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1. 发明申请

US20050008934A1 Redox active reversible electrode and novel battery using the same 审中-公开
标题翻译：氧化还原活性可逆电极和新型电池使用相同
公开(公告)号：US20050008934A1
公开(公告)日：2005-01-13
申请号：US10913620
申请日：2004-08-06
申请人： Noboru Oyama , Miyuki Matsukawa , Takeshi Shimomura , Shuichiro Yamaguchi
发明人： Noboru Oyama , Miyuki Matsukawa , Takeshi Shimomura , Shuichiro Yamaguchi
IPC分类号： H01G9/00 , H01G9/22 , H01G11/02 , H01G11/42 , H01G11/48 , H01M4/137 , H01M4/58 , H01M4/60 , H01M10/052 , H01M10/36 , H01M4/00
CPC分类号： H01M10/052 , H01G9/22 , H01G11/02 , H01G11/42 , H01G11/48 , H01M4/137 , H01M4/5815 , H01M4/60 , H01M4/606 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： A redox active reversible electrode includes a conductive substrate and a redox active film formed on at least one surface of the conductive substrate. The redox active film contains a redox active sulfur compound and an electrically conductive polymer of a π electron conjugated compound having p-type doping characteristics.
摘要翻译：氧化还原活性可逆电极包括形成在导电基材的至少一个表面上的导电基材和氧化还原活性膜。氧化还原活性膜含有氧化还原活性硫化合物和具有p型掺杂特性的π电子共轭化合物的导电聚合物。

2. 发明申请

US20090023888A1 METHOD OF PRODUCING SULFUR-CONTAINING AROMATIC POLYMER 审中-公开
标题翻译：生产含硫的芳族聚合物的方法
公开(公告)号：US20090023888A1
公开(公告)日：2009-01-22
申请号：US12223301
申请日：2007-01-26
申请人： Tomoo Sarukawa , Masahiko Taniguchi , Takeshi Shimomura , Shuichiro Yamaguchi , Noboru Oyama
发明人： Tomoo Sarukawa , Masahiko Taniguchi , Takeshi Shimomura , Shuichiro Yamaguchi , Noboru Oyama
IPC分类号： C08G75/14
CPC分类号： H01M4/137 , C08G75/14 , C08G75/16 , H01M4/606 , H01M4/608 , H01M10/052 , H01M2004/028
摘要： A method of producing a polymer of a sulfur-containing aromatic compound includes reacting, under heating, a halide of a sulfur-containing aromatic compound having at least one aromatic ring and at least one ring containing one or more disulfide bonds wherein one side of the disulfide-containing ring constitutes one side of the aromatic ring, with inorganic sulfur in an amount equivalent to 2 to 8 S atoms relative to 1 mol of the halide of the sulfur-containing aromatic compound in the presence of at least one inorganic base selected from the group consisting of an alkali metal hydroxide, an alkali metal hydrogen carbonate and an alkali metal carbonate and/or at least one organic base selected from the group consisting of a tri(lower alkyl)amine and a heterocyclic amine in an organic solvent.
摘要翻译：含硫芳香族化合物的聚合物的制造方法包括在加热下使具有至少一个芳环的含硫芳香族化合物的卤化物与至少一个含有一个以上二硫键的环进行反应，二硫化物环构成芳环的一侧，相对于1摩尔含硫芳族化合物的卤化物，在至少一种选自以下的无机碱的存在下，相当于2〜8S原子的无机硫在有机溶剂中由碱金属氢氧化物，碱金属碳酸氢盐和碱金属碳酸盐和/或至少一种选自三（低级烷基）胺和杂环胺的有机碱组成的组。

3. 发明授权

US5186808A Film-coated sensor 失效
标题翻译：薄膜传感器
公开(公告)号：US5186808A
公开(公告)日：1993-02-16
申请号：US548931
申请日：1990-07-27
申请人： Shuichiro Yamaguchi , Naoto Uchida , Satoru Kasai , Takeshi Shimomura , Noboru Oyama
发明人： Shuichiro Yamaguchi , Naoto Uchida , Satoru Kasai , Takeshi Shimomura , Noboru Oyama
IPC分类号： G01N27/333 , A61B5/145 , A61B5/1473 , A61B5/15 , G01N27/30 , G01N27/327
CPC分类号： A61B5/14542 , A61B5/14865 , A61B2562/02
摘要： A film-coated sensor is formed by providing an electrically conductive substrate (2), which has a sectional area of less than 10.sup.-5 cm.sup.2, connected to a lead wire (5) at one end of an insulative capillary (1) and inscribed in the capillary (1), and providing a coating film (7) at another end, which is open, of the capillary (1) by an electrolytic polymerization process.The film-coated sensor obtained has a surface which is uniform, the film coating is easy to control, and since the sensor is not readily susceptible to flow of a specimen fluid, there is little drift and response is quick. Owing to its small size, the sensor is capable of measuring very small samples and of performing measurement upon being directly inserted into a living body or tissue.The sensor can be used also as an enzyme sensor by coating the surface of the film-coated sensor with a fixing enzyme film.
摘要翻译： PCT No.PCT / JP89 / 00085 Sec。 371日期1990年7月27日第 102（e）1990年7月27日PCT PCT 1989年1月27日PCT公布。公开号WO89 / 07262 日本1989年8月10日。薄膜涂层传感器是通过提供导电基片（2）形成的，导电基片（2）的截面积小于10-5厘米2，与导线（5）的一端连接绝缘毛细管（1）并内接在毛细管（1）中，并通过电解聚合过程在毛细管（1）的开口的另一端提供涂膜（7）。获得的涂膜传感器具有均匀的表面，膜涂层易于控制，并且由于传感器不容易受到样品流体的流动，因此几乎没有漂移和响应快。由于传感器尺寸小，所以传感器能够测量非常小的样品，并且直接插入生物体或组织中进行测量。传感器也可以通过用固定酶膜涂覆薄膜传感器的表面作为酶传感器。

4. 发明申请

US20090095942A1 Positive Electrode Material for Lithium Secondary Battery 审中-公开
标题翻译：锂二次电池正极材料
公开(公告)号：US20090095942A1
公开(公告)日：2009-04-16
申请号：US11883117
申请日：2005-09-09
申请人： Shuichiro Yamaguchi , Kenichi Hamazaki , Yasumasa Mochizuki , Takeshi Shimomura , Masahide Ozaki , Satoru Yatabe , Noboru Oyama
发明人： Shuichiro Yamaguchi , Kenichi Hamazaki , Yasumasa Mochizuki , Takeshi Shimomura , Masahide Ozaki , Satoru Yatabe , Noboru Oyama
IPC分类号： H01B1/12 , C08G73/02 , C08G73/06
CPC分类号： H01M4/5825 , H01M4/131 , H01M4/136 , H01M4/525 , H01M4/624 , H01M2004/028
摘要： It is a first object of the present invention to provide a lithium secondary battery using a conductive polymer such as polyaniline, which exhibits a stable electrical conductivity over a long time. To achieve the first object, there is provided a positive electrode material for a lithium secondary battery, comprising an electrically conductive polymer having an amino group, a hydrogen bonding compound, and a protonic acid. Further, it is a second object of the present invention to provide a lithium secondary battery exhibiting a high charge-discharge capacity while using a conductive polymer such as polyaniline. To achieve the second object, there is provided a positive electrode material for a lithium secondary battery, comprising an electrically conductive polymer, and LiNiO2 and/or liFePO4.
摘要翻译：本发明的第一个目的是提供一种使用聚苯胺等导电性高分子的锂二次电池，其长时间显示出稳定的导电性。为了实现第一个目的，提供了一种用于锂二次电池的正极材料，其包括具有氨基的导电聚合物，氢键化合物和质子酸。此外，本发明的第二个目的是提供一种在使用聚苯胺等导电性聚合物的同时显示高充放电能力的锂二次电池。为了实现第二个目的，提供了一种用于锂二次电池的正极材料，其包括导电聚合物和LiNiO 2和/或LiFePO 4。

5. 发明授权

US4981570A Ion carrier membrane, and ion sensor having same 失效
标题翻译：离子载体膜和离子传感器
公开(公告)号：US4981570A
公开(公告)日：1991-01-01
申请号：US378233
申请日：1989-08-07
申请人： Shuichiro Yamaguchi , Takanao Suzuki , Norio Daikuhara , Takeshi Shimomura , Noboru Oyama
发明人： Shuichiro Yamaguchi , Takanao Suzuki , Norio Daikuhara , Takeshi Shimomura , Noboru Oyama
IPC分类号： G01N27/333
CPC分类号： G01N27/3335
摘要： The surface of an electrically conductive substrate (1) is provided with a redox layer (5) by an electrolytic polymerization process, and the surface of the resulting member is further provided with an ion carrier membrane (6) which includes polyvinyl chloride, a plasticizer and an ion carrier, thereby forming an ion sensor. Used as the plasticizer is one selected from among phthalate plasticizers, maleate plasticizers, adipate plasticizers, carboxylate plasticizers and polycaprolactone plasticizers, or one selected from among plasticizers comprising modified ethylene - vinyl acetate copolymer. The ion sensor obtained has low solubility in the plasticizer of the redox layer and therefore is highly stable. Since the ion sensor has little toxicity, it can be used in vivo. A preferred plasticizer is benzopohenon-tetracarboxylic under cyclic acid.

6. 发明申请

US20070026310A1 Redox-active reversible electrode and secondary battery using the same 审中-公开
标题翻译：氧化还原活性可逆电极和二次电池使用相同
公开(公告)号：US20070026310A1
公开(公告)日：2007-02-01
申请号：US11544437
申请日：2006-09-29
申请人： Noboru Oyama , Tomoo Sarukawa , Takeshi Shimomura , Shuichiro Yamaguchi , Masahiko Taniguchi , Toshiharu Matoba , Shinji Miyakawa , Masanobu Sato
发明人： Noboru Oyama , Tomoo Sarukawa , Takeshi Shimomura , Shuichiro Yamaguchi , Masahiko Taniguchi , Toshiharu Matoba , Shinji Miyakawa , Masanobu Sato
IPC分类号： H01M4/60 , C07C321/30
CPC分类号： H01M10/052 , H01M4/131 , H01M4/136 , H01M4/137 , H01M4/505 , H01M4/525 , H01M4/58 , H01M4/60 , H01M4/624 , H01M10/0525 , H01M10/054 , Y02T10/7011
摘要： A redox-active reversible electrode has a redox-active film on a surface of an electrically conductive substrate. The redox-active film includes a redox-active sulfur-containing substance which has at least one aromatic ring and a ring containing at least one disulfide bond, with a side of the disulfide-containing ring constituting a side of the aromatic ring, and which has a property that it is capable of reversibly releasing and receiving one or more electrons per disulfide-containing ring without the disulfide-containing ring being opened.
摘要翻译：氧化还原活性的可逆电极在导电性基板的表面具有氧化还原活性膜。氧化还原活性膜包括氧化还原活性含硫物质，其具有至少一个芳香环和含有至少一个二硫键的环，二硫键环的一侧构成芳环的一侧，并且其中具有能够在不含有二硫键的环打开的情况下可逆地释放和接收每个含二硫键的一个或多个电子的性质。

7. 发明授权

US5213675A Reference electrode, ion sensor and method of manufacturing the same 失效
标题翻译：参比电极，离子传感器及其制造方法
公开(公告)号：US5213675A
公开(公告)日：1993-05-25
申请号：US717645
申请日：1991-06-19
申请人： Shuichiro Yamaguchi , Takeshi Shimomura , Naoto Uchida , Teruaki Katsube , Noboru Oyama
发明人： Shuichiro Yamaguchi , Takeshi Shimomura , Naoto Uchida , Teruaki Katsube , Noboru Oyama
IPC分类号： G01N27/30
CPC分类号： G01N27/414
摘要： A reference electrode for generating a reference potential on an ion sensor is disclosed. The reference electrode has a lamination film covering a surface of an electrically conductive substrate and formed by alternately laminating silver halide thin films and hydrophobic resin thin films.
摘要翻译：公开了一种用于在离子传感器上产生参考电位的参考电极。参考电极具有覆盖导电性基板的表面并通过交替层叠卤化银薄膜和疏水性树脂薄膜而形成的层叠膜。

8. 发明授权

US5205920A Enzyme sensor and method of manufacturing the same 失效
标题翻译：酶传感器及其制造方法
公开(公告)号：US5205920A
公开(公告)日：1993-04-27
申请号：US487372
申请日：1990-03-02
申请人： Noboru Oyama , Takeshi Shimomura , Shuichiro Yamaguchi
发明人： Noboru Oyama , Takeshi Shimomura , Shuichiro Yamaguchi
IPC分类号： C12Q1/00
CPC分类号： C12Q1/004
摘要： An enzyme sensor is disclosed, which has a two-layer fixed film structure consisting of a reduction function layer including an electron movement medium and di-valent iron ions and an enzyme-fixed layer covering said reduction function layer, and in which hydrogen peroxide generated through decomposition of glucose or the like in the enzyme-fixed layer is reduced by electron movement medium and di-valent iron ions in the reduction function layer.Thus, the construction of enzyme sensor is simplified, measurement is extremely facilitated, and the measurement time is reduced.As a different principle of enzyme sensor, an electrically conductive substrate of conductive carbon or the like is covered with an oxygen-reducing catalytic function layer and enzyme layer.Thus, there is no problem of contamination of enzyme sensor, and it is possible to readily manufacture and miniaturize enzyme sensors.
摘要翻译：公开了一种酶传感器，其具有由包括电子移动介质和二价铁离子的还原功能层和覆盖所述还原功能层的酶固定层组成的两层固定膜结构，其中产生过氧化氢通过酶固定层中的葡萄糖等的分解，还原功能层中的电子移动介质和二价铁离子被还原。因此，酶传感器的结构简单化，极大的方便了测量，测量时间缩短。作为酶传感器的不同原理，导电性碳等的导电性基材被氧还原性催化剂层和酶层覆盖。因此，酶传感器没有污染的问题，可以容易地制造和微型化酶传感器。

9. 发明授权

US5066383A Reference electrode, ion sensor and method of manufacturing the same 失效
标题翻译：参考电极，离子传感器及其制造方法
公开(公告)号：US5066383A
公开(公告)日：1991-11-19
申请号：US426713
申请日：1989-10-26
申请人： Shuichiro Yamaguchi , Takeshi Shimomura , Naoto Uchida , Teruaki Katsube , Noboru Oyama
发明人： Shuichiro Yamaguchi , Takeshi Shimomura , Naoto Uchida , Teruaki Katsube , Noboru Oyama
IPC分类号： G01N27/30
CPC分类号： G01N27/301 , G01N27/414
摘要： A reference electrode for generating a reference potential on an ion sensor is disclosed. The reference electrode has a lamination film covering a surface of an electrically conductive substrate and formed by alternately laminating silver halide thin films and hydrophobic resin thin films.

10. 发明授权

US5061976A FET electrode with carbon gate 失效
标题翻译：具有碳栅的FET电极
公开(公告)号：US5061976A
公开(公告)日：1991-10-29
申请号：US687214
申请日：1991-04-19
申请人： Takeshi Shimomura , Shuichiro Yamaguchi , Takanao Suzuki , Noboru Oyama
发明人： Takeshi Shimomura , Shuichiro Yamaguchi , Takanao Suzuki , Noboru Oyama
IPC分类号： G01N27/414
CPC分类号： G01N27/414
摘要： The surface of a gate insulating membrane of an ion-selective field-effect transistor (ISFET) (10) is coated with a carbon thin membrane (4), and the surface of the latter is coated with an electrolytic polmerization membrane (3) of 2,6 xylenol. The ISFET obtained exhibits hydrogen-ion selectivity, little drift, high stability and little response to light. If the surface of the electrolytic polmerization membrane (3) of 2,6 xylenol is coated with another ion-selective membrane or enzyme-active membrane, various ions and the concentration of a biological substrate can be measured.
摘要翻译： PCT No.PCT / JP87 / 00900 Sec。 371日期：1989年7月19日 102（e）日期1989年7月19日PCT提交1987年11月19日PCT公布。第WO88 / 04049号公报日期：1988年6月2日。离子选择性场效应晶体管（ISFET）（10）的栅极绝缘膜的表面涂覆有碳薄膜（4），并且其表面涂覆有电解聚磷膜（3）为2,6二甲苯酚。所获得的ISFET具有氢离子选择性，漂移小，稳定性高，对光的反应小。如果2,6-二甲苯酚的电解聚合膜（3）的表面被另外的离子选择膜或酶活性膜包覆，则可以测定各种离子和生物体的浓度。

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