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    • 5. 发明授权
    • Polyarylene sulfide resin composition
    • 聚芳硫醚树脂组合物
    • US5258450A
    • 1993-11-02
    • US469374
    • 1990-01-24
    • Akira NakataNaoki YamamotoHiroshi MoriTakuya Ueno
    • Akira NakataNaoki YamamotoHiroshi MoriTakuya Ueno
    • C08L51/08C08L81/02C08L83/08C08K7/04C08K7/14C08L81/04
    • C08L81/02C08L51/08C08L83/08
    • A polyarylene sulfide resin composition obtainable by mixing and reacting(A) 99 to 60 parts by weight of a polyarylene sulfide resin,(B) 1 to 40 parts by weight of a polyorganosiloxane rubber, in which 0.1 to 20 wt. % of a siloxane compound represented by the following formula (I):HS(CH.sub.2).sub.p --SiR.sub.n (OR').sub.3-n (I) wherein R represents a methyl, ethyl, propyl or phenyl group, R' represents a methyl or ethyl group, n represents an integer of 0, 1 or 2, and p represents an integer of 1 to 6, are copolymerized, having an average particle size of 0.1 to 0.5 .mu.m and a degree of swelling of 3 to 50 measured by immersing in toluene, or a polyorganosiloxane graft copolymer prepared by graft-polymerizing a monomer comprising at least one of an unsaturated carboxylic acid and its anhydride to a polyorganosiloxane rubber having an average particle size of 0.1 to 0.5 .mu.m and a degree of swelling of 3 to 50 measured by immersing in toluene,(C) 0.01 to 10 parts by weight, based on 100 parts by weight of the total weight of the components (A) and (B), of at least one polyfunctional compound selected from the group consisting of polyfunctional isocyanate compounds, polyfunctional oxazoline compounds and polyfunctional epoxy compounds, and(D) 0 to 300 wt. %, based on the total weight of the components (A), (B) and (C), of a filler. The composition having excellent impact resistance without a large reduction in the properties inherent to a polyarylene sulfide resin.
    • 7. 发明授权
    • Polyarylene sulfide resin
    • 聚芳硫醚树脂
    • US5270375A
    • 1993-12-14
    • US967543
    • 1992-10-27
    • Naoki YamamotoAkira YanagaseHiroshi MoriAkira Nakata
    • Naoki YamamotoAkira YanagaseHiroshi MoriAkira Nakata
    • C08L51/08C08L81/02C08K3/40
    • C08L81/02C08L51/08
    • A polyarylene sulfide resin composition comprising 60-99 parts by weight of a polyarylenesulfide resin (A), 40-1 parts by weight of a polyorganosiloxane graft copolymer (B) prepared by grafting a vinyl monomer on a polyorganosiloxane rubber having a degree of swelling in a range of 3-50 measured using toluene as a solvent and an average particle size in a range of 0.15 .mu.m-0.5 .mu.m and being copolymerized with a graft-linking agent, where the total amount of the (A) component and the (B) component is 100 parts by weight, and 0-150 parts by weight of a reinforcing filler (C). A polyarylene sulfide resin composition according to the present invention is excellent in impact resistance, heat resistance, mechanical strength and moldability and useful for an engineering plastic.
    • 包含60-99重量份的聚芳硫醚树脂(A)的聚芳硫醚树脂组合物,40-1重量份通过将乙烯基单体接枝在具有膨胀度的聚有机硅氧烷橡胶上制备的聚有机硅氧烷接枝共聚物(B) 使用甲苯作为溶剂测定的3-50的范围内,平均粒径在0.15μm〜0.5μm的范围内,并与接枝交联剂共聚,其中(A)成分和 (B)成分为100重量份,0-150重量份增强填料(C)。 本发明的聚芳硫醚树脂组合物的耐冲击性,耐热性,机械强度和成型性优异,对于工程塑料是有用的。
    • 8. 发明授权
    • Thermoplastic polyester resin composition
    • 热塑性聚酯树脂组合物
    • US5102941A
    • 1992-04-07
    • US510672
    • 1990-04-18
    • Naoki YamamotoHiroshi MoriAkira Nakata
    • Naoki YamamotoHiroshi MoriAkira Nakata
    • C08K5/54C08L67/02
    • C08K5/54C08L67/02
    • Disclosed is a thermoplastic polyester resin composition, which comprises (A) 99-60 parts by weight of a thermoplastic polyester resin, (B) 1-40 parts by weight of a polyorganosiloxane rubber, (C) 0.01-10 parts by weight, per 100 parts by weight of the sum of the components (A) and (B), of an organic silane compound having at least one functional group selected from the group consisting of an epoxy group, and isocyanate group and an amino group, and (D) 0-300 parts by weight, per 100 parts by weight of the sum of the components (A) and (B), of a reinforcing filler. This composition results in a shaped article having an improved impact resistance while retaining good heat stability and weatherability inherently possessed by the thermoplastic polyester.
    • 公开了一种热塑性聚酯树脂组合物,其包含(A)99-60重量份的热塑性聚酯树脂,(B)1-40重量份的聚有机硅氧烷橡胶,(C)为0.01-10重量份, 具有至少一种选自环氧基,异氰酸酯基和氨基的官能团的有机硅烷化合物的组分(A)和(B)之和的100重量份,和(D )0-300重量份,相对于100重量份的组分(A)和(B)的总和,增强填料。 该组合物导致具有改善的抗冲击性的成型制品,同时保持热塑性聚酯固有的良好的热稳定性和耐候性。