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1. 发明授权

US4246091A Process for the electrolytic treatment of alkali halide 失效
标题翻译：碱卤化物电解处理方法
公开(公告)号：US4246091A
公开(公告)日：1981-01-20
申请号：US883675
申请日：1978-03-06
申请人： Naohiro Murayama , Makoto Fukuda , Sirou Sujuki , Teruo Sakagami
发明人： Naohiro Murayama , Makoto Fukuda , Sirou Sujuki , Teruo Sakagami
IPC分类号： C08J5/22 , C25B13/08
CPC分类号： C08J5/2293 , C08J2327/12
摘要： A process for the electronic treatment of alkali halide. Use is made of a cation exchange membrane having as its ion exchange radicals, sulfonic acid radicals. This membrane is treated with primary to tertiary monoamine or its salt or quatary ammonium salt and then heat-treated at a temperature higher than 100.degree. C. and lower than melting point of the reaction product and then subjected to drying, so as to improving the cation-selecting performance of the membrane and to increase its current efficiency.
摘要翻译：碱卤化物的电子处理方法。使用具有作为其离子交换基团的磺酸基的阳离子交换膜。该膜用一级至三级单胺或其盐或季铵盐处理，然后在高于100℃且低于反应产物的熔点的温度下进行热处理，然后进行干燥膜的阳离子选择性能并提高其电流效率。

2. 发明授权

US4111780A Apparatus and process for the electrolytic treatment of alkali metal halide solution with ion exchange membranes 失效
标题翻译：用离子交换膜对碱金属卤化物溶液进行电解处理的装置和方法
公开(公告)号：US4111780A
公开(公告)日：1978-09-05
申请号：US743294
申请日：1976-11-18
申请人： Naohiro Murayama , Makoto Fukuda , Teruo Sakagami , Shirou Suzuki , Yoshikazu Kokubu , Toshio Enoki
发明人： Naohiro Murayama , Makoto Fukuda , Teruo Sakagami , Shirou Suzuki , Yoshikazu Kokubu , Toshio Enoki
IPC分类号： C08J5/22 , C25B1/46 , C25B9/00 , C25B9/08 , C25B9/10 , C25B13/08 , C25B1/16 , C25B1/26
CPC分类号： C25B1/46 , C08J5/22 , C08J5/2237 , C08J2327/12
摘要： This invention relates to an apparatus for the electrolytic treatment of alkali halide solution in a three chamber type electrolytic bath assembly comprising an anodic chamber, an intermediate chamber and a cathodic chamber arranged one after another in series. Each chamber is separated from its neighboring chamber by means of an anodic ion exchange membrane. The apparatus is characterized, according to this invention, in that the first one of the membranes separating the intermediate and anodic chambers is made of a fluorine-containing resin, while the second membrane separating the intermediate and cathodic chambers includes, as its main ion exchange radical, a pendant type phenolic radical or derivative thereof. The inventive process, which utilizes the above-described apparatus characterized in that it utilizes a caustic alkali concentration in the intermediate chamber which ranges from about 10 - 20 wt. % while the output caustic alkali developed at and delivered from the cathodic chamber amounts to a concentration ranging from about 30 to 50 wt. %.

3. 发明授权

US4212712A Process for the electrolytic treatment of alkali metal halide solution using ion exchange membranes 失效
标题翻译：使用离子交换膜电解处理碱金属卤化物溶液的方法
公开(公告)号：US4212712A
公开(公告)日：1980-07-15
申请号：US905468
申请日：1978-05-12
申请人： Naohiro Murayama , Makoto Fukuda , Teruo Sakagami , Shirou Suzuki , Yoshikazu Kokubu , Toshio Enoki
发明人： Naohiro Murayama , Makoto Fukuda , Teruo Sakagami , Shirou Suzuki , Yoshikazu Kokubu , Toshio Enoki
IPC分类号： C08J5/22 , C25B1/46 , C25B1/16 , C25B1/26
CPC分类号： C25B1/46 , C08J5/2237 , C08J2327/18
摘要： This invention relates to an apparatus for the electrolytic treatment of alkali halide solution in a three chamber type electrolytic bath assembly comprising an anodic chamber, an intermediate chamber and a cathodic chamber arranged one after another in series. Each chamber is from its neighboring chamber by means of a cationic permselective membrane. The apparatus is characterized, according to this invention, in that the first one of the membranes separating the intermediate and anodic chambers is made of a fluorine-containing resin, while the second membrane separating the intermediate and cathodic chambers includes, as its main ion exchange radial, a pendant type phenolic radical or derivative thereof. The inventive process, which utilizes the above-described apparatus is characterized in that it utilizes a caustic alkali concentration in the intermediate chamber which ranges from about 10-20 wt.% while the output caustic alkali developed at and delivered from the cathodic chamber amounts to a concentration ranging from about 30 to 50 wt.%.
摘要翻译：本发明涉及一种用于在三室型电解槽组件中电解处理碱金属卤化物溶液的装置，其包括依次排列的阳极室，中间室和阴极室。每个室通过阳离子选择性渗透膜从其相邻的室中。该装置的特征在于，根据本发明，分离中间和阳极室的第一个膜由含氟树脂制成，而分离中间和阴极室的第二膜包括作为其主要离子交换桡骨，侧基型酚基或其衍生物。利用上述装置的本发明的方法的特征在于，其在中间室中的碱性碱浓度范围为约10-20重量％，而在阴极室处产生并输出的输出苛性碱达到浓度范围为约30至50重量％。

4. 发明授权

US4076604A Process for the electrolytic treatment of alkali halide 失效
标题翻译：碱卤化物电解处理方法
公开(公告)号：US4076604A
公开(公告)日：1978-02-28
申请号：US732095
申请日：1976-10-13
申请人： Naohiro Murayama , Kenichi Nakamura , Makoto Fukuda , Teruo Sakagami , Shirou Suzuki
发明人： Naohiro Murayama , Kenichi Nakamura , Makoto Fukuda , Teruo Sakagami , Shirou Suzuki
IPC分类号： C25B1/46 , C25B1/16 , C25B1/26
CPC分类号： C25B1/46
摘要： In an electrolytic treatment of alkali halide for the manufacture of alkali hydroxide, a three-chamber type reaction vessel assembly is used so as to provide an anodic chamber, an intermediate chamber and a cathodic chamber arranged in succession one after another and mutually separated by means of anodic (i.e., cationic selective) ion exchange membranes. From the intermediate chamber, low concentration caustic alkali solution is obtained, while from the cathodic chamber, high concentration caustic alkali solution is obtained. In this electrolytic process, the system is operated with the cathodic chamber supplied with no water or aqueous content. The high concentration caustic alkali solution is made from water and alkali metal ions conveyed from the intermediate chamber to the cathodic chamber and exclusively and osmotically passed through the anodic ion exchange membrane. The polymers or copolymers of the anodic ion exhange membrane include sulfonic acid, carboxylic acid and/or phenolic radicals. As the method for the introduction of these radicals, formation of corresponding copolymers may be utilized in the most recommended way. As an example, the membrane may comprise a fluorinated polymer having a cyclic ring structure unit and pendant type sulfonic acid radicals.
摘要翻译：在用于制造碱金属氢氧化物的碱金属卤化物的电解处理中，使用三室式反应容器组件，以便提供一个接一个地连续排列并相互分离的阳极室，中间室和阴极室的阳极（即阳离子选择性）离子交换膜。从中间室获得低浓度苛性碱溶液，而从阴极室获得高浓度苛性碱溶液。在这种电解过程中，系统在没有水或含水量的阴极室运行。高浓度苛性碱溶液由从中间室输送到阴极室的水和碱金属离子制成，并且渗透通过阳极离子交换膜。阳离子离子膜的聚合物或共聚物包括磺酸，羧酸和/或酚基。作为引入这些基团的方法，可以以最推荐的方式使用相应的共聚物的形成。作为示例，膜可以包含具有环状结构单元和侧链型磺酸基团的氟化聚合物。

5. 发明授权

US4497710A Substrate for liquid chromatography and process for isolating and purifying fat-soluble substance by the liquid chromatography on the substrate 失效
标题翻译：用于液相色谱的底物和用于通过底物上的液相色谱分离和纯化脂溶性物质的方法
公开(公告)号：US4497710A
公开(公告)日：1985-02-05
申请号：US428655
申请日：1982-09-30
申请人： Masakatsu Wagu , Shoichiro Hayashi , Naohiro Murayama , Teruo Sakagami
发明人： Masakatsu Wagu , Shoichiro Hayashi , Naohiro Murayama , Teruo Sakagami
IPC分类号： B01J20/285 , B01D15/08 , B01J20/26 , B01J20/281 , G01N30/88
CPC分类号： B01J20/26 , B01D15/08
摘要： A substrate for liquid chromatography comprising a spherical particle of highly cross-linked polymer which is produced from (a) 100 parts by weight of a monomer of vinyl ester, acrylate or methacrylate, these esters having a long alkyl chain, if desired, together with a comonomer copolymerizable with the monomer and (b) 10 to 80 parts by weight of a cross-linking agent copolymerizable with the monomer and having at least two functional groups, and a process for isolating and purifying a fat-soluble substance, for instance, a lower alkyl ester of eicosapentaenoic acid or docosahexaenoic acid by means of the liquid chromatography on the substrate.
摘要翻译：一种用于液相色谱的底物，其包含高交联聚合物的球形颗粒，其由（a）100重量份的乙烯基酯，丙烯酸酯或甲基丙烯酸酯的单体制得，如果需要，这些酯具有长的烷基链，以及可与单体共聚的共聚单体和（b）10〜80重量份的可与单体共聚并具有至少两个官能团的交联剂，以及分离和纯化脂溶性物质的方法，例如，通过底物上的液相色谱法分离二十碳五烯酸或二十二碳六烯酸的低级烷基酯。

6. 发明授权

US4428873A Electrooptical element 失效
标题翻译：电光元件
公开(公告)号：US4428873A
公开(公告)日：1984-01-31
申请号：US297016
申请日：1981-08-27
申请人： Naohiro Murayama , Teruo Sakagami , Masuhiro Shoji
发明人： Naohiro Murayama , Teruo Sakagami , Masuhiro Shoji
IPC分类号： G02F1/00 , G02F1/361 , G02F1/07 , G02F1/03
CPC分类号： G02F1/0009 , G02F1/3615
摘要： An electrooptical solid element comprises a formed resin composition comprising a low molecular polar substance having a Kerr type electrooptical effect, and an organic polymer substance compatible with the low molecular polar substance. The formed resin composition is prepared by a method such as melt mixing on rollers, or dissolution in a common solvent followed by evaporation of the solvent. This formed resin composition is prepared in various shapes such as a polygon, a film, a prism and a polygonal pole. At least a pair of electrodes are provided on the surfaces of the formed resin composition, and further at least one of the electrodes may can be made of a transparent material.
摘要翻译：电光固体元件包括形成的树脂组合物，其包含具有克尔型电光效应的低分子极性物质和与低分子量物质相容的有机聚合物物质。所形成的树脂组合物通过诸如在辊上熔融混合或溶解在普通溶剂中然后蒸发溶剂的方法制备。这种形成的树脂组合物被制备成各种形状，例如多边形，薄膜，棱镜和多边形极。至少一对电极设置在所形成的树脂组合物的表面上，并且另外至少一个电极可以由透明材料制成。

7. 发明授权

US4314032A Crosslinked polyvinyl alcohol gel 失效
标题翻译：交联聚乙烯醇凝胶
公开(公告)号：US4314032A
公开(公告)日：1982-02-02
申请号：US85682
申请日：1979-10-17
申请人： Naohiro Murayama , Teruo Sakagami
发明人： Naohiro Murayama , Teruo Sakagami
IPC分类号： C08F8/00 , C08F8/12
CPC分类号： C08F8/00 , C08F8/12 , Y10S524/916
摘要： A crosslinked polyvinyl alcohol gel having vinyl alcohol units and crosslinking units having the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are respectively the same or different and selected from the group consisting of --CH.sub.2 --CH.dbd.CH.sub.2, --CH.sub.2 --CH.tbd.CH and ##STR2## as a packing for a gel chromatography.
摘要翻译：具有乙烯醇单元的交联聚乙烯醇凝胶和具有式“IMAGE”的交联单元，其中R 1，R 2和R 3分别相同或不同，并且选自-CH 2 -CH = CH 2，-CH 2 -CH 3 CH 和作为凝胶色谱法的包装。

8. 发明授权

US4021509A Production of impact-resistant, thermoplastic resin compositions 失效
标题翻译：耐冲击热塑性树脂组合物的生产
公开(公告)号：US4021509A
公开(公告)日：1977-05-03
申请号：US569071
申请日：1975-04-17
申请人： Naohiro Murayama , Takayuki Katto , Yo Iizuka , Teruo Sakagami
发明人： Naohiro Murayama , Takayuki Katto , Yo Iizuka , Teruo Sakagami
IPC分类号： C08F279/06 , C08L25/14 , C08L33/12 , C08L51/04 , C08L9/06
CPC分类号： C08L25/14 , C08F279/06 , C08L33/12 , C08L51/04
摘要： A thermoplastic resin composition of excellent transparency and high impact strength is produced by causing methyl methacrylate and styrene monomers to undergo post polymerization in the presence of a conjugated diolefin polymer rubber latex containing at least 50 percent by weight of a conjugated diolefin monomer as the constituent of the rubber such as butadiene, wherein a polyethylene oxide of an average molecular weight of at least 100,000 has been added to the rubber latex either prior to or at the time of the post polymerization to cause the rubber latex to partly coagulate, thereby to prepare a graft polymer. The graft copolymer can be blended with methyl methacrylate-styrene copolymers.
摘要翻译：通过在含有至少50重量％的共轭二烯烃单体的共轭二烯烃聚合物橡胶胶乳的存在下使甲基丙烯酸甲酯和苯乙烯单体进行后聚合来制备具有优异的透明性和高冲击强度的热塑性树脂组合物作为在后聚合之前或之后，在橡胶胶乳中加入平均分子量为至少100,000的聚环氧乙烷的橡胶如丁二烯，导致橡胶胶乳部分凝结，从而制备接枝聚合物。接枝共聚物可与甲基丙烯酸甲酯 - 苯乙烯共聚物共混。

9. 发明授权

US4615943A Vinylidene fluoride copolymer film 失效
标题翻译：偏二氟乙烯共聚物膜
公开(公告)号：US4615943A
公开(公告)日：1986-10-07
申请号：US810905
申请日：1985-12-20
申请人： Teruo Sakagami , Noriyuki Arakawa , Naohiro Murayama
发明人： Teruo Sakagami , Noriyuki Arakawa , Naohiro Murayama
IPC分类号： B29C41/00 , B29K27/12 , B29L7/00 , C08J5/18 , C08L27/16 , B32B27/00 , B32B15/00 , C08F29/16
CPC分类号： C08J5/18 , C08L27/16 , C08J2327/16 , Y10T428/26 , Y10T428/261 , Y10T428/3154 , Y10T428/31544
摘要： A transparent film of a vinylidene fluoride copolymer, comprising a dry film of a vinylidene fluoride copolymer having a parallel light transmittance of 85% or higher at a film thickness of 30 microns. The transparent film is obtained by forming a mixture of a vinylidene fluoride copolymer having a specifically high molecular weight with a solvent into a film, preferably by casting, and evaporating off the solvent.
摘要翻译：一种偏氟乙烯共聚物的透明膜，其包含在30微米厚度下平行光透射率为85％或更高的偏二氟乙烯共聚物的干膜。透明膜通过将具有特别高分子量的偏二氟乙烯共聚物与溶剂形成混合物而获得，优选通过浇铸而蒸发掉溶剂。

10. 发明授权

US4578445A Halogen-containing lens material 失效
公开(公告)号：US4578445A
公开(公告)日：1986-03-25
申请号：US716460
申请日：1985-03-27
申请人： Teruo Sakagami , Yasufumi Fujii , Naohiro Murayama
发明人： Teruo Sakagami , Yasufumi Fujii , Naohiro Murayama
IPC分类号： C08F20/00 , C08F20/22 , C08F20/26 , C08F20/30 , C08F220/00 , C08F220/28 , C08F220/30 , C08F290/00 , C08F299/02 , G02B1/04 , C08F220/22
CPC分类号： C08F220/30 , C08F220/28 , G02B1/04
摘要： A lens material having a refractive index n.sub.D.sup.20 of at least 1.57 or more and an Abbe's number .nu. of at least 30, comprising: a copolymer comprising (I) 10 to 85% by weight of a halogen-containing monomer represented by the following formula (1), (II) 15 to 90% by weight of a halogen-containing monomer represented by the following formula (2), and (III) 0 to 20% by weight of a monomer copolymerizable with the above mentioned monomers, the composition of the copolymer being based on the total quantity of the monomers (I), (II), and (III): ##STR1## wherein: D represents ##STR2## in which n represents an integer selected from the group consisting of 0, 1, and 2; each R.sup.1 represents hydrogen or a methyl group; Y represents CHOH; and r represents 0 or 1; each of X.sup.1 and X.sup.2 represents, independently from each other, a methyl group in which one through three of the hydrogen atoms are substituted by a member selected from the group consisting of bromine, iodine and a hydroxyl group (OH group), with the proviso that the number of substitution of the OH group is only one; X.sup.3 represents a methyl group in which one through three of the hydrogen atoms are substituted by a member selected from the group consisting of bromine, iodine and D, with the proviso that the number of substitution of D is only one; wherein at least one of X.sup.1, X.sup.2, and X.sup.3 contains at least one bromine or iodine; ##STR3## wherein: each R.sup.2 represents hydrogen or a methyl group; p represents an integer selected from the group consisting of 0, 1, 2, and 3; X.sup.4 represents bromine or iodine; and q represents an integer selected from the group consisting of 1, 2, 3, 4, and 5.An example of the copolymer is 1-methacryloxy-2,2-di(bromomethyl)-3-bromopropane/methacryloxypolyethyoxy-2,4,6-tribromobenzene/styrene/divinylbenzene having a n.sub.D.sup.20 of 1.596 and a .nu. of 35.3.

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