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    • 1. 发明授权
    • Curable crosslinking system with monobenzaldimine as crosslinker
    • 可变交联体系,以单苯甲醛亚胺为交联剂
    • US5451653A
    • 1995-09-19
    • US365723
    • 1994-12-28
    • Ning ChenChao-Fong TienThomas M. SantosussoLarry A. WasowskiRobert K. Pinschmidt, Jr.
    • Ning ChenChao-Fong TienThomas M. SantosussoLarry A. WasowskiRobert K. Pinschmidt, Jr.
    • C08F8/30C08G18/83
    • C08F8/30C08G18/833
    • This invention relates to improved crosslinking systems for polymeric dispersions and solutions having suitability for coatings, adhesives and use in many other applications. These systems are based upon crosslinkable polymers having a plurality of activated keto methylene groups, e.g., a beta diketone such as an acetoacetate or a keto cyano methylene functional groups and a crosslinkable component comprising an aldimine. A sufficient amount of the aldimine curing agent is used to effect reaction with the polymer containing the activated keto methylene groups and cure thereof. The improvement in the crosslinking system resides in the utilization of a monoaldimine having only one aldimine group and no other methylene reactive group as a crosslinking agent. Another improvement variation to that previously suggested comprises a redispersible polymer(s) containing activated methylene functionality and combined with the monoaldimine and the use of heterocyclic aldimine.
    • 本发明涉及用于聚合物分散体的改进的交联体系和具有适用于涂料,粘合剂和在许多其它应用中使用的溶液。 这些体系基于具有多个活化的酮亚甲基的可交联聚合物,例如β-二酮如乙酰乙酸酯或酮基氰基亚甲基官能团,以及可交联组分,其包含醛亚胺。 使用足够量的醛亚胺固化剂来与含有活化酮亚甲基的聚合物进行反应并固化。 交联体系的改进在于利用仅具有一个醛亚胺基并且没有其它亚甲基反应性基团的单醛亚胺作为交联剂。 与之前提出的另一改进的变化包括含有活化的亚甲基官能团的可再分散的聚合物并与单醛亚胺和使用杂环醛亚胺组合。