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    • 1. 发明申请
    • WET ETCHANTS INCLUDING AT LEAST ONE ETCH BLOCKER
    • 包括至少一个蚀刻块的软件包
    • US20120187335A1
    • 2012-07-26
    • US13413157
    • 2012-03-06
    • Nishant SinhaJ. Neil Greeley
    • Nishant SinhaJ. Neil Greeley
    • C09K13/08C09K13/00
    • C09K13/08C09K13/06H01L21/31055H01L21/31111
    • Methods for preventing isotropic removal of materials at corners formed by seams, keyholes, and other anomalies in films or other structures include use of etch blockers to cover or coat such corners. This covering or coating prevents exposure of the corners to isotropic etch solutions and cleaning solutions and, thus, prevents higher material removal rates at the corners than at smoother areas of the structure or film. Solutions, including wet etchants and cleaning solutions, that include at least one type of etch blocker are also disclosed, as are systems for preventing higher rates of material removal at corners formed by seams, crevices, or recesses in a film or other structure. Semiconductor device structures in which etch blockers are located so as to prevent isotropic etchants from removing material from corners of seams, crevices, or recesses in a surface of a film or other structure at undesirably high rates are also disclosed.
    • 在膜或其他结构中由接缝,键孔和其它异常形成的角部处的各向同性物质的各向同性除去方法包括使用蚀刻阻挡剂来覆盖或涂覆这些角。 这种覆盖物或涂层防止角部暴露于各向同性蚀刻溶液和清洁溶液,并且因此防止在角部比在结构或膜的平滑区域更高的材料去除速率。 还公开了包括至少一种类型的蚀刻阻挡剂的解决方案,包括湿蚀刻剂和清洁溶液,以及用于防止在膜或其它结构中由接缝,缝隙或凹陷形成的拐角处更高速率的材料去除的系统。 还公开了其中蚀刻阻挡剂被定位以防止各向同性蚀刻剂从不期望的高速率的膜或其它结构的表面中的接缝,裂缝或凹陷的角落移除材料的半导体器件结构。
    • 2. 发明授权
    • Wet etchants including at least one etch blocker
    • 湿蚀刻剂包括至少一个蚀刻阻挡剂
    • US08729002B2
    • 2014-05-20
    • US13413157
    • 2012-03-06
    • Nishant SinhaJ. Neil Greeley
    • Nishant SinhaJ. Neil Greeley
    • C25F3/02
    • C09K13/08C09K13/06H01L21/31055H01L21/31111
    • Methods for preventing isotropic removal of materials at corners formed by seams, keyholes, and other anomalies in films or other structures include use of etch blockers to cover or coat such corners. This covering or coating prevents exposure of the corners to isotropic etch solutions and cleaning solutions and, thus, prevents higher material removal rates at the corners than at smoother areas of the structure or film. Solutions, including wet etchants and cleaning solutions, that include at least one type of etch blocker are also disclosed, as are systems for preventing higher rates of material removal at corners formed by seams, crevices, or recesses in a film or other structure. Semiconductor device structures in which etch blockers are located so as to prevent isotropic etchants from removing material from corners of seams, crevices, or recesses of a film or other structure at undesirably high rates are also disclosed.
    • 在膜或其他结构中由接缝,键孔和其它异常形成的角部处的各向同性物质的各向同性除去方法包括使用蚀刻阻挡剂来覆盖或涂覆这些角。 这种覆盖物或涂层防止角部暴露于各向同性蚀刻溶液和清洁溶液,并且因此防止在角部比在结构或膜的平滑区域更高的材料去除速率。 还公开了包括至少一种类型的蚀刻阻挡剂的解决方案,包括湿蚀刻剂和清洁溶液,以及用于防止在膜或其它结构中由接缝,缝隙或凹陷形成的拐角处更高速率的材料去除的系统。 还公开了其中蚀刻阻挡剂被定位以防止各向同性蚀刻剂从不期望的高速率的接缝,裂缝或膜或其它结构的凹陷的角落移除材料的半导体器件结构。
    • 3. 发明申请
    • COMPOSITIONS AND METHODS FOR SUBSTANTIALLY EQUALIZING RATES AT WHICH MATERIAL IS REMOVED OVER AN AREA OF A STRUCTURE OR FILM THAT INCLUDES RECESSES OR CREVICES
    • 用于大量均衡化的材料的组合物和方法,其材料在包括封面或构件的结构或膜片的区域中被移除
    • US20090042401A1
    • 2009-02-12
    • US11834258
    • 2007-08-06
    • Nishant SinhaJ. Neil Greeley
    • Nishant SinhaJ. Neil Greeley
    • H01L21/302B32B9/06C09K13/00
    • C09K13/08C09K13/06H01L21/31055H01L21/31111
    • Methods for preventing isotropic removal of materials at corners formed by seams, keyholes, and other anomalies in films or other structures include use of etch blockers to cover or coat such corners. This covering or coating prevents exposure of the corners to isotropic etch solutions and cleaning solutions and, thus, higher material removal rates at the corners than at smoother areas of the structure or film from which material is removed. Solutions, including wet etchants and cleaning solutions, that include at least one type of etch blocker are also disclosed, as are systems for preventing higher rates of material removal at corners formed by seams, crevices, or recesses in a film or other structure. Semiconductor device structures in which etch blockers are located so as to prevent isotropic etchants from removing material from corners of seams, crevices, or recesses in a surface of a film or other structure at undesirably high rates are also disclosed.
    • 在膜或其他结构中由接缝,键孔和其它异常形成的角部处的各向同性物质的各向同性除去方法包括使用蚀刻阻挡剂来覆盖或涂覆这些角。 这种覆盖物或涂层防止角部暴露于各向同性蚀刻溶液和清洁溶液,并且因此在除去材料的结构或膜的更光滑的区域处在角部处更高的材料去除速率。 还公开了包括至少一种类型的蚀刻阻挡剂的解决方案,包括湿蚀刻剂和清洁溶液,以及用于防止在膜或其它结构中由接缝,缝隙或凹陷形成的拐角处更高速率的材料去除的系统。 还公开了其中蚀刻阻挡剂被定位以防止各向同性蚀刻剂从不期望的高速率的膜或其它结构的表面中的接缝,裂缝或凹陷的角落移除材料的半导体器件结构。
    • 4. 发明授权
    • Methods for substantially equalizing rates at which material is removed over an area of a structure or film that includes recesses or crevices
    • 用于在包括凹陷或缝隙的结构或膜的区域上去除材料的速率基本相等的方法
    • US08153019B2
    • 2012-04-10
    • US11834258
    • 2007-08-06
    • Nishant SinhaJ. Neil Greeley
    • Nishant SinhaJ. Neil Greeley
    • C09K13/08C11D7/28
    • C09K13/08C09K13/06H01L21/31055H01L21/31111
    • Methods for preventing isotropic removal of materials at corners formed by seams, keyholes, and other anomalies in films or other structures include use of etch blockers to cover or coat such corners. This covering or coating prevents exposure of the corners to isotropic etch solutions and cleaning solutions and, thus, prevents higher material removal rates at the corners than at smoother areas of the structure or film from which material is removed. Solutions, including wet etchants and cleaning solutions, that include at least one type of etch blocker are also disclosed, as are systems for preventing higher rates of material removal at corners formed by seams, crevices, or recesses in a film or other structure. Semiconductor device structures in which etch blockers are located so as to prevent isotropic etchants from removing material from corners of seams, crevices, or recesses in a surface of a film or other structure at undesirably high rates are also disclosed.
    • 在膜或其他结构中由接缝,键孔和其它异常形成的角部处的各向同性物质的各向同性除去方法包括使用蚀刻阻挡剂来覆盖或涂覆这些角。 这种覆盖物或涂层防止角部暴露于各向同性蚀刻溶液和清洁溶液,并且因此防止在角质层处更高的材料去除速率,而不是从其中去除材料的结构或膜的更光滑的区域。 还公开了包括至少一种类型的蚀刻阻挡剂的解决方案,包括湿蚀刻剂和清洁溶液,以及用于防止在膜或其它结构中由接缝,缝隙或凹陷形成的拐角处更高速率的材料去除的系统。 还公开了其中蚀刻阻挡剂被定位以防止各向同性蚀刻剂从不期望的高速率的膜或其它结构的表面中的接缝,裂缝或凹陷的角落移除材料的半导体器件结构。
    • 7. 发明授权
    • Methods of removing silicon oxide
    • 去除氧化硅的方法
    • US08252194B2
    • 2012-08-28
    • US12114380
    • 2008-05-02
    • Mark W. KiehlbauchJ. Neil GreeleyPaul A. Morgan
    • Mark W. KiehlbauchJ. Neil GreeleyPaul A. Morgan
    • H01L21/302
    • H01L21/31116H01L21/0337
    • A method of removing at least a portion of a silicon oxide material is disclosed. The silicon oxide is removed by exposing a semiconductor structure comprising a substrate and the silicon oxide to an ammonium fluoride chemical treatment and a subsequent plasma treatment, both of which may be effected in the same vacuum chamber of a processing apparatus. The ammonium fluoride chemical treatment converts the silicon oxide to a solid reaction product in a self-limiting reaction, the solid reaction product then being volatilized by the plasma treatment. The plasma treatment includes a plasma having an ion bombardment energy of less than or equal to approximately 20 eV. An ammonium fluoride chemical treatment including an alkylated ammonia derivative and hydrogen fluoride is also disclosed.
    • 公开了一种去除至少一部分氧化硅材料的方法。 通过将包括衬底和氧化硅的半导体结构暴露于氟化铵化学处理和随后的等离子体处理中去除氧化硅,二者都可以在处理设备的相同真空室中进行。 氟化铵化学处理在自限制反应中将氧化硅转化为固体反应产物,然后固体反应产物通过等离子体处理而挥发。 等离子体处理包括具有小于或等于约20eV的离子轰击能的等离子体。 还公开了包括烷基化氨衍生物和氟化氢的氟化铵化学处理。
    • 8. 发明申请
    • AMMONIUM FLUORIDE CHEMISTRIES
    • 氟化铵化学品
    • US20120309999A1
    • 2012-12-06
    • US13570866
    • 2012-08-09
    • Mark W. KiehlbauchJ. Neil GreeleyPaul A. Morgan
    • Mark W. KiehlbauchJ. Neil GreeleyPaul A. Morgan
    • C07F7/02
    • H01L21/31116H01L21/0337
    • A method of removing at least a portion of a silicon oxide material is disclosed. The silicon oxide is removed by exposing a semiconductor structure comprising a substrate and the silicon oxide to an ammonium fluoride chemical treatment and a subsequent plasma treatment, both of which may be effected in the same vacuum chamber of a processing apparatus. The ammonium fluoride chemical treatment converts the silicon oxide to a solid reaction product in a self-limiting reaction, the solid reaction product then being volatilized by the plasma treatment. The plasma treatment includes a plasma having an ion bombardment energy of less than or equal to approximately 20 eV. An ammonium fluoride chemical treatment including an alkylated ammonia derivative and hydrogen fluoride is also disclosed.
    • 公开了一种去除至少一部分氧化硅材料的方法。 通过将包括衬底和氧化硅的半导体结构暴露于氟化铵化学处理和随后的等离子体处理中去除氧化硅,二者都可以在处理设备的相同真空室中进行。 氟化铵化学处理在自限制反应中将氧化硅转化为固体反应产物,然后固体反应产物通过等离子体处理而挥发。 等离子体处理包括具有小于或等于约20eV的离子轰击能的等离子体。 还公开了包括烷基化氨衍生物和氟化氢的氟化铵化学处理。
    • 10. 发明申请
    • METHODS OF REMOVING SILICON OXIDE AND GASEOUS MIXTURES FOR ACHIEVING SAME
    • 去除氧化硅和气相混合物的方法
    • US20090275205A1
    • 2009-11-05
    • US12114380
    • 2008-05-02
    • Mark W. KiehlbauchJ. Neil GreeleyPaul A. Morgan
    • Mark W. KiehlbauchJ. Neil GreeleyPaul A. Morgan
    • H01L21/302
    • H01L21/31116H01L21/0337
    • A method of removing at least a portion of a silicon oxide material is disclosed. The silicon oxide is removed by exposing a semiconductor structure comprising a substrate and the silicon oxide to an ammonium fluoride chemical treatment and a subsequent plasma treatment, both of which may be effected in the same vacuum chamber of a processing apparatus. The ammonium fluoride chemical treatment converts the silicon oxide to a solid reaction product in a self-limiting reaction, the solid reaction product then being volatilized by the plasma treatment. The plasma treatment includes a plasma having an ion bombardment energy of less than or equal to approximately 20 eV. An ammonium fluoride chemical treatment including an alkylated ammonia derivative and hydrogen fluoride is also disclosed.
    • 公开了一种去除至少一部分氧化硅材料的方法。 通过将包括衬底和氧化硅的半导体结构暴露于氟化铵化学处理和随后的等离子体处理中去除氧化硅,二者都可以在处理设备的相同真空室中进行。 氟化铵化学处理在自限制反应中将氧化硅转化为固体反应产物,然后固体反应产物通过等离子体处理而挥发。 等离子体处理包括具有小于或等于约20eV的离子轰击能的等离子体。 还公开了包括烷基化氨衍生物和氟化氢的氟化铵化学处理。