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    • 2. 发明授权
    • Silver halide color photographic lightsensitive material and compound used therein
    • 卤化银彩色照相感光材料及其中使用的化合物
    • US06492100B2
    • 2002-12-10
    • US09923456
    • 2001-08-08
    • Hisashi MikoshibaYoshio ShimuraNaoto MatsudaHiroshi Fukuzawa
    • Hisashi MikoshibaYoshio ShimuraNaoto MatsudaHiroshi Fukuzawa
    • G03C108
    • C07D487/04G03C5/50G03C7/30G03C7/3835
    • A silver halide color photographic lightsensitive material comprising at least one photosensitive silver halide emulsion layer on a support, wherein the emulsion layer contains a magenta coupler represented by formula (M-1) below: wherein R1 represents a substituted or nonsubstituted alkyl group, each of L1 and L2 independently represents a substituted or nonsubstituted alkylene group, or substituted or nonsubstituted arylene group, in —L3—G, L3 represents —NH—SO2— or —SO2—NH—CO— (in these representations, bonding direction is not defined) and G represents a substituted or nonsubstituted alkyl group or substituted or nonsubstituted aryl group, alternatively —L3—G represents —COOH or OH, X represents a hydrogen atom or a group which splits off when coupling with an oxidized form of a developing agent, n represents 1 or 2, when L2 is an alkylene group, or n represents an integer from 1 to 5, when L2 is an arylene group, and a plurality of —L3—G's can be the same or different, when n is 2 or more.
    • 一种卤化银彩色照相感光材料,其在载体上包含至少一种感光卤化银乳剂层,其中所述乳剂层含有由下式(M-1)表示的品红色偶联剂:其中R 1表示取代或未取代的烷基, L1和L2独立地表示-L3-G中的取代或未取代的亚烷基或取代或未取代的亚芳基,L3表示-NH-SO2-或-SO2-NH-CO-(在这些表示中,键合方向未定义 ),G表示取代或未取代的烷基或取代或未取代的芳基,或者-L3-G表示-COOH或OH,X表示氢原子或当与显影剂的氧化形式偶联时分裂的基团, n表示1或2,当L2为亚烷基时,或n表示1〜5的整数,当L2为亚芳基时,多个-L3-G可相同或不同,n为2时 或者更多。
    • 3. 发明授权
    • Silver halide color photosensitive material and color image forming method using the same
    • 卤化银色感光材料和使用其的彩色图像形成方法
    • US06391533B1
    • 2002-05-21
    • US09897043
    • 2001-07-03
    • Hisashi MikoshibaYoshio ShimuraNaoto Matsuda
    • Hisashi MikoshibaYoshio ShimuraNaoto Matsuda
    • G03C108
    • G03C7/3835G03C7/3212
    • A silver halide color photosensitive material comprising each at least one blue-, green-, and red-sensitive emulsion layer on a support. The material contains a magenta coupler of formula (MC-1): wherein R1 represents a t-alkyl group, s, m, and n represent 0 or 1, R2 to R7 represent H, halogen atom, alkyl, or aryl group, L represents —NR8SO2—, —SO2NR8—, —SO2NR8CO—, —NR8COO—, —NR8CONR9—, or —COO—, R8 and R9 represent H, alkyl, or aryl group, J represents —CO—, —COO—, —O—, —S—, —CONR10—, —NR10CO—, —NR10COO—, —NR10NR11—, —SO2—, —SO2NR10—, or —CONR10SO2—, R10 and R11 represent H, alkyl, or aryl group, B represents an alkyl group of C1-70 or an aryl group of C6-70, p represents an integer from 1 to 5, G represents halogen atom, alkyl, aryl, or alkoxy group, and q represents an integer from 0 to 4, provided that is excluded from the magenta coupler.
    • 一种卤化银色感光材料,其在载体上包含至少一种蓝,绿和红敏感乳剂层。 该材料含有式(MC-1)的品红成色剂:其中R1表示叔烷基,s,m和n表示0或1,R2至R7表示H,卤素原子,烷基或芳基,L 表示-NR8SO2-,-SO2NR8-,-SO2N8C-,-NR8COO-,-NR8CONR9-或-COO-,R8和R9表示H,烷基或芳基,J表示-CO-,-COO-,-O - ,-S - , - CONR 10 - , - NR 10 CO - , - NR 10 COO - , - NR 10 NR 11 - , - SO 2 - , - SO 2 NR 10 - 或-CONR 10 SO 2 - ,R 10和R 11表示H,烷基或芳基,B表示 C 1-7的烷基或C 6-70的芳基,p表示1〜5的整数,G表示卤素原子,烷基,芳基或烷氧基,q表示0〜4的整数,条件是不包括 从洋红色耦合器。
    • 6. 发明授权
    • Silver halide color photographic lightsensitive material and method of forming color image using the same
    • 卤化银彩色照相感光材料和使用其形成彩色图像的方法
    • US06548237B2
    • 2003-04-15
    • US09897067
    • 2001-07-03
    • Hisashi MikoshibaHiroshi FukuzawaNaoto Matsuda
    • Hisashi MikoshibaHiroshi FukuzawaNaoto Matsuda
    • G03C146
    • G03C7/301G03C7/3835G03C7/39216G03C7/39236G03C7/3924G03C7/3928
    • A silver halide color photographic lightsensitive material comprises a support and a silver halide emulsion layer. The lightsensitive material contains a magenta coupler of Formula (MC-I): {R31 and R32 includes a hydrogen atom, alkyl and aryl groups}, and at least one compound selected from Formulae (TS-I) to (TS-III): {R1a and R2a includes a hydrogen atom, alkyl and aryl groups, —X1a— and —X2a— includes —O— and —N(R24)— (R24 includes an alkyl group), and R2 R3, R5, and R6 include hydrogen and halogen atoms, alkyl, alkoxy and acylamino groups, R11 to R14 include alkyl and alkenyl groups, X2 includes alkoxy group and X3 includes a group of nonmetallic atoms required to form a 5-7 membered ring, R21 includes a hydrogen atom, R22 includes alkyl and aryl groups, X4 includes —CO—R123, —CO—O—R123 and —CO—NR124(R125) (R123 includes alkyl and aryl groups, R124 and R125 include a hydrogen atom, alkyl and aryl groups)}.
    • 卤化银彩色照相感光材料包括载体和卤化银乳剂层。 光敏材料包含式(MC-1)的品红成色剂:{R 31和R 32包括氢原子,烷基和芳基}和至少一种选自式(TS-1)至(TS-III)的化合物: {R1a和R2a包括氢原子,烷基和芳基,-X1a和-X2a包括-O-和-N(R24) - (R24包括烷基),R2 R3,R5和R6包括氢 和卤原子,烷基,烷氧基和酰氨基,R 11至R 14包括烷基和烯基,X 2包括烷氧基,X 3包括形成5-7元环所需的一组非金属原子,R 21包括氢原子,R 22包括 烷基和芳基,X 4包括-CO-R123,-CO-O-R123和-CO-NR124(R125)(R123包括烷基和芳基,R124和R125包括氢原子,烷基和芳基)}。
    • 9. 发明授权
    • Silver halide color reversal photosensitive material and color image forming method using the same
    • 卤化银颜色反转感光材料和使用其的彩色图像形成方法
    • US06440650B1
    • 2002-08-27
    • US09708684
    • 2000-11-09
    • Naoto MatsudaHisashi Mikoshiba
    • Naoto MatsudaHisashi Mikoshiba
    • G03C746
    • G03C5/50G03C1/0051G03C7/30G03C7/3022G03C7/3029G03C7/3041G03C7/3805G03C7/3825G03C2007/3025G03C2200/38
    • A silver halide color reversal photosensitive material comprising at least one blue-sensitive emulsion layer, at least one green-sensitive emulsion layer, and at least one red-sensitive emulsion layer on a transparent support, and capable of forming a color image when the photosensitive material was subjected to color development in the presence of an aromatic primary amine color developing agent after the photosensitive material was subjected to first development of black-and-white development, wherein the silver halide content in the photosensitive material before the first development is 2.5 to 6.0 g in terms of silver per m2 of the photosensitive material, the silver halide content in an unexposed portion of the photosensitive material immediately before the color development is 1.0 to 2.5 g in terms of silver per m2 of the photosensitive material, and the maximum density of each of cyan, magenta, and yellow in the color image after the color development is 3.0 or more.
    • 一种卤化银颜色反转感光材料,其包含至少一种感蓝乳剂层,至少一种感绿乳剂层和至少一种在透明支撑体上的感红乳剂层,并且当感光体上形成彩色图像时 在感光材料进行黑白显影的第一次显影之后,在芳族伯胺显色剂的存在下使材料进行着色显影,其中在第一次显影之前的感光材料中的卤化银含量为2.5〜 以每平方米感光材料计为6.0克,感光材料之前感光材料的未曝光部分中的卤化银含量为每平方米感光材料银为1.0至2.5克,最大密度 在彩色显影后的彩色图像中的青色,品红色和黄色各自为3.0以上。
    • 10. 发明授权
    • Silver halide color photographic light-sensitive material and color image formation method using the same
    • 卤化银彩色摄影感光材料和使用其的彩色图像形成方法
    • US06656673B2
    • 2003-12-02
    • US09899100
    • 2001-07-06
    • Naoto MatsudaHisashi Mikoshiba
    • Naoto MatsudaHisashi Mikoshiba
    • G03C146
    • G03C7/3225G03C5/50G03C7/30G03C7/3029G03C7/346G03C7/3825G03C7/3885G03C2007/3034
    • A silver halide color photographic light-sensitive material has a red-, green-, and blue-sensitive emulsion layer in this order from the side closest to a support. The green-sensitive layer contains a coupler represented by formula (MC-I), and the red-sensitive emulsion layer contains a coupler represented by formula (CC-I): wherein R1 represents a hydrogen atom or substituent; one of G1 and G2 represents C, the other represents N; and R2 represents a substituent which substitutes one of G1 and G2 which is C; X represents a hydrogen atom or a splitting off group; wherein Rc1 represents a hydrogen atom or alkyl group, Rc2 represents an alkyl or aryl group, n is 1, 2, or 3, and Y is positioned in the meta and/or para position of the phenyl group with respect to the sulfonyl group, and represents alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulfonyloxy, sulfamoylamino, sulfonamide, ureido, oxycarbonyl, oxycarbonylamino, or carbamoyl group.
    • 卤化银彩色照相感光材料从最靠近载体的一侧依次具有红,绿和蓝敏感乳剂层。 感光层包含由式(MC-1)表示的成色剂,并且感红乳剂层含有由式(CC-I)表示的成色剂:其中R1表示氢原子或取代基; G1和G2之一表示C,另一个表示N; 并且R 2表示取代基为G的G 1和G 2之一的取代基; X表示氢原子或分解基团;其中Rc1表示氢原子或烷基,Rc2表示烷基或芳基,n为1,2或3,Y位于间位和/或对位 苯基相对于磺酰基,代表烷基,烯基,烷氧基,芳氧基,酰氧基,酰氨基,磺酰氧基,氨磺酰基氨基,磺酰胺,脲基,氧羰基,氧羰基氨基或氨基甲酰基。