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    • 3. 发明授权
    • Process for the production of carbon filaments utilizing an acrylic
precursor
    • 利用丙烯酸前体生产碳丝的方法
    • US4112059A
    • 1978-09-05
    • US523764
    • 1974-11-14
    • Andrew H. DiEdwardoRobert Dix
    • Andrew H. DiEdwardoRobert Dix
    • D01F9/22D01F9/12
    • D01F9/22
    • An improved overall process is provided for producing carbon filaments beginning with a multifilament acrylic precursor. The process facilitates the thermal transformation of the acrylic fibrous material in the absence of undesirable coalescence between adjoining filaments. An extremely thin deposition of colloidal silica initially is provided upon the surface of the multifilament acrylic precursor (as described), the fibrous material thermally stabilized in the absence of coalescence (as described), the colloidal silica substantially removed, and the thermally stabilized fibrous material carbonized (as described). The resulting carbon filaments exhibit improved physical properties and particularly are suited for use as fibrous reinforcement in a resinous matrix.
    • 提供了一种改进的整体方法,用于从复丝丙烯酸前体开始生产碳丝。 该方法有助于丙烯酸纤维材料在相邻长丝之间不存在不期望的聚结的情况下的热转化。 最初提供极薄的胶体二氧化硅的沉积物,在复丝丙烯酸类前体的表面上(如所述),在不存在聚结(如所述)的情况下热稳定的纤维材料,基本上除去的胶体二氧化硅,以及热稳定的纤维材料 碳化(如所述)。 所得碳丝显示出改进的物理性能,特别适合用作树脂基质中的纤维增强剂。
    • 5. 发明授权
    • Vertical pyrolysis furnace for use in the production of carbon fibers
    • 立式热解炉用于生产碳纤维
    • US4020273A
    • 1977-04-26
    • US635515
    • 1975-11-26
    • Robert DixRichard F. MarkelJames A. ParkerJohn P. RiggsDale T. Vest
    • Robert DixRichard F. MarkelJames A. ParkerJohn P. RiggsDale T. Vest
    • D01F9/32F27D11/02H05B3/00
    • F27D11/02D01F9/32H05B3/0014
    • A vertical pyrolysis furnace used in the carbonization or high temperature heat treatment of a continuous length of organic fibrous material is disclosed. The oven includes a central conduit or passage having a plurality of independently controlled heating zones disposed circumferentially therearound and spaced axially therealong. The conduit and heating elements are surrounded by suitable insulating material and a gas-tight shell. At the top of the furnace an exhaust manifold is provided which communicates with the central conduit. An environmental seal is provided at the upper end of the exhaust manifold and at the bottom of the conduit. Suitable gaseous inlets communicate with the furnace for an inert gaseous atmosphere which is controlled such that free convection causes the gaseous atmosphere to rise vertically through the central conduit to the exhaust chamber located at the upper end thereof. A continuous length of organic fibrous material moves vertically downwardly through the central conduit from the upper environmental seal to the lower environmental seal. The independently controlled heating zones provide a vertically downwardly increasing temperature gradient, up to a desired maximum value which extends over a prescribed length, which drives off toxic gaseous by-products from the continuous length of organic fibrous material. The heating zone placement and lower environmental seal permit the continuous length of organic fibrous material to cool substantially before exiting to the atmosphere.
    • 公开了一种用于连续长度的有机纤维材料的碳化或高温热处理的立式热解炉。 烤箱包括具有多个独立控制的加热区域的中心管道或通道,其周向设置并沿其轴向间隔设置。 导管和加热元件由合适的绝缘材料和气密外壳包围。 在炉顶部设置有与中心导管连通的排气歧管。 在排气歧管的上端和导管的底部设有环境密封。 合适的气体入口与炉子连通,用于惰性气体气氛,其被控制使得自由对流使得气态气氛垂直地升高通过位于其上端的排气室。 连续长度的有机纤维材料通过中央导管从上部环境密封件向下垂直移动到下部环境密封件。 独立控制的加热区域提供垂直向下增加的温度梯度,达到期望的最大值,其延伸超过规定的长度,其驱使有机纤维材料的连续长度的有毒气体副产物。 加热区放置和较低的环境密封允许连续长度的有机纤维材料在离开大气之前基本上冷却。