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    • 3. 发明授权
    • Network copolymer crosslinked compositions and methods of making the same
    • 网络共聚物交联组合物及其制备方法
    • US08669337B2
    • 2014-03-11
    • US12646333
    • 2009-12-23
    • Ning LuSigfredo GonzalezEmie M. SilvestreGeng Wang
    • Ning LuSigfredo GonzalezEmie M. SilvestreGeng Wang
    • C08F230/02C08F220/38
    • C08F220/38C08F228/02C08F230/02
    • The present invention is directed to a network composition having the reaction product of: (i) at least one anionic polymerizable ethylenically unsaturated monomer (I) selected from the group consisting of [CH2═C(R3)C(O)OXa(C2H4O)b(C3H6O)c(C4H8O)d]pP(O)(OY)q(OZ)r where R3═H or alkyl of 1 to about 6 carbon atoms; X=alkyl, aryl, or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a is 0 to about 100; b is 0 to about 100; c is 0 to about 100; d is 0 to about 100; q is 0 to about 2; r is 0 to about 2; p is 1 to about 3 subject to the limitation that p+q+r=3; and Y and Z is H, or metal ion; and CH2═C(R3)C(O)OXa′(C2H4O)b′(C3H6O)c′(C4H8O)d′—SO3—Y) where R3═H or alkyl of from 1 to about 6 carbon atoms; X=alkyl, aryl, or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a′ is 0 to about 100; b′ is 0 to about 100; c′ is 0 to about 100; d′ is 0 to about 100; Y is H, or metal ion; and (ii) one or more additional monomers (II) selected from the group consisting of acrylic acid/acrylate, methacrylic acid/methacrylate, acrylamides, vinyl acetate and styrene, which are copolymerizable with (I); and (iii) a cross-linking agent (III), capable of copolymerizing with (I) and (II).
    • 本发明涉及一种具有以下反应产物的网络组合物:(i)至少一种选自[CH2 = C(R3)C(O)OXa(C2H4O))的阴离子可聚合烯属不饱和单体(I) b(C 3 H 6 O)c(C 4 H 8 O)d] pP(O)(OY)q(OZ)r其中R 3 = H或1至约6个碳原子的烷基; X = 0至约9个碳原子的烷基,芳基或烷芳基双基连接基团; a为0〜100; b为0至约100; c为0至约100; d为0至约100; q为0〜2; r为0〜2; p为1至约3,但受限于p + q + r = 3; Y和Z是H或金属离子; 和C 2 = C(R 3)C(O)O X a'(C 2 H 4 O)b'(C 3 H 6 O)c'(C 4 H 8 O)d-SO 3 -Y)其中R 3 = H或1至约6个碳原子的烷基; X = 0至约9个碳原子的烷基,芳基或烷芳基双基连接基团; a'为0至约100; b'为0至约100; c'为0至约100; d'为0至约100; Y是H或金属离子; 和(ii)可与(I)共聚的一种或多种选自丙烯酸/丙烯酸酯,甲基丙烯酸/甲基丙烯酸酯,丙烯酰胺,乙酸乙烯酯和苯乙烯的另外的单体(II); 和(iii)能够与(I)和(II)共聚的交联剂(III)。
    • 4. 发明授权
    • Clarifying agents for organomodified silicones
    • 有机改性硅氧烷的澄清剂
    • US08580285B2
    • 2013-11-12
    • US13156499
    • 2011-06-09
    • Benjamin FalkSigfredo Gonzalez
    • Benjamin FalkSigfredo Gonzalez
    • A61K8/06A61K8/02
    • C08L83/12A61K8/894A61K8/898A61K2800/10A61K2800/262A61Q19/00C08G77/388C08G77/46C08L83/08
    • There is provided herein a composition comprising a silicone copolymer of the general formula (I) MaMEcDdDEeTfTEgQh where M=R1R2R3SiO1/2; ME=R4R5RESiO1/2; D=R6R7SiO2/2; DE=R8RESiO2/2; T=R9RESiO2/2; T=R9SiO3/2; TE=RESiO2/2; and Q=SiO4/2; where R1, R2, R3, R4, R5, R6, R7, R8, and R9 are each independently selected from the group of monovalent hydrocarbon radicals RE is a monovalent radical defined as: —R10O—(C2H4O)h(C3H6O)i(C4H8O)i—R11 or —R12 with the provision that the copolymer must contain at least one RE group; R10 is a linear or branched divalent hydrocarbon radical containing from 3 to about 10 carbon atoms; R11 is H or —C(═O)CH3 or a monovalent saturated or unsaturated hydrocarbon radical, optionally containing heteroatoms and hydroxyl groups, containing from 1 to about 30 carbon atoms; R12 is a hydrocarbon radical, containing from 2 to about 30 carbon atoms and at least 1 hydroxyl group, optionally containing heteroatoms; subscripts a, b, c, d, e, f, and g are 0 or positive subject to the limitation a+b+c+d+e+f+g
    • 本文提供了包含通式(I)MaMEcDdDEeTfTEgQh的硅氧烷共聚物的组合物,其中M = R1R2R3SiO1 / 2; ME = R4R5RESiO1 / 2; D = R6R7SiO2 / 2; DE = R8RESiO2 / 2; T = R9RESiO2 / 2; T = R9SiO3 / 2; TE = RESiO2 / 2; 和Q = SiO4 / 2; 其中R 1,R 2,R 3,R 4,R 5,R 6,R 7,R 8和R 9各自独立地选自一价烃基RE中的一价基团,定义如下:-R10O-(C 2 H 4 O)h(C 3 H 6 O) C4H8O)i-R11或-R12,条件是共聚物必须含有至少一个RE基团; R 10是含有3至约10个碳原子的直链或支链二价烃基; R 11是H或-C(= O)CH 3或任选含有1至约30个碳原子的杂原子和羟基的一价饱和或不饱和烃基; R 12是含有2至约30个碳原子和至少1个羟基,任选地含有杂原子的烃基; 下标a,b,c,d,e,f和g分别为0或正,受限于a + b + c + d + e + f + g <1000; 下标h,i和j为0或正数,受限于h + i + j小于100; 和b)有机油。
    • 6. 发明申请
    • METHOD OF TREATING HAIR
    • 处理头发的方法
    • US20110268681A1
    • 2011-11-03
    • US12771089
    • 2010-04-30
    • Sigfredo GonzalezAnne DussaudJoAnne Tully
    • Sigfredo GonzalezAnne DussaudJoAnne Tully
    • A61K8/58A61Q5/00
    • There is provided herein a method of treating thermally and/or chemically damaged including the following steps: contacting thermally and/or chemically damaged hair with a hair treating composition comprising a aminosilicone of the general formula (I): MDxD′yM  (I) wherein: M=R1R22SiO1/2 D=R22SiO2/2, and D′=R2R3SiO2/2, and where R1 is an alkyl group having 12 to 50 carbon atoms, R2 is a substituted or un-substituted hydrocarbon group having 1 to about 6 carbon atoms, R3 is 3-aminopropyl group and/or a N-(2-aminoethyl)-3-aminopropyl group, x has a value of 1 to about 2,000, and y has a value of 1 to about 50.
    • 本文提供了热和/或化学损伤的处理方法,包括以下步骤:将热和/或化学损伤的毛发与包含通式(I)的氨基硅氧烷的头发处理组合物接触:MDxD'YM(I)其中 :M = R1R22SiO1 / 2D = R22SiO2 / 2,D'= R2R3SiO2 / 2,其中R1是具有12-50个碳原子的烷基,R2是具有1至约6个碳原子的取代或未取代的烃基 原子,R 3为3-氨基丙基和/或N-(2-氨基乙基)-3-氨基丙基,x为1至约2,000,y为1至约50的值。
    • 9. 发明授权
    • Network copolymer crosslinked emulsions and demulsifying compositions comprising the same
    • 网络共聚物交联乳液和包含其的破乳组合物
    • US08809444B2
    • 2014-08-19
    • US12646364
    • 2009-12-23
    • Ning LuSigfredo GonzalezErnie M. SilvestreGeng Wang
    • Ning LuSigfredo GonzalezErnie M. SilvestreGeng Wang
    • C08K5/541
    • C08F220/26A61K8/8152A61K2800/54A61Q1/02A61Q5/12C08F220/38C08F230/02
    • The present invention is directed to a network composition the reaction product of: (i) at least one anionic polymerizable ethylenically unsaturated monomer (I) selected from the group consisting of [CH2═C(R3)C(O)OXa(C2H4O)b(C3H6O)c(C4H8O)d]pP(O)(OY)q(OZ)r where R3═H or alkyl of 1 to about 6 carbon atoms; X=alkyl, aryl, or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a is 0 to about 100; b is 0 to about 100; c is 0 to about 100; d is 0 to about 100; q is 0 to about 2; r is 0 to about 2; p is 1 to about 3 subject to the limitation that p+q+r=3; and Y and Z is H, or metal ion; and CH2═C(R3)C(O)OXa′(C2H4O)b′(C3H6O)c′(C4H8O)d′—SO3—Y) where R3═H or alkyl of from 1 to about 6 carbon atoms; X=alkyl, aryl, or alkaryl diradical connecting group of 0 to about 9 carbon atoms; a′ is 0 to about 100; b′ is 0 to about 100; c′ is 0 to about 100; d′ is 0 to about 100; Y is H, or metal ion; and (ii) one or more additional monomers (II) selected from the group consisting of acrylic acid/acrylate, methacrylic acid/methacrylate, acrylamides, vinyl acetate and styrene, which are copolymerizable with (I); and (iii) a cross-linking agent (III), capable of copolymerizing with (I) and (II).
    • 本发明涉及一种网络组合物,其反应产物为:(i)至少一种选自[CH 2 = C(R 3)C(O)O X a(C 2 H 4 O)b的阴离子可聚合烯属不饱和单体(I) (C 3 H 6 O)c(C 4 H 8 O)d] pP(O)(OY)q(OZ)r其中R 3 = H或1至约6个碳原子的烷基; X = 0至约9个碳原子的烷基,芳基或烷芳基双基连接基团; a为0〜100; b为0至约100; c为0至约100; d为0至约100; q为0〜2; r为0〜2; p为1至约3,但受限于p + q + r = 3; Y和Z是H或金属离子; (C 3 H 6 O)c'(C 4 H 8 O)d-SO 3-Y)其中R 3 = H或1至约6个碳原子的烷基; X = 0至约9个碳原子的烷基,芳基或烷芳基双基连接基团; a'为0至约100; b'为0至约100; c'为0至约100; d'为0至约100; Y是H或金属离子; 和(ii)可与(I)共聚的一种或多种选自丙烯酸/丙烯酸酯,甲基丙烯酸/甲基丙烯酸酯,丙烯酰胺,乙酸乙烯酯和苯乙烯的另外的单体(II); 和(iii)能够与(I)和(II)共聚的交联剂(III)。
    • 10. 发明申请
    • CLARIFYING AGENTS FOR ORGANOMODIFIED SILICONES
    • 用于有机硅的澄清剂
    • US20120315229A1
    • 2012-12-13
    • US13156499
    • 2011-06-09
    • Benjamin FALKSigfredo Gonzalez
    • Benjamin FALKSigfredo Gonzalez
    • A61K8/895C08K5/101C08K5/11A61K47/34A61Q1/06A61Q1/10A61Q3/00A61Q3/02A61Q3/04A61Q5/00A61Q5/04A61Q5/06A61Q5/08A61Q5/10A61Q5/12A61Q9/02A61Q15/00A61Q17/02A61Q17/04A61Q19/00A61Q5/02C08L83/06
    • C08L83/12A61K8/894A61K8/898A61K2800/10A61K2800/262A61Q19/00C08G77/388C08G77/46C08L83/08
    • There is provided herein a composition comprising a silicone copolymer of the general formula (I) MaMEcDdDEeTfTEgQh where M=R1R2R3SiO1/2; ME=R4R5RESiO1/2; D=R6R7SiO2/2; DE=R8RESiO2/2; T=R9RESiO2/2; T=R9SiO3/2; TE=RESiO2/2; and Q=SiO4/2; where R1, R2, R3, R4, R5, R6, R7, R8, and R9 are each independently selected from the group of monovalent hydrocarbon radicals optionally containing heteroatoms, carbonyl groups, and hydroxyl groups, each independently having from about 1 to about 20 carbon atoms; RE is a monovalent radical defined as: —R10O—(C2H4O)h(C3H6O)i(C4H8O)i—R11 or —R12 with the provision that the copolymer must contain at least one RE group; R10 is a linear or branched divalent hydrocarbon radical containing from 3 to about 10 carbon atoms; R11 is H or —C(═O)CH3 or a monovalent saturated or unsaturated hydrocarbon radical, optionally containing heteroatoms and hydroxyl groups, containing from 1 to about 30 carbon atoms; R12 is a hydrocarbon radical, containing from 2 to about 30 carbon atoms and at least 1 hydroxyl group, optionally containing heteroatoms; subscripts a, b, c, d, e, f, and g are 0 or positive subject to the limitation a+b+c+d+e+f+g
    • 本文提供了包含通式(I)MaMEcDdDEeTfTEgQh的硅氧烷共聚物的组合物,其中M = R1R2R3SiO1 / 2; ME = R4R5RESiO1 / 2; D = R6R7SiO2 / 2; DE = R8RESiO2 / 2; T = R9RESiO2 / 2; T = R9SiO3 / 2; TE = RESiO2 / 2; 和Q = SiO4 / 2; 其中R 1,R 2,R 3,R 4,R 5,R 6,R 7,R 8和R 9各自独立地选自任选含有杂原子,羰基和羟基的一价烃基,其各自独立地具有约1至约20 碳原子 RE是定义为:-R10O-(C 2 H 4 O)h(C 3 H 6 O)i(C 4 H 8 O)i -R 11或-R 12的一价基团,条件是共聚物必须含有至少一个RE基团; R 10是含有3至约10个碳原子的直链或支链二价烃基; R 11是H或-C(= O)CH 3或任选含有1至约30个碳原子的杂原子和羟基的一价饱和或不饱和烃基; R 12是含有2至约30个碳原子和至少1个羟基,任选地含有杂原子的烃基; 下标a,b,c,d,e,f和g分别为0或正,受限于a + b + c + d + e + f + g <1000; 下标h,i和j为0或正数,受限于h + i + j小于100; 并且b)含有至少1个酯基-C(= O)O-的有机油,其表现出Hansen溶解度参数为14 <δD<18,4 <δH<10和3 <δP<15,并且其中组合物 粘度小于20,000cps。 还提供含有该组合物的硅氧烷乳液,含有所述硅氧烷乳液的个人护理组合物,以及处理含硅氧烷表面活性剂的方法,包括混合组合物的内容物。