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1. 发明授权

US5232471A Membranes formed from nitrated polyarylates 失效
标题翻译：由硝化多芳基化合物形成的膜
公开(公告)号：US5232471A
公开(公告)日：1993-08-03
申请号：US883316
申请日：1992-05-13
申请人： Ning Chen , Chao-Fong Tien , Stephanie M. Patton
发明人： Ning Chen , Chao-Fong Tien , Stephanie M. Patton
IPC分类号： B01D71/48 , C08G63/682 , C08G63/685
CPC分类号： C08G63/6826 , B01D71/48 , C08G63/6856
摘要： Polymeric membranes derived from aromatic polyarylates formed from nitrated dicarboxylic acid chlorides and cardo bisphenol having halo-substituents on all portions ortho to the hydroxyl groups are provided which exhibit high gas permselectivities.
摘要翻译：提供衍生自由硝化二羧酸氯化物形成的芳族多芳基化合物的聚合物膜和在羟基的所有部分上具有卤素取代基的卡诺双酚，其具有高的气体选择性。

2. 发明授权

US5451653A Curable crosslinking system with monobenzaldimine as crosslinker 失效
标题翻译：可变交联体系，以单苯甲醛亚胺为交联剂
公开(公告)号：US5451653A
公开(公告)日：1995-09-19
申请号：US365723
申请日：1994-12-28
申请人： Ning Chen , Chao-Fong Tien , Thomas M. Santosusso , Larry A. Wasowski , Robert K. Pinschmidt, Jr.
发明人： Ning Chen , Chao-Fong Tien , Thomas M. Santosusso , Larry A. Wasowski , Robert K. Pinschmidt, Jr.
IPC分类号： C08F8/30 , C08G18/83
CPC分类号： C08F8/30 , C08G18/833
摘要： This invention relates to improved crosslinking systems for polymeric dispersions and solutions having suitability for coatings, adhesives and use in many other applications. These systems are based upon crosslinkable polymers having a plurality of activated keto methylene groups, e.g., a beta diketone such as an acetoacetate or a keto cyano methylene functional groups and a crosslinkable component comprising an aldimine. A sufficient amount of the aldimine curing agent is used to effect reaction with the polymer containing the activated keto methylene groups and cure thereof. The improvement in the crosslinking system resides in the utilization of a monoaldimine having only one aldimine group and no other methylene reactive group as a crosslinking agent. Another improvement variation to that previously suggested comprises a redispersible polymer(s) containing activated methylene functionality and combined with the monoaldimine and the use of heterocyclic aldimine.
摘要翻译：本发明涉及用于聚合物分散体的改进的交联体系和具有适用于涂料，粘合剂和在许多其它应用中使用的溶液。这些体系基于具有多个活化的酮亚甲基的可交联聚合物，例如β-二酮如乙酰乙酸酯或酮基氰基亚甲基官能团，以及可交联组分，其包含醛亚胺。使用足够量的醛亚胺固化剂来与含有活化酮亚甲基的聚合物进行反应并固化。交联体系的改进在于利用仅具有一个醛亚胺基并且没有其它亚甲基反应性基团的单醛亚胺作为交联剂。与之前提出的另一改进的变化包括含有活化的亚甲基官能团的可再分散的聚合物并与单醛亚胺和使用杂环醛亚胺组合。

3. 发明授权

US5536784A Water borne crosslinkable compositions 失效
标题翻译：水性交联组合物
公开(公告)号：US5536784A
公开(公告)日：1996-07-16
申请号：US319365
申请日：1994-10-06
申请人： Chung-Ling Mao , Ning Chen , Chao-Fong Tien
发明人： Chung-Ling Mao , Ning Chen , Chao-Fong Tien
IPC分类号： C08F283/00 , C08G18/08 , C08G18/10 , C08G18/83 , C09D175/14 , C08L61/00
CPC分类号： C09D175/14 , C08F283/00 , C08G18/0823 , C08G18/10 , C08G18/831
摘要： This invention relates to improved water-based polymeric dispersions having suitability for coatings and other applications which are based upon polymers having a plurality of acetoacetate functional groups and a crosslinkable component comprising a plurality of aromatic aldimine. The basic acetoacetate/benzaldimine containing system comprises an aqueous polymeric dispersion wherein the polymer has a plurality of acetoacetate groups and an effective amount of a curing agent having a plurality of benzaldimine functional groups. The improvement in providing for water-stable polymeric dispersions suitable for coatings and other applications comprises an aqueous dispersion comprising a polymeric component preferably derived from a plurality of polymerizable ethylenically unsaturated monomer units having pendant araldimine or heterocyclic aldimine functionality. Acetoacetate containing monomers generally are used in forming the polymer and a preferred monomer acetoacetoxyethymethacrylate. The polymer incorporating a plurality of benzaldimine functionality generally is formed by emulsion or suspension polymerization and the adimine functionality is benzaldimine.
摘要翻译：本发明涉及对基于具有多个乙酰乙酸酯官能团的聚合物和包含多个芳族醛亚胺的可交联组分的涂料和其它应用的适用性的改进的水基聚合物分散体。含有乙酰乙酸酯/苯并二醛的碱性体系基本包括含水聚合物分散体，其中聚合物具有多个乙酰乙酸酯基团和有效量的具有多个苯甲酰亚胺官能团的固化剂。提供适用于涂料和其它应用的水稳定聚合物分散体的改进包括含有聚合物组分的水分散体，其优选衍生自具有侧链芳醛亚胺或杂环醛亚胺官能团的多个可聚合的烯属不饱和单体单元。含乙酰乙酸酯的单体通常用于形成聚合物和优选的乙酰乙酰氧基乙基甲基丙烯酸酯单体。掺入多种苯并二氮茚官能团的聚合物通常通过乳液或悬浮聚合形成，并且亚胺官能团是苯甲酰亚胺。

4. 发明授权

US5521246A Low temperature self-crosslinking aqueous urethane-vinyl polymers for coating applications 失效
标题翻译：用于涂料应用的低温自交联水性聚氨酯 - 乙烯基聚合物
公开(公告)号：US5521246A
公开(公告)日：1996-05-28
申请号：US280047
申请日：1994-07-25
申请人： Chao-Fong Tien , Chung-Ling Mao , Jeanine M. Snyder , Adalgery Beck
发明人： Chao-Fong Tien , Chung-Ling Mao , Jeanine M. Snyder , Adalgery Beck
IPC分类号： C08G18/08 , C08G18/10 , C08G18/83 , C09D175/04 , C08L75/00
CPC分类号： C08G18/10 , C08G18/0823 , C08G18/831 , C09D175/04
摘要： The present invention is directed to improved aqueous dispersions containing polyurethane/vinyl polymers and to a method for making such aqueous polyurethane-vinyl polymer dispersion. The aqueous dispersions comprise a urethane prepolymer having carboxyl functionality therein and a vinyl monomer polymerized therewith. The improvement in these dispersions resides in shelf-stability and self crosslinkability at low temperature with the polyurethanes having the carboxyl functionality in quaternary form and such dispersions containing polymer having pendant epoxide groups. When the aqueous dispersions are cast as a film and the water removed, crosslinking between the carboxyl group and epoxide group occurs.The aqueous polymer dispersion is prepared by(a) forming a carboxy-containing, water-dispersible, isocyanate-terminated polyurethane prepolymer,(b) adding a vinyl monomer mixture which contains a polyethylenically unsaturated monomer to the prepolymer to make a prepolymer/monomer mixture,(c) adding a tertiary amine capable of forming a quaternary ammonium carboxylate to the prepolymer/monomer mixture,(d) dispersing the prepolymer/monomer mixture in water,(e) optionally adding an oil-soluble free radical initiator and a chain extender to the aqueous dispersion,(f) polymerizing the vinyl monomers and competing the chain extension of the prepolymer by heating the aqueous dispersion, and,(g) incorporating a polymer having pendant epoxide groups into the emulsion.
摘要翻译：本发明涉及包含聚氨酯/乙烯基聚合物的改进的水性分散体和制备这种聚氨酯 - 乙烯基聚合物聚合物水分散体的方法。水分散体包含其中具有羧基官能团的氨基甲酸酯预聚物和与其聚合的乙烯基单体。这些分散体的改进在于在低温下的储存稳定性和自交联性，其中聚氨酯具有四元形式的羧基官能团，并且这种分散体含有具有侧链环氧基团的聚合物。当水性分散体以膜形式浇铸并除去水时，发生羧基和环氧基之间的交联。通过（a）形成含羧基的水分散性异氰酸酯封端的聚氨酯预聚物，（b）向预聚物中加入含有多烯属不饱和单体的乙烯基单体混合物以制备预聚物/单体混合物（c）向预聚物/单体混合物中加入能形成羧酸季铵的叔胺，（d）将预聚物/单体混合物分散在水中，（e）任选加入油溶性自由基引发剂和扩链剂（f）聚合乙烯基单体并通过加热水分散体来竞争预聚物的链延伸，和（g）将具有侧链环氧基团的聚合物掺入乳液中。

5. 发明授权

US5007945A Membranes formed from aromatic polyarylates 失效
标题翻译：由芳香族聚芳酯形成的膜
公开(公告)号：US5007945A
公开(公告)日：1991-04-16
申请号：US508763
申请日：1990-04-12
申请人： Chao-Fong Tien , Andrew D. Surnamer
发明人： Chao-Fong Tien , Andrew D. Surnamer
IPC分类号： B01D71/48 , C08G63/682
CPC分类号： C08G63/6826 , B01D71/48
摘要： The present invention is a class of polymeric membranes formed from aromatic polyarylates derived from dicarboxylic acid chlorides and cardo bisphenols having halo substituents on all portions ortho to the hydroxy functions. These polyarylate membranes exhibit high gas permselectivities and are useful in various gas separation applications.

6. 发明授权

US5594065A Two component waterborne crosslinkable polyurethane/acrylate-hybrid systems 失效
标题翻译：双组分水性交联聚氨酯/丙烯酸酯 - 混合体系
公开(公告)号：US5594065A
公开(公告)日：1997-01-14
申请号：US436534
申请日：1995-05-09
申请人： Chao-Fong Tien , Charles R. Hegedus , Thomas M. Santosusso , Jeanine M. Snyder , Lisa A. Mercando
发明人： Chao-Fong Tien , Charles R. Hegedus , Thomas M. Santosusso , Jeanine M. Snyder , Lisa A. Mercando
IPC分类号： C08G18/00 , C08G18/08 , C08G18/10 , C08G18/12 , C08G18/32 , C08G18/67 , C09D175/00 , C09D175/04 , C09D175/16 , C08L75/04 , C08F8/32
CPC分类号： C09D175/16 , C08G18/0823 , C08G18/10 , C08G18/12 , C08G18/672
摘要： An improved two component coating system based upon crosslinkable hydroxy containing polymers and a polyisocyanate crosslinker. The improvement resides in the utilization of a water-borne hydroxy-terminated polyurethane prepolymer/acrylate hybrid, preferably a hydroxy acrylate hybrid, in combination with a water-dispersible polyisocyanate. The two component coating composition can be prepared by:a) forming a carboxy-containing, water-dispersible, isocyanate-terminated polyurethane prepolymer,b) adding at least one acrylic monomer which contains a hydroxy-group to the carboxy-containing, water-dispersible, isocyanate-terminated polyurethane prepolymer to form a prepolymer/monomer mixture,c) adding an alkanolamine to the prepolymer/monomer mixture to introduce hydroxy functionality into the polyurethane prepolymer,d) dispersing the prepolymer/monomer mixture in water,e) adding an oil-soluble free radical initiator and a hydroxy-containing chain extender to the aqueous dispersion,f) polymerizing the acrylic monomers and completing the chain extension of the prepolymer by heating the aqueous dispersion, andg) mixing the resulting hybrid dispersion with a water-dispersible polyisocyanate.
摘要翻译：基于可交联羟基聚合物和多异氰酸酯交联剂的改进的双组分涂料体系。改进在于水性羟基封端的聚氨酯预聚物/丙烯酸酯杂化物，优选羟丙基酯杂化物与水分散性多异氰酸酯的组合的利用。双组分涂料组合物可以通过以下方法制备：a）形成含羧基的水分散性异氰酸酯封端的聚氨酯预聚物，b）将至少一种含有羟基的丙烯酸单体加入含羧基的水溶性聚氨酯预聚物中，可分散的异氰酸酯封端的聚氨酯预聚物以形成预聚物/单体混合物，c）将烷醇胺加入到预聚物/单体混合物中以将羟基官能团引入聚氨酯预聚物中，d）将预聚物/单体混合物分散在水中，e）油溶性自由基引发剂和含羟基的扩链剂，f）聚合丙烯酸单体并通过加热水分散体完成预聚物的链延伸，和g）将得到的混合分散体与水溶性自由基引发剂可分散多异氰酸酯。

7. 发明授权

US5013332A Membranes formed from rigid polyarylates 失效
标题翻译：由刚性多芳基化合物形成的膜
公开(公告)号：US5013332A
公开(公告)日：1991-05-07
申请号：US518400
申请日：1990-05-03
申请人： Andrew D. Surnamer , Chao-Fong Tien
发明人： Andrew D. Surnamer , Chao-Fong Tien
IPC分类号： B01D71/48 , C08G63/193 , C08G63/682
CPC分类号： B01D71/48 , C08G63/193 , C08G63/6826
摘要： The present invention is a class of polymeric membranes formed from aromatic polyarylates derived from dicarboxylic acid chlorides and conformationally rigid cyclohexyl bisphenols having halo or methyl substituents on all positions ortho to the hydroxy functions. These polarylate membranes exhibit high gas permselectivities and are useful in various gas separation applications.

8. 发明授权

US5977215A Low temperature self-crosslinking aqueous dispersions of urethane-vinyl polymers for coating applications 失效
标题翻译：用于涂料应用的聚氨酯 - 乙烯基聚合物的低温自交联水分散体
公开(公告)号：US5977215A
公开(公告)日：1999-11-02
申请号：US876785
申请日：1997-06-16
申请人： Chao-Fong Tien , Chung-Ling Mao , Jeanine M. Snyder , Adalgery Beck
发明人： Chao-Fong Tien , Chung-Ling Mao , Jeanine M. Snyder , Adalgery Beck
IPC分类号： C08G18/08 , C08G18/10 , C08G18/83 , C09D175/04 , C08L63/00
CPC分类号： C08G18/10 , C08G18/0823 , C08G18/831 , C09D175/04
摘要： The present invention is directed to improved aqueous dispersions containing polyurethane/vinyl polymers. The improved aqueous dispersions comprise polymer particles of a urethane prepolymer having carboxyl functionality therein and a vinyl monomer polymerized thereon, which are shelf stable and self crosslinkable at a low temperature. The polyurethanes have pendant carboxyl functionality in quaternary form and pendant epoxide groups provided by glycidyl acrylates and/or methacrylates. When the aqueous dispersions are cast as film and the water is removed, crosslinking between the carboxyl group and the epoxide group occurs.
摘要翻译：本发明涉及改进的含有聚氨酯/乙烯基聚合物的水性分散体。改进的水性分散体包括其中具有羧基官能团的聚氨酯预聚物和在其上聚合的乙烯基单体的聚合物颗粒，其在低温下是稳定的和可自交联的。聚氨酯具有季羧酸官能团和丙烯酸缩水甘油酯和/或甲基丙烯酸酯提供的环氧化物基团。当水性分散体浇铸成膜并除去水时，发生羧基和环氧基团之间的交联。

9. 发明授权

US5034027A Membranes formed from rigid aromatic polyamides 失效
标题翻译：由刚性芳族聚酰胺形成的膜
公开(公告)号：US5034027A
公开(公告)日：1991-07-23
申请号：US502584
申请日：1990-03-30
申请人： Chao-Fong Tien , Andrew D. Surnamer , Michael Langsam
发明人： Chao-Fong Tien , Andrew D. Surnamer , Michael Langsam
IPC分类号： B01D71/56 , C08G69/26
CPC分类号： B01D71/56 , C08G69/26
摘要： The present invention is a class of polymeric membranes formed from aromatic polyamides derived from dicarboxylic acid chlorides and cardo diamines having alkyl substituents on all portions ortho to the amine functions. These polyamide membranes exhibit high gas permselectivities and are useful in various gas separation applications.

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