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1. 发明授权

US4254240A Continuous process for the preparation of bromochlorinated butyl rubber 失效
标题翻译：连续制备溴代丁基橡胶的方法
公开(公告)号：US4254240A
公开(公告)日：1981-03-03
申请号：US74156
申请日：1979-09-10
申请人： Neil F. Newman , Robert Roper , Roger K. West
发明人： Neil F. Newman , Robert Roper , Roger K. West
IPC分类号： C08F8/00 , C08F8/20 , C08F8/22
CPC分类号： C08F8/20
摘要： A solution of butyl rubber in an inert solution such as n-hexane is halogenated in a continuous process using bromine chloride vapor and high intensity mixing means for both the halogenation and subsequent neutralization steps. Adjustment of the mole ratio of bromine chloride to isoprene, where an isobutylene-isoprene butyl copolymer is used, to less than about 1.5 to 1 prevents overhalogenation and significant molecular weight loss, while the use of bromine chloride vapor results in improved process safety.The doubly halogenated product, containing both bromine and chlorine in its structure can be vulcanized in the absence of sulfur, e.g., with zinc oxide. It is particularly useful in rubber compositions where the singly halogenated product is employed, but demonstrates product performance advantages compared to both brominated butyl rubber and chlorinated butyl rubber.
摘要翻译：丁基橡胶在惰性溶液如正己烷中的溶液在连续方法中被卤化，使用溴氯化物蒸气和用于卤化和随后的中和步骤的高强度混合装置。使用异丁烯 - 异戊二烯丁基共聚物的氯化异丁烯与异戊二烯的摩尔比（其中使用异丁烯 - 异戊二烯丁基共聚物）的调节小于约1.5比1可以防止过度卤化和显着的分子量损失，而溴氯化物蒸汽的使用导致改进的工艺安全性。在其结构中含有溴和氯的双卤代产物可以在不存在硫的情况下硫化，例如用氧化锌。在使用单卤代产物的橡胶组合物中特别有用，但与溴化丁基橡胶和氯化丁基橡胶相比，它们具有优异的产品性能。

2. 发明授权

US4900461A Viscosity modifier polymers (E-98) 失效
标题翻译：粘度调节剂聚合物（E-98）
公开(公告)号：US4900461A
公开(公告)日：1990-02-13
申请号：US194431
申请日：1988-05-13
申请人： Gary Ver Strate , Ricardo Bloch , Mark J. Struglinski , John E. Johnston , Roger K. West
发明人： Gary Ver Strate , Ricardo Bloch , Mark J. Struglinski , John E. Johnston , Roger K. West
IPC分类号： C08F4/60 , C08F4/639 , C08F4/68 , C08F210/02 , C08F210/16 , C10M143/02
CPC分类号： C10M143/02 , C08F210/02 , C08F210/16 , C10M2205/00 , C10M2205/02 , C10M2205/022 , C10M2205/10 , C10N2220/02
摘要： The present invention relates to novel copolymers of alpha-olefins comprised of intramolecularly heterogeneous and intermolecularly homogeneous copolymer chains.

3. 发明授权

US5798420A Ethylene-alpha olefin block copolymers and methods for production thereof 失效
标题翻译：乙烯-α-烯烃嵌段共聚物及其制备方法
公开(公告)号：US5798420A
公开(公告)日：1998-08-25
申请号：US858328
申请日：1997-05-19
申请人： Charles Cozewith , Gary William Ver Strate , Roger K. West , Gaetano A. Capone
发明人： Charles Cozewith , Gary William Ver Strate , Roger K. West , Gaetano A. Capone
IPC分类号： C08F4/639 , C08F4/68 , C08F10/00 , C08F297/06 , C08F297/08 , C08L53/00 , C09J153/00 , C10L1/16 , C10L1/198 , C10L1/238 , C10M143/02 , C10M143/14 , C10M149/02 , C10N20/02
CPC分类号： C10L1/198 , C08F297/06 , C08F297/08 , C09J153/00 , C10L1/1641 , C10L1/1666 , C10L1/238 , C10M143/02 , C10M2205/00 , C10M2205/02 , C10M2205/022 , C10M2205/10 , C10M2205/14 , C10M2215/04 , C10M2215/042 , C10M2215/26 , C10M2217/046 , C10M2217/06 , C10N2220/02 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： This invention relates to block polymers containing both crystalline and elastomeric blocks, the block copolymer having an A block and a B block. The A block is a polyethylene or an ethylene polymer optionally containing an alpha-olefin and optionally a non-conjugated diene, and is generally crystalline. The B block is an ethylene, .alpha.-olefin copolymer. Also disclosed is a process for manufacture of the block copolymers and methods for coupling the block copolymers. Coupled block copolymers are useful as thermoplastic elastomers exhibiting physical properties approaching those of crosslinked EP or EPDM elastomers, but showing thermal processability after coupling. The block copolymers of the present invention may also be used as a lubricant or fuel additive, as a plastics blend component, and as a component in hot melt adhesives.
摘要翻译：本发明涉及含有结晶和弹性体嵌段的嵌段聚合物，嵌段共聚物具有A嵌段和B嵌段。 A嵌段是任选含有α-烯烃和任选的非共轭二烯的聚乙烯或乙烯聚合物，并且通常是结晶的。 B嵌段是乙烯，α-烯烃共聚物。还公开了制备嵌段共聚物的方法和用于偶联嵌段共聚物的方法。耦合的嵌段共聚物可用作显示物理性质接近交联的EP或EPDM弹性体的热塑性弹性体，但显示偶联后的热加工性。本发明的嵌段共聚物也可以用作润滑剂或燃料添加剂，作为塑料共混组分，以及作为热熔粘合剂中的组分。

4. 发明授权

US5733980A Ethylene .alpha.-olefin block copolymers and methods for production thereof 失效
标题翻译：乙烯-α-烯烃嵌段共聚物及其制备方法
公开(公告)号：US5733980A
公开(公告)日：1998-03-31
申请号：US532372
申请日：1995-09-22
申请人： Charles Cozewith , Gary William Ver Strate , Roger K. West , Gaetano A. Capone
发明人： Charles Cozewith , Gary William Ver Strate , Roger K. West , Gaetano A. Capone
IPC分类号： C08F4/20 , C08F4/68 , C08F297/08 , C10C3/02 , C10L1/14 , C10L1/16 , C10L1/18 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/238 , C10L1/24 , C10L1/26 , C10L1/30 , C10M143/02 , C10M143/14 , C10M149/02 , C10N30/02 , C08L23/04 , C08L23/16
CPC分类号： C10L1/198 , C08F297/08 , C10C3/026 , C10L1/146 , C10L1/1633 , C10L1/1641 , C10L1/1666 , C10L1/1683 , C10L1/238 , C10L1/2437 , C10L1/2475 , C10L1/2493 , C10L1/2683 , C10L1/303 , C10M143/02 , C10M143/14 , C10M149/02 , C10L1/1966 , C10L1/206 , C10L1/2691 , C10M2205/00 , C10M2205/02 , C10M2205/022 , C10M2205/08 , C10M2205/10 , C10M2207/021 , C10M2207/023 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2215/04 , C10M2215/042 , C10M2215/223 , C10M2215/224 , C10M2215/26 , C10M2217/046 , C10M2217/06 , C10M2221/041 , C10M2225/00 , C10M2225/02 , C10N2220/02 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/106 , C10N2240/40 , C10N2240/402 , C10N2240/403 , C10N2240/404 , C10N2240/405 , C10N2240/406 , C10N2240/407 , C10N2240/408 , C10N2240/409 , C10N2260/00
摘要： This invention relates to block polymers containing both crystalline and elastomeric blocks, the block copolymer having an A block and a B block. The A block is a polyethylene or an ethylene polymer optionally containing an alpha-olefin and is generally crystalline. The B block contains an ethylene, .alpha.-olefin copolymer segment and optionally contain an ethylene, .alpha.-olefin, non-conjugated diene terpolymer segment. If the B block contains a diene containing segment, the diene containing segment is furthest from the junction of the A and the B blocks. Also disclosed is a process for manufacture of the block copolymers and methods for coupling the block copolymers. Coupled block copolymers are useful as thermoplastic elastomers exhibiting physical properties approaching those of crosslinked EP or EPDM elastomers, but showing thermal processability after coupling. The block copolymers of the present invention may also be used as a lubricant or fuel additive, as a plastics blend component, in bitumen blends, as a component in hot melt adhesives and as a component of roof sheeting compounds.
摘要翻译：本发明涉及含有结晶和弹性体嵌段的嵌段聚合物，嵌段共聚物具有A嵌段和B嵌段。 A嵌段是任选含有α-烯烃并且通常是结晶的聚乙烯或乙烯聚合物。 B嵌段含有乙烯，α-烯烃共聚物链段，任选地含有乙烯，α-烯烃，非共轭二烯三元共聚物链段。如果B嵌段含有含二烯烃链段，则含二烯烃链段距离A和B嵌段的结点最远。还公开了制备嵌段共聚物的方法和用于偶联嵌段共聚物的方法。偶联嵌段共聚物可用作显示物理性质接近交联的EP或EPDM弹性体的热塑性弹性体，但显示偶联后的热加工性。本发明的嵌段共聚物也可用作沥青混合物中的润滑剂或燃料添加剂，作为塑料混合物组分，作为热熔粘合剂中的组分和作为屋顶薄片化合物的组分。

5. 发明授权

US4804794A Viscosity modifier polymers 失效
标题翻译：粘度调节剂聚合物
公开(公告)号：US4804794A
公开(公告)日：1989-02-14
申请号：US072825
申请日：1987-07-13
申请人： Gary Ver Strate , Ricardo Bloch , Mark J. Struglinski , John E. Johnston , Roger K. West
发明人： Gary Ver Strate , Ricardo Bloch , Mark J. Struglinski , John E. Johnston , Roger K. West
IPC分类号： C08F4/60 , C08F4/639 , C08F4/68 , C08F210/02 , C08F210/16 , C10M143/02 , C10L1/16
CPC分类号： C10M143/02 , C08F210/02 , C08F210/16 , C10M2205/00 , C10M2205/02 , C10M2205/022 , C10M2205/10 , C10N2220/02
摘要： The present invention relats to novel copolymers of alpha-olefins comprised of intramolecularly heterogeneous and intermolecularly homogeneous copolymer chains.

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