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1. 发明申请

US20090050845A1 BETA TYPE SIALON FLUORESCENT SUBSTANCE 有权
标题翻译： BETA型SIALON荧光物质
公开(公告)号：US20090050845A1
公开(公告)日：2009-02-26
申请号：US11914272
申请日：2006-05-10
申请人： Naoto Hirosaki , Hideyuki Emoto , Masahiro Ibukiyama
发明人： Naoto Hirosaki , Hideyuki Emoto , Masahiro Ibukiyama
IPC分类号： C09K11/80
CPC分类号： C09K11/0883 , C09K11/7734 , Y02B20/181
摘要： A β type Sialon fluorescent substance is disclosed that is capable of achieving enhanced brightness of a white light emitting diode using blue to ultraviolet light as a light source. In the fluorescent substance which contains not less than 90% by mass of a β type Sialon composition represented by general formula: Si6-zAlzOzN8-z as a host material wherein z is not less than 0.24 and not more than 0.42, Eu is present dissolved in solid solution as a luminescent center at a content of 0.05 to 0.2% by atom. The β type Sialon fluorescent substance is preferably in the form of a powder having an average particle size of not less than 1 μm and not more than 20 μm. A white LED of good luminescent characteristics can be obtained by using a blue or ultraviolet light emitting diode as a excitation light source in combination with a fluorescent substance that emits yellow or red light.
摘要翻译：公开了一种β型赛隆荧光物质，其能够实现使用蓝色至紫外光作为光源的白色发光二极管的增强的亮度。在含有不少于90质量％的由通式Si 6-z Al z O z N 8-z表示的β型Sialon组合物作为主体材料的荧光物质中，其中z不小于0.24且不大于0.42，Eu存在溶解作为发光中心的固溶体，含量为0.05〜0.2原子％。 β型赛隆荧光物质优选为平均粒径不小于1μm且不大于20μm的粉末形式。通过使用蓝色或紫外线发光二极管作为激发光源与发出黄色或红色光的荧光物质组合，可以获得良好发光特性的白色LED。

2. 发明申请

US20070248519A1 Alpha-Siaion Powder and Method for Producing the Same 审中-公开
标题翻译： Alpha-Siaion粉及其制造方法
公开(公告)号：US20070248519A1
公开(公告)日：2007-10-25
申请号：US11572858
申请日：2005-06-14
申请人： Mamoru Mitomo , Naoto Hirosaki , Hideyuki Emoto , Masahiro Ibukiyama
发明人： Mamoru Mitomo , Naoto Hirosaki , Hideyuki Emoto , Masahiro Ibukiyama
IPC分类号： C01F17/00
CPC分类号： C01B21/0826 , C01B21/0821 , C01P2002/84 , C01P2004/52 , C01P2004/61 , C04B35/597 , C04B35/6262 , C04B2235/3203 , C04B2235/3206 , C04B2235/3208 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3229 , C04B2235/3865 , C04B2235/3873 , C04B2235/442 , C04B2235/5481 , C04B2235/608 , C04B2235/766 , C04B2235/9646 , C09K11/0883 , C09K11/7734
摘要： An α-sialon which is represented by general formula: (M1)x (M2)y (Si, Al)12 (O, N)16 (wherein M1 represents one or more elements selected from the group which consists of Li, Mg, Ca, Y and lanthanoid (except La and Ce) and M2 represents one or more elements selected from the group which consists of Ce, Pr, Eu, Tb, Yb and Er and wherein 0.3
摘要翻译：由通式表示的α-赛隆：（M1）x（M2）y（Si，Al）12（O，N ）16（其中M1表示选自由Li，Mg，Ca，Y和镧系元素（La和Ce除外）组成的组中的一种或多种元素，M2表示一种或多种选自其由Ce，Pr，Eu，Tb，Yb和Er组成，其中0.3

3. 发明授权

US07906040B2 α-Sialon, α-sialon phosphor and method for producing the same 有权
标题翻译： α-赛隆，α-赛隆荧光体及其制造方法
公开(公告)号：US07906040B2
公开(公告)日：2011-03-15
申请号：US11629467
申请日：2005-06-14
申请人： Mamoru Mitomo , Naoto Hirosaki , Hideyuki Emoto , Masahiro Ibukiyama
发明人： Mamoru Mitomo , Naoto Hirosaki , Hideyuki Emoto , Masahiro Ibukiyama
IPC分类号： C09K11/08 , C09K11/66 , C09K11/61 , C09K11/02 , C09K11/77
CPC分类号： C09K11/7734 , C04B35/597 , C04B35/6262 , C04B2235/3203 , C04B2235/3206 , C04B2235/3208 , C04B2235/3215 , C04B2235/3224 , C04B2235/3225 , C04B2235/3229 , C04B2235/3865 , C04B2235/3873 , C04B2235/442 , C04B2235/445 , C04B2235/5436 , C04B2235/549 , C04B2235/658 , C04B2235/724 , C04B2235/766 , C04B2235/9646 , C09K11/0883
摘要： An α-sialon is offered which is represented by general formula: (M1)X(M2)Y(Si, Al)12(O, N)16 (wherein M1 represents one or more elements selected from the group which consists of Li, Mg, Ca, Y and lanthanoid (except La and Ce) and M2 represents one or more elements selected from the group which consists of Ce, Pr, Eu, Tb, Yb and Er and wherein 0.3
摘要翻译：提供α-sialon，其通式为：（M1）X（M2）Y（Si，Al）12（O，N）16（其中M1表示选自Li， Mg，Ca，Y和镧系元素（La和Ce除外），M2表示选自Ce，Pr，Eu，Tb，Yb和Er中的一种或多种元素，其中0.3

4. 发明授权

US08003011B2 β type sialon fluorescent substance 有权
标题翻译：＆bgr 型赛隆荧光物质
公开(公告)号：US08003011B2
公开(公告)日：2011-08-23
申请号：US11914272
申请日：2006-05-10
申请人： Naoto Hirosaki , Hideyuki Emoto , Masahiro Ibukiyama
发明人： Naoto Hirosaki , Hideyuki Emoto , Masahiro Ibukiyama
IPC分类号： C09K11/64
CPC分类号： C09K11/0883 , C09K11/7734 , Y02B20/181
摘要： A β type Sialon fluorescent substance is disclosed that is capable of achieving enhanced brightness of a white light emitting diode using blue to ultraviolet light as a light source. In the fluorescent substance which contains not less than 90% by mass of a β type Sialon composition represented by general formula: Si6-zAlzOzN8-z as a host material wherein z is not less than 0.24 and not more than 0.42, Eu is present dissolved in solid solution as a luminescent center at a content of 0.05 to 0.2% by atom. The β type Sialon fluorescent substance is preferably in the form of a powder having an average particle size of not less than 1 μm and not more than 20 μm. A white LED of good luminescent characteristics can be obtained by using a blue or ultraviolet light emitting diode as a excitation light source in combination with a fluorescent substance that emits yellow or red light.
摘要翻译： A＆bgr 公开了能够实现使用蓝色至紫外光作为光源的白色发光二极管的增强亮度的型号赛隆荧光物质。在含有不少于90质量％的＆bgr的荧光物质中，由通式Si 6-z Al z O z N 8-z表示的Sialon组合物作为主体材料，其中z不小于0.24且不大于0.42，Eu以0.05-0.2％的含量溶解在作为发光中心的固溶体中，Eu以0.05-0.2％的含量存在原子。＆bgr 赛隆型荧光物质优选为平均粒径为1μm以上且20μm以下的粉末状。通过使用蓝色或紫外线发光二极管作为激发光源与发出黄色或红色光的荧光物质组合，可以获得良好发光特性的白色LED。

5. 发明申请

US20080064586A1 A-Sia1on, A-Sia1on Phosphor And Method For Producing The Same 有权
标题翻译： A-Sia1on，A-Sia1on荧光粉及其制造方法
公开(公告)号：US20080064586A1
公开(公告)日：2008-03-13
申请号：US11629467
申请日：2005-06-14
申请人： Mamoru Mitomo , Naoto Hirosaki , Hideyuki Emoto , Masahiro Ibukiyama
发明人： Mamoru Mitomo , Naoto Hirosaki , Hideyuki Emoto , Masahiro Ibukiyama
IPC分类号： C04B35/599
CPC分类号： C09K11/7734 , C04B35/597 , C04B35/6262 , C04B2235/3203 , C04B2235/3206 , C04B2235/3208 , C04B2235/3215 , C04B2235/3224 , C04B2235/3225 , C04B2235/3229 , C04B2235/3865 , C04B2235/3873 , C04B2235/442 , C04B2235/445 , C04B2235/5436 , C04B2235/549 , C04B2235/658 , C04B2235/724 , C04B2235/766 , C04B2235/9646 , C09K11/0883
摘要： An α-sialon is offered which is represented by general formula: (M1)X (M2)Y (Si, Al)12 (O, N)16 (wherein M1 represents one or more elements selected from the group which consists of Li, Mg, Ca, Y and lanthanoid (except La and Ce) and M2 represents one or more elements selected from the group which consists of Ce, Pr, Eu, Tb, Yb and Er and wherein 0.3
摘要翻译：提供的α-赛隆由以下通式表示：（M1）X（M2）Y（Si，Al）12（O ，N）16（其中M1表示选自由Li，Mg，Ca，Y和镧系元素（La和Ce除外）组成的组中的一种或多种元素，M2表示选自以下的一种或多种元素：由Ce，Pr，Eu，Tb，Yb和Er组成的组，其中0.3

6. 发明授权

US09062252B2 Phosphor, manufacture thereof, light-emitting device, and image display device 有权
标题翻译：荧光体，其制造方法，发光装置和图像显示装置
公开(公告)号：US09062252B2
公开(公告)日：2015-06-23
申请号：US13690340
申请日：2012-11-30
申请人： Naoto Hirosaki , Takashi Takeda , Shiro Funahashi
发明人： Naoto Hirosaki , Takashi Takeda , Shiro Funahashi
IPC分类号： C09K11/77 , C09K11/08 , H01J61/44 , H05B33/14 , H01J1/63 , H05B33/12 , H01L33/50
CPC分类号： C09K11/7786 , C09K11/0883 , C09K11/7703 , C09K11/7718 , C09K11/7731 , C09K11/7734 , C09K11/7746 , C09K11/7761 , H01J1/63 , H01J61/44 , H01L33/502 , H01L2224/45144 , H01L2224/48091 , H01L2224/48247 , H01L2224/73265 , H01L2224/8592 , H01L2924/12044 , H01L2924/181 , H05B33/12 , H05B33/14 , H01L2924/00014 , H01L2924/00 , H01L2924/00012
摘要： Provided is a chemically-thermally stable phosphor having different emission characteristics from the conventional and exhibiting high emission intensity with an LED of 470 nm or less. A phosphor of the present invention includes an inorganic crystal of a crystal represented by Sr1Si3Al2O4N4, another inorganic crystal represented by A1(D,E)5X8 and having the same crystal structure as Sr1Si3Al2O4N4, and/or a solid-solution crystal thereof, all with M (one or more kinds of elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb) being solid-solved, wherein A is one or more kinds selected from Mg, Ca, Sr and Ba; D is one or more kinds selected from Si, Ge, Sn, Ti, Zr and Hf; E is one or more kinds selected from B, Al, Ga, In, Sc, Y and La; and X is one or more kinds selected from O, N and F.
摘要翻译：提供了一种化学热稳定的荧光体，其具有与常规的发射特性不同并且具有470nm或更小的LED的高发射强度。本发明的荧光体包括由Sr 1 Si 3 Al 2 O 4 N 4表示的结晶的无机结晶，Al（D，E）5X8表示的另一种无机结晶，与Sr 1 Si 3 Al 2 O 4 N 4具有相同的晶体结构，和/或其固溶体晶体，全部具有 M（选自Mn，Ce，Pr，Nd，Sm，Eu，Tb，Dy和Yb中的一种或多种元素）是固溶的，其中A是选自Mg，Ca，Sr和Ba中的一种或多种 ; D是选自Si，Ge，Sn，Ti，Zr和Hf中的一种或多种; E是选自B，Al，Ga，In，Sc，Y和La中的一种或多种; X是选自O，N和F的一种或多种。

7. 发明授权

US08674392B2 Light-emitting device 有权
标题翻译：发光装置
公开(公告)号：US08674392B2
公开(公告)日：2014-03-18
申请号：US13580791
申请日：2011-01-27
申请人： Kenichi Yoshimura , Hiroshi Fukunaga , Kohsei Takahashi , Naoto Hirosaki
发明人： Kenichi Yoshimura , Hiroshi Fukunaga , Kohsei Takahashi , Naoto Hirosaki
IPC分类号： H01L33/00
CPC分类号： H01L33/504 , C09K11/0883 , C09K11/64 , C09K11/7734 , C09K11/7792 , H01L2224/48091 , H01L2224/73265 , H01L2924/181 , H05B33/14 , Y02B20/181 , H01L2924/00012 , H01L2924/00014
摘要： Disclosed is a light-emitting device that exhibits good color rendering and highly efficiently emits white light in an incandescent bulb color range. The semiconductor light-emitting device (1) of the present invention includes: a semiconductor light-emitting element (2) that emits blue light; a green phosphor (14) that absorbs the blue light and emits green light; and an orange phosphor (13) that absorbs the blue light and emits orange light. The orange phosphor (13) produces an emission spectrum having a peak at a wavelength of equal to or greater than 590 nm but equal to or less than 630 nm and having a full width at half maximum of 130 nm or greater at the peak, the full width at half maximum of the emission spectrum of the orange phosphor (13) being broader than a full width at half maximum of an emission spectrum of the green phosphor (14). The orange phosphor (13) exhibits an absorptance having a peak wavelength of 420 nm or greater. ABS(530) and ABS(MAX) satisfy a relation, ABS(530)/ABS(MAX)
摘要翻译：本发明公开了一种显示良好的显色性且高效率地在白炽灯泡颜色范围内发出白光的发光装置。本发明的半导体发光器件（1）包括：发射蓝光的半导体发光元件（2）; 吸收蓝色光并发出绿色光的绿色荧光体（14）; 以及吸收蓝色光并发出橙色光的橙色荧光体（13）。橙色荧光体（13）产生在波长等于或大于590nm但等于或小于630nm并且在峰值处具有130nm或更大的半峰全宽的发射光谱，橙色荧光体（13）的发射光谱的一半的全宽比绿色荧光体（14）的发射光谱的半峰全宽。橙色荧光体（13）表现出峰值波长为420nm以上的吸收率。 ABS（530）和ABS（MAX）满足ABS（530）/ ABS（MAX）<0.60的关系，其中ABS（MAX）是其峰值波长处的橙色磷光体（13）的吸收率，ABS ）是在530nm波长处的橙色荧光体（13）的吸收率。

8. 发明申请

US20140028179A1 PHOSPHOR, PRODUCTION METHOD FOR THE SAME, AND LIGHT-EMITTING DEVICE 有权
标题翻译：磷光体，其制造方法和发光装置
公开(公告)号：US20140028179A1
公开(公告)日：2014-01-30
申请号：US13983756
申请日：2012-02-03
申请人： Naoto Hirosaki , Ryo Yoshimatsu , Shintaro Watanabe
发明人： Naoto Hirosaki , Ryo Yoshimatsu , Shintaro Watanabe
IPC分类号： C09K11/77 , H05B33/12
CPC分类号： C09K11/7731 , C09K11/0883 , C09K11/7734 , H05B33/12
摘要： A phosphor indicated by general formula MeaRebSicAldNeOf. In the formula: Me has Sr as an essential element thereof and can include one or more types of element selected from Na, Li, Mg, Ca, Ba, Sc, Y, and La; and Re has Eu as an essential element thereof and can include one or more types of element selected from Mn, Ce, Tb, Yb, and Sm. In addition, when a=1−x, b=x, c=(2+2p)×(1−y), d=(2−2p)×y, e=(1+4p)×(1−z), and f=(1+4p)×z, parameters p, x, y, and z fulfill the following: 1.620
摘要翻译：由通式MeaRebSicAldNeOf表示的荧光体。在下式中：Me具有Sr作为其必需元素，并且可以包括选自Na，Li，Mg，Ca，Ba，Sc，Y和La中的一种或多种元素; Re为Eu的必需元素，可以包含选自Mn，Ce，Tb，Yb，Sm中的1种以上的元素。另外，当a = 1-x，b = x，c =（2 + 2p）×（1-y）时，d =（2-2p）×y，e =（1 + 4p）×（1-z ），f =（1 + 4p）×z，参数p，x，y和z满足以下要求：1.620

9. 发明授权

US08550645B2 Illumination device for display device, and display device 有权
标题翻译：显示装置的照明装置和显示装置
公开(公告)号：US08550645B2
公开(公告)日：2013-10-08
申请号：US13131494
申请日：2009-11-25
申请人： Hisayuki Miki , Kousuke Shioi , Naoto Hirosaki
发明人： Hisayuki Miki , Kousuke Shioi , Naoto Hirosaki
IPC分类号： G09F13/04 , G09F13/08 , H01J1/62 , H01J63/04
CPC分类号： C09K11/7734 , C04B35/597 , C04B35/6262 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3224 , C04B2235/3852 , C04B2235/3865 , C04B2235/3878 , C04B2235/3895 , C04B2235/5436 , C04B2235/5445 , C04B2235/761 , C09K11/0883 , H01L33/486 , H01L33/502 , H01L33/504 , H01L2224/45144 , H01L2224/48091 , H01L2224/48247 , H01L2224/8592 , H01L2924/15747 , H01L2924/181 , H05B33/14 , Y02B20/181 , Y10T428/2993 , H01L2924/00014 , H01L2924/00 , H01L2924/00012
摘要： An illumination device for a display device, which is formed from a substrate and a plurality of white light-emitting devices disposed on top of the substrate, and can be used as a backlight for a liquid crystal display panel, wherein the white light-emitting devices have a light source and a phosphor that is excited by the light source and emits light, and a fluorescent material with a composition represented by a general formula: M(0)aM(1)bM(2)x−(vm+n)M(3)(vm+n)−yOnNz−n is used as the phosphor.
摘要翻译：一种用于显示装置的照明装置，其由基板和设置在基板顶部的多个白色发光装置形成，并且可以用作液晶显示面板的背光源，其中白色发光器件具有由光源激发并发光的光源和荧光体，以及具有由以下通式表示的组成的荧光材料：M（0）aM（1）bM（2）x-（vm + n ）M（3）（vm + n）-yOnNz-n用作荧光体。

10. 发明授权

US08513876B2 Fluorescent substance, method for producing the same, and light-emitting device using the same 有权
标题翻译：荧光物质及其制造方法以及使用其的发光装置
公开(公告)号：US08513876B2
公开(公告)日：2013-08-20
申请号：US12600971
申请日：2008-05-01
申请人： Kousuke Shioi , Naoto Hirosaki
发明人： Kousuke Shioi , Naoto Hirosaki
IPC分类号： H01J1/62
CPC分类号： C09K11/7728 , C04B35/597 , C04B35/6262 , C04B35/62675 , C04B35/6268 , C04B35/62685 , C04B2235/3201 , C04B2235/3203 , C04B2235/3205 , C04B2235/3206 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3262 , C04B2235/3852 , C04B2235/3865 , C04B2235/3873 , C04B2235/3878 , C04B2235/3891 , C04B2235/3895 , C04B2235/5296 , C04B2235/5436 , C04B2235/5445 , C09K11/0883 , H01L33/502 , H01L2224/45144 , H01L2224/48091 , H01L2224/48247 , H01L2224/8592 , H01L2924/181 , H05B33/14 , Y10T428/265 , H01L2924/00014 , H01L2924/00 , H01L2924/00012
摘要： The present invention provides a fluorescent substance exhibiting higher brightness as compared to conventional fluorescent substances, a method for producing the same, and a light-emitting device using such a fluorescent substance. Specifically, the fluorescent substance comprises an α-sialon crystal structure having the same crystal structure with an α-type silicon nitride crystal, which includes at least an M(0) element (where M(0) represents one or two elements selected from Sr and La), an M(1) element (where M(1) represents one or more elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm and Yb), Si, Al, and nitrogen.
摘要翻译：本发明提供了与常规荧光物质相比显示更高亮度的荧光物质，其制备方法和使用这种荧光物质的发光装置。具体地说，荧光物质包含具有与α型氮化硅晶体相同的晶体结构的α-赛隆晶体结构，其至少包括M（O）元素（其中M（0）表示选自Sr 和La），M（1）元素（其中M（1）表示选自Mn，Ce，Pr，Nd，Sm，Eu，Tb，Dy，Ho，Er，Tm和Yb中的一种或多种元素），Si， Al和氮。

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