α represents the number of rotation per minute, β (mm) represents the pitch and γ (mm) represents the transfer path length of the stirring and transfer device, the temperature Tin (° C.) in the development device during stirring and transfer of the two component developing agent satisfies the following relationship (II): 30° C.
    • 一种图像形成方法,包括:对图像承载部件进行充电; 照射图像承载部件的表面以在其上形成静电潜像; 通过包括用于转移和搅拌显影剂的搅拌和转印装置的显影装置,用包括载体的二组分显影剂和包含母体调色剂颗粒和外部添加剂的调色剂显影静电潜像; 将显影的图像转印到转印介质上; 并将显影图像固定在转印介质上,其中调色剂包括作为粘合剂树脂的多元醇类树脂,其分子链中具有多个羟基的多元醇类树脂,其中环氧基(EX / OH) EX)至羟基(OH)的摩尔比为0.990至1.010,搅拌和转移装置满足以下关系式(I):1.0×10 6 <= alphaxbetaxgamma = 16.0×10 6 / SUP>,其中α表示每分钟的旋转数,β(mm)表示间距,γ(mm)表示搅拌和转移装置的转移路径长度,显影装置内的温度Tin(℃) 双组分显影剂的搅拌和转印满足以下关系式(II):30℃