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    • 2. 发明授权
    • Network copolymer crosslinked compositions and methods of making the same
    • 网络共聚物交联组合物及其制备方法
    • US08669337B2
    • 2014-03-11
    • US12646333
    • 2009-12-23
    • Ning LuSigfredo GonzalezEmie M. SilvestreGeng Wang
    • Ning LuSigfredo GonzalezEmie M. SilvestreGeng Wang
    • C08F230/02C08F220/38
    • C08F220/38C08F228/02C08F230/02
    • The present invention is directed to a network composition having the reaction product of: (i) at least one anionic polymerizable ethylenically unsaturated monomer (I) selected from the group consisting of [CH2═C(R3)C(O)OXa(C2H4O)b(C3H6O)c(C4H8O)d]pP(O)(OY)q(OZ)r where R3═H or alkyl of 1 to about 6 carbon atoms; X=alkyl, aryl, or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a is 0 to about 100; b is 0 to about 100; c is 0 to about 100; d is 0 to about 100; q is 0 to about 2; r is 0 to about 2; p is 1 to about 3 subject to the limitation that p+q+r=3; and Y and Z is H, or metal ion; and CH2═C(R3)C(O)OXa′(C2H4O)b′(C3H6O)c′(C4H8O)d′—SO3—Y) where R3═H or alkyl of from 1 to about 6 carbon atoms; X=alkyl, aryl, or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a′ is 0 to about 100; b′ is 0 to about 100; c′ is 0 to about 100; d′ is 0 to about 100; Y is H, or metal ion; and (ii) one or more additional monomers (II) selected from the group consisting of acrylic acid/acrylate, methacrylic acid/methacrylate, acrylamides, vinyl acetate and styrene, which are copolymerizable with (I); and (iii) a cross-linking agent (III), capable of copolymerizing with (I) and (II).
    • 本发明涉及一种具有以下反应产物的网络组合物:(i)至少一种选自[CH2 = C(R3)C(O)OXa(C2H4O))的阴离子可聚合烯属不饱和单体(I) b(C 3 H 6 O)c(C 4 H 8 O)d] pP(O)(OY)q(OZ)r其中R 3 = H或1至约6个碳原子的烷基; X = 0至约9个碳原子的烷基,芳基或烷芳基双基连接基团; a为0〜100; b为0至约100; c为0至约100; d为0至约100; q为0〜2; r为0〜2; p为1至约3,但受限于p + q + r = 3; Y和Z是H或金属离子; 和C 2 = C(R 3)C(O)O X a'(C 2 H 4 O)b'(C 3 H 6 O)c'(C 4 H 8 O)d-SO 3 -Y)其中R 3 = H或1至约6个碳原子的烷基; X = 0至约9个碳原子的烷基,芳基或烷芳基双基连接基团; a'为0至约100; b'为0至约100; c'为0至约100; d'为0至约100; Y是H或金属离子; 和(ii)可与(I)共聚的一种或多种选自丙烯酸/丙烯酸酯,甲基丙烯酸/甲基丙烯酸酯,丙烯酰胺,乙酸乙烯酯和苯乙烯的另外的单体(II); 和(iii)能够与(I)和(II)共聚的交联剂(III)。
    • 3. 发明授权
    • Network copolymer crosslinked emulsions and demulsifying compositions comprising the same
    • 网络共聚物交联乳液和包含其的破乳组合物
    • US08809444B2
    • 2014-08-19
    • US12646364
    • 2009-12-23
    • Ning LuSigfredo GonzalezErnie M. SilvestreGeng Wang
    • Ning LuSigfredo GonzalezErnie M. SilvestreGeng Wang
    • C08K5/541
    • C08F220/26A61K8/8152A61K2800/54A61Q1/02A61Q5/12C08F220/38C08F230/02
    • The present invention is directed to a network composition the reaction product of: (i) at least one anionic polymerizable ethylenically unsaturated monomer (I) selected from the group consisting of [CH2═C(R3)C(O)OXa(C2H4O)b(C3H6O)c(C4H8O)d]pP(O)(OY)q(OZ)r where R3═H or alkyl of 1 to about 6 carbon atoms; X=alkyl, aryl, or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a is 0 to about 100; b is 0 to about 100; c is 0 to about 100; d is 0 to about 100; q is 0 to about 2; r is 0 to about 2; p is 1 to about 3 subject to the limitation that p+q+r=3; and Y and Z is H, or metal ion; and CH2═C(R3)C(O)OXa′(C2H4O)b′(C3H6O)c′(C4H8O)d′—SO3—Y) where R3═H or alkyl of from 1 to about 6 carbon atoms; X=alkyl, aryl, or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a′ is 0 to about 100; b′ is 0 to about 100; c′ is 0 to about 100; d′ is 0 to about 100; Y is H, or metal ion; and (ii) one or more additional monomers (II) selected from the group consisting of acrylic acid/acrylate, methacrylic acid/methacrylate, acrylamides, vinyl acetate and styrene, which are copolymerizable with (I); and (iii) a cross-linking agent (III), capable of copolymerizing with (I) and (II).
    • 本发明涉及一种网络组合物,其反应产物为:(i)至少一种选自[CH 2 = C(R 3)C(O)O X a(C 2 H 4 O)b的阴离子可聚合烯属不饱和单体(I) (C 3 H 6 O)c(C 4 H 8 O)d] pP(O)(OY)q(OZ)r其中R 3 = H或1至约6个碳原子的烷基; X = 0至约9个碳原子的烷基,芳基或烷芳基双基连接基团; a为0〜100; b为0至约100; c为0至约100; d为0至约100; q为0〜2; r为0〜2; p为1至约3,但受限于p + q + r = 3; Y和Z是H或金属离子; (C 3 H 6 O)c'(C 4 H 8 O)d-SO 3-Y)其中R 3 = H或1至约6个碳原子的烷基; X = 0至约9个碳原子的烷基,芳基或烷芳基双基连接基团; a'为0至约100; b'为0至约100; c'为0至约100; d'为0至约100; Y是H或金属离子; 和(ii)可与(I)共聚的一种或多种选自丙烯酸/丙烯酸酯,甲基丙烯酸/甲基丙烯酸酯,丙烯酰胺,乙酸乙烯酯和苯乙烯的另外的单体(II); 和(iii)能够与(I)和(II)共聚的交联剂(III)。
    • 4. 发明申请
    • NETWORK COPOLYMER CROSSLINKED COMPOSITIONS AND PRODUCTS COMPRISING THE SAME
    • 网络共聚物交联组合物和包含该组合物的产品
    • US20110152083A1
    • 2011-06-23
    • US12975885
    • 2010-12-22
    • Ning LuSigfredo GonzalezEmie M. SilvestreGeng Wang
    • Ning LuSigfredo GonzalezEmie M. SilvestreGeng Wang
    • A01N57/12C08F230/02C08L43/02A61K8/81A61K31/80A01P11/00A01P7/04A01P3/00A01P13/00A61Q5/02A61Q5/12A61Q19/00A61Q15/00A61Q9/02A61Q9/04A61Q3/02A61Q5/06A61Q5/08A61Q17/04A61Q1/10A61Q1/02A61Q1/06A61Q1/04A61Q19/10A61Q1/14A61P17/10A61Q11/00A61P17/02A61P3/02A61P31/10A61P31/00A61P39/06C05D9/00C05C9/00C11D3/37
    • C09D4/00
    • The present invention provides for a household, agricultural, coating or personal care product composition containing the crosslinked reaction product of a network composition the reaction product of: (i) at least one anionic polymerizable ethylenically unsaturated monomer (I) selected from the group consisting of [CH2═C(R3)C(O)OXa(C2H4O)b(C3H6O)c(C4H8O)d]pP(O)(OY)q(OZ)r where R3═H or alkyl of 1 to about 6 carbon atoms; X=alkyl, aryl, or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a is 0 to about 100; b is 0 to about 100; c is 0 to about 100; d is 0 to about 100; q is 0 to about 2; r is 0 to about 2; p is 1 to about 3 subject to the limitation that p+q+r=3; and Y and Z is H, or metal ion; and CH2═C(R3)C(O)OXa′(C2H4O)b′(C3H6O)c′(C4H8O)d′—SO3—Y) where R3═H or alkyl of from 1 to about 6 carbon atoms; X=alkyl, aryl, or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a′ is 0 to about 100; b′ is 0 to about 100; c′ is 0 to about 100; d′ is 0 to about 100; Y is H, or metal ion; and (ii) one or more additional monomers (II) selected from the group consisting of acrylic acid/acrylate, methacrylic acid/methacrylate, acrylamides, vinyl acetate and styrene, which are copolymerizable with (I); and (iii) a cross-linking agent (III), capable of copolymerizing with (I) and (II).
    • 本发明提供一种家用,农业,涂料或个人护理产品组合物,其含有网状组合物的交联反应产物,反应产物为:(i)至少一种选自下组的阴离子可聚合烯属不饱和单体(I) [O 2 O](OZ)r其中R 3 = H或1至约6个碳原子的烷基(C 1 -C 4)C(O)O X a(C 2 H 4 O)b(C 3 H 6 O) ; X = 0至约9个碳原子的烷基,芳基或烷芳基双基连接基团; a为0〜100; b为0至约100; c为0至约100; d为0至约100; q为0〜2; r为0〜2; p为1至约3,但受限于p + q + r = 3; Y和Z为H或金属离子; (C 3 H 6 O)c'(C 4 H 8 O)d-SO 3-Y)其中R 3 = H或1至约6个碳原子的烷基; X = 0至约9个碳原子的烷基,芳基或烷芳基双基连接基团; a'为0至约100; b'为0至约100; c'为0至约100; d'为0至约100; Y是H或金属离子; 和(ii)可与(I)共聚的一种或多种选自丙烯酸/丙烯酸酯,甲基丙烯酸/甲基丙烯酸酯,丙烯酰胺,乙酸乙烯酯和苯乙烯的另外的单体(II); 和(iii)能够与(I)和(II)共聚的交联剂(III)。
    • 5. 发明申请
    • NETWORK COPOLYMER CROSSLINKED COMPOSITIONS AND METHODS OF MAKING THE SAME
    • 网络共聚物交联组合物及其制备方法
    • US20110152444A1
    • 2011-06-23
    • US12646333
    • 2009-12-23
    • Ning LUSigfredo GonzalezEmie M. SilvestreGeng Wang
    • Ning LUSigfredo GonzalezEmie M. SilvestreGeng Wang
    • C08L41/00C08F230/02C08F228/02C08L43/00
    • C08F220/38C08F228/02C08F230/02
    • The present invention is directed to a network composition having the reaction product of: (i) at least one anionic polymerizable ethylenically unsaturated monomer (I) selected from the group consisting of [CH2═C(R3)C(O)OXa(C2H4O)b(C3H6O)c(C4H8O)d]pP(O)(OY)q(OZ)r where R3═H or alkyl of 1 to about 6 carbon atoms; X=alkyl, aryl, or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a is 0 to about 100; b is 0 to about 100; c is 0 to about 100; d is 0 to about 100; q is 0 to about 2; r is 0 to about 2; p is 1 to about 3 subject to the limitation that p+q+r=3; and Y and Z is H, or metal ion; and CH2═C(R3)C(O)OXa′(C2H4O)b′(C3H6O)c′(C4H8O)d′—SO3—Y) where R3═H or alkyl of from 1 to about 6 carbon atoms; X=alkyl, aryl, or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a′ is 0 to about 100; b′ is 0 to about 100; c′ is 0 to about 100; d′ is 0 to about 100; Y is H, or metal ion; and (ii) one or more additional monomers (II) selected from the group consisting of acrylic acid/acrylate, methacrylic acid/methacrylate, acrylamides, vinyl acetate and styrene, which are copolymerizable with (I); and (iii) a cross-linking agent (III), capable of copolymerizing with (I) and (II).
    • 本发明涉及一种具有以下反应产物的网络组合物:(i)至少一种选自[CH 2 = C(R 3)C(O)O X a(C 2 H 4 O))的阴离子可聚合烯属不饱和单体(I) b(C 3 H 6 O)c(C 4 H 8 O)d] pP(O)(OY)q(OZ)r其中R 3 = H或1至约6个碳原子的烷基; X = 0至约9个碳原子的烷基,芳基或烷芳基双基连接基团; a为0〜100; b为0至约100; c为0至约100; d为0至约100; q为0〜2; r为0〜2; p为1至约3,但受限于p + q + r = 3; Y和Z是H或金属离子; (C 3 H 6 O)c'(C 4 H 8 O)d-SO 3-Y)其中R 3 = H或1至约6个碳原子的烷基; X = 0至约9个碳原子的烷基,芳基或烷芳基双基连接基团; a'为0至约100; b'为0至约100; c'为0至约100; d'为0至约100; Y是H或金属离子; 和(ii)可与(I)共聚的一种或多种选自丙烯酸/丙烯酸酯,甲基丙烯酸/甲基丙烯酸酯,丙烯酰胺,乙酸乙烯酯和苯乙烯的另外的单体(II); 和(iii)能够与(I)和(II)共聚的交联剂(III)。
    • 6. 发明申请
    • NETWORK COPOLYMER CROSSLINKED EMULSIONS AND DEMULSIFYING COMPOSITIONS COMPRISING THE SAME
    • 网络共聚物交联乳液和包含它们的组合物
    • US20110152423A1
    • 2011-06-23
    • US12646364
    • 2009-12-23
    • Ning LuSigfredo GonzalezEmie M. SilvestreGeng Wang
    • Ning LuSigfredo GonzalezEmie M. SilvestreGeng Wang
    • C08K5/541C08L43/02
    • C08F220/26A61K8/8152A61K2800/54A61Q1/02A61Q5/12C08F220/38C08F230/02
    • The present invention is directed to a network composition the reaction product of: (i) at least one anionic polymerizable ethylenically unsaturated monomer (I) selected from the group consisting of [CH2═C(R3)C(O)OXa(C2H4O)b(C3H6O)c(C4H8O)d]pP(O)(OY)q(OZ)r where R3═H or alkyl of 1 to about 6 carbon atoms; X=alkyl, aryl, or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a is 0 to about 100; b is 0 to about 100;c is 0 to about 100; d is 0 to about 100; q is 0 to about 2; r is 0 to about 2; p is 1 to about 3 subject to the limitation that p+q+r=3; and Y and Z is H, or metal ion; and CH2═C(R3)C(O)OXa′(C2H4O)b′(C3H6O)c′(C4H8O)d′—SO3—Y) where R3═H or alkyl of from 1 to about 6 carbon atoms; X=alkyl, aryl, or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a′ is 0 to about 100; b′ is 0 to about 100; c′ is 0 to about 100; d′ is 0 to about 100; Y is H, or metal ion; and (ii) one or more additional monomers (II) selected from the group consisting of acrylic acid/acrylate, methacrylic acid/methacrylate, acrylamides, vinyl acetate and styrene, which are copolymerizable with (I); and (iii) a cross-linking agent (III), capable of copolymerizing with (I) and (II).
    • 本发明涉及一种网络组合物,其反应产物为:(i)至少一种选自[CH 2 = C(R 3)C(O)O X a(C 2 H 4 O)b的阴离子可聚合烯属不饱和单体(I) (C 3 H 6 O)c(C 4 H 8 O)d] pP(O)(OY)q(OZ)r其中R 3 = H或1至约6个碳原子的烷基; X = 0至约9个碳原子的烷基,芳基或烷芳基双基连接基团; a为0〜100; b为0至约100; c为0至约100; d为0至约100; q为0〜2; r为0〜2; p为1至约3,但受限于p + q + r = 3; Y和Z是H或金属离子; (C 3 H 6 O)c'(C 4 H 8 O)d-SO 3-Y)其中R 3 = H或1至约6个碳原子的烷基; X = 0至约9个碳原子的烷基,芳基或烷芳基双基连接基团; a'为0至约100; b'为0至约100; c'为0至约100; d'为0至约100; Y是H或金属离子; 和(ii)可与(I)共聚的一种或多种选自丙烯酸/丙烯酸酯,甲基丙烯酸/甲基丙烯酸酯,丙烯酰胺,乙酸乙烯酯和苯乙烯的另外的单体(II); 和(iii)能够与(I)和(II)共聚的交联剂(III)。
    • 7. 发明授权
    • Clarifying agents for organomodified silicones
    • 有机改性硅氧烷的澄清剂
    • US08580285B2
    • 2013-11-12
    • US13156499
    • 2011-06-09
    • Benjamin FalkSigfredo Gonzalez
    • Benjamin FalkSigfredo Gonzalez
    • A61K8/06A61K8/02
    • C08L83/12A61K8/894A61K8/898A61K2800/10A61K2800/262A61Q19/00C08G77/388C08G77/46C08L83/08
    • There is provided herein a composition comprising a silicone copolymer of the general formula (I) MaMEcDdDEeTfTEgQh where M=R1R2R3SiO1/2; ME=R4R5RESiO1/2; D=R6R7SiO2/2; DE=R8RESiO2/2; T=R9RESiO2/2; T=R9SiO3/2; TE=RESiO2/2; and Q=SiO4/2; where R1, R2, R3, R4, R5, R6, R7, R8, and R9 are each independently selected from the group of monovalent hydrocarbon radicals RE is a monovalent radical defined as: —R10O—(C2H4O)h(C3H6O)i(C4H8O)i—R11 or —R12 with the provision that the copolymer must contain at least one RE group; R10 is a linear or branched divalent hydrocarbon radical containing from 3 to about 10 carbon atoms; R11 is H or —C(═O)CH3 or a monovalent saturated or unsaturated hydrocarbon radical, optionally containing heteroatoms and hydroxyl groups, containing from 1 to about 30 carbon atoms; R12 is a hydrocarbon radical, containing from 2 to about 30 carbon atoms and at least 1 hydroxyl group, optionally containing heteroatoms; subscripts a, b, c, d, e, f, and g are 0 or positive subject to the limitation a+b+c+d+e+f+g
    • 本文提供了包含通式(I)MaMEcDdDEeTfTEgQh的硅氧烷共聚物的组合物,其中M = R1R2R3SiO1 / 2; ME = R4R5RESiO1 / 2; D = R6R7SiO2 / 2; DE = R8RESiO2 / 2; T = R9RESiO2 / 2; T = R9SiO3 / 2; TE = RESiO2 / 2; 和Q = SiO4 / 2; 其中R 1,R 2,R 3,R 4,R 5,R 6,R 7,R 8和R 9各自独立地选自一价烃基RE中的一价基团,定义如下:-R10O-(C 2 H 4 O)h(C 3 H 6 O) C4H8O)i-R11或-R12,条件是共聚物必须含有至少一个RE基团; R 10是含有3至约10个碳原子的直链或支链二价烃基; R 11是H或-C(= O)CH 3或任选含有1至约30个碳原子的杂原子和羟基的一价饱和或不饱和烃基; R 12是含有2至约30个碳原子和至少1个羟基,任选地含有杂原子的烃基; 下标a,b,c,d,e,f和g分别为0或正,受限于a + b + c + d + e + f + g <1000; 下标h,i和j为0或正数,受限于h + i + j小于100; 和b)有机油。
    • 10. 发明申请
    • METHOD OF TREATING HAIR
    • 处理头发的方法
    • US20110268681A1
    • 2011-11-03
    • US12771089
    • 2010-04-30
    • Sigfredo GonzalezAnne DussaudJoAnne Tully
    • Sigfredo GonzalezAnne DussaudJoAnne Tully
    • A61K8/58A61Q5/00
    • There is provided herein a method of treating thermally and/or chemically damaged including the following steps: contacting thermally and/or chemically damaged hair with a hair treating composition comprising a aminosilicone of the general formula (I): MDxD′yM  (I) wherein: M=R1R22SiO1/2 D=R22SiO2/2, and D′=R2R3SiO2/2, and where R1 is an alkyl group having 12 to 50 carbon atoms, R2 is a substituted or un-substituted hydrocarbon group having 1 to about 6 carbon atoms, R3 is 3-aminopropyl group and/or a N-(2-aminoethyl)-3-aminopropyl group, x has a value of 1 to about 2,000, and y has a value of 1 to about 50.
    • 本文提供了热和/或化学损伤的处理方法,包括以下步骤:将热和/或化学损伤的毛发与包含通式(I)的氨基硅氧烷的头发处理组合物接触:MDxD'YM(I)其中 :M = R1R22SiO1 / 2D = R22SiO2 / 2,D'= R2R3SiO2 / 2,其中R1是具有12-50个碳原子的烷基,R2是具有1至约6个碳原子的取代或未取代的烃基 原子,R 3为3-氨基丙基和/或N-(2-氨基乙基)-3-氨基丙基,x为1至约2,000,y为1至约50的值。