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1. 发明授权

US5178669A Composition for reversible thermal recording media 失效
标题翻译：可逆热记录介质的组成
公开(公告)号：US5178669A
公开(公告)日：1993-01-12
申请号：US613874
申请日：1991-01-31
申请人： Niro Watanabe , Toyoko Shimizu , Yoshihiro Hino
发明人： Niro Watanabe , Toyoko Shimizu , Yoshihiro Hino
IPC分类号： B41M5/30 , B41M5/333
CPC分类号： B41M5/3335 , B41M5/305
摘要： A composition for reversible thermal recording media which contains an amphoteric compound having at least one of a phenolic hydroxyl group and a carboxyl group and also having an amino group either as a functional group or as part of a salt compound, and a leuco compound.
摘要翻译： PCT No.PCT / JP90 / 00464 Sec。 371日期1991年1月31日 102（e）日期1991年1月31日PCT提交1990年4月6日PCT公布。 WO90 / 11898 PCT出版物 1990年10月18日的日期。一种可逆热记录介质的组合物，其含有具有酚羟基和羧基中的至少一个并且还具有作为官能团的氨基或作为盐化合物的一部分的氨基的两性化合物，和无色复合物。

2. 发明授权

US5231505A Rewritable recording display apparatus and method of erasing record 失效
标题翻译：可记录的记录显示装置和擦除记录的方法
公开(公告)号：US5231505A
公开(公告)日：1993-07-27
申请号：US715925
申请日：1991-06-14
申请人： Niro Watanabe , Yoshihiro Hino , Masashi Tamura , Masaru Ohnishi , Keiki Yamada , Takashi Hiroishi , Narihiro Matoba
发明人： Niro Watanabe , Yoshihiro Hino , Masashi Tamura , Masaru Ohnishi , Keiki Yamada , Takashi Hiroishi , Narihiro Matoba
IPC分类号： B41M5/30
CPC分类号： B41M5/305
摘要： A rewritable recording/display apparatus using a rewritable recording medium in which color development reaction occurs by thermal energy at a predetermined temperature, and in which a color extinguishing reaction occurs by thermal energy at a temperature lower than the color development temperature, and which is capable of repeatingly performing recording and erasing of images. The apparatus also has a color developing heating device for recording an image on the rewritable recording medium by heating the rewritable recording medium, and an erasing heating device for erasing the image after the image has been recorded. Thus, the apparatus is designed so as to have a recording section simplified and reduced in size, and to reduce the maintenance and running cost. A method of erasing a rewritable record enables images to be erased completely or suitably in terms of practice and enables formation of high-quality image after erasing of the previous image.

3. 发明授权

US6045953A Photosensitive recording material, photosensitive recording medium, and process for producing hologram using this photosensitive recording medium 失效
标题翻译：感光记录材料，感光记录介质，以及使用该光敏记录介质制造全息图的方法
公开(公告)号：US6045953A
公开(公告)日：2000-04-04
申请号：US852206
申请日：1997-05-06
申请人： Yasushi Ohe , Hiromitsu Ito , Niro Watanabe
发明人： Yasushi Ohe , Hiromitsu Ito , Niro Watanabe
IPC分类号： G03F7/027 , G03C1/73 , G03F7/00 , G03F7/004 , G03F7/029 , G03F7/038 , G03H1/02 , G03H1/04 , G03H1/00
CPC分类号： G03F7/029 , G03F7/001 , G03F7/038 , G03F7/0045 , G03H2001/026 , G03H2260/12
摘要： A photosensitive recording material comprising an alicyclic, solvent-soluble, thermosetting epoxy oligomer capable of cationic polymerization, the oligomer being of a specified structure, an aliphatic monomer having at least one ethylenically unsaturated bond, the monomer being liquid at normal temperature and pressure, having a boiling point of 100.degree. C. or above at normal pressure and being capable of radical polymerization, a photoinitiator selected from the group consisting of i) a first photoinitiator capable of simultaneously generating a radical species that activates radical polymerization and a Br.o slashed.nsted acid or Lewis acid that activates cationic polymerization, upon exposure to actinic radiation, and ii) a second photoinitiator comprised of a radical polymerization photoinitiator capable of generating a radical species that activates radical polymerization upon exposure to actinic radiation and a cationic polymerization photoinitiator capable of generating a Br.o slashed.nsted acid or Lewis acid that activates cationic polymerization upon exposure to actinic radiation, and a spectral sensitizer that sensitizes the first photoinitiator or second photoinitiator; the aliphatic monomer being mixed in an amount of from 20 parts by weight to 80 parts by weight based on 100 parts by weight of the alicyclic epoxy oligomer. This photosensitive recording material is highly effective for producing a volume type phase hologram having superior diffraction efficiency, transparency, weatherability such as thermal resistance, and chemical stability.
摘要翻译：一种光敏记录材料，其包含能够进行阳离子聚合的脂环族，溶剂可溶的热固性环氧低聚物，具有特定结构的低聚物，具有至少一个烯属不饱和键的脂族单体，所述单体在常温常压下为液体，具有在常压下沸点为100℃以上并且能够进行自由基聚合的光引发剂，选自i）第一光引发剂，其能够同时产生激活自由基聚合的自由基物质和Br + 526 nsted 酸或路易斯酸，其在暴露于光化辐射下激活阳离子聚合，和ii）第二光引发剂，其包含能够产生在暴露于光化辐射时活化自由基聚合的自由基聚合光引发剂和能产生能量的阳离子聚合光引发剂一个Br + 526 nsted 暴露于光化辐射时激活阳离子聚合的酸或路易斯酸，以及使第一光引发剂或第二光引发剂敏化的光谱增感剂; 脂肪族单体以相对于100重量份脂环族环氧低聚物为20重量份〜80重量份的量混合。该感光记录材料对于制造具有优异的衍射效率，透明性，耐热性如耐热性和化学稳定性的体积型相位全息图是非常有效的。

4. 发明授权

US5658845A Reversible thermal recording medium and method of producing the same 失效
标题翻译：可逆热记录介质及其制造方法
公开(公告)号：US5658845A
公开(公告)日：1997-08-19
申请号：US462199
申请日：1995-06-05
申请人： Niro Watanabe , Yuji Nakatsu , Keiki Yamada , Masaru Ohnishi
发明人： Niro Watanabe , Yuji Nakatsu , Keiki Yamada , Masaru Ohnishi
IPC分类号： B41M5/337 , B41M5/28 , B41M5/30 , B41M5/323 , B41M5/333 , B41M5/36 , B41M5/26
CPC分类号： B41M5/3335 , B41M5/287 , B41M5/323 , B41M5/3375
摘要： A reversible thermal recording medium having a core material capable of being change in state by heat and a recording layer including capsules containing this core material. A repeatability corresponding to the limit of possible repeated recording/erasing effected by a physical or chemical change in the material constituting the recording can be obtained. A deterioration in image quality caused by transfer of a part of the recording layer to the heating unit can be prevented and repeat characteristics can be improved, thereby limiting the running cost.
摘要翻译：具有能够通过加热状态变化的芯材的可逆热记录介质和包含该芯材的胶囊的记录层。可以获得对应于由构成记录的材料的物理或化学变化所影响的可能的重复记录/擦除的限制的重复性。可以防止由于将记录层的一部分转印到加热单元而导致的图像质量的劣化，并且可以提高重复特性，从而限制运行成本。

5. 发明授权

US5344808A Intermediate transfer medium and process for producing image-recorded article making use of the same 失效
标题翻译：中间转印介质和使用相同图像记录制品的方法
公开(公告)号：US5344808A
公开(公告)日：1994-09-06
申请号：US111468
申请日：1993-08-25
申请人： Niro Watanabe , Tatsuya Morimitsu , Kazuhisa Hoshino , Akihiko Kobayashi , Kiyoshi Horie , Naoaki Shindo , Yoshiaki Tada , Takashi Sato
发明人： Niro Watanabe , Tatsuya Morimitsu , Kazuhisa Hoshino , Akihiko Kobayashi , Kiyoshi Horie , Naoaki Shindo , Yoshiaki Tada , Takashi Sato
IPC分类号： B41M5/382 , B41M5/42 , B41M5/52 , B41M5/035 , B41M5/38 , G02B5/32
CPC分类号： B41M5/42 , B41M5/38257 , B41M5/52 , Y10S428/913 , Y10S428/914 , Y10T428/24851 , Y10T428/24868 , Y10T428/24876 , Y10T428/24942
摘要： An intermediate transfer medium comprises a heat-resistant base sheet and provided thereon a release layer and an image-receiving adhesive layer on which an image pattern is formed by a sublimation transfer means in accordance with image data, said image-receiving adhesive layer, on which said image pattern has been formed, being transferred to a transfer substrate together with said release layer to produce an image-recorded article, wherein said image-receiving adhesive layer is comprised of a thermoplastic resin having a glass transition point of 50.degree. C. or above and a filler added to the thermoplastic resin and selected from the group consisting of an inorganic filler having a melting point of 200.degree. C. or above and an organic filler having a softening point or decomposition point of 200.degree. C. or above.
摘要翻译：中间转印介质包括耐热基片，其上设置有释放层和图像接收粘合剂层，根据图像数据，通过升华转印装置形成图像图案，所述图像接收粘合剂层在其上所述图像图案已经形成，与所述释放层一起转印到转印基板上以产生图像记录制品，其中所述图像接收粘合剂层由玻璃化转变点为50℃的热塑性树脂组成。并且添加到热塑性树脂中并选自熔点为200℃以上的无机填料和软化点或分解点为200℃以上的有机填料的填料。

6. 发明授权

US5837647A Reversible thermal recording medium 失效
公开(公告)号：US5837647A
公开(公告)日：1998-11-17
申请号：US784099
申请日：1997-01-15
申请人： Niro Watanabe , Yuji Nakatsu , Keiki Yamada , Masaru Ohnishi
发明人： Niro Watanabe , Yuji Nakatsu , Keiki Yamada , Masaru Ohnishi
IPC分类号： B41M5/337 , B41M5/28 , B41M5/30 , B41M5/323 , B41M5/333 , B41M5/36
CPC分类号： B41M5/3335 , B41M5/287 , B41M5/323 , B41M5/3375
摘要： A reversible thermal recording medium having a core material capable of being change in state by heat and a recording layer including capsules containing this core material. A repeatability corresponding to the limit of possible repeated recording/erasing effected by a physical or chemical change in the material constituting the recording can be obtained. A deterioration in image quality caused by transfer of a part of the recording layer to the heating unit can be prevented and repeat characteristics can be improved, thereby limiting the running cost.

7. 发明授权

US5837348A Reversible thermal recording medium and method of producing the same 失效
标题翻译：可逆热记录介质及其制造方法
公开(公告)号：US5837348A
公开(公告)日：1998-11-17
申请号：US782937
申请日：1997-01-13
申请人： Niro Watanabe , Yuji Nakatsu , Keiki Yamada , Masaru Ohnishi
发明人： Niro Watanabe , Yuji Nakatsu , Keiki Yamada , Masaru Ohnishi
IPC分类号： B41M5/337 , B41M5/28 , B41M5/30 , B41M5/323 , B41M5/333 , B41M5/36
CPC分类号： B41M5/3335 , B41M5/287 , B41M5/323 , B41M5/3375
摘要： A reversible thermal recording medium having a core material capable of being change in state by heat and a recording layer including capsules containing this core material. A repeatability corresponding to the limit of possible repeated recording/erasing effected by a physical or chemical change in the material constituting the recording can be obtained. A deterioration in image quality caused by transfer of a part of the recording layer to the heating unit can be prevented and repeat characteristics can be improved, thereby limiting the running cost.
摘要翻译：具有能够通过加热状态变化的芯材的可逆热记录介质和包含该芯材的胶囊的记录层。可以获得对应于由构成记录的材料的物理或化学变化所影响的可能的重复记录/擦除的限制的重复性。可以防止由于将记录层的一部分转印到加热单元而导致的图像质量的劣化，并且可以提高重复特性，从而限制运行成本。

8. 发明授权

US5672559A Reversible thermal recording medium and method of producing the same 失效
公开(公告)号：US5672559A
公开(公告)日：1997-09-30
申请号：US531865
申请日：1995-09-21
申请人： Niro Watanabe , Yuji Nakatsu , Keiki Yamada , Masaru Ohnishi
发明人： Niro Watanabe , Yuji Nakatsu , Keiki Yamada , Masaru Ohnishi
IPC分类号： B41M5/337 , B41M5/28 , B41M5/30 , B41M5/323 , B41M5/333 , B41M5/36 , B41M5/34
CPC分类号： B41M5/3335 , B41M5/287 , B41M5/323 , B41M5/3375
摘要： A reversible thermal recording medium having a core material capable of being change in state by heat and a recording layer including capsules containing this core material. A repeatability corresponding to the limit of possible repeated recording/erasing effected by a physical or chemical change in the material constituting the recording can be obtained. A deterioration in image quality caused by transfer of a part of the recording layer to the heating unit can be prevented and repeat characteristics can be improved, thereby limiting the running cost.

9. 发明授权

US5637551A Reversible thermal recording medium and method of producing same 失效
标题翻译：可逆热记录介质及其制造方法
公开(公告)号：US5637551A
公开(公告)日：1997-06-10
申请号：US714970
申请日：1996-09-17
申请人： Niro Watanabe , Yuji Nakatsu , Keiki Yamada , Masaru Ohnishi
发明人： Niro Watanabe , Yuji Nakatsu , Keiki Yamada , Masaru Ohnishi
IPC分类号： B41M5/337 , B41M5/28 , B41M5/30 , B41M5/323 , B41M5/333 , B41M5/36
CPC分类号： B41M5/3335 , B41M5/287 , B41M5/323 , B41M5/3375
摘要： A reversible thermal recording medium having a core material capable of being change in state by heat and a recording layer including capsules containing this core material. A repeatability corresponding to the limit of possible repeated recording/erasing effected by a physical or chemical change in the material constituting the recording can be obtained. A deterioration in image quality caused by transfer of a part of the recording layer to the heating unit can be prevented and repeat characteristics can be improved, thereby limiting the running cost.
摘要翻译：具有能够通过加热状态变化的芯材的可逆热记录介质和包含该芯材的胶囊的记录层。可以获得对应于由构成记录的材料的物理或化学变化所影响的可能的重复记录/擦除的限制的重复性。可以防止由于将记录层的一部分转印到加热单元而引起的图像质量的劣化，并且可以提高重复特性，从而限制运行成本。

10. 发明授权

US5278129A Rewritable thermosensitive recording medium 失效
标题翻译：可重写热敏记录介质
公开(公告)号：US5278129A
公开(公告)日：1994-01-11
申请号：US972939
申请日：1992-11-06
申请人： Niro Watanabe , Atsushi Kijima , Yuji Nakatsu , Susumu Watanabe
发明人： Niro Watanabe , Atsushi Kijima , Yuji Nakatsu , Susumu Watanabe
IPC分类号： B41M5/36
CPC分类号： B41M5/363
摘要： A rewritable thermosensitive recording medium having a recording layer, the transparency of which reversibly changes depending on the temperature thereof. Further, the recording layer contains a matrix material and an organic low-molecular-weight material dispersed in the matrix material as main components thereof. Moreover, an alicyclic dicarboxylic acid compound is added to the organic low-molecular-weight material dispersed in the matrix material. Furthermore, by adding the alicyclic dicarboxylic acid compound to the organic low-molecular-weight material, the eutectic point of the organic low-molecular-weight material and the alicyclic dicarboxylic acid compound becomes higher than the melting point of the organic low-molecular-weight material. Additionally, in spite of the fact that the amount of the alicyclic dicarboxylic acid compound to be added to the organic low-molecular-weight material is small, the difference between the eutectic point of the organic low-molecular-weight material and the alicyclic dicarboxylic acid compound and the melting point of the organic low-molecular-weight material is much larger than those obtained in cases of conventional recording materials. Consequently, the range of temperature, to which the recording layer should be heated for changing a state thereof from an opaque state to a transparent state, can be considerably enlarged without reducing the opacity of the recording layer.
摘要翻译：一种具有记录层的可重写热敏记录介质，其透明度根据其温度可逆地改变。此外，记录层含有分散在基质材料中的基质材料和有机低分子量材料作为其主要成分。此外，在分散在基质材料中的有机低分子量材料中加入脂环族二羧酸化合物。此外，通过向有机低分子量材料中添加脂环族二羧酸化合物，有机低分子量材料和脂环族二羧酸化合物的共晶点变得高于有机低分子量材料的熔点，重量材料。此外，尽管添加到有机低分子量材料中的脂环族二羧酸化合物的量小，但是有机低分子量材料的共晶点与脂环族二羧酸之间的差异酸性化合物和有机低分子量材料的熔点远远大于常规记录材料的熔点。因此，可以在不降低记录层的不透明性的情况下，显着地扩大将记录层从不透明状态改变为透明状态而被加热的温度范围。

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