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1. 发明授权

US09644069B2 Polymer of fluorine-containing sulfonated poly(arylene ether)s and method of manufacturing the same 有权
公开(公告)号：US09644069B2
公开(公告)日：2017-05-09
申请号：US14792639
申请日：2015-07-07
申请人： National Sun Yat-sen University
发明人： Wen-yao Huang , Hsu-feng Lee , Benjamin Britton , Chun-che Lee , Steven Holdcroft , Jun-jie Pang , Yi-yun Hsu , Yu-chao Tseng
IPC分类号： C08G14/00 , C08G65/48 , C09D171/12 , B01J39/20
CPC分类号： H01M8/1067 , B01J39/19 , B01J39/20 , C08G65/40 , C08G65/4025 , C08G65/48 , C08G2650/02 , C08G2650/48 , C08J5/2262 , C08J2371/10 , C09D171/12 , H01M8/1025 , H01M8/1039 , H01M2008/1095
摘要： A polymer of fluorine-containing sulfonated poly(arylene ether)s and a manufacturing method thereof are provided. The polymer is formed by processing a nucleophilic polycondensation between a fluorine-containing monomer having an electron-withdrawing group and a multi-phenyl monomer. A main structure of the polymer of fluorine-containing sulfonated poly(arylene ether)s has a first portion with fluoro or trifluoromethyl substituted phenyl groups, and a second portion with sulfonated phenyl groups.

2. 发明授权

US09209472B2 Polymer of sulfonated poly(arylene ether)s and manufacturing method thereof 有权
标题翻译：磺化聚（亚芳基醚）聚合物及其制备方法
公开(公告)号：US09209472B2
公开(公告)日：2015-12-08
申请号：US14669019
申请日：2015-03-26
申请人： National Sun Yat-sen University
发明人： Wen-yao Huang , Chun-Che Lee , Hsu-feng Lee , Steven Holdcroft
IPC分类号： C08G8/02 , H01M8/10 , C08G75/23 , C09D171/12
CPC分类号： H01M8/1032 , C08G65/40 , C08G65/48 , C08G75/23 , C08G2650/40 , C09D171/12 , H01M2008/1095
摘要： A polymer of sulfonated poly(arylene ether)s (PAEs) and a manufacturing method thereof are provided. A main structure of the PAEs has a first side formed by multi-phenyl glycol monomer and a second side formed by multi-phenyl dihalo monomer with an electron-withdrawing group. The glycol monomer and the dihalo monomer are reacted with each other by a nucleophilic displacement reaction, so as to form the main structure of the PAEs. A film made of the PAEs has a better size stability under a high water uptake.
摘要翻译：提供磺化聚（亚芳基醚）（PAEs）的聚合物及其制造方法。 PAE的主要结构具有由多苯基乙二醇单体形成的第一面和由具有吸电子基团的多苯基二卤代单体形成的第二面。二醇单体和二卤单体通过亲核置换反应彼此反应，形成PAEs的主要结构。由PAEs制成的薄膜在高吸水率下具有更好的尺寸稳定性。

3. 发明授权

US09018336B2 Polymer of sulfonated poly(arlene ether)s and manufacturing method thereof 有权
标题翻译：磺化聚（芳醚）聚合物及其制备方法
公开(公告)号：US09018336B2
公开(公告)日：2015-04-28
申请号：US14164209
申请日：2014-01-26
申请人： National Sun Yat-sen University
发明人： Wen-yao Huang , Chun-Che Lee , Hsu-feng Lee , Steven Holdcroft
IPC分类号： C08G75/23
CPC分类号： H01M8/1032 , C08G65/40 , C08G65/48 , C08G75/23 , C08G2650/40 , C09D171/12 , H01M2008/1095
摘要： A polymer of sulfonated poly(arylene ether)s (PAEs) and a manufacturing method thereof are provided. A main structure of the PAEs has a first side formed by multi-phenyl glycol monomer and a second side formed by multi-phenyl dihalo monomer with an electron-withdrawing group. The glycol monomer and the dihalo monomer are reacted with each other by a nucleophilic displacement reaction, so as to form the main structure of the PAEs. A film made of the PAEs has a better size stability under a high water uptake.
摘要翻译：提供磺化聚（亚芳基醚）（PAEs）的聚合物及其制造方法。 PAE的主要结构具有由多苯基乙二醇单体形成的第一面和由具有吸电子基团的多苯基二卤代单体形成的第二面。二醇单体和二卤单体通过亲核置换反应彼此反应，形成PAEs的主要结构。由PAEs制成的薄膜在高吸水率下具有更好的尺寸稳定性。

4. 发明授权

US08987407B2 Fuel cell catalyst layer having sulfonated poly(arylene ether)s and manufacturing method thereof 有权
标题翻译：具有磺化聚（亚芳基醚）的燃料电池催化剂层及其制造方法
公开(公告)号：US08987407B2
公开(公告)日：2015-03-24
申请号：US14161766
申请日：2014-01-23
申请人： National Sun Yat-sen University
发明人： Wen-yao Huang , Chun-Che Lee , Hsu-feng Lee , Steven Holdcroft
IPC分类号： H01M4/90 , H01M4/88
CPC分类号： H01M4/9008 , H01M4/8668 , H01M4/8828 , H01M4/926 , H01M2008/1095
摘要： A fuel cell catalyst layer having sulfonated poly(arylene ether)s and a manufacturing method therefor are provided. The manufacturing method includes steps of: providing at least one type of sulfonated poly(arylene ether)s; mixing the sulfonated poly(arylene ether)s with a catalyst composition to prepare a catalyst slurry; and coating the catalyst slurry to form a film which is dried to be an electrode catalyst layer, in which the weight ratio of the sulfonated poly(arylene ether)s is 5-50 wt %. The sulfonated poly(arylene ether)s in the electrode catalyst layer can provide good thermal stability, glass transition temperature, chemical resistance, mechanical properties, water impermeability, low proton transmission loss, and a relatively simple process to shorten the manufacturing time and lower the cost thereof.
摘要翻译：提供具有磺化聚（亚芳基醚）的燃料电池催化剂层及其制造方法。制造方法包括以下步骤：提供至少一种类型的磺化聚（亚芳基醚）; 将磺化聚（亚芳基醚）与催化剂组合物混合以制备催化剂浆料; 并涂覆催化剂浆料以形成干燥成电极催化剂层的膜，其中磺化聚（亚芳基醚）的重量比为5-50重量％。电极催化剂层中的磺化聚（亚芳基醚）可以提供良好的热稳定性，玻璃化转变温度，耐化学性，机械性能，不透水性，低质子传导损耗，以及缩短制造时间的较简单的工艺，成本。

5. 发明授权

US09748594B2 Polymer of fluorine-containing sulfonated poly(arylene ether)s and method of manufacturing the same 有权
公开(公告)号：US09748594B2
公开(公告)日：2017-08-29
申请号：US15479299
申请日：2017-04-05
申请人： National Sun Yat-sen University
发明人： Wen-yao Huang , Hsu-feng Lee , Benjamin Britton , Chun-che Lee , Steven Holdcroft , Jun-jie Pang , Yi-yun Hsu , Yu-chao Tseng
IPC分类号： C08G14/00 , H01M8/1067 , C08G65/48 , C08J5/22 , B01J39/19 , C08G65/40 , H01M8/1025 , H01M8/1039 , H01M8/1018
CPC分类号： H01M8/1067 , B01J39/19 , B01J39/20 , C08G65/40 , C08G65/4025 , C08G65/48 , C08G2650/02 , C08G2650/48 , C08J5/2262 , C08J2371/10 , C09D171/12 , H01M8/1025 , H01M8/1039 , H01M2008/1095
摘要： A polymer of fluorine-containing sulfonated poly(arylene ether)s and a manufacturing method thereof are provided. The polymer is formed by processing a nucleophilic polycondensation between a fluorine-containing monomer having an electron-withdrawing group and a multi-phenyl monomer. A main structure of the polymer of fluorine-containing sulfonated poly(arylene ether)s has a first portion with fluoro or trifluoromethyl substituted phenyl groups, and a second portion with sulfonated phenyl groups.

6. 发明授权

US09676906B1 Polymer of poly(arylene ether)s, manufacturing method thereof and polymer light emitting diode with organic light emitting layer made from the same 有权
公开(公告)号：US09676906B1
公开(公告)日：2017-06-13
申请号：US15077928
申请日：2016-03-23
申请人： National Sun Yat-sen University , Wah Hong Industrial Corp.
发明人： Wen-yao Huang , Hsu-feng Lee , Yi-chiang Huang , Mei-ying Chang , Tzu-sheng Huang , Hsin-yi Wen , Chih-chen Wu
IPC分类号： C08G8/02 , C08G65/40 , H01L51/00 , C09K11/06 , C09D5/22 , C09D171/00 , H01L51/50 , H01L51/56
CPC分类号： C08G65/40 , C08G65/4025 , C08G65/4093 , C08G2650/48 , C09D5/22 , C09D171/00 , C09D171/12 , C09K11/06 , C09K2211/1416 , C09K2211/1425 , H01L51/0007 , H01L51/0035 , H01L51/0039 , H01L51/0043 , H01L51/5012 , H01L51/56
摘要： A polymer of poly(arylene ether)s, a manufacturing method thereof, and a polymer light emitting diode with an organic light emitting layer made from the polymer are provided. The polymer is formed by processing a nucleophilic polycondensation between a fluoro-containing monomer having an electron-withdrawing group and a multi-phenyl monomer. The polymer has a host portion with fluoro- or trifluoromethyl substituents, and a customer portion with multi-phenyl groups.

7. 发明申请

US20150031849A1 POLYMER OF SULFONATED POLY(ARYLENE ETHER)S AND MANUFACTURING METHOD THEREOF 有权
标题翻译：磺化聚（聚亚乙基醚）聚合物及其制备方法
公开(公告)号：US20150031849A1
公开(公告)日：2015-01-29
申请号：US14164209
申请日：2014-01-26
申请人： National Sun Yat-sen University
发明人： Wen-yao Huang , Chun-Che Lee , Hsu-feng Lee , Steven Holdcroft
IPC分类号： C08G75/23
CPC分类号： H01M8/1032 , C08G65/40 , C08G65/48 , C08G75/23 , C08G2650/40 , C09D171/12 , H01M2008/1095
摘要： A polymer of sulfonated poly(arylene ether)s (PAEs) and a manufacturing method thereof are provided. A main structure of the PAEs has a first side formed by multi-phenyl glycol monomer and a second side formed by multi-phenyl dihalo monomer with an electron-withdrawing group. The glycol monomer and the dihalo monomer are reacted with each other by a nucleophilic displacement reaction, so as to form the main structure of the PAEs. A film made of the PAEs has a better size stability under a high water uptake.
摘要翻译：提供磺化聚（亚芳基醚）（PAEs）的聚合物及其制造方法。 PAE的主要结构具有由多苯基乙二醇单体形成的第一面和由具有吸电子基团的多苯基二卤代单体形成的第二面。二醇单体和二卤单体通过亲核置换反应彼此反应，形成PAEs的主要结构。由PAEs制成的薄膜在高吸水率下具有更好的尺寸稳定性。

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