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1. 发明授权

US4501859A Process for the manufacture of halogenated polymers 失效
标题翻译：制备卤化聚合物的方法
公开(公告)号：US4501859A
公开(公告)日：1985-02-26
申请号：US481279
申请日：1983-04-01
申请人： Neil F. Newman , Ronald C. Kowalski
发明人： Neil F. Newman , Ronald C. Kowalski
IPC分类号： C08C19/12 , C08F8/20 , C08F8/22
CPC分类号： C08C19/12 , C08F8/20
摘要： Continuous halogenation of polymers is achieved in an extruder-reactor employing reactants, conditions and design features directed to maximizing mixing and contact of the polymer with the halogenating agent and neutralizing agent while simultaneously minimizing side reactions and polymer degradation. The polymer passes through three extruder-reactor zones under controlled conditions to achieve halogenation: feed, reaction, neutralization, and optionally a wash and exit zone. Various halogenated polymers are produced, for example, halogenated linear low density polyethylene and halogenated butyl rubber.
摘要翻译：聚合物的连续卤化在使用反应物的挤出机反应器中实现，条件和设计特征旨在使聚合物与卤化剂和中和剂的混合和接触最大化，同时最小化副反应和聚合物降解。聚合物在受控条件下通过三个挤出机 - 反应器区域，以实现卤化：进料，反应，中和，以及任选的洗涤和出口区域。制备各种卤化聚合物，例如卤化线性低密度聚乙烯和卤化丁基橡胶。

2. 发明授权

US3985832A Method of covulcanizing chlorinated low unsaturation rubbers with high unsaturation rubber 失效
标题翻译：氯化低不饱和度橡胶与高不饱和度橡胶共硫化的方法
公开(公告)号：US3985832A
公开(公告)日：1976-10-12
申请号：US537857
申请日：1975-01-02
申请人： Neil F. Newman
发明人： Neil F. Newman
IPC分类号： C08L23/00 , B60C5/14 , C08J3/24 , C08J5/12 , C08K3/10 , C08K3/16 , C08K5/00 , C08K5/02 , C08L1/00 , C08L23/26 , C08L23/28 , C08L27/00 , C08L101/00 , C08L9/00 , C08C19/32
CPC分类号： C08J5/12 , C08K3/16 , C08K5/0025 , C08K5/02 , C08L23/283 , C08J2323/28
摘要： Disclosed are chlorinated low unsaturation rubbers exhibiting improved adhesion properties and improved covulcanization ability with high unsaturation rubbers. Also disclosed is a method of preparing these rubbers which comprises reacting the chlorinated rubber with certain bromine and/or iodine containing compounds.
摘要翻译：本发明公开了具有改善的粘合性能和提高的高不饱和性橡胶的共硫化能力的氯化低不饱和性橡胶。还公开了制备这些橡胶的方法，其包括使氯化橡胶与某些含溴和/或碘的化合物反应。

3. 依法登记的发明

USH1475H Process for halogenating para-alkyl styrene/isoolefin copolymers 失效
标题翻译：卤代对位烷基苯乙烯/异烯烃共聚物的方法
公开(公告)号：USH1475H
公开(公告)日：1995-08-01
申请号：US547480
申请日：1990-07-02
申请人： Neil F. Newman , Donald A. White , Lawrence W. Flatley , William M. Davis
发明人： Neil F. Newman , Donald A. White , Lawrence W. Flatley , William M. Davis
IPC分类号： C08F8/20 , C08F12/08 , C08C19/14
CPC分类号： C08F8/20
摘要： A process for halogenating copolymers of an isoolefin having from 4 to 7 carbon atoms and a para-alkylstyrene in the melt phase is provided in which the halogenation reaction is performed in a continuous flow device, such as an extruder-reactor. Halogenated copolymers produced by the process are also provided.

4. 发明授权

US5077345A Halogenation of polymers with improved neutralization 失效
标题翻译：聚合物的改性改性中和
公开(公告)号：US5077345A
公开(公告)日：1991-12-31
申请号：US486773
申请日：1990-03-01
申请人： Neil F. Newman , Irwin J. Gardner
发明人： Neil F. Newman , Irwin J. Gardner
IPC分类号： C08F8/20 , C08L23/28
CPC分类号： C08F8/20 , C08L23/283 , Y02P20/582
摘要： A halogenation process is provided for halogenating a polymer, in which process the halogenation reaction product is neutralized by reaction of an aqueous alkaline material in the presence of a critical limited amount of alcohol to increase the neutralization rate.
摘要翻译：提供用于卤化聚合物的卤化方法，其中卤化反应产物在临界有限量的醇存在下通过碱性水溶液的反应中和以提高中和率。

5. 发明授权

US4650832A Process for the manufacture of halogenated polymers 失效
标题翻译：制备卤化聚合物的方法
公开(公告)号：US4650832A
公开(公告)日：1987-03-17
申请号：US788425
申请日：1985-10-17
申请人： Ronald C. Kowalski , William M. Davis , Neil F. Newman , Zisis A. Foroulis , Francis P. Baldwin
发明人： Ronald C. Kowalski , William M. Davis , Neil F. Newman , Zisis A. Foroulis , Francis P. Baldwin
IPC分类号： C08F8/20 , C08F8/22
CPC分类号： C08F8/20
摘要： In a process for the continuous halogenation of polymers by contacting polymer and halogenating agent in a continuous flow device in which means are provided for disengaging reaction by-products and unreacted halogenating agent from the reaction mixture, by deforming and disrupting the halogenated polymer surface and injecting an inert and/or reactive gas into the halogenated polymers immediately after reaction thereby neutralizing the product. In a preferred embodiment the process is carried out in an extruder-reactor and an optional, supplementary inert and/or reactive gas scrubbing zone is included. The process is amenable to saturated and unsaturated polymers.
摘要翻译：在聚合物和卤化剂在连续流动装置中连续卤化聚合物的方法中，其中提供了用于使反应副产物和未反应的卤化剂从反应混合物中分离的方法，通过变形和破坏卤化聚合物表面并注入惰性和/或反应性气体在反应后立即进入卤代聚合物，从而中和产物。在优选的实施方案中，该方法在挤出机 - 反应器中进行，并且包括任选的补充的惰性和/或反应性气体洗涤区。该方法适用于饱和和不饱和聚合物。

6. 发明授权

US4632963A Halogenated butyl rubber 失效
公开(公告)号：US4632963A
公开(公告)日：1986-12-30
申请号：US597187
申请日：1984-04-05
申请人： Irwin J. Gardner , James V. Fusco , Neil F. Newman , Ronald C. Kowalski , William M. Davis , Francis P. Baldwin
发明人： Irwin J. Gardner , James V. Fusco , Neil F. Newman , Ronald C. Kowalski , William M. Davis , Francis P. Baldwin
IPC分类号： C08L23/28 , C08F8/00 , C08F8/18 , C08F8/20 , C08F8/48 , C08L1/00 , C08L21/00 , C08L23/00 , C08L23/26 , C08L27/00 , C08L101/00 , C08F8/22
CPC分类号： C08F8/18 , C08F8/48
摘要： An improved halogenated butyl rubber wherein the polymer has a conjugated diene content of less than 0.25 mole % and a halogen content of at least 0.6 wt. %; at least 20 mole % of the halogen being in a primary allylic configuration.

7. 发明授权

US4554326A Process for the manufacture of halogenated polymers 失效
标题翻译：制备卤化聚合物的方法
公开(公告)号：US4554326A
公开(公告)日：1985-11-19
申请号：US481320
申请日：1983-04-01
申请人： Ronald C. Kowalski , William M. Davis , Neil F. Newman , Z. Andrew Foroulis , Francis P. Baldwin
发明人： Ronald C. Kowalski , William M. Davis , Neil F. Newman , Z. Andrew Foroulis , Francis P. Baldwin
IPC分类号： C08F8/00 , C08C19/12 , C08F8/20 , C08F8/22
CPC分类号： C08F8/20 , C08C19/12
摘要： In a process for the continuous halogenation of polymers by contacting polymer and halogenating agent in a continuous flow device in which the polymer and halogenating agent are subjected to deformation during reaction and in which means are provided for disengaging reaction by-products and unreacted halogenating agent from the reaction mixture, a significant process improvement is realized by injecting an inert gas into the halogenated polymers immediately after reaction in order to neutralize the product. In a preferred embodiment the process is carried out in an extruder-reactor and an optional, supplementary inert gas scrubbing zone is included. The process is amenable to saturated and unsaturated polymers.
摘要翻译：在聚合物和卤化剂在连续流动装置中使聚合物和卤化剂在反应期间经受变形的连续卤化反应过程中，并且提供了用于使反应副产物和未反应的卤化剂从反应混合物中，通过在反应后立即向惰性气体中注入惰性气体以中和产物来实现显着的工艺改进。在优选的实施方案中，该方法在挤出机 - 反应器中进行，并且包括任选的补充惰性气体洗涤区。该方法适用于饱和和不饱和聚合物。

8. 发明授权

US4548995A Process for the manufacture of halogenated polymers 失效
标题翻译：制备卤化聚合物的方法
公开(公告)号：US4548995A
公开(公告)日：1985-10-22
申请号：US651621
申请日：1984-09-17
申请人： Ronald C. Kowalski , William M. Davis , Neil F. Newman , Z. Andrew Foroulis , Francis P. Baldwin
发明人： Ronald C. Kowalski , William M. Davis , Neil F. Newman , Z. Andrew Foroulis , Francis P. Baldwin
IPC分类号： C08F8/00 , C08C19/12 , C08F8/20 , C08F8/22
CPC分类号： C08F8/20 , C08C19/12
摘要： In a process for the continuous halogenation of polymers by contacting polymer and halogenating agent in a continuous flow device in which means are provided for disengaging reaction by-products and unreacted halogenating agent from the reaction mixture, by deforming and disrupting the halogenated polymer surface and injecting an inert gas into the halogenated polymers immediately after reaction thereby neutralizing the product. In a preferred embodiment the process is carried out in an extruder-reactor and an optional, supplementary inert gas scrubbing zone is included. The process is amenable to saturated and unsaturated polymers.
摘要翻译：在聚合物和卤化剂在连续流动装置中连续卤化聚合物的方法中，其中提供了用于使反应副产物和未反应的卤化剂从反应混合物中分离的方法，通过变形和破坏卤化聚合物表面并注入在反应后立即将惰性气体引入卤化聚合物中，从而中和产物。在优选的实施方案中，该方法在挤出机 - 反应器中进行，并且包括任选的补充惰性气体洗涤区。该方法适用于饱和和不饱和聚合物。

9. 发明授权

US4384072A Process for the manufacture of halogenated elastomers 失效
标题翻译：制造卤化弹性体的方法
公开(公告)号：US4384072A
公开(公告)日：1983-05-17
申请号：US306882
申请日：1981-09-30
申请人： Neil F. Newman , Ronald C. Kowalski
发明人： Neil F. Newman , Ronald C. Kowalski
IPC分类号： C08F8/00 , C08C19/12 , C08C19/20 , C08F8/18 , C08F8/20 , C08F8/34 , C08F8/22
CPC分类号： C08F8/20 , C08C19/12 , Y02P20/143
摘要： Continuous halogenation of olefinically unsaturated rubber is achieved in an extruder - reactor employing reactants, conditions and design features directed to maximizing mixing and contact of the rubber with the halogenating agent and neutralizing agent while simultaneously minimizing side reactions and polymer degradation. The rubber passes through five extruder-reactor zones under controlled conditions to achieve halogenation: feed, reaction, neutralization, wash and exit. The halogenated rubber, for example, halogenated butyl rubber can be vulcanized in the absence of sulfur, e.g., with zinc oxide and stearic acid, and is useful in all applications where commercially available chlorinated and brominated rubbers are presently employed.
摘要翻译：在使用反应物的挤出机 - 反应器中实现烯属不饱和橡胶的连续卤化，条件和设计特征旨在使橡胶与卤化剂和中和剂的混合和接触最大化，同时最小化副反应和聚合物降解。橡胶在受控条件下通过五个挤出机 - 反应器区域以实现卤化：进料，反应，中和，洗涤和排出。卤化橡胶例如卤化丁基橡胶可以在不存在硫的情况下硫化，例如用氧化锌和硬脂酸硫化，并且可用于目前使用市售的氯化和溴化橡胶的所有应用中。

10. 发明授权

US4254240A Continuous process for the preparation of bromochlorinated butyl rubber 失效
标题翻译：连续制备溴代丁基橡胶的方法
公开(公告)号：US4254240A
公开(公告)日：1981-03-03
申请号：US74156
申请日：1979-09-10
申请人： Neil F. Newman , Robert Roper , Roger K. West
发明人： Neil F. Newman , Robert Roper , Roger K. West
IPC分类号： C08F8/00 , C08F8/20 , C08F8/22
CPC分类号： C08F8/20
摘要： A solution of butyl rubber in an inert solution such as n-hexane is halogenated in a continuous process using bromine chloride vapor and high intensity mixing means for both the halogenation and subsequent neutralization steps. Adjustment of the mole ratio of bromine chloride to isoprene, where an isobutylene-isoprene butyl copolymer is used, to less than about 1.5 to 1 prevents overhalogenation and significant molecular weight loss, while the use of bromine chloride vapor results in improved process safety.The doubly halogenated product, containing both bromine and chlorine in its structure can be vulcanized in the absence of sulfur, e.g., with zinc oxide. It is particularly useful in rubber compositions where the singly halogenated product is employed, but demonstrates product performance advantages compared to both brominated butyl rubber and chlorinated butyl rubber.
摘要翻译：丁基橡胶在惰性溶液如正己烷中的溶液在连续方法中被卤化，使用溴氯化物蒸气和用于卤化和随后的中和步骤的高强度混合装置。使用异丁烯 - 异戊二烯丁基共聚物的氯化异丁烯与异戊二烯的摩尔比（其中使用异丁烯 - 异戊二烯丁基共聚物）的调节小于约1.5比1可以防止过度卤化和显着的分子量损失，而溴氯化物蒸汽的使用导致改进的工艺安全性。在其结构中含有溴和氯的双卤代产物可以在不存在硫的情况下硫化，例如用氧化锌。在使用单卤代产物的橡胶组合物中特别有用，但与溴化丁基橡胶和氯化丁基橡胶相比，它们具有优异的产品性能。

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