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1. 发明授权

US06716930B2 Method for processing ethylene-vinyl alcohol copolymer solution 有权
标题翻译：乙烯 - 乙烯醇共聚物溶液加工方法
公开(公告)号：US06716930B2
公开(公告)日：2004-04-06
申请号：US09922692
申请日：2001-08-07
申请人： Noboru Yanagida , Masafumi Mikami
发明人： Noboru Yanagida , Masafumi Mikami
IPC分类号： C08F610
CPC分类号： C08F6/10 , C08F8/12 , C08F2800/20 , C08L29/00 , C08F218/08 , C08F210/02
摘要： A method for processing a solution of ethylene-vinyl alcohol copolymer in a solvent other than water, which involves continuously substituting a part of the solvent in the solution with water to produce a high-concentration ethylene vinyl alcohol copolymer solution without gelling, whereby an ethylene-vinyl alcohol copolymer solution is fed into a column vessel selected from a plate column and a packed column, and a part of the solvent in the solution is substituted with water in the column vessel.
摘要翻译：一种乙烯 - 乙烯醇共聚物在除水以外的溶剂中的溶液的处理方法，该方法包括用水连续取代该溶液中的一部分溶剂以产生不凝胶化的高浓度乙烯乙烯醇共聚物溶液，由此乙烯 - 乙烯醇共聚物溶液加入到选自板柱和填充柱的柱式容器中，溶液中的一部分溶剂在塔容器中用水代替。

2. 发明授权

US07021613B2 Antivibration device 失效
标题翻译：防振装置
公开(公告)号：US07021613B2
公开(公告)日：2006-04-04
申请号：US10374041
申请日：2003-02-27
申请人： Masafumi Mikami , Katsutaka Momose
发明人： Masafumi Mikami , Katsutaka Momose
IPC分类号： B60G11/22
CPC分类号： B60G21/0551 , B60G2200/21 , B60G2204/1434 , B60G2204/41042 , F16F1/3814 , F16F1/387
摘要： A toe correction bushing (1) is composed of a main body (2) and a stopper member (3), wherein the main body (2) is integrally provided with an inner cylinder (4), an outer cylinder (5), and an elastic body (6). The outer cylinder (5) is provided at part of the axial end with an outwardly opening inclined section (7). A recessed space (8) is provided inside of the inclined section (7). The stopper member (3) is provided with a circular plate section (20) and a stopper projection (23) at the peripheral section thereof. A boss (21) provided at the central section of the stopper member (3) is press-fitted into one end of the inner cylinder (4) for integration and at the same time, the stopper projection (23) is caused to engage the recessed space (8). When a lateral force F to the right is applied to the outer cylinder (5), the axial movement of the outer cylinder (5) is controlled by the stopper projection (23) and displaced in the direction perpendicular to the axis by an inclined plane (24) for toe correction. It is possible to change characteristics of the toe correction by changing the material, shape or the like of the stopper projection (23).
摘要翻译：脚趾修正衬套（1）由主体（2）和止动构件（3）构成，其中主体（2）整体地设置有内筒（4），外筒（5）和弹性体（6）。外筒（5）在轴向端部的一部分设置有向外开口的倾斜部（7）。凹部空间（8）设置在倾斜部（7）的内部。止动构件（3）在其周边部分设置有圆板部分（20）和止动突起（23）。设置在止动构件（3）的中央部的凸台（21）压配合到内筒（4）的一端以一体化，同时使止动突起（23）与凹陷空间（8）。当向外筒（5）施加右侧的横向力F时，通过止动突起（23）控制外筒（5）的轴向移动，并使其与垂直于轴线的方向移动一倾斜平面（24）用于脚趾矫正。可以通过改变止动突起（23）的材料，形状等来改变脚趾校正的特性。

3. 发明授权

US6087512A Process for preparation of glycidyl ether 失效
标题翻译：缩水甘油醚的制备方法
公开(公告)号：US6087512A
公开(公告)日：2000-07-11
申请号：US147715
申请日：1999-04-29
申请人： Yoshiro Furukawa , Kazuhiro Kitaori , Tetsuya Yanagimoto , Masafumi Mikami , Hiroshi Yoshimoto , Junzo Otera
发明人： Yoshiro Furukawa , Kazuhiro Kitaori , Tetsuya Yanagimoto , Masafumi Mikami , Hiroshi Yoshimoto , Junzo Otera
IPC分类号： C07D301/28 , C07D303/22 , C07D303/23
CPC分类号： C07D303/22 , C07D301/28
摘要： A process for preparation of a glycidyl ether which is characrelized in reacting an epoxy compound of the formula ##STR1## wherein X is halogen or sulfonyloxy in the presence of a fluoride salt, with an alcohol. According to the above method, glycigyl ethers or their optically active compounds important as intermediates for synthesis of medicines are easily obtained in good yield and especially the optically active compounds are obtained with highly optical purity.
摘要翻译： PCT No.PCT / JP97 / 03221 Sec。 371日期1999年4月29日第 102（e）1999年4月29日PCT PCT 1997年9月12日PCT公布。公开号WO98 / 12186 日期：1998年3月26日一种制备缩水甘油醚的方法，该方法在使氟化物盐存在下与醇存在下，使下式的环氧化合物其中X为卤素或磺酰氧基反应而得到特征。根据上述方法，容易以良好的产率获得作为药物合成中间体重要的缩水甘油醚或其光学活性化合物，特别是以高光学纯度获得光学活性化合物。

4. 发明申请

US20060019993A1 1-Amido-3-(2-hydroxyphenoxy)-2-propanol derivatives and a process for preparing 2-amidomethyl-1,4-benzodioxane derivatives 失效
标题翻译： 1-酰氨基-3-（2-羟基苯氧基）-2-丙醇衍生物及其制备方法2-氨基甲基-1,4-苯并二恶烷衍生物
公开(公告)号：US20060019993A1
公开(公告)日：2006-01-26
申请号：US11183746
申请日：2005-07-19
申请人： Yasushi Miki , Masafumi Mikami
发明人： Yasushi Miki , Masafumi Mikami
IPC分类号： A61K31/44 , A61K31/40 , A61K31/277 , A61K31/325 , A61K31/16
CPC分类号： C07D209/48 , C07D405/06
摘要： An 1-amido-3-(2-hydroxyphenoxy)-2-propanol derivative represented by the following formula (1), wherein cycle A may have further 1 to 4 substituents, and said substituent means a substituent selected from the group consisting of saturated or unsaturated C1-4 alkyl group, aralkyl group in which alkyl moiety has 1 to 4 carbon atoms, aryl group, halogen atom, halogenated C1-4 alkyl group, C2-5 alkanoyl group, mono or dialkylcarbamoyl group in which alkyl moiety has 1 to 4 carbon atoms, cyano group and nitro group, and the substituents at positions 3 and 6, or at positions 4 and 5 on the cycle A are different each other. Other ring may be fused at positions 3 and 4, or at positions 5 and 6 on the cycle A to form a condensed polycyclic hydrocarbon with the cycle A. R1 is alkanoyl group or aroyl group, and R2 is hydrogen atom, alkanoyl group or aroyl group, or R1 and R2 may be combined together with the N atom to form a cyclic imido group, which is useful as an intermediate of medicines, etc.
摘要翻译：由下式（1）表示的1-酰胺基-3-（2-羟基苯氧基）-2-丙醇衍生物，其中环A可以具有1〜4个取代基，所述取代基是指选自饱和的或不饱和C 1-4烷基，其中烷基部分具有1至4个碳原子的芳烷基，芳基，卤素原子，卤代C 1-4烷基，C 2-5烷酰基，其中烷基部分具有1个的单或二烷基氨基甲酰基至4个碳原子，氰基和硝基，并且在循环A上位置3和6，或位置4和5的取代基彼此不同。其它环可以在循环A的3和4位或5和6位融合，形成具有循环A的缩合多环烃.R 1是烷酰基或芳酰基，R O 2是氢原子，烷酰基或芳酰基，或者R 1和R 2可以与N原子一起形成环状亚胺基，可用作药物中间体等。

5. 发明授权

US06620977B1 Process for producing butanetriol derivative 失效
标题翻译：制备丁三醇衍生物的方法
公开(公告)号：US06620977B1
公开(公告)日：2003-09-16
申请号：US09581086
申请日：2000-06-09
申请人： Makoto Hirata , Masafumi Mikami , Yoshiro Furukawa
发明人： Makoto Hirata , Masafumi Mikami , Yoshiro Furukawa
IPC分类号： C07C4118
CPC分类号： C07C303/28 , C07C303/30 , Y02P20/55 , C07C309/66
摘要： A process for preparing a butanetriol derivative of the formula (1) useful as intermediates of medicines wherein R1 is the same defined below, which comprises reacting a compound of the formula (3) wherein R1 and R2 are the different protecting groups, and an ethylene glycol derivative in a basic condition to prepare a compound of the formula (4) or (4a) wherein R1 and R2 are the same defined above, and then subjecting the compound (4) or (4a) to selective deprotection reaction.
摘要翻译：用于制备式（1）的丁内三醇衍生物的方法，其用作R1中的药物的中间体，其定义如下，其包括使式（3）化合物（其中R 1和R 2是不同的保护基团）和乙二醇衍生物制备式（4）或（4a）化合物，其中R1和R2与上述定义相同，然后使化合物（4）或（4a）进行选择性脱保护反应。

6. 发明授权

US5446173A Cyclic sulfide compound, polymerizable compositions for optical products and optical products formed thereof 失效
标题翻译：环硫化物，由其形成的光学产品的可聚合组合物和光学产品
公开(公告)号：US5446173A
公开(公告)日：1995-08-29
申请号：US35598
申请日：1993-03-23
申请人： Hiroyuki Kanesaki , Tetsuyuki Saika , Masafumi Mikami
发明人： Hiroyuki Kanesaki , Tetsuyuki Saika , Masafumi Mikami
IPC分类号： C07D327/04 , C07D327/06 , C07D333/18 , C07D335/02 , C07D339/06 , C08G18/38 , G02B1/04 , C07D335/00 , C07D333/32
CPC分类号： G02B1/04 , C07D327/04 , C07D327/06 , C07D333/18 , C07D335/02 , C07D339/06 , C08G18/3874 , C08G18/3876
摘要： The present invention provides a cyclic sulfide compound represented by a general formula (I) ##STR1## (where R.sup.1 represents --CH.sub.2 --CH.sub.2 --, --CH.sub.2 --CH.sub.2 --CH.sub.2 --, --CH.sub.2 --O--CH.sub.2 --, --CH.sub.2 --O--, or --CH.sub.2 --S--). Polymerizable compositions for manufacturing optical products with this compound as their main component can be readily molded into plastic lenses which give superhigh refractive indices and high Abbe numbers or those which give high refractive indices and high Abbe number with low sp.grs. in addition thereto. The castings obtained from said polymerizable compositions are useful as plastic lenses for glasses, manifesting optical uniformity and being excellent in processability, transparency, and thermal, impact and light resistance. Further these polymerizable resin compositions are usable preferably as such optical products as prisms, optical fibers, optical disc substrates, color filters, or infrared absorption filters.
摘要翻译：本发明提供由通式（I）表示的环状硫化合物（I）（其中R 1表示-CH 2 -CH 2 - ， - CH 2 -CH 2 - ， - CH 2 -O-CH 2 - ， - CH 2 -O-或-CH 2 -S-）。用于制造具有该化合物作为其主要成分的光学产品的可聚合组合物可以容易地模制成具有超高折射率和高阿贝数的塑料透镜，或者具有低折射率的那些和具有低sp.grs的高阿贝数。除此之外。从所述可聚合组合物获得的铸件可用作玻璃的塑料透镜，表现出光学均匀性并且加工性，透明性以及热，冲击和耐光性优异。此外，这些可聚合树脂组合物优选可用作棱镜，光纤，光盘基板，滤色器或红外吸收滤光片等光学产品。

7. 发明授权

US07208634B2 Oxidation method of primary or secondary alcohol 有权
标题翻译：一级或二级酒精的氧化方法
公开(公告)号：US07208634B2
公开(公告)日：2007-04-24
申请号：US11290474
申请日：2005-12-01
申请人： Kimitaka Igi , Makoto Hirata , Masafumi Mikami
发明人： Kimitaka Igi , Makoto Hirata , Masafumi Mikami
IPC分类号： C07C45/29
CPC分类号： C07D317/30 , C07B41/06 , C07C45/30 , C07C49/04 , C07C47/575 , C07C47/228 , C07C49/403 , C07C47/02 , C07C47/54
摘要： A method for preparing an aldehyde or ketone by oxidizing a primary or secondary alcohol in the presence of a nitroxyl radical compound and a co-oxidant in an organic solvent, which process is characterized in using an organic N-bromoamide compound or a combination of N-chlorosuccinimide and a compound having bromide ion as the co-oxidant.
摘要翻译：一种通过在有机溶剂中在硝酰自由基化合物和助氧化剂存在下氧化伯醇或仲醇制备醛或酮的方法，其特征在于使用有机N-溴代酰胺化合物或N - 氯代琥珀酰亚胺和具有溴离子的化合物作为助氧化剂。

8. 发明申请

US20060122434A1 Novel oxidation method of primary or secondary alcohol 有权
标题翻译：伯或仲醇的新型氧化法
公开(公告)号：US20060122434A1
公开(公告)日：2006-06-08
申请号：US11290474
申请日：2005-12-01
申请人： Kimitaka Igi , Makoto Hirata , Masafumi Mikami
发明人： Kimitaka Igi , Makoto Hirata , Masafumi Mikami
IPC分类号： C07C45/29
CPC分类号： C07D317/30 , C07B41/06 , C07C45/30 , C07C49/04 , C07C47/575 , C07C47/228 , C07C49/403 , C07C47/02 , C07C47/54
摘要： A method for preparing an aldehyde or ketone by oxidizing a primary or secondary alcohol in the presence of a nitroxyl radical compound and a co-oxidant in an organic solvent, which process is characterized in using an organic N-bromoamide compound or a combination of N-chlorosuccinimide and a compound having bromide ion as the co-oxidant.
摘要翻译：一种通过在有机溶剂中在硝酰自由基化合物和助氧化剂存在下氧化伯醇或仲醇制备醛或酮的方法，其特征在于使用有机N-溴代酰胺化合物或N - 氯代琥珀酰亚胺和具有溴离子的化合物作为助氧化剂。

9. 发明授权

US6156941A Process for producing 1,2-propanediol 失效
标题翻译： 1,2-丙二醇生产工艺
公开(公告)号：US6156941A
公开(公告)日：2000-12-05
申请号：US423980
申请日：1999-12-20
申请人： Kousei Ikai , Naotaka Kameyama , Yoshiro Furukawa , Masafumi Mikami
发明人： Kousei Ikai , Naotaka Kameyama , Yoshiro Furukawa , Masafumi Mikami
IPC分类号： C07C29/58 , C07C31/18
CPC分类号： C07C29/58 , C07B2200/07
摘要： The present invention provides a process for obtaining 1,2-propanediol or optically active substances thereof in high yields and at a low cost using readily available starting materials. According to the process of the present invention, 3-halogeno-1,2-propanediol of the general formula [I] is catalytically hydrogenated in an alcoholic solvent having two or more carbon atoms in the presence of a base of an equivalent or less to the starting material to give 1,2-propanediol of the formula [II]. In the formula [I], X stands for a halogen atom. ##STR1##
摘要翻译： PCT No.PCT / JP98 / 02166 Sec。 371 1999年12月20日第 102（e）1999年12月20日日期PCT提交1998年5月18日PCT公布。 WO98 / 52893 PCT出版物日期：1998年11月26日本发明提供了使用容易获得的原料以高产率和低成本获得1,2-丙二醇或其光学活性物质的方法。根据本发明的方法，通式[I]的3-卤代-1,2-丙二醇在碱的存在下，在具有两个或多个碳原子的醇溶剂中进行催化氢化，该碱为等于或小于等于或小于得到式[II]的1,2-丙二醇的原料。在式[I]中，X表示卤素原子。

10. 发明授权

US07368608B2 1-amido-3-(2-hydroxyphenoxy)-2-propanol derivatives and a process for preparing 2-amidomethyl-1,4-benzodioxane derivatives 失效
标题翻译： 1-氨基-3-（2-羟基苯氧基）-2-丙醇衍生物及其制备方法2-氨基甲基-1,4-苯并二恶烷衍生物
公开(公告)号：US07368608B2
公开(公告)日：2008-05-06
申请号：US11183746
申请日：2005-07-19
申请人： Yasushi Miki , Masafumi Mikami
发明人： Yasushi Miki , Masafumi Mikami
IPC分类号： C07C217/02 , C07C45/29 , C07D209/48 , C07D321/00
CPC分类号： C07D209/48 , C07D405/06
摘要： An 1-amido-3-(2-hydroxyphenoxy)-2-propanol derivative represented by the following formula (1), wherein cycle A may have further 1 to 4 substituents, and said substituent means a substituent selected from the group consisting of saturated or unsaturated C1-4 alkyl group, aralkyl group in which alkyl moiety has 1 to 4 carbon atoms, aryl group, halogen atom, halogenated C1-4 alkyl group, C2-5 alkanoyl group, mono or dialkylcarbamoyl group in which alkyl moiety has 1 to 4 carbon atoms, cyano group and nitro group, and the substituents at positions 3 and 6, or at positions 4 and 5 on the cycle A are different each other. Other ring may be fused at positions 3 and 4, or at positions 5 and 6 on the cycle A to form a condensed polycyclic hydrocarbon with the cycle A. R1 is alkanoyl group or aroyl group, and R2 is hydrogen atom, alkanoyl group or aroyl group, or R1 and R2 may be combined together with the N atom to form a cyclic imido group, which is useful as an intermediate of medicines, etc.
摘要翻译：由下式（1）表示的1-酰胺基-3-（2-羟基苯氧基）-2-丙醇衍生物，其中环A可以具有1〜4个取代基，所述取代基是指选自饱和的或不饱和C 1-4烷基，其中烷基部分具有1至4个碳原子的芳烷基，芳基，卤素原子，卤代C 1-4烷基，C 2-5烷酰基，其中烷基部分具有1个的单或二烷基氨基甲酰基至4个碳原子，氰基和硝基，并且在循环A上位置3和6，或位置4和5的取代基彼此不同。其它环可以在循环A的3和4位或5和6位融合，形成具有循环A的缩合多环烃.R 1是烷酰基或芳酰基，R O 2是氢原子，烷酰基或芳酰基，或者R 1和R 2可以与N原子一起形成环状亚胺基，可用作药物中间体等。

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