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1. 发明授权

US06673454B1 Thermosetting powder coating composition 失效
标题翻译：热固性粉末涂料组合物
公开(公告)号：US06673454B1
公开(公告)日：2004-01-06
申请号：US09674331
申请日：2001-05-10
申请人： Nobuhiko Tsuda , Takahiro Kitahara , Ryuji Iwakiri , Masaru Nagato , Ryoichi Fukagawa , Go Nagai
发明人： Nobuhiko Tsuda , Takahiro Kitahara , Ryuji Iwakiri , Masaru Nagato , Ryoichi Fukagawa , Go Nagai
IPC分类号： B32B2726
CPC分类号： C09D127/12 , Y10T428/3154 , Y10T428/31544 , C08L2666/28
摘要： To provide the thermosetting powder coating composition which comprises a fluorine-containing copolymer having crosslinkable functional group and a curing agent, in which the fluorine-containing copolymer has a fluoroolefin unit, has a fluorine content of not less than 10% by weight and is not dissolved in tetrahydrofuran substantially. A coating line can be shared with other powder coating composition because even when the composition mixes to other powder coating composition, it causes no coating defects, and yet a coated article having a coating film excellent in physical properties can be provided.
摘要翻译：为了提供含有具有交联性官能团的含氟共聚物和含氟共聚物具有氟代烯烃单元的固化剂的热固性粉末涂料组合物，其含氟量不小于10重量％基本上溶于四氢呋喃。涂布线可以与其它粉末涂料组合物共用，因为即使当组合物与其它粉末涂料组合物混合时，也不会产生涂层缺陷，并且可以提供具有优异物理性质的涂膜的涂布制品。

2. 发明授权

US06506843B1 Thermosetting powder coating composition 失效
标题翻译：热固性粉末涂料组合物
公开(公告)号：US06506843B1
公开(公告)日：2003-01-14
申请号：US09674314
申请日：2001-04-06
申请人： Nobuhiko Tsuda , Takahiro Kitahara , Ryuji Iwakiri , Masaru Nagato , Ryoichi Fukagawa , Go Nagai
发明人： Nobuhiko Tsuda , Takahiro Kitahara , Ryuji Iwakiri , Masaru Nagato , Ryoichi Fukagawa , Go Nagai
IPC分类号： C09D503
CPC分类号： C09D127/16 , C08L33/12 , C08L2666/04
摘要： To provide a thermosetting powder coating composition which comprises a powder of a composite resin comprising a vinylidene fluoride polymer having crosslinkable functional group and a methyl methacrylate polymer and having a melt flow rate of 1 to 1,000 g/10 min when measured at 130° C. at a load of 2.1 kg. The coating composition has advantages that the preparation thereof is easy because pulverization can be carried out at room temperature as well as at low temperatures, the composite resin has excellent compatibility with various curing agents and the composition gives a coating film having excellent properties.
摘要翻译：提供一种热固性粉末涂料组合物，其包含具有交联性官能团的偏二氟乙烯聚合物和甲基丙烯酸甲酯聚合物的复合树脂的粉末，并且在130℃下测量时熔体流动速率为1至1,000g / 10min。负荷2.1公斤。该涂料组合物的优点在于，其制备容易，因为粉碎可以在室温和低温下进行，复合树脂与各种固化剂具有优异的相容性，组合物得到具有优异性能的涂膜。

3. 发明授权

US06743842B1 Fluorine-containing resin powder coating composition 失效
标题翻译：含氟树脂粉末涂料组合物
公开(公告)号：US06743842B1
公开(公告)日：2004-06-01
申请号：US09868071
申请日：2001-06-14
申请人： Ryoichi Fukagawa , Nobuhiko Tsuda , Masaru Nagato , Go Nagai , Ryuji Iwakiri
发明人： Ryoichi Fukagawa , Nobuhiko Tsuda , Masaru Nagato , Go Nagai , Ryuji Iwakiri
IPC分类号： C08K524
CPC分类号： C09D127/12 , C08L33/06 , C08L83/02 , C08L83/04 , C08L2666/14 , C08L2666/02
摘要： To provide a powder coating composition which comprises 100 parts by weight of fluorine-containing resin and 1 to 40 parts by weight of tetrafunctional or trifunctional silicate compound or a condensation product thereof, has a function of removing electrostatic charge and gives a coating film having a high hardness and stain-proof property.
摘要翻译：为了提供一种包含100重量份含氟树脂和1至40重量份四官能或三官能硅酸盐化合物或其缩合产物的粉末涂料组合物，具有除去静电荷的功能，并得到具有高硬度和防污性能。

4. 发明授权

US06361865B1 Method for surface-coating synthetic resins 失效
标题翻译：表面涂布合成树脂的方法
公开(公告)号：US06361865B1
公开(公告)日：2002-03-26
申请号：US09423046
申请日：2000-03-09
申请人： Nobuhiko Tsuda , Ryuji Iwakiri , Masaru Nagato , Katsuhiko Imoto
发明人： Nobuhiko Tsuda , Ryuji Iwakiri , Masaru Nagato , Katsuhiko Imoto
IPC分类号： B32B2736
CPC分类号： C08J7/047 , C08J2427/00 , C09D127/12 , Y10T428/31507
摘要： A surface protective coating layer being excellent in weather resistance and chemical resistance is formed on a synthetic resin substrate. An aqueous dispersion of fluorine-containing resin is applied to the synthetic resin substrate.
摘要翻译：在合成树脂基板上形成耐候性和耐化学性优异的表面保护涂层。将含氟树脂的水分散体涂布在合成树脂基材上。

5. 发明授权

US06359030B1 Aqueous resin dispersion composition 失效
标题翻译：水性树脂分散组合物
公开(公告)号：US06359030B1
公开(公告)日：2002-03-19
申请号：US09529984
申请日：2000-04-24
申请人： Nobuhiko Tsuda , Katsuhiko Imoto , Nobuo Mitsuhata , Masaru Nagato
发明人： Nobuhiko Tsuda , Katsuhiko Imoto , Nobuo Mitsuhata , Masaru Nagato
IPC分类号： C08L8300
CPC分类号： C09D127/16 , C08L33/12 , C08L2666/04
摘要： An aqueous-dispersing composition of synthetic resin (A) having an intrinsic viscosity “&eegr;” of from 0.3 to 2.0 measured at 35° C. in a methyl ethyl ketone solvent or a mixture of that aqueous dispersion and an aqueous dispersion of synthetic resin (B) having an intrinsic viscosity “&eegr;” of not less than 0.6 which is larger by 0.3 or more than the intrinsic viscosity “&eegr;” of the synthetic resin (A) when the intrinsic viscosity is measured at 35° C. in a methyl ethyl ketone solvent. The aqueous-dispersing composition and the mixture have improved film forming property and can give a coating film being excellent in chemical resistance, water resistance, mechanical properties and further hot water resistance.
摘要翻译：在甲基乙基酮溶剂或该水性分散体与合成树脂的水分散体的混合物中，在35℃下测定的特性粘度“η”为0.3〜2.0的合成树脂（A）的水分散组合物（ B），特性粘度“η”不小于0.6，当特性粘度在35℃下在甲基乙基中测定时，该特性粘度“η”大于合成树脂（A）的特性粘度“eta” 酮溶剂。水性分散组合物和混合物具有改进的成膜性，并且可以得到耐化学性，耐水性，机械性能和耐热水性更好的涂膜。

6. 发明授权

US06350806B1 Aqueous fluoropolymer dispersion composition 失效
标题翻译：水性含氟聚合物分散体组合物
公开(公告)号：US06350806B1
公开(公告)日：2002-02-26
申请号：US09529977
申请日：2000-04-24
申请人： Nobuhiko Tsuda , Katsuhiko Imoto , Nobuo Mitsuhata , Masaru Nagato
发明人： Nobuhiko Tsuda , Katsuhiko Imoto , Nobuo Mitsuhata , Masaru Nagato
IPC分类号： C08K334
CPC分类号： C09D127/12 , C08K3/36 , C09D127/16 , C08L27/12 , C08L2666/54 , C08L2666/28
摘要： An aqueous-dispersing composition which gives a coating being excellent in storage stability and forming a coating film being excellent in stain-proofing property and stain removable property and having sufficient gloss and hardness, and the composition contains said colloidal silica, in solid content, in an amount of more than 50 parts by weight up to 300 parts by weight and said organoalkoxysilane in an amount of 0.1 to 20 parts by weight on the basis of 100 parts by weight in solid content of an aqueous dispersion of fluorine-containing polymer particles.
摘要翻译：一种水分散性组合物，其具有保存稳定性优异且形成涂膜的防污性和污渍除去性优异，光泽度和硬度好的涂膜，该组合物含有固体含量的所述胶体二氧化硅基于100重量份固体含量的含氟聚合物颗粒的水分散体，其量大于50重量份，至多300重量份，所述有机烷氧基硅烷的量为0.1至20重量份。

7. 发明授权

US06326437B1 Aqueous-dispersing composition of crosslinkable fluorine-containing resin 失效
标题翻译：可交联含氟树脂的水分散组合物
公开(公告)号：US06326437B1
公开(公告)日：2001-12-04
申请号：US09530012
申请日：2000-04-24
申请人： Nobuhiko Tsuda , Katsuhiko Imoto , Nobuo Mitsuhata , Masaru Nagato
发明人： Nobuhiko Tsuda , Katsuhiko Imoto , Nobuo Mitsuhata , Masaru Nagato
IPC分类号： C08F25908
CPC分类号： C09D151/003 , C08F8/42 , C08F259/08 , C08L51/003 , C08F14/18
摘要： An aqueous-dispersing composition of a crosslinkable fluorine-containing resin which comprises an aqueous dispersion of a fluorine-containing seed polymer (B) obtained by seed-polymerizing a non-fluorine-containing monomer containing a non-fluorine-containing monomer (a) having carboxyl group and/or acetoacetyl group and a reactive &agr;,&bgr;-unsaturated group, in an aqueous medium in the presence of particles of a fluorine-containing polymer (A) and a polyvalent metal compound capable of metal crosslinking.
摘要翻译：一种交联性含氟树脂的水分散组合物，其含有通过将含有非氟单体（a）的非含氟单体进行种子聚合得到的含氟种子聚合物（B）的水分散体，在含氟聚合物（A）的颗粒和能够进行金属交联的多价金属化合物的存在下，在水性介质中具有羧基和/或乙酰乙酰基和反应性α，β-不饱和基团。

8. 发明授权

US06541552B1 Aqueous-dispersing composition of synthetic resin and silicate oligomer 失效
标题翻译：合成树脂和硅酸盐低聚物的水分散组合物
公开(公告)号：US06541552B1
公开(公告)日：2003-04-01
申请号：US09554500
申请日：2000-05-16
申请人： Nobuhiko Tsuda , Katsuhiko Imoto , Nobuo Mitsuhata , Masaru Nagato
发明人： Nobuhiko Tsuda , Katsuhiko Imoto , Nobuo Mitsuhata , Masaru Nagato
IPC分类号： C08L524
CPC分类号： C09D183/02 , C08K5/5415 , C09D5/024 , Y10T428/264 , C08L2666/04 , C08L2666/14 , C08L2666/02
摘要： To provide the aqueous-dispersing composition of synthetic resin which is excellent in stain-proofing property, weather resistance and storage stability and is capable of forming a coating film having a high gloss. The aqueous-dispersing composition of synthetic resin comprises an aqueous dispersion of synthetic resin and a condensate of tetrafunctional silicate compound represented by the formula (I): wherein R comprises R1 (R1 is methyl and/or ethyl) and R2 (R2 is at least one linear or branched alkyl group having 3 to 10 carbon atoms), n is 2 to 15, and contains the condensate of tetrafunctional silicate compound in an amount of 1 to 100 parts by weight on the basis of 100 parts by weight of solid content in the aqueous dispersion of synthetic resin.
摘要翻译：提供防污性，耐候性和保存稳定性优异的合成树脂的水分散组合物，能够形成具有高光泽度的涂膜。合成树脂的水分散组合物包括合成树脂的水性分散体和由式（I）表示的四官能硅酸盐化合物的缩合物：其中R包括R 1（R 1是甲基和/或乙基），R 2（R 2至少是一个具有3至10个碳原子的直链或支链烷基），n为2至15，并且基于100重量份的固体含量为100重量份，含有1至100重量份的四官能硅酸盐化合物的缩合物合成树脂的水性分散体。

9. 发明授权

US06075110A Stain-proofing agent for preventing adherence of stain and non-aqueous composition for paints containing said agent 失效
标题翻译：用于防止污渍粘附的防污剂和含有所述试剂的油漆的非水性组合物
公开(公告)号：US06075110A
公开(公告)日：2000-06-13
申请号：US894400
申请日：1997-08-18
申请人： Haruhiko Mohri , Susumu Wada , Akira Chida , Masaru Nagato , Keiko Kunimasa , Yoshiki Shimizu
发明人： Haruhiko Mohri , Susumu Wada , Akira Chida , Masaru Nagato , Keiko Kunimasa , Yoshiki Shimizu
IPC分类号： C08L83/02 , C09D7/12 , C09D127/12 , C09D133/06 , C09D143/04 , C09D183/02 , C08G77/08
CPC分类号： C09D183/02 , C09D127/12 , C09D133/06 , C09D143/04 , C09D5/1637 , C09D7/1233 , C08K5/5415 , C08L83/02
摘要： A stain-proofing agent comprising a compound represented by the formula (1): ##STR1## and non-aqueous composition for paints comprising the stain-proofing agent, resin, curing agent and/or curing catalyst and being capable of forming a coating film remarkably excellent in stain-proofing property.
摘要翻译： PCT No.PCT / JP96 / 00354 Sec。 371日期：1997年8月18日 102（e）日期1997年8月18日PCT提交1996年2月16日PCT公布。公开号WO96 / 26254 PCT。日期1996年8月29日一种防污剂，其包含式（1）表示的化合物：和含有防污剂，树脂，固化剂和/或固化催化剂的涂料用非水性组合物，能够形成涂膜具有优异的防污性能。

10. 发明授权

US09018306B2 Curable fluorine-containing polymer composition 有权
标题翻译：可固化含氟聚合物组合物
公开(公告)号：US09018306B2
公开(公告)日：2015-04-28
申请号：US12664535
申请日：2008-06-09
申请人： Masayuki Hayashi , Eiji Kitaura , Peter Cheshire Hupfield , Katsuhiko Imoto , Masaru Nagato
发明人： Masayuki Hayashi , Eiji Kitaura , Peter Cheshire Hupfield , Katsuhiko Imoto , Masaru Nagato
IPC分类号： C09D5/16 , C08F8/42 , C08G18/62 , C08G18/81 , C08G18/83 , C08K5/5415 , C08L33/16 , C09D127/16 , C09D131/02 , C09D133/16 , C09D183/10 , C08F214/28 , C08F216/14 , C08F218/10 , C08L83/04 , C08L83/10
CPC分类号： C09D5/1675 , C08F8/42 , C08F214/28 , C08F216/1416 , C08F218/10 , C08G18/6279 , C08G18/8108 , C08G18/837 , C08K5/5415 , C08L33/16 , C08L83/04 , C08L83/10 , C09D127/16 , C09D131/02 , C09D133/16 , C09D183/10 , C08F214/267 , C08L27/12 , C08L27/16 , C08L83/00 , C08L2666/14
摘要： There is provided a curable fluorine-containing polymer composition which is rapidly cured at relatively low temperature by hydrosilylation reaction to form a coating film having not only high hardness and flexibility but also water- and oil-repellency, thereby giving stain-proofing effect for a long period of time, especially maintaining property of removing and wiping-off stain. The curable fluorine-containing polymer composition comprises a fluorine-containing polymer comprising a fluorinated ethylenic monomer unit and an un-fluorinated ethylenic monomer unit, in which a part or the whole of the un-fluorinated ethylenic monomer units are units represented by the formula: where R1 is hydrogen atom or methyl group; R2 is a hydrocarbon group having ethylenic C═C; X is —C(O)NH— or —C(O)—; R3 is —O—, —O[CH(R4)]mO—, —(CH2)mO—, —OC(O)—(CH2)nO— or —(CH2)mOC(O)—(CH2)nO—, where R4 is —H, —OH, —CH2OH or —O—X—R2, a siloxane compound having hydrogen atom bonded to silicon atom, a catalyst for hydrosilylation reaction, and a siloxane compound having no hydrogen atom bonded to silicon atom.
摘要翻译：提供了一种可固化的含氟聚合物组合物，其通过氢化硅烷化反应在相对低的温度下快速固化以形成不仅具有高硬度和柔韧性，而且具有防水拒油性的涂膜，从而赋予防污效果长时间，特别是保持去除和擦拭污渍的性能。可固化含氟聚合物组合物包含含有氟化乙烯性单体单元和未氟化的乙烯性单体单元的含氟聚合物，其中一部分或全部未氟化的烯属单体单元是由下式表示的单元：其中R1是氢原子或甲基; R2是具有烯属C = C的烃基; X是-C（O）NH-或-C（O） - ; R 3是-O-，-O [CH（R 4）] m O - ， - （CH 2）m O - ， - OC（O） - （CH 2）n O-或 - （CH 2）mOC（O） - （CH 2）其中R 4为-H，-OH，-CH 2 OH或-O-X-R 2，具有与硅原子键合的氢原子的硅氧烷化合物，氢化硅烷化反应的催化剂和与硅原子键合的无氢原子的硅氧烷化合物。

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