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1. 发明申请

US20090156854A1 ADAMANTANE DERIVATIVES AND PROCESS FOR PRODUCING THE SAME 审中-公开
标题翻译：亚胺衍生物及其生产方法
公开(公告)号：US20090156854A1
公开(公告)日：2009-06-18
申请号：US12363895
申请日：2009-02-02
申请人： Naoyoshi HATAKEYAMA , Shinji Tanaka , Hidetoshi Ono , Yasunari Okada
发明人： Naoyoshi HATAKEYAMA , Shinji Tanaka , Hidetoshi Ono , Yasunari Okada
IPC分类号： C07C255/01 , C07C69/533
CPC分类号： C07C69/54 , C07C67/29 , C07C303/28 , C07C309/66 , C07C2603/74
摘要： The present invention provides an adamantane derivative (I) having a structure represented by the general formula (I); an adamantane derivative (II) having a structure represented by the general formula (II); and a process for producing those adamantane derivatives. An alcohol form of an adamantane compound is reacted with a sulfonyl compound to obtain the adamantane derivative (II), which is then reacted with an alcohol to obtain the adamantane derivative (I). The adamantane derivative (I) and adamantane derivative (II) each having the structure represented by the general formula (I) and general formula (II), respectively, is a novel adamantyl (meth)acrylate compound and useful as a monomer for functional resins such as a photosensitive resin in the field of photolithography.
摘要翻译：本发明提供具有由通式（I）表示的结构的金刚烷衍生物（I）; 具有由通式（II）表示的结构的金刚烷衍生物（II）; 以及生产这些金刚烷衍生物的方法。将金刚烷化合物的醇形式与磺酰基化合物反应，得到金刚烷衍生物（II），然后与醇反应得到金刚烷衍生物（I）。分别具有由通式（I）和通式（II）表示的结构的金刚烷衍生物（I）和金刚烷衍生物（II）分别是新型金属（甲基）丙烯酸酯金属化合物，并且可用作功能性树脂的单体例如光刻领域的感光性树脂。

2. 发明授权

US07528279B2 Adamantane derivatives and process for producing the same 有权
标题翻译：金刚烷衍生物及其制备方法
公开(公告)号：US07528279B2
公开(公告)日：2009-05-05
申请号：US10588080
申请日：2005-02-01
申请人： Naoyoshi Hatakeyama , Shinji Tanaka , Hidetoshi Ono , Yasunari Okada
发明人： Naoyoshi Hatakeyama , Shinji Tanaka , Hidetoshi Ono , Yasunari Okada
IPC分类号： C07C69/54 , C07C67/29 , C07C303/28 , C07C303/44 , C07C309/66
CPC分类号： C07C69/54 , C07C67/29 , C07C303/28 , C07C309/66 , C07C2603/74
摘要： The present invention provides an adamantane derivative (I) having a structure represented by the general formula (I); an adamantane derivative (II) having a structure represented by the general formula (II); and a process for producing those adamantane derivatives. An alcohol form of an adamantane compound is reacted with a sulfonyl compound to obtain the adamantane derivative (II), which is then reacted with an alcohol to obtain the adamantane derivative (I). The adamantane derivative (I) and adamantane derivative (II) each having the structure represented by the general formula (I) and general formula (II), respectively, is a novel adamantyl(meth)acrylate compound and useful as a monomer for functional resins such as a photosensitive resin in the field of photolithography.
摘要翻译：本发明提供具有由通式（I）表示的结构的金刚烷衍生物（I）; 具有由通式（II）表示的结构的金刚烷衍生物（II）; 以及生产这些金刚烷衍生物的方法。将金刚烷化合物的醇形式与磺酰基化合物反应，得到金刚烷衍生物（II），然后与醇反应得到金刚烷衍生物（I）。分别具有由通式（I）和通式（II）表示的结构的金刚烷衍生物（I）和金刚烷衍生物（II）分别是新型金属（甲基）丙烯酸酯金属化合物，并且可用作功能性树脂的单体例如光刻领域的感光性树脂。

3. 发明申请

US20070129532A1 Adamantane derivatives and process for producing the same 有权
标题翻译：金刚烷衍生物及其制备方法
公开(公告)号：US20070129532A1
公开(公告)日：2007-06-07
申请号：US10588080
申请日：2005-02-01
申请人： Naoyoshi Hatakeyama , Shinji Tanaka , Hidetoshi Ono , Yasunari Okada
发明人： Naoyoshi Hatakeyama , Shinji Tanaka , Hidetoshi Ono , Yasunari Okada
IPC分类号： C08G69/14
CPC分类号： C07C69/54 , C07C67/29 , C07C303/28 , C07C309/66 , C07C2603/74
摘要： The present invention provides an adamantane derivative (I) having a structure represented by the general formula (I); an adamantane derivative (II) having a structure represented by the general formula (II); and a process for producing those adamantane derivatives. An alcohol form of an adamantane compound is reacted with a sulfonyl compound to obtain the adamantane derivative (II), which is then reacted with an alcohol to obtain the adamantane derivative (I). The adamantane derivative (I) and adamantane derivative (II) each having the structure represented by the general formula (I) and general formula (II), respectively, is a novel adamantyl(meth)acrylate compound and useful as a monomer for functional resins such as a photosensitive resin in the field of photolithography.
摘要翻译：本发明提供具有由通式（I）表示的结构的金刚烷衍生物（I）; 具有由通式（II）表示的结构的金刚烷衍生物（II）; 以及生产这些金刚烷衍生物的方法。将金刚烷化合物的醇形式与磺酰基化合物反应，得到金刚烷衍生物（II），然后与醇反应得到金刚烷衍生物（I）。分别具有由通式（I）和通式（II）表示的结构的金刚烷衍生物（I）和金刚烷衍生物（II）分别是新型金属（甲基）丙烯酸酯金属化合物，并且可用作功能性树脂的单体例如光刻领域的感光性树脂。

4. 发明授权

US07402712B2 Adamantyl vinyl ether compound and production process for the same 失效
标题翻译：金刚烷基乙烯基醚化合物及其制备方法相同
公开(公告)号：US07402712B2
公开(公告)日：2008-07-22
申请号：US10862423
申请日：2004-06-08
申请人： Naoyoshi Hatakeyama , Shinji Tanaka , Hidetoshi Ono , Kouichi Kodoi
发明人： Naoyoshi Hatakeyama , Shinji Tanaka , Hidetoshi Ono , Kouichi Kodoi
IPC分类号： C07C43/18
CPC分类号： C07C43/30 , C07C43/313 , C07C49/753 , C07C2603/74
摘要： Provided by the present invention are an adamantyl vinyl ether compound which is useful as a monomer for functional resins in the photolithography field or a raw material therefor and medical and agricultural intermediates and a production process for the same.The present invention relates to a production process for an adamantyl vinyl ether compound, characterized by subjecting an adamantyl vinyl ether compound having a specific structure and alcohol having an eliminating group in a β position to chloroalkyl-etherification, then subjecting it to etherification to form an adamantyl group-containing ether and then subjecting it to vinyl-etherification.
摘要翻译：由本发明提供的金刚烷基乙烯基醚化合物可用作光刻领域中的功能性树脂的单体或其原料，医药和农业中间体及其生产方法。金刚烷基乙烯基醚化合物的制造方法技术领域本发明涉及一种金刚烷基乙烯基醚化合物的制造方法，其特征在于，将具有特定结构的金刚烷基乙烯基醚化合物和具有消除基团的醇在β位置进行氯代烷基醚化，然后使其进行醚化，形成含有金刚烷基的醚，然后使其进行乙烯基醚化。

5. 发明申请

US20050131247A1 Perfluoroadamantly acrylate compound and intermediate therefor 失效
标题翻译：全氟多官能丙烯酸酯化合物及其中间体
公开(公告)号：US20050131247A1
公开(公告)日：2005-06-16
申请号：US10499305
申请日：2002-12-20
申请人： Shinji Tanaka , Toshihide Yoshitome , Kouichi Kodoi , Hidetoshi Ono , Naoyoshi Hatakeyama
发明人： Shinji Tanaka , Toshihide Yoshitome , Kouichi Kodoi , Hidetoshi Ono , Naoyoshi Hatakeyama
IPC分类号： C07C69/54 , C07C35/52 , C07C69/00 , C07C69/013 , C07C69/653 , C08F20/22 , C08F297/04 , C08L33/06 , C08L33/08 , C08L53/02 , C07C69/62 , C07C35/22 , C07C69/52
CPC分类号： C07C69/653 , C07C35/52 , C07C2603/74 , C08F297/04 , C08L33/04 , C08L33/06 , C08L33/08 , C08L53/02 , C08L53/025 , C08L2666/24 , C08L33/00 , C08L2666/04 , C08L2666/02
摘要： A perfluoroadamantyl acrylate compound which is highly useful as a raw material for functional resins,etc.;and an intermediate therefore. The perfluoroadamantyl acrylate compound comprises perfluoroadamantane having a CH2═C(R)COO group(wherein R is a hydrogen atom, a methyl group or a trifluoromethyl group) at the 1-position, at each of the 1- and 3-positions, at each of the 1-,3- and 5-positions, at each of the 1-,3-,5- and 7-positions, or at the 2-position.
摘要翻译：作为功能性树脂的原料高度有用的丙烯酸全氟金刚烷酯化合物等;以及中间体。全氟金刚烷基丙烯酸酯化合物包括在1位上具有CH 2 -C（R）COO基团（其中R是氢原子，甲基或三氟甲基）的全氟金刚烷，在1 - ，3 - ，5 - 和7 - 位，或2-位的每个位置上，在1 - ，3 - 和5 - 位的每个位置上有1 - 和3 - 位。

6. 发明申请

US20060149073A1 Adamantane derivative and process for producing the same 有权
标题翻译：金刚烷衍生物及其制备方法
公开(公告)号：US20060149073A1
公开(公告)日：2006-07-06
申请号：US10540547
申请日：2003-12-18
申请人： Shinji Tanaka , Hidetoshi Ono , Kouichi Kodoi , Naoyoshi Hatakeyama
发明人： Shinji Tanaka , Hidetoshi Ono , Kouichi Kodoi , Naoyoshi Hatakeyama
IPC分类号： C07C43/18
CPC分类号： C07C43/12 , C07C43/192 , C07C49/517 , C07C2603/74 , G03F7/0045
摘要： Provided is an adamantane derivative represented by Formula (I) or (II): wherein X represents a halogen atom; Y represents an alkyl group having 1 to 10 carbon atoms, a halogenated alkyl group having 1 to 10 carbon atoms, a halogen atom or a hetero atom-containing group; R1 to R4 represent independently hydrogen, a halogen atom, an alkyl group having 1 to 10 carbon atoms or a halogenated alkyl group having 1 to 10 carbon atoms; m represents an integer of 0 to 15, and n represents an integer of 0 to 10; and excluded is a case where in Formula (I), m and n are 0 at the same time and R3 and R4 are a hydrogen atom at the same time. Capable of being provided is a novel adamantane derivative which is useful as a modifying agent for a resin for a photoresist and a dry etching resistance-improving agent in the photolithography field, agricultural and medical intermediates and other various industrial products.
摘要翻译：提供由式（I）或（II）表示的金刚烷衍生物：其中X表示卤素原子; Y表示碳原子数1〜10的烷基，碳原子数1〜10的卤代烷基，卤原子或含杂原子的基团。 R 1至R 4独立地表示氢，卤素原子，具有1至10个碳原子的烷基或具有1至10个碳原子的卤代烷基; m表示0〜15的整数，n表示0〜10的整数。并且排除是在式（I）中同时m和n同时为0并且R 3和R 4同时为氢原子的情况。可以提供的是一种新颖的金刚烷衍生物，其可用作光刻胶树脂和光刻领域的干蚀刻抗蚀剂改性剂，农业和医疗中间体等各种工业产品的改性剂。

7. 发明授权

US07423180B2 Bis(3-amino-4-hydroxyphenyl)adamantane derivatives and process for production thereof 失效
标题翻译：双（3-氨基-4-羟基苯基）金刚烷衍生物及其制备方法
公开(公告)号：US07423180B2
公开(公告)日：2008-09-09
申请号：US10547553
申请日：2004-02-26
申请人： Shinji Tanaka , Hidetoshi Ono , Kouichi Kodoi , Naoyoshi Hatakeyama
发明人： Shinji Tanaka , Hidetoshi Ono , Kouichi Kodoi , Naoyoshi Hatakeyama
IPC分类号： C07C211/00
CPC分类号： C07C215/80 , C07C2603/74 , H05K3/285 , H05K3/4676
摘要： The invention provides compounds which are excellent in terms of heat resistance, mechanical characteristics, electric characteristics, physical properties, etc. and which provide a novel material useful for, for example, interlayer insulating film or protective film for use in semiconductor devices, interlayer insulating film for use in multilayer wiring boards, cover coating in flexible printed circuits, or a liquid crystal alignment layer.The compounds are bis(3-amino-4-hydroxyphenyl)adamantane derivatives having a structure represented by formula (I) or (II): (each of R1 to R4 represents a halogen atom, a hydroxyl group, an alkyl group, an alkoxyl group, a carboxyl group, or an alkoxycarbonyl group, each of m and a is an integer of 0 to 3, and each of n and b is an integer of 0 to 14, with the proviso that the case where the following three conditions in formula (I) are met is excluded: R2 is methyl and present at a bridgehead; m is 0; and n is 2).
摘要翻译：本发明提供了在耐热性，机械特性，电特性，物理性质等方面优异的化合物，其提供了用于例如用于半导体器件的层间绝缘膜或保护膜的新型材料，层间绝缘用于多层布线板的膜，柔性印刷电路中的覆盖层或液晶取向层。这些化合物是具有由式（I）或（II）表示的结构的双（3-氨基-4-羟基苯基）金刚烷衍生物：（R 1至R 4中的每一个） >表示卤素原子，羟基，烷基，烷氧基，羧基或烷氧基羰基，m和a分别为0〜3的整数，n和b分别为 0至14，条件是满足式（I）中的以下三个条件的情况除外：R 2是甲基并存在于桥头堡; m是0; n是2 ）。

8. 发明授权

US07084295B2 Perfluoroadamantyl acrylate compound and intermediate therefor 失效
标题翻译：全氟金刚烷基丙烯酸酯化合物及其中间体
公开(公告)号：US07084295B2
公开(公告)日：2006-08-01
申请号：US10499305
申请日：2002-12-20
申请人： Shinji Tanaka , Toshihide Yoshitome , Kouichi Kodoi , Hidetoshi Ono , Naoyoshi Hatakeyama
发明人： Shinji Tanaka , Toshihide Yoshitome , Kouichi Kodoi , Hidetoshi Ono , Naoyoshi Hatakeyama
IPC分类号： C07C69/00
CPC分类号： C07C69/653 , C07C35/52 , C07C2603/74 , C08F297/04 , C08L33/04 , C08L33/06 , C08L33/08 , C08L53/02 , C08L53/025 , C08L2666/24 , C08L33/00 , C08L2666/04 , C08L2666/02
摘要： A perfluoroadamantyl acrylate compound which is highly useful as a raw material for functional resins,etc.;and an intermediate therefore. The perfluoroadamantyl acrylate compound comprises perfluoroadamantane having a CH2═C(R)COO group(wherein R is a hydrogen atom, a methyl group or a trifluoromethyl group) at the 1-position, at each of the 1- and 3-positions, at each of the 1-, 3- and 5-positions, at each of the 1-, 3-, 5- and 7-positions, or at the 2-position.
摘要翻译：作为功能性树脂的原料高度有用的丙烯酸全氟金刚烷酯化合物等;以及中间体。全氟金刚烷基丙烯酸酯化合物包括在1位上具有CH 2 -S（R）COO基团（其中R是氢原子，甲基或三氟甲基）的全氟金刚烷，在1-，3-，5-和7-位，或2-位中的每个位置，1-和3-位上的1-和3-位。

9. 发明申请

US20060161016A1 Bis(3-amino-4-hydroxyphenyl)adamantane derivatives and process for production thereof 失效
标题翻译：双（3-氨基-4-羟基苯基）金刚烷衍生物及其制备方法
公开(公告)号：US20060161016A1
公开(公告)日：2006-07-20
申请号：US10547553
申请日：2004-02-26
申请人： Shinji Tanaka , Hidetoshi Ono , Kouichi Kodoi , Naoyoshi Hatakeyama
发明人： Shinji Tanaka , Hidetoshi Ono , Kouichi Kodoi , Naoyoshi Hatakeyama
IPC分类号： C07C229/54 , C07C213/10
CPC分类号： C07C215/80 , C07C2603/74 , H05K3/285 , H05K3/4676
摘要： The invention provides compounds which are excellent in terms of heat resistance, mechanical characteristics, electric characteristics, physical properties, etc. and which provide a novel material useful for, for example, interlayer insulating film or protective film for use in semiconductor devices, interlayer insulating film for use in multilayer wiring boards, cover coating in flexible printed circuits, or a liquid crystal alignment layer. The compounds are bis(3-amino-4-hydroxyphenyl)adamantane derivatives having a structure represented by formula (I) or (II): (each of R1 to R4 represents a halogen atom, a hydroxyl group, an alkyl group, an alkoxyl group, a carboxyl group, or an alkoxycarbonyl group, each of m and a is an integer of 0 to 3, and each of n and b is an integer of 0 to 14, with the proviso that the case where the following three conditions in formula (I) are met is excluded: R2 is methyl and present at a bridgehead; m is 0; and n is 2).
摘要翻译：本发明提供了在耐热性，机械特性，电特性，物理性质等方面优异的化合物，其提供了用于例如用于半导体器件的层间绝缘膜或保护膜的新型材料，层间绝缘用于多层布线板的膜，柔性印刷电路中的覆盖层或液晶取向层。这些化合物是具有由式（I）或（II）表示的结构的双（3-氨基-4-羟基苯基）金刚烷衍生物：（R 1至R 4中的每一个） >表示卤素原子，羟基，烷基，烷氧基，羧基或烷氧基羰基，m和a分别为0〜3的整数，n和b分别为 0至14，条件是满足式（I）中的以下三个条件的情况除外：R 2是甲基并存在于桥头堡; m是0; n是2 ）。

10. 发明授权

US07470824B2 Adamantane derivative and process for producing the same 有权
标题翻译：金刚烷衍生物及其制备方法
公开(公告)号：US07470824B2
公开(公告)日：2008-12-30
申请号：US10540547
申请日：2003-12-18
申请人： Shinji Tanaka , Hidetoshi Ono , Kouichi Kodoi , Naoyoshi Hatakeyama
发明人： Shinji Tanaka , Hidetoshi Ono , Kouichi Kodoi , Naoyoshi Hatakeyama
IPC分类号： C07C43/18
CPC分类号： C07C43/12 , C07C43/192 , C07C49/517 , C07C2603/74 , G03F7/0045
摘要： Provided is an adamantane derivative represented by Formula (I) or (II): wherein X represents a halogen atom; Y represents an alkyl group having 1 to 10 carbon atoms, a halogenated alkyl group having 1 to 10 carbon atoms, a halogen atom or a hetero atom-containing group; R1 to R4 represent independently hydrogen, a halogen atom, an alkyl group having 1 to 10 carbon atoms or a halogenated alkyl group having 1 to 10 carbon atoms; m represents an integer of 0 to 15, and n represents an integer of 0 to 10; and excluded is a case where in Formula (I), m and n are 0 at the same time and R3 and R4 are a hydrogen atom at the same time. Capable of being provided is a novel adamantane derivative which is useful as a modifying agent for a resin for a photoresist and a dry etching resistance-improving agent in the photolithography field, agricultural and medical intermediates and other various industrial products.
摘要翻译：提供由式（I）或（II）表示的金刚烷衍生物：其中X表示卤素原子; Y表示碳原子数1〜10的烷基，碳原子数1〜10的卤代烷基，卤原子或含杂原子的基团。 R 1〜R 4分别独立地表示氢，卤素原子，碳原子数1〜10的烷基或碳原子数1〜10的卤代烷基。 m表示0〜15的整数，n表示0〜10的整数。并且排除是在式（I）中同时m和n同时为0且R3和R4同时为氢原子的情况。可以提供的是一种新颖的金刚烷衍生物，其可用作光刻胶树脂和光刻领域的干蚀刻抗蚀剂改性剂，农业和医疗中间体等各种工业产品的改性剂。

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