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    • 8. 发明授权
    • (Meth) acryloyl group-containing oxetane compound and production method thereof
    • (甲基)丙烯酰基氧杂环丁烷化合物及其制备方法
    • US07659413B2
    • 2010-02-09
    • US10588072
    • 2005-02-09
    • Hirotoshi KamataKatsutoshi MorinakaHiroshi Uchida
    • Hirotoshi KamataKatsutoshi MorinakaHiroshi Uchida
    • C07D407/00
    • C07D305/06
    • The present invention relates to an oxetane compound containing a (meth)acryloyl group represented by formula (1) having a high copolymerizability with compounds containing a (meth)acryloyl group, and to a production method of an oxetane compound containing a (meth)acryloyl group which is characterized by reacting an isocyanate compound having a (meth)acryloyl group represented by formula (5) with an oxetane compound containing a hydroxyl group represented by formula (6). (In the formula, R1 represents a hydrogen atom or a methyl group, A represents —OR2— or a bond, R2 represents a divalent hydrocarbon group which may contain an oxygen atom in the main chain, R3 represents a linear or branched alkylene group having 1 to 6 carbon atoms, and R4 represents a linear or branched alkyl group having 1 to 6 carbon atoms.)
    • 本发明涉及含有与(甲基)丙烯酰基的化合物具有高共聚性的由式(1)表示的(甲基)丙烯酰基的氧杂环丁烷化合物,以及含有(甲基)丙烯酰基 其特征在于使由式(5)表示的具有(甲基)丙烯酰基的异氰酸酯化合物与式(6)所示的含有羟基的氧杂环丁烷化合物反应。 (式中,R 1表示氢原子或甲基,A表示-OR 2 - 或键,R 2表示可以在主链中含有氧原子的二价烃基,R 3表示直链状或支链状的亚烷基, 1〜6个碳原子,R4表示碳原子数1〜6的直链或支链烷基)
    • 9. 发明申请
    • (Meth) acryloyl group-containing oxetane compound and production method thereof
    • (甲基)丙烯酰基氧杂环丁烷化合物及其制备方法
    • US20070060760A1
    • 2007-03-15
    • US10588072
    • 2005-02-09
    • Hirotoshi KamataKatsutoshi MorinakaHiroshi Uchida
    • Hirotoshi KamataKatsutoshi MorinakaHiroshi Uchida
    • C07D305/02
    • C07D305/06
    • The present invention relates to an oxetane compound containing a (meth)acryloyl group represented by formula (1) having a high copolymerizability with compounds containing a (meth)acryloyl group, and to a production method of an oxetane compound containing a (meth)acryloyl group which is characterized by reacting an isocyanate compound having a (meth)acryloyl group represented by formula (5) with an oxetane compound containing a hydroxyl group represented by formula (6). (In the formula, R1 represents a hydrogen atom or a methyl group, A represents —OR2— or a bond, R2 represents a divalent hydrocarbon group which may contain an oxygen atom in the main chain, R3 represents a linear or branched alkylene group having 1 to 6 carbon atoms, and R4 represents a linear or branched alkyl group having 1 to 6 carbon atoms.)
    • 本发明涉及含有与(甲基)丙烯酰基的化合物具有高共聚性的由式(1)表示的(甲基)丙烯酰基的氧杂环丁烷化合物,以及含有(甲基)丙烯酰基 其特征在于使由式(5)表示的具有(甲基)丙烯酰基的异氰酸酯化合物与式(6)所示的含有羟基的氧杂环丁烷化合物反应。 (式中,R 1表示氢原子或甲基,A表示-OR 2 - 或键,R 2表示 可以在主链中含有氧原子的二价烃基R 3表示具有1〜6个碳原子的直链或支链亚烷基,R 4表示 具有1至6个碳原子的直链或支链烷基)
    • 10. 发明申请
    • Method For Producing (Meth)Acrylate Derivative Having Isocyanate Group
    • 生产具有异氰酸酯基团(甲基)丙烯酸酯衍生物的方法
    • US20070197762A1
    • 2007-08-23
    • US10594231
    • 2005-03-22
    • Kaneo NozawaKatsutoshi Morinaka
    • Kaneo NozawaKatsutoshi Morinaka
    • C08G63/00
    • C07C263/20C07C263/16C07C265/04
    • The invention aims to provide a method whereby (meth)acrylate derivatives having an isocyanate group can be obtained in high yield by dehydrochlorination of 3-chloropropionate derivatives having an isocyanate group under industrially advantageous and mild conditions, and the content of residual hydrolyzable chlorine can be reduced. A method for producing a (meth)acrylate derivative having an isocyanate group comprises performing dehydrochlorination of a 3-chloropropionate derivative having an isocyanate group in the presence of a basic nitrogen compound having a tertiary nitrogen, the tertiary nitrogen of the basic nitrogen compound having at least one group other than an aromatic ring group.
    • 本发明的目的在于提供一种方法,可以在工业上有利且温和的条件下,通过使具有异氰酸酯基的3-氯丙酸酯衍生物的脱氯化氢以高产率获得具有异氰酸酯基的(甲基)丙烯酸酯衍生物,残留的可水解氯的含量可以为 减少 具有异氰酸酯基的(甲基)丙烯酸酯衍生物的制造方法包括在具有叔氮的碱性氮化合物的存在下,对具有异氰酸酯基的3-氯丙酸酯衍生物进行脱氯化氢,碱式氮化合物的叔氮具有 除芳香族环以外的至少一个基团。